7 article(s) from Cravotto, Giancarlo
Graphical Abstract
Scheme 1: The reaction of CDs with oxiranes.
Figure 1: Jar-temperature changes during the reaction of 1,2-propylene oxide and cyclodextrins in the presenc...
Figure 2: Comparative SEM pictures of a β-CD bead and β-CDP (20 mmol, Table 3, entry 10).
Figure 3: Comparison of β-CDP (Table 3, entry 9) and γ-CDP (Table 3, entry 12) prepared in a ball mill on 2 mmol scale.
Figure 4: Normalised particle-size distribution of insoluble CD polymers (entries 9, 10, and 12 of Table 3).
Figure 5: UV–vis spectra and adsorption isotherm of the insoluble β-CDP polymer in 10 ml 0.050 mM MO solution...
Figure 6: UV–vis spectral changes of 0.050 mM MO solution by GPTS-β-CD (left) and GPTS-γ-CD (right), as prepa...
Figure 7: UV–vis spectral changes of 0.050 mM MO solution by GPTS-β-CD (left) and GPTS-γ-CD (right), as prepa...
Graphical Abstract
Scheme 1: TEMPO-catalysed aerobic oxidative procedures of alcohols. a) Anelli–Montanari protocol: NaOCl (1.25...
Scheme 2: TEMPO-assisted oxidation of 4-nitrobenzylic alcohol under mechanical activation conditions [65].
Scheme 3: Scope of primary alcohols in oxidation under ambient air.
Scheme 4: Scope of secondary alcohols in oxidation under ambient air.
Graphical Abstract
Scheme 1: Nucleophilic substitution of the 4-toluenesulfonyl group. The formalism for the mechanochemical act...
Figure 1: Effect of jar size on the reaction time using an equal number (30) of steel balls (ø 1 mm) for the ...
Figure 2: Effect of ball size on the reaction time to a full conversion of Ts-β-CD: a) reactions performed at...
Figure 3: Reaction time as a function of ball materials at 550 min−1 in glass vials of 25 mL: a) equal weight...
Graphical Abstract
Scheme 1: Synthesis of per-6-derivatized CDs. Ball milling conditions: 1500 steel balls of 1 mm diameter and ...
Graphical Abstract
Figure 1: (a) Multihorn-flow US reactor, (b) Cavitational turbine, (c) Pilot-scale BM, (d) High-pressure MW r...
Figure 2: Trends in CD papers and CD use in green chemical processes.
Figure 3: Distribution of energy efficient methods in CD publications.
Figure 4: Document type dealing with CD chemistry under non-conventional techniques (conference proceedings a...
Figure 5: Document type dealing with sustainable technologies in CD publications.
Scheme 1: Synthesis of 6I-(p-toluenesulfonyl)-β-CD.
Scheme 2: Example of CuAAC with 6I-azido-6I-deoxy-β-CD and phenylacetylene.
Scheme 3: Synthesis of 6I-benzylureido-6I-deoxy-per-O-acetyl-β-CD.
Scheme 4: Synthesis of 3I-azido-3I-deoxy-altro-α, β- and γ-CD.
Scheme 5: Synthesis of 2-2’ bridged bis(β-CDs). Reaction conditions: 1) TBDMSCl, imidazole, dry pyridine, sti...
Scheme 6: Insoluble reticulated CD polymer.
Scheme 7: CD-HDI cross linked polymers.
Scheme 8: Derivatization of 6I-(p-toluenesulfonyl)-β-CD by tosyl displacement.
Scheme 9: Synthetic scheme for the preparation of heptakis(6-amino-6-deoxy)-β-CD, heptakis(6-deoxy-6-ureido)-...
Scheme 10: Structure of CD derivatives obtained via MW-assisted CuAAC.
Scheme 11: Preparation of SWCN CD-DOTA carrier.
Graphical Abstract
Scheme 1: Reaction pathway of aerobic oxidative esterification of alcohols.
Figure 1: Screening of different catalysts and bases in the catalytic oxidative esterification of benzylalcoh...
Scheme 2: Catalyst regeneration and oxidative esterification of benzaldehyde (2nd cycle).
Graphical Abstract
Scheme 1: Synthesis of benzyl isocyanate.