Gold nanoparticle-decorated reduced graphene oxide as a highly effective catalyst for the selective α,β-dehydrogenation of N-alkyl-4-piperidones

• Brenda Flore Kenyim,
• Mihir Tzalis,
• Marilyn Kaul,
• Robert Oestreich,
• Aysenur Limon,
• Chancellin Pecheu Nkepdep and
• Christoph Janiak

Beilstein J. Nanotechnol. 2026, 17, 218–238, doi:10.3762/bjnano.17.15

• , scanning electron microscopy (SEM) and nitrogen gas sorption surface area analysis using the Brunauer–Emmett–Teller (BET) theory were employed to evaluate the surface structure, porosity, and overall texture of the materials. The SEM image in Figure 2a reveals the typical structure of AC, characterized by

• loading exhibited no catalytic activity. Conversion rates and yields of the reaction were determined by gas chromatography (GC) using calibration curves of the starting material and the product (see Supporting Information File 1). The amount of supported gold in the composite was calculated by assuming

Time of flight secondary ion mass spectrometry imaging of contaminant species in chemical vapour deposited graphene on copper

• Barry Brennan,
• Vlad-Petru Veigang-Radulescu,
• Philipp Braeuninger-Weimer,
• Stephan Hofmann and
• Andrew J. Pollard

Beilstein J. Nanotechnol. 2026, 17, 200–213, doi:10.3762/bjnano.17.13

• substrate, depending on processing conditions employed and the chemical species present on the surface. This has implications for the gas permeation barrier properties of this material, graphene transfer mechanisms, as well as the effectiveness of using the oxidation of the copper foil as a rapid graphene

• diffusion of material present in the copper foil before growth [36][37], which could lead to variations in the properties of graphene once transferred from the Cu foil to an alternative substrate. We also explore the gas permeation properties of the CVD graphene on Cu [38] by examining the oxygen detected

• evidence of the substrate Cu signal, specifically the signal related to Cu oxide. The gas permeation barrier properties of graphene are well known [47][48], and as such it is possible to compare the level of oxidation of the Cu foil after graphene growth by comparing the regions where the Cu surface is

Structure-dependent thermochromism of PAZO thin films: theory and experiment

• Georgi Mateev,
• Dean Dimov,
• Nataliya Berberova-Buhova,
• Nikoleta Kircheva,
• Todor Dudev,
• Ludmila Nikolova,
• Elena Stoykova,
• Keehoon Hong,
• Dimana Nazarova,
• Silvia Angelova and
• Lian Nedelchev

Beilstein J. Nanotechnol. 2026, 17, 186–199, doi:10.3762/bjnano.17.12

• calculations at r.t. for dimer formation reactions reveal that, from the thermodynamic point of view, the formation of a–d dimers is possible, the reactions are characterized by negative values of Gibbs energies ranging from −24.3 to −9.3 kcal·mol−1 in the gas phase, and from −10.8 to −3.7 kcal·mol−1 in

• ΔEel, ΔEth, PΔV (work term), and ΔS between the products and reactants were used to evaluate the gas-phase free energy of the supramolecular complex formation/aggregation, ΔG1, at T = 298.15 K according to: Solvation effects were accounted for by employing the solvation model based on density (SMD) [31

• ] as implemented in Gaussian 09 suite of programs [32]. Single-point calculations were performed at the ωB97XD/6-31+G(d,p) level in the gas phase (ε = 1) and in chloroform (ε = 5) for the corresponding structures optimized at the ωB97XD/6-31G(d,p) level (ωB97XD/6-31+G(d,p)//ωB97XD/6-31G(d,p

Reduced graphene oxide paper electrode for lithium-ion cells – towards optimized thermal reduction

• Agata Pawłowska,
• Magdalena Baran,
• Stefan Marynowicz,
• Aleksandra Izabela Banasiak,
• Adrian Racki,
• Adrian Chlanda,
• Tymoteusz Ciuk,
• Marta Wolczko and
• Andrzej Budziak

Beilstein J. Nanotechnol. 2026, 17, 24–37, doi:10.3762/bjnano.17.3

• applied for thermogravimetric analysis. The measurement was performed in an inert gas flow. The heating rate in this experiment was set to 3 °C/min with a final temperature of 800 °C. The sample was cut to fit the platinum pan. Elemental combustion analysis A LECO O836 analyzer was utilized to determine

• postulate that the gas release was rather a continuous phenomenon, driven by the heating process. The exposition of the flake edges and paths resulting from the removal of the gaseous products can be beneficial regarding the electrode design for cells operating liquid or gel electrolytes, ensuring improved

