Influence of ion beam current on the structural, optical, and mechanical properties of TiO₂ coatings: ion beam-assisted vs conventional electron beam evaporation

• Agata Obstarczyk and
• Urszula Wawrzaszek

Beilstein J. Nanotechnol. 2025, 16, 1097–1112, doi:10.3762/bjnano.16.81

• result of a considerable increase in grain size after annealing. In contrast, such notable differences were not observed for films deposited by IBAD. In the case of annealed films deposited with Iibg = 3 A, a decrease of the bandgap from 3.23 to 3.10 eV was observed. According to Dejam et al. [46

• on hν follows the exponential relation [46][52]: where α0 is a constant and Eu is the Urbach energy. After post-process annealing, Eu for the film deposited with conventional EBE method increased by almost four times from 0.22 to 0.87 eV (Figure 5d). The Urbach energies for as-deposited and annealed

Piezoelectricity of hexagonal boron nitrides improves bone tissue generation as tested on osteoblasts

• Sevin Adiguzel,
• Nilay Cicek,
• Zehra Cobandede,
• Feray B. Misirlioglu,
• Hulya Yilmaz and
• Mustafa Culha

Beilstein J. Nanotechnol. 2025, 16, 1068–1081, doi:10.3762/bjnano.16.78

• bandgap energy [46]. Supporting Information File 1, Figure S3 (f) illustrates that the hydrodynamic size of hBNs in aqueous suspension is approximately 120 nm. The zeta potential value is −42.5 ± 1.18 mV, indicating greater negativity than −30 mV, demonstrating stability [47]. Figure 1 shows PRFM

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

• disciplines such as organic chemistry [31][32][33][34][35], polymer chemistry [36][37][38][39][40], and materials chemistry [41][42][43][44]. Consequently, soft materials, including polymers [45][46][47][48][49], liquid crystals [50][51][52][53][54] and gels [55][56][57][58][59], have been developed

A calix[4]arene-based supramolecular nanoassembly targeting cancer cells and triggering the release of nitric oxide with green light

• Cristina Parisi,
• Loredana Ferreri,
• Tassia J. Martins,
• Francesca Laneri,
• Samantha Sollima,
• Antonina Azzolina,
• Antonella Cusimano,
• Nicola D’Antona,
• Grazia M. L. Consoli and
• Salvatore Sortino

Beilstein J. Nanotechnol. 2025, 16, 1003–1013, doi:10.3762/bjnano.16.75

• , supramolecular nanoconstructs, and nanomaterials photoreleasing NO have been developed as potential nanomedicines over the last decades [40][41][42][43][44][45][46][47][48][49][50]. In this regard, generating NO with highly biocompatible long wavelength green or red light is highly desirable over blue or even UV

Time-resolved probing of laser-induced nanostructuring processes in liquids

• Maximilian Spellauge,
• David Redka,
• Mianzhen Mo,
• Changyong Song,
• Heinz Paul Huber and
• Anton Plech

Beilstein J. Nanotechnol. 2025, 16, 968–1002, doi:10.3762/bjnano.16.74

• to melting, reshaping (Figure 1B,C), evaporation, and phase explosion near the critical point (Figure 1H) [39][46][47][48]; (ii) stress-induced decompositions, where competition between heating and expansion leads to spallation or cavitation [36][49][50] (Figure 1I); (iii) non-thermal processes

• to liquid) should lead to restructuring. In a simple model, the laser energy is converted into heat that will be localized in the absorbing part within the laser penetration depth. Absorption is linear as expressed by the (known) absorption cross section. In the model by Takami et al. [46], which is

Shape, membrane morphology, and morphodynamic response of metabolically active human mitochondria revealed by scanning ion conductance microscopy

• Eric Lieberwirth,
• Anja Schaeper,
• Regina Lange,
• Ingo Barke,
• Simone Baltrusch and
• Sylvia Speller

