Ultrathin water layers on mannosylated gold nanoparticles

• Maiara A. Iriarte Alonso,
• Jorge H. Melillo,
• Silvina Cerveny,
• Yujin Tong and
• Alexander M. Bittner

Beilstein J. Nanotechnol. 2025, 16, 2183–2198, doi:10.3762/bjnano.16.151

• microbalance observations of highly hydrated cellulose films [48], which found 3.6 mol water per cellulose subunit at 97% RH. Under hydrophobic conditions, PEG AuNPs show a moderate increase in AFM height, corresponding to one water layer, not observed under hydrophilic conditions. It is possible that this is

• of dimanno-AuNPs and PEG AuNPs was recorded in a broad-band VSFG system at Fritz-Haber-Institute (Max-Planck-Gesellschaft, Berlin, Germany). Gold thin films (200 nm on 10 nm Cr on glass) were used as surfaces. Prior to sample deposition, the surfaces were cleaned with ethanol and Milli-Q water under

Electron transport through nanoscale multilayer graphene and hexagonal boron nitride junctions

• Aleksandar Staykov and
• Takaya Fujisaki

Beilstein J. Nanotechnol. 2025, 16, 2132–2143, doi:10.3762/bjnano.16.147

• [2], nanoscale electronics and electronic components [3], thermoelectric devices [4], and transparent films [5]. Graphene is a two-dimensional zero-bandgap semiconductor with excellent bulk conductivity. Its in-plane electron transport strongly depends on lattice order, lattice defects, and three

Evaluating metal-organic precursors for focused ion beam-induced deposition through solid-layer decomposition analysis

• Benedykt R. Jany,
• Katarzyna Madajska,
• Aleksandra Butrymowicz-Kubiak,
• Franciszek Krok and
• Iwona B. Szymańska

Beilstein J. Nanotechnol. 2025, 16, 1942–1951, doi:10.3762/bjnano.16.135

• masks, and resistance, with the flexibility of depositing materials on non-planar surfaces [4][5][14]. The FIBID method has several advantages compared to the FEBID technique in depositing thin films on substrates. First, ions generate more secondary electrons on the substrate surface than electrons

• previously in CVD, and β-diketonates are the most common CVD precursors, yielding films of high purity up to 99 atom % [5][15][22][23][24][25][26]. In FEBID, silver(I) carboxylates, in contrast to β-diketonates, result in high metal content in the deposits. Recent research [5] using [Ag2(μ-O2CR)2], where R

• a more in-depth understanding of the proposed pathway for successful testing of the new potential FIBID precursors. The Fabrication of the Precursor Thin Layer The metal-organic precursors films for the FIB/SEM experiments were deposited by sublimation using a glassware sublimation apparatus. The Si

Quantum circuits with SINIS structures

• Mikhail Tarasov,
• Mikhail Fominskii,
• Aleksandra Gunbina,
• Artem Krasilnikov,
• Maria Mansfeld,
• Dmitrii Kukushkin,
• Andrei Maruhno,
• Valeria Ievleva,
• Mikhail Strelkov,
• Daniil Zhogov,
• Konstantin Arutyunov,
• Vyacheslav Vdovin,
• Vladislav Stolyarov and
• Valerian Edelman

Beilstein J. Nanotechnol. 2025, 16, 1931–1941, doi:10.3762/bjnano.16.134

• tunnel junction In tunnel structures, the barrier is a dielectric layer between two metal films (often the oxide layer on the surface of the first metal layer is used as a dielectric). The first experimental study of a tunnel junction was carried out in 1960 [21] for an aluminum–aluminum oxide–lead

• are the thicknesses of the normal metal and superconductor films, respectively. Another feature of the tunnel–NIS junction is the phenomenon of electron cooling. This process is a transfer of heat from a normal metal to a superconductor and is caused by the fact that charge carriers with higher energy

Electrical, photocatalytic, and sensory properties of graphene oxide and polyimide implanted with low- and medium-energy silver ions

• Josef Novák,
• Eva Štěpanovská,
• Petr Malinský,
• Vlastimil Mazánek,
• Jan Luxa,
• Ulrich Kentsch and
• Zdeněk Sofer

Beilstein J. Nanotechnol. 2025, 16, 1794–1811, doi:10.3762/bjnano.16.123

• for the precise introduction of implanted atoms into the surface layers without the need for subsequent chemical modification, thus opening new possibilities in the development of functional thin films. In this study, Ag ions were used to modify polymer matrices to improve chemical and electronic