Quantitative estimation of nanoparticle/substrate adhesion by atomic force microscopy

• Aydan Çiçek,
• Markus Kratzer,
• Christian Teichert and
• Christian Mitterer

Beilstein J. Nanotechnol. 2026, 17, 1–14, doi:10.3762/bjnano.17.1

• of copper nanoparticles to silicon substrates deposited under varying conditions using DC magnetron sputter inert gas condensation. Atomic force microscopy was utilized as a tool for the manipulation of the nanoparticles and to measure lateral forces for their displacement, with cantilever

• NPs, deposited using different landing conditions, and a Si substrate. Cu NPs were synthesized via magnetron sputter inert gas condensation at different applied substrate bias voltages to vary their kinetic energy during landing at the substrate, thereby influencing their adhesion properties. AFM was

• were plasma-cleaned in a Diener electronic Tetra 30 system at a N2 pressure of 50 Pa for 20 min. Immediately after plasma cleaning, the substrates were loaded in the NP deposition chamber. The NP deposition experiments were conducted using DC magnetron sputter inert gas condensation in a Moorfield

Internal 3D temperature mapping in biological systems using ratiometric light-sheet imaging and lipid-coated upconversion nanothermometers

• Dannareli Barron-Ortiz,
• Enric Pérez-Parets,
• Rubén D. Cadena-Nava,
• Emilio J. Gualda,
• Jacob Licea-Rodríguez,
• Juan Hernández-Cordero,
• Pablo Loza-Álvarez and
• Israel Rocha-Mendoza

Beilstein J. Nanotechnol. 2025, 16, 2306–2316, doi:10.3762/bjnano.16.159

• phototoxicity [38]. The ladder-like energy level structure of Ln3+ ions enable efficient photon UC of near-infrared (NIR) light, even with moderate excitation intensities (1–103 W·cm−2) attainable with gas-based lamps or continuous wave lasers [39]. Temperature measurements using Ln3+-doped nanomaterials have

• 100 µL of UCNPs in a round-bottomed flask. The resulting mixture was then evaporated under a constant flow of N2 gas while stirring in a circular motion for 30 min. After solvent evaporation, 2 mL of Milli-Q water were added to the flask for rehydration overnight at 4 °C. The resulting water

Terahertz-range on-chip local oscillator based on Josephson junction arrays for superconducting quantum-limited receivers

• Fedor V. Khan,
• Lyudmila V. Filippenko,
• Andrey B. Ermakov,
• Mikhail Yu. Fominsky and
• Valery P. Koshelets

Beilstein J. Nanotechnol. 2025, 16, 2296–2305, doi:10.3762/bjnano.16.158

• proven itself for many times both in laboratory and in real-life conditions. The terahertz SIS-mixer integrated on the same chip with the LO based on a flux-flow oscillator (FFO) and a receiving antenna [13] was used to study the irradiation of the human body [15], gas spectroscopy [16], and the

• atmosphere gas components at the TELIS mission on board of the stratospheric balloon [17]. However, the LO based on FFO has some problems yet to be solved. The operation frequency of the FFO is limited by the gap frequency of the superconducting niobium that forms one or both of its electrodes [18

Ultrathin water layers on mannosylated gold nanoparticles

• Maiara A. Iriarte Alonso,
• Jorge H. Melillo,
• Silvina Cerveny,
• Yujin Tong and
• Alexander M. Bittner

Beilstein J. Nanotechnol. 2025, 16, 2183–2198, doi:10.3762/bjnano.16.151

• dimannose groups. The increased water adsorption of dimanno-AuNPs, compared to the well-studied PEG AuNPs, makes them candidates for gas sensing applications. Sensors are usually kept dry and then become hydrated in standard environments. Whenever dry conditions are problematic, our study suggests testing

Microplastic pollution in Himalayan lakes: assessment, risks, and sustainable remediation strategies

• Sameeksha Rawat,
• S. M. Tauseef and
• Madhuben Sharma

Beilstein J. Nanotechnol. 2025, 16, 2144–2167, doi:10.3762/bjnano.16.148

• samples from the environment makes nanoscale plastics yet another challenge. Sophisticated methods such as thermal extraction desorption (TED) and gas chromatography-mass spectrometry (GC-MS) are now routinely used to detect these particles. But these methods involve a lot of expertise and equipment. The

Quality by design optimization of microemulsions for topical delivery of Passiflora setacea seed oil