Beilstein J. Nanotechnol. 2025, 16, 951–967, doi:10.3762/bjnano.16.73

• cation layer on their surfaces, which is responsible for ionic conductivity in physiological media (Figure 8b). Microtubules align along direct current electric field lines and can be vibrationally excited at megahertz frequencies by electric dipole antennas [46]. Other relevant properties include

Characterization of ion track-etched conical nanopores in thermal and PECVD SiO₂ using small angle X-ray scattering

• Shankar Dutt,
• Rudradeep Chakraborty,
• Christian Notthoff,
• Pablo Mota-Santiago,
• Christina Trautmann and
• Patrick Kluth

Beilstein J. Nanotechnol. 2025, 16, 899–909, doi:10.3762/bjnano.16.68

• , and the type and energy of the ions used [13][29][40]. Track-etch technology has been used for the commercial fabrication of cylindrical nanopores in polymers for filtration applications [41][42][43][44][45][46]. Only recently we have adapted this technology to generate conical nanopores in silicon

Heat-induced transformation of nickel-coated polycrystalline diamond film studied in situ by XPS and NEXAFS

• Olga V. Sedelnikova,
• Yuliya V. Fedoseeva,
• Dmitriy V. Gorodetskiy,
• Yuri N. Palyanov,
• Elena V. Shlyakhova,
• Eugene A. Maksimovskiy,
• Anna A. Makarova,
• Lyubov G. Bulusheva and
• Aleksandr V. Okotrub

Beilstein J. Nanotechnol. 2025, 16, 887–898, doi:10.3762/bjnano.16.67

• spectrum was fitted by three doublets, related to the spin–orbit splitting into Ni 3p3/2 and Ni 3p1/2 components, separated by 1.6 eV (Figure 3a). The most intense doublet with the Ni 3p3/2 component at 66.1 eV is attributed to metallic nickel [46]. The high-energy doublet with the Ni 3p3/2 component at

Ar⁺ implantation-induced tailoring of RF-sputtered ZnO films: structural, morphological, and optical properties

• Manu Bura,
• Divya Gupta,
• Arun Kumar and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 872–886, doi:10.3762/bjnano.16.66

• represent sub-bandgap absorptions due to defects. The optical bandgap values decrease after implantation from 3.29 ± 0.05 eV to 2.89 ± 0.04 eV with the rise in ion fluence. This is assigned to the emergence of defect-trapping levels between valence band and conduction band [46]. These trapping levels can be

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• dimensionality [42]. This effect was theoretically predicted [43], but it was never experimentally observed on chemically synthesized NPs, where an expansion typically occurs [44][45][46], possibly due to the higher Ce3+ surface concentration compared to physically synthesized NPs. The short- and long-range

Synchrotron X-ray photoelectron spectroscopy study of sodium adsorption on vertically arranged MoS₂ layers coated with pyrolytic carbon

• Alexander V. Okotrub,
• Anastasiya D. Fedorenko,
• Anna A. Makarova,
• Veronica S. Sulyaeva,
• Yuliya V. Fedoseeva and
• Lyubov G. Bulusheva

Beilstein J. Nanotechnol. 2025, 16, 847–859, doi:10.3762/bjnano.16.64

• associated with the substrate. The absence of the Si 2p line in the spectra of MoS2 and PyC-MoS2 films indicates the formation of a continuous MoS2 film with a thickness of more than 3 nm [46]. The atomic concentrations of Mo and S in the MoS2 film are about 9 and 28 atom %, respectively, and decrease to

• were measured at 830 eV. Scheme of the sodium deposition on PyC, MoS2, and PyC-MoS2 films and subsequent vacuum annealing. Supporting Information Supporting Information File 46: EDX spectroscopy study of Pt layers protecting MoS2 surface, XPS survey spectra of the studied samples, and XPS Na 2s

Facile one-step radio frequency magnetron sputtering of Ni/NiO on stainless steel for an efficient electrode for hydrogen evolution reaction

• Ha Huu Do,
• Khac Binh Nguyen,
• Phuong N. Nguyen and
• Hoai Phuong Pham

Beilstein J. Nanotechnol. 2025, 16, 837–846, doi:10.3762/bjnano.16.63

• smaller energy barrier for water electrolysis to produce hydrogen. These outcomes indicate that Ni/NiO/SS-10 shows the highest HER efficiency among the investigated electrodes. Its overpotential is comparable with Ni-based nanomaterials in the literature, as depicted in Table 2 [40][41][42][43][44][45][46

• ) [41], NiP2/NiO (94 mV·dec−1) [45], Ni5P4 (98 mV·dec−1) [46], and NiCoP/rGO (124.1 mV·dec−1) [47]. Generally, Tafel slopes are used to determine the HER mechanism, which could follow the Volmer–Heyrovsky or Volmer–Tafel pathway [49]. In this work, the Tafel value of Ni/NiO/SS-10 is between 40 and 120

Synthesis and magnetic transitions of rare-earth-free Fe–Mn–Ni–Si-based compositionally complex alloys at bulk and nanoscale

• Shabbir Tahir,
• Tatiana Smoliarova,
• Carlos Doñate-Buendía,
• Michael Farle,
• Natalia Shkodich and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 823–836, doi:10.3762/bjnano.16.62

• irradiation of the target material submerged in a liquid environment. This makes PLAL a safe, scalable and environmentally friendly approach [46][47][48]. Research on the synthesis of CoCrFeMnNi Cantor alloy NPs by PLAL demonstrated that this method consistently produces NPs with near-equiatomic compositions

Supramolecular hydration structure of graphene-based hydrogels: density functional theory, green chemistry and interface application

• Hon Nhien Le,
• Duy Khanh Nguyen,
• Minh Triet Dang,
• Huyen Trinh Nguyen,
• Thi Bang Tam Dao,
• Trung Do Nguyen,
• Chi Nhan Ha Thuc and
• Van Hieu Le

Beilstein J. Nanotechnol. 2025, 16, 806–822, doi:10.3762/bjnano.16.61

• cm−1 is attributed to the bending vibration of Zn-O-Si bonds in the GO-SG-ZH nanocomposite [44]. Supramolecular systems with non-covalent interactions and reversible cross-links are recognized to provide extraordinary properties and applications [45][46][47]. Reversible self-assembly is an advantage

Morphology and properties of pyrite nanoparticles obtained by pulsed laser ablation in liquid and thin films for photodetection

• Akshana Parameswaran Sreekala,
• Bindu Krishnan,
• Rene Fabian Cienfuegos Pelaes,
• David Avellaneda Avellaneda,
• Josué Amílcar Aguilar-Martínez and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 785–805, doi:10.3762/bjnano.16.60

• the peak fitting is in accordance to the hybrids reported [46][47]. The Fe 2p1/2 peak does not require deconvolution due to its relatively lower intensity and minimal contribution to the overall spectral profile. Specifically, in studies of iron, as proposed by Grosvenor et al., the Fe 2p3/2 peak

Changes of structural, magnetic and spectroscopic properties of microencapsulated iron sucrose nanoparticles in saline

• Sabina Lewińska,
• Pavlo Aleshkevych,
• Roman Minikayev,
• Anna Bajorek,
• Mateusz Dulski,
• Krystian Prusik,
• Tomasz Wojciechowski and
• Anna Ślawska-Waniewska

Beilstein J. Nanotechnol. 2025, 16, 762–784, doi:10.3762/bjnano.16.59

• Sabina Lewinska Pavlo Aleshkevych Roman Minikayev Anna Bajorek Mateusz Dulski Krystian Prusik Tomasz Wojciechowski Anna Slawska-Waniewska Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warsaw, Poland Silesian Center for Education and Interdisciplinary Research

• Research, 75 Pułku Piechoty 1A, 41-500 Chorzów, Poland International Research Centre MagTop, Institute of Physics, Polish Academy of Sciences, Aleja Lotników 32/46, 02-668 Warsaw, Poland 10.3762/bjnano.16.59 Abstract The structural and physical properties of microencapsulated iron sucrose and their

• saline [46]. The disappearance of the ZFC peak for the FS12 and FST samples also fits into these assumptions, and supposedly means the decrease of the core diameter to the ultra-low value for which the blocking process vanish. The result obtained for FST well coincide with the TEM images where metallic

Efficiency of single-pulse laser fragmentation of organic nutraceutical dispersions in a circular jet flow-through reactor

• Tina Friedenauer,
• Maximilian Spellauge,
• Alexander Sommereyns,
• Verena Labenski,
• Tuba Esatbeyoglu,
• Christoph Rehbock,
• Heinz P. Huber and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2025, 16, 711–727, doi:10.3762/bjnano.16.55

• application-relevant at the interface between nutritional science and the pharmaceutical industry [46][47]. This study aims to elucidate how an organic MP suspension needs to be designed to enable energy- and process-efficient fragmentation with just one nominal laser pulse-per-particle (and practically only

Nanostructured materials characterized by scanning photoelectron spectromicroscopy

• Matteo Amati,
• Alexey S. Shkvarin,
• Alexander I. Merentsov,
• Alexander N. Titov,
• María Taeño,
• David Maestre,
• Sarah R. McKibbin,
• Zygmunt Milosz,
• Ana Cremades,
• Rainer Timm and
• Luca Gregoratti

Beilstein J. Nanotechnol. 2025, 16, 700–710, doi:10.3762/bjnano.16.54

• can be occasionally necessary in order to avoid overlapping of Ni 2p signal with other XPS contributions in doped NiO or Ni-based compounds. Taeño et al. [46] recently reported the study of NiO microcrystals with self-organized microcavities synthesized by a vapor–solid process at temperatures ranging

• sample treated at 1200 °C. f) XPS energy filtered image from e) corresponding to the Ni2+/Ni3+ ratio. Adapted with permission from Cryst. Growth Des. 2020, 20, 4082–4091. Copyright 2020 American Chemical Society. Figure 3 was reprinted with permission from [46], Copyright 2020 American Chemical Society

The impact of tris(pentafluorophenyl)borane hole transport layer doping on interfacial charge extraction and recombination

• Konstantinos Bidinakis and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 678–689, doi:10.3762/bjnano.16.52

• particular, the CPD value of the perovskite layer is influenced by the composition and the doping of the perovskite [15][46]. In Figure 3, the potential profiles plotted for the four devices exhibit features that deviate from the ideal profiles of a p-i-n junction (See Supporting Information File 1, Section

• interfaces are approximately equal in their voltage drop magnitude and therefore contribute equally to charge extraction. Devices that exhibit two charge separating junctions are more prone to charge recombination compared to devices with just one junction [46]. On the contrary, devices that incorporate BCF

Colloidal few layered graphene–tannic acid preserves the biocompatibility of periodontal ligament cells

• Teissir Ben Ammar,
• Naji Kharouf,
• Dominique Vautier,
• Housseinou Ba,
• Nivedita Sudheer,
• Philippe Lavalle and
• Vincent Ball

Beilstein J. Nanotechnol. 2025, 16, 664–677, doi:10.3762/bjnano.16.51

• activity The Alamar Blue (AB) assay was used to quantify the metabolic activity of PDL cells in direct contact with FLG and TA solutions by detecting the oxidation–reduction rate of AB [46]. This assay has gained significant popularity as a common method for examining cytotoxic effects induced by various

• test compounds [46]. Briefly, cells were seeded at a density of 1 × 105 cells/well (passages 3 to 7) in a 96-well plate with α-MEM essential medium supplemented with 10% FBS, 100 µg·mL−1 penicillin, and 100 µg·mL−1 streptomycin (Dutscher). The cells were treated with FLG and TA in fresh medium at

Nanoscale capacitance spectroscopy based on multifrequency electrostatic force microscopy

• Pascal N. Rohrbeck,
• Lukas D. Cavar,
• Franjo Weber,
• Peter G. Reichel,
• Mara Niebling and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 637–651, doi:10.3762/bjnano.16.49