• yield. Such properties are promising for applications including photocatalytic water purification, self-cleaning surfaces, and light-activated antimicrobial coatings [20]. The elemental composition of the modified films was characterized by Rutherford backscattering spectrometry (RBS) and elastic recoil

• often leads to the displacement of the target nuclei and to significant defect formation in the irradiated material, such as substitution defects [21]. We performed an initial estimation of the ions’ energy losses and range depth of the implanted Ag ions in GO and PI films using SRIM software [22]. This

Ambient pressure XPS at MAX IV

• Mattia Scardamaglia,
• Ulrike Küst,
• Alexander Klyushin,
• Rosemary Jones,
• Jan Knudsen,
• Robert Temperton,
• Andrey Shavorskiy and
• Esko Kokkonen

Beilstein J. Nanotechnol. 2025, 16, 1677–1694, doi:10.3762/bjnano.16.118

• performance in integrated circuits. Its precision, scalability, and ability to produce conformal films on intricate surfaces make ALD a cornerstone in the pursuit of miniaturization and enhanced performance in technology. ALD achieves such high levels of growth control by a well-separated alternating exposure

• –liquid interfaces and is particularly relevant for battery research. Corrosion Nanometer-thin and spontaneously formed oxide layers, also known as passive films, play a crucial role in the corrosion resistance of many advanced alloys. The current knowledge of the passive films’ structure and composition

• evolution of passive films under electrochemical stress [67][68]. Batteries The dip-and-pull method allows for surface-sensitive XPS measurements of interfaces that are typically hidden inside batteries. Whilst the cell geometry obviously differs dramatically from that of any conventional cell, the approach

Photocatalytic degradation of ofloxacin in water assisted by TiO₂ nanowires on carbon cloth: contributions of H₂O₂ addition and substrate absorbability

• Iram Hussain,
• Lisha Zhang,
• Zhizhen Ye and
• Jin-Ming Wu

Beilstein J. Nanotechnol. 2025, 16, 1567–1579, doi:10.3762/bjnano.16.111

• with the benchmark commercial P25 TiO2 nanoparticles deposited on a Ti substrate. All thin films were controlled to be of almost identical film thickness for a reasonable comparison. Both nanowire samples exhibit a photoactivity superior to that of the benchmark P25 when utilized in the form of thin

• films. It also indicates that the highly adsorptive carbon cloth substrate, as suggested by the dark adsorption curves in Figure 9b, contributes to the photoactivity of TiO2 nanowires. This fact indicates a synergistic effect resulting from substrate adsorption and TiO2 photodegradation. The synergistic

• effect may involve (1) carbon cloth possessing a substantial specific surface area and surface mesopores, which offers numerous adsorption sites, thereby concentrating solute molecules near the surface of thin films [13], (2) the transfer of photogenerated electrons from TiO2 to the conductive carbon

Modeling magnetic properties of cobalt nanofilms used as a component of spin hybrid superconductor–ferromagnetic structures

• Aleksey Fedotov,
• Olesya Severyukhina,
• Anastasia Salomatina and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2025, 16, 1557–1566, doi:10.3762/bjnano.16.110

• thin films and the formation of Neel domain walls. Keywords: ferromagnetic properties; LAMMPS; mathematical modeling; MEAM; molecular dynamics; spin dynamics; Introduction Thin film structures [1][2] are increasingly employed each year in a wide range of applications, serving as functional [3][4

• . Due to active experimental and theoretical research on thin films, significant progress has been made in recent years. Since the information in the field of thin film technologies is updated quite rapidly, there is a need for a thorough study and optimization of the main technological processes that

• structure and composition of Co–Ni–Fe films were evaluated, and it was found out how the deposition rate affects the conversion of a weak magnetic field into magnetic induction. In addition, thin-film structures based on Fe and Co are among the most promising materials that can be applied in the creation of

Transient electronics for sustainability: Emerging technologies and future directions

• Jae-Young Bae,
• Myung-Kyun Choi and
• Seung-Kyun Kang

Beilstein J. Nanotechnol. 2025, 16, 1545–1556, doi:10.3762/bjnano.16.109

• van der Waals films via photonic sintering allows for the development of novel forms of transient electronic devices, thereby further broadening the scope of their potential applications [31]. The foundational principles of transient electronics rest on the deliberate selection and integration of

• but also of electrical and mechanical performance. For instance, Mg-3Zn, which suffers from phase separation in bulk form, can be synthesized as a uniform alloy in thin films, offering improved corrosion resistance [61]. Moreover, bioresorbable amorphous metal (metallic glass) films have demonstrated

• thick Mg trace for up to three weeks in PBS (pH 7.4, 37 °C). However, organic films suffer from intrinsic porosity due to their polymer chain structure, which limits their water-blocking performance compared to inorganic counterparts. In contrast, inorganic coatings, traditionally employed in the field

Influence of laser beam profile on morphology and optical properties of silicon nanoparticles formed by laser ablation in liquid

• Natalie Tarasenka,
• Vladislav Kornev,
• Alena Nevar and
• Nikolai Tarasenko

Beilstein J. Nanotechnol. 2025, 16, 1533–1544, doi:10.3762/bjnano.16.108

• the nanometer range and different morphologies is continuously growing. One aspect of current studies is further improvement of the properties and performance of the developed silicon-based devices. As a result, crystalline films based on silicon [1][2] as well as nano-sized silicon materials have

• become an emerging field of research [3][4][5][6][7]. The expanding application areas require silicon nanomaterials of different morphologies, including quantum dots, nanowires, and nanocrystalline films. Si nanowires, for example, are considered as a promising alternative to silicon electrodes in Li-ion

Cross-reactivities in conjugation reactions involving iron oxide nanoparticles

• Shoronia N. Cross,
• Katalin V. Korpany,
• Hanine Zakaria and
• Amy Szuchmacher Blum

Beilstein J. Nanotechnol. 2025, 16, 1504–1521, doi:10.3762/bjnano.16.106

• , Figure S1.i), we see that both samples show significant broadening, and a change in the relative intensities of the two peaks. Similar broadening and lineshapes (relative intensities) were observed for Cy5-hexafluorophosphate thin films, and attributed to H-aggregate formation [59]. With the FTIR results

Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications

• Akshana Parameswaran Sreekala,
• Pooja Raveendran Nair,
• Jithin Kundalam Kadavath,
• Bindu Krishnan,
• David Avellaneda Avellaneda,
• M. R. Anantharaman and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104

• ; nanocolloids to thin films; photocatalysis; photovoltaics and photodetection; surface-enhanced Raman spectroscopy (SERS); Review 1 Introduction This section provides a brief introduction to the fundamental laser processing techniques used in liquids, including ablation, fragmentation, melting, irradiation; it

• , and HER/OER devices. These films exhibit unique morphologies and properties due to the controlled nanoparticle size and dispersion. Additionally, these nanocolloids enable facile, low-temperature, single-step film fabrication under standard laboratory conditions, making it an efficient and versatile

• method for developing advanced functional materials. This section of the discussion focuses on the fabrication of thin films using laser-processed nanocolloids by various techniques such as electrophoretic deposition (EPD), spin-dip coating, spin coating, drop-casting, and spray deposition. The choice of

The role of biochar in combating microplastic pollution: a bibliometric analysis in environmental contexts

• Tuan Minh Truong Dang,
• Thao Thu Thi Huynh,
• Guo-Ping Chang-Chien and
• Ha Manh Bui

Beilstein J. Nanotechnol. 2025, 16, 1401–1416, doi:10.3762/bjnano.16.102

• contribute to increased MP removal efficiency, particularly for nanosized particles [43]. Field studies on agricultural runoff reveal diverse MP contamination, including PVC films (500–1000 µm), fragments (45–500 µm, comprising PS, PA, PC, HDPE, LDPE, PET), and beads (40–48 µm, consisting solely of PE

Synthesis and antibacterial properties of nanosilver-modified cellulose triacetate membranes for seawater desalination

• Lei Wang,
• Shizhe Li,
• Kexin Xu,
• Wenjun Li,
• Ying Li and
• Gang Liu

Beilstein J. Nanotechnol. 2025, 16, 1380–1391, doi:10.3762/bjnano.16.100

• evidence of the successful sequential functionalization of the CTA membrane. In addition, at a temperature of 800 °C, both the CTA and PCTA films exhibit a residual mass of 0%, indicating complete decomposition or volatilization, leaving no significant inorganic residues. In contrast, the Ag@PCTA film

• and Bruening have reported that Ag nanoparticle-containing films have the same antibacterial effect as films containing Ag ions [49]. The nanoparticle-containing films may be much better because they minimize the amount of Ag ions absorbed in the body. The present work confirms the good antibacterial

Wavelength-dependent correlation of LIPSS periodicity and laser penetration depth in stainless steel

• Nitin Chaudhary,
• Chavan Akash Naik,
• Shilpