2 article(s) from Perez-Luna, Alejandro
C3–Si bond functionalization of biomass-derived 3-silylated furfural platforms.
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Preparation of 3-silylated 2-furyl carbinols.
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C–Si bond functionalization of 2,3-disubstituted furyl carbinols by 1,4-silyl migration.
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Attempts of C3–Si bond functionalization promoted by intramolecular activation via alkoxide.
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Alkoxide-promoted cyclic siloxane formation from 2-[(3-benzyldimethylsilyl)furyl] carbinol 4c.
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TBAF-promoted cyclic siloxane formation from 2-[(3-benzyldimethylsilyl)furyl] carbinol 4c.
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Pd-catalyzed arylation of 2-[(3-benzyldimethylsilyl)furyl] carbinol 4c.
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Cu-catalyzed allylation and methylation of 2-[(3-benzyldimethylsilyl)furyl] carbinols. aCuI⋅PPh3 (1...
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Beilstein J. Org. Chem. 2022, 18, 1256–1263, doi:10.3762/bjoc.18.131
Anticipated formation of alkylidene zinc carbenoids by reaction of dialkylzincs with β-(propargylox...
Preparation of β-(propargyloxy)enoates having pendant haloalkynes. Reagents and conditions: (a) 2 (...
Possible reaction pathways to account for the formation of product 5.
Test experiments to gain insight into the mechanism of formation of alkylidene zinc intermediate 7.
Mechanistic rationale for the reaction of dialkylzincs with β-(propargyloxy)enoate 3a.
Beilstein J. Org. Chem. 2013, 9, 236–245, doi:10.3762/bjoc.9.28
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