• directly are referred to as scanning capacitance microscopy (SCM) [29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50][51][52][53][54], whereas methods measuring the capacitive tip–sample force are referred to as scanning capacitance force microscopy (SCFM) [24][25][55

A formulation containing Cymbopogon flexuosus essential oil: improvement of biochemical parameters and oxidative stress in diabetic rats

• Ailton Santos Sena-Júnior,
• Cleverton Nascimento Santana Andrade,
• Pedro Henrique Macedo Moura,
• Jocsã Hémany Cândido dos Santos,
• Cauãn Torres Trancoso,
• Eloia Emanuelly Dias Silva,
• Deise Maria Rego Rodrigues Silva,
• Ênio Pereira Telles,
• Luiz André Santos Silva,
• Isabella Lima Dantas Teles,
• Sara Fernanda Mota de Almeida,
• Daniel Alves de Souza,
• Jileno Ferreira Santos,
• Felipe José Aidar Martins,
• Ana Mara de Oliveira e Silva,
• Sandra Lauton-Santos,
• Guilherme Rodolfo Souza de Araujo,
• Cristiane Bani Correa,
• Rogéria De Souza Nunes,
• Lysandro Pinto Borges and
• Ana Amélia Moreira Lira

Beilstein J. Nanotechnol. 2025, 16, 617–636, doi:10.3762/bjnano.16.48

• ) significantly reduced the values when compared to the negative control group (2.76 mg/dL) and the positive control group (2.85 mg/dL) (Figure 8C). Regarding renal markers, Dobhal et al. [46] showed in their study an increase in uric acid levels in rats after inducing diabetes and a significant reduction in

Polyurethane/silk fibroin-based electrospun membranes for wound healing and skin substitute applications

• Iqra Zainab,
• Zohra Naseem,
• Syeda Rubab Batool,
• Muhammad Waqas,
• Ahsan Nazir and
• Muhammad Anwaar Nazeer

Beilstein J. Nanotechnol. 2025, 16, 591–612, doi:10.3762/bjnano.16.46

• ]. Electrospun nanofibrous membrane as a dermal substitute Millions of individuals worldwide are affected by a leading source of morbidity, which is chronic non-healing wounds with extensive injury areas [46]. For the management of such wounds, bioresorbable skin substitutes with optimum biomechanical

Feasibility analysis of carbon nanofiber synthesis and morphology control using a LPG premixed flame

• Iftikhar Rahman Bishal,
• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Faizuan Bin Abdullah,
• I Putu Tedy Indrayana and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2025, 16, 581–590, doi:10.3762/bjnano.16.45

• equivalence ratio was reduced to 1.6, the average diameter of CNF increased by 46% to 114 nm, with amorphous carbon observed. The said observation is due to the effects of the increased flame temperature as the equivalence ratio approaches stoichiometry conditions from the rich side. This increases the

Functionalized gold nanoflowers on carbon screen-printed electrodes: an electrochemical platform for biosensing hemagglutinin protein of influenza A H1N1 virus

• Carlos Enrique Torres-Méndez,
• Sharmilee Nandi,
• Klara Martinovic,
• Patrizia Kühne,
• Yifan Liu,
• Sam Taylor,
• Maria Lysandrou,
• Maria Ines Berrojo Romeyro Mascarenhas,
• Viktoria Langwallner,
• Javier Enrique Sebastián Alonso,
• Ivana Jovanovic,
• Maike Lüftner,
• Georgia-Vasiliki Gkountana,
• David Bern,
• Abdul-Raouf Atif,
• Ehsan Manouchehri Doulabi,
• Gemma Mestres and
• Masood Kamali-Moghaddam

Beilstein J. Nanotechnol. 2025, 16, 540–550, doi:10.3762/bjnano.16.42

• measurements [46]. Furthermore, compatibility with microfluidic devices is important for the development of portable biosensing devices with automated functions and of simple use. Different antigens of the influenza A H1N1 virus have been targeted for detection over the years. In order to make a substantial