• Daniel T. Pereira,
• Douglas Dourado,
• Danielle T. Freire,
• Dayanne L. Porto,
• Cícero F. S. Aragão,
• Myla L. de Souza,
• Guilherme R. S. de Araujo,
• Ana Maria Costa,
• Wógenes N. Oliveira,
• Anne Sapin-Minet,
• Éverton N. Alencar and
• Eryvaldo Sócrates T. Egito

Beilstein J. Nanotechnol. 2025, 16, 2116–2131, doi:10.3762/bjnano.16.146

• poor physicochemical and organoleptic properties. This study aimed to develop and optimize a topical microemulsion (ME) system incorporating P. setacea seed oil using quality by design principles to address formulation challenges. The oil was extracted via Soxhlet and characterized by gas

• ), followed by gas chromatography coupled with mass spectroscopy (GC–MS) analysis. The relative composition of fatty acids is presented in Table 1, and the corresponding chromatogram is provided in Figure S1 (Supporting Information File 1). The major constituents identified in OPS were linoleic acid (64.69

• , the organic (n-hexane) layer was collected and washed three times with saturated NaCl solution to remove residual reagents. A 200 µL aliquot of the organic phase was then dried at room temperature in pre-weighted vials. FAME quantification was performed using a gas chromatograph (GC Agilent 8860

Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• high surface area and customizable chiral environments. A highly important and highly developed area of application of chiral materials possessing a high surface area is chromatography [11][12][13]. Techniques like high-performance liquid chromatography (HPLC) [13] and gas chromatography [14] are

• measurements more difficult. There are other valuable methods for investigating transport in porous media such as gas-adsorption methods, X-ray tomography [24][25], neutron imaging techniques [26][27], optical imaging techniques [27][28], or impedance spectroscopy [29][30]. For all of them, it is difficult to

Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• molecules are more probable in the liquid phase as compared to the cavitation bubble due to a much higher concentration of the target material species in the bubble as compared to that of the liquid molecules. Moreover, since NPs are shown to be partially localized in the gas bubble and partially travelling

• , produced either through liquid evaporation or from reactive species generated during decomposition, such as hydrogen, hydrogen peroxide, and oxygen. The type of gas emitted depends on the liquid composition and can influence the morphology of the resulting NPs. As shown in [55], the ablation in ethanol

Evaluating metal-organic precursors for focused ion beam-induced deposition through solid-layer decomposition analysis

• Benedykt R. Jany,
• Katarzyna Madajska,
• Aleksandra Butrymowicz-Kubiak,
• Franciszek Krok and
• Iwona B. Szymańska

Beilstein J. Nanotechnol. 2025, 16, 1942–1951, doi:10.3762/bjnano.16.135

• create a new precursor, extensive testing using specialized gas injection systems is required along with time-consuming and costly chemical analysis typically conducted using scanning electron microscopy (SEM). This process can be quite challenging due to its complexity and expense. Here, the response of

• irradiation differs from gas-phase deposition, we think that our method can be employed to optimize pre-screen and score new potential precursors for FIB applications by significantly reducing the time required and conserving valuable resources. Keywords: backscattered electrons (BSE); carboxylates; energy

• duration of the electron or ion beam pulses. In FEBID and FIBID, volatile precursor molecules are delivered to the substrate surface via a gas injection system (GIS), where they adsorb and are subsequently decomposed by a focused electron or ion beam with energies in the kiloelectronvolt range. While

Targeting the vector of arboviruses Aedes aegypti with nanoemulsions based on essential oils: a review with focus on larvicidal and repellent properties

• Laryssa Ferreira do Nascimento Silva,
• Douglas Dourado,
• Thayse Silva Medeiros,
• Mariana Alice Gonzaga Gabú,
• Maria Cecilia Queiroga dos Santos,
• Daiane Rodrigues dos Santos,
• Mylena Lemos dos Santos,
• Gabriel Bezerra Faierstein,
• Rosângela Maria Rodrigues Barbosa and
• Fabio Rocha Formiga

Beilstein J. Nanotechnol. 2025, 16, 1894–1913, doi:10.3762/bjnano.16.132

• efficiency reached 85.4%, according to gas chromatography analysis. In the tests, Sprague Dawley rats received the formulation applied to their backs before being exposed to 50 female Ae. aegypti for 8 hours. The average protection was 87.81%, surpassing the pure oil (54.57%) and falling below DEET (100

Further insights into the thermodynamics of linear carbon chains for temperatures ranging from 13 to 300 K

• Alexandre Rocha Paschoal,
• Thiago Alves de Moura,
• Juan S. Rodríguez-Hernández,
• Carlos William de Araujo Paschoal,
• Yoong Ahm Kim,
• Morinobu Endo and
• Paulo T. Araujo

Beilstein J. Nanotechnol. 2025, 16, 1818–1825, doi:10.3762/bjnano.16.125

• interactions, and that mutual interactions between chain-like structures and their hosts are second-order effects [61][62][63][64][65]. Sulfur chains inside SWCNT have also demonstrated enhanced field-emission properties and outstanding gas-sensing properties [66][67], which once again corroborate the idea

Multifunctional anionic nanoemulsion with linseed oil and lecithin: a preliminary approach for dry eye disease

• Niédja Fittipaldi Vasconcelos,
• Almerinda Agrelli,
• Rayane Cristine Santos da Silva,
• Carina Lucena Mendes-Marques,
• Isabel Renata de Souza Arruda,
• Priscilla Stela Santana de Oliveira,
• Mércia Liane de Oliveira and
• Giovanna Machado

Beilstein J. Nanotechnol. 2025, 16, 1711–1733, doi:10.3762/bjnano.16.120

• . These characterizations were performed to ensure the quality and stability of the formulations and to evaluate their suitability for ophthalmic applications. Gas chromatograph with flame ionization detection (GC-FID) LO’s fatty acid methyl esters were transesterified as described in [37][38]. Briefly, 1

• phase. The supernatant was washed three times with 10% (w/v) citric acid and then concentrated via rotary evaporation. A 2 µL aliquot of the supernatant was injected in split injection mode (1:10 in ethyl acetate) into a gas chromatograph with flame ionization detection (GC-FID) model 7290 A (Agilent

• Technologies, USA). The column used was a SP®-2560 capillary GC column (100 m × 0.25 mm × 0.20 µm) (Supelco). The injector temperature was maintained at 230 °C, with helium (He) serving as the carrier gas at a flow rate of 1 mL·min−1. The oven temperature was programmed to increase from 150 to 300 °C at a rate

Ambient pressure XPS at MAX IV

• Mattia Scardamaglia,
• Ulrike Küst,
• Alexander Klyushin,
• Rosemary Jones,
• Jan Knudsen,
• Robert Temperton,
• Andrey Shavorskiy and
• Esko Kokkonen

Beilstein J. Nanotechnol. 2025, 16, 1677–1694, doi:10.3762/bjnano.16.118

• tracking surface chemical processes in real time. Due to the scattering of the photoelectrons in a gas environment at millibar pressures, APXPS is intrinsically a photon-hungry technique. Although pioneering work on gases and liquids performed by Kai and Hans Siegbahn date back to the 1970s [1], it was

• –gas, solid–liquid, and liquid–gas interfaces in situ and under operando conditions. In this review, we highlight exemplary APXPS experiments conducted in different environments to study solid–gas and solid–liquid interfaces. APXPS at MAX IV is making a considerable contribution in various scientific

• fields including catalysis, energy materials, and corrosion, to name a few. As an example in catalysis research, we will discuss experiments on solid–gas interfaces about single-atom catalysts, catalysis in confined space, time-resolved catalysis, and photocatalysis. Remaining in the solid–gas

Nanotechnology-based approaches for the removal of microplastics from wastewater: a comprehensive review

• Nayanathara O Sanjeev,
• Manjunath Singanodi Vallabha and
• Rebekah Rubidha Lisha Rabi

Beilstein J. Nanotechnol. 2025, 16, 1607–1632, doi:10.3762/bjnano.16.114

• calorimetry, pyrolysis gas chromatography mass spectrometry, and thermal extraction desorption gas chromatography are useful in identifying the chemical composition of MPs but are destructive analytical techniques [132][133]. Spectroscopic analysis like Raman spectroscopy often suffers from a poor signal-to

Modeling magnetic properties of cobalt nanofilms used as a component of spin hybrid superconductor–ferromagnetic structures

• Aleksey Fedotov,
• Olesya Severyukhina,
• Anastasia Salomatina and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2025, 16, 1557–1566, doi:10.3762/bjnano.16.110

• potential multi-body model: where Fi is the immersion function of each atom in the electron gas created by electrons of all other atoms of the system; ϕij(rij) is the pair potential function; rij = |rij| = |rj − rj| is the distance between two atoms with numbers i and j; and is the background electron

Transient electronics for sustainability: Emerging technologies and future directions

• Jae-Young Bae,
• Myung-Kyun Choi and
• Seung-Kyun Kang

Beilstein J. Nanotechnol. 2025, 16, 1545–1556, doi:10.3762/bjnano.16.109

• materials exhibit strong potential for the use in implantable medical devices. For instance, Ge nanomembranes have been employed in fully biodegradable strain and temperature sensors, demonstrating proven biocompatibility and gas-free dissolution. In addition, IGZO has been utilized to fabricate transient

Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications

• Akshana Parameswaran Sreekala,
• Pooja Raveendran Nair,
• Jithin Kundalam Kadavath,
• Bindu Krishnan,
• David Avellaneda Avellaneda,
• M. R. Anantharaman and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104

• comprehensive understanding of the process flow, from the laser-induced ejection of material into the gas phase, through its processing and movement in the plume, to its eventual deposition onto a substrate. Figure 1 shows key developments in thin film synthesis and laser-based processing from 1909 to 2025

• substrate and the spray nozzle, substrate temperature, and precursor solution concentration. Additionally, the properties of the films depend on variables like the spray rate, ambient atmosphere, droplet size, carrier gas, and post-deposition cooling. One of the key advantages of this method is its ability

Ferroptosis induction by engineered liposomes for enhanced tumor therapy

• Alireza Ghasempour,
• Mohammad Amin Tokallou,
• Mohammad Reza Naderi Allaf,
• Mohsen Moradi,
• Hamideh Dehghan,
• Mahsa Sedighi,
• Mohammad-Ali Shahbazi and
• Fahimeh Lavi Arab

Beilstein J. Nanotechnol. 2025, 16, 1325–1349, doi:10.3762/bjnano.16.97

• chemodynamic and gas treatment could trigger mitochondrial damage and the formation of mtROS, resulting in the production of LPO active substances and finally inducing ferroptosis [150]. Figure 3 summarizes the key mechanisms of enhanced cancer therapy, which include induction of ferroptosis, apoptosis, and

Deep-learning recognition and tracking of individual nanotubes in low-contrast microscopy videos

• Vladimir Pimonov,
• Said Tahir and
• Vincent Jourdain

Beilstein J. Nanotechnol. 2025, 16, 1316–1324, doi:10.3762/bjnano.16.96

• and carrier gas. Oxygen and water sensors monitored gas-phase contaminants at the outlet line. In situ microscopy Nanotube growth was imaged in situ using a custom-built optical setup for homodyne polarization microscopy. A supercontinuum source (Fianium SC-400-4, 2 ps pulses, 40 MHz, spectral range

Acrocomia aculeata oil-loaded nanoemulsion: development, anti-inflammatory properties, and cytotoxicity evaluation

• Verónica Bautista-Robles,
• Hady Keita,
• Edgar Julián Paredes Gamero,
• Layna Tayná Brito Leite,
• Jessica de Araújo Isaías Muller,
• Mônica Cristina Toffoli Kadri,
• Ariadna Lafourcade Prada and
• Jesús Rafael Rodríguez Amado

Beilstein J. Nanotechnol. 2025, 16, 1277–1288, doi:10.3762/bjnano.16.93

• min. Once cooled, the solution was extracted with 5 mL of n-hexane and centrifuged. 20 μL of supernatant (hexane phase) were injected directly into the GC-MS system (Mega 2 series gas chromatograph coupled to a SHIMADZU GC-MS-QP500 mass spectrometer (GC-MS) (Japan)) [60]. A 30 m × 0.32 mm capillary

• column with a 0.25 mm thick layer (66DB-5MS, Agilent Technologies, USA) was used as the stationary phase. Helium gas was used as carrier gas at a flow rate of 1.0 mL/min with a split ratio of 1:10. The injector temperature was set to 250 °C. The oven temperature was set to 130 °C for 10 min and then

Better together: biomimetic nanomedicines for high performance tumor therapy

• Imran Shair Mohammad,
• Gizem Kursunluoglu,
• Anup Kumar Patel,
• Hafiz Muhammad Ishaq,
• Cansu Umran Tunc,
• Dilek Kanarya,
• Mubashar Rehman,
• Omer Aydin and
• Yin Lifang

Beilstein J. Nanotechnol. 2025, 16, 1246–1276, doi:10.3762/bjnano.16.92

• asymmetrical catalysis of urea to ammonia acts as a gas jet to propel the microrobots to the desired site of action [54]. 1.2 Lipoprotein-based biomimetic nanoparticles Lipoproteins are complex structures with a lipid core, usually cholesterol esters and triglycerides, surrounded by a monolayer of