3 article(s) from Linden, Anthony
Graphical Abstract
Scheme 1: Reactions of aryl/hetarylthiochalcones 1a–d with 1,4-naphthoquinone (2b).
Scheme 2: Reactions of thiochalcones 1a–d with 1,4-anthraquinones 2c and 2d.
Figure 1: ORTEP plot [29] of the molecular structure of 4k showing the major conformation of the disordered thiop...
Figure 2: Products of the reactions of thiochalcones 1a and 1b with 1,4-benzoquinone (2a) and of 1a with mena...
Graphical Abstract
Scheme 1: Reactions of aromatic thiocarbonyl S-methanides 2a,b with ferrocenyl thioketones 1 (Table 1).
Figure 1: ORTEP Plot [16] of the molecular structures of the ferrocenyl-substituted 1,3-dithiolanes 5b and 5f (wi...
Scheme 2: Reactions of cycloaliphatic thiocarbonyl S-methanides with ferrocenyl hetaryl thioketones 1 (Table 1).
Scheme 3: Reaction of 3c with ferrocenyl methyl thioketone 1e.
Scheme 4: Mesomeric stabilization of the 1,5-diradical intermediate in the reaction of aromatic thiocarbonyl S...
Graphical Abstract
Scheme 1: Hetero-Diels–Alder reaction of thiobenzophenone (1a) with dimethyl acetylenedicarboxylate (2a) [10].
Scheme 2: Synthesis of polycyclic thiopyrans via the hetero-Diels–Alder reaction/1,3-hydrogen shift sequence.
Figure 1: ORTEP Plot [19] of the molecular structure of 4b, drawn using 50% probability displacement ellipsoids.
Scheme 3: Reactions of aryl/hetaryl thioketones with methyl propiolate (Table 1).
Scheme 4: Oxidation of selected thiopyrans 4 and 5 to give the corresponding sulfones.
Figure 2: ORTEP Plot [19] of the molecular structure of one of the symmetry-independent molecules of 6d, drawn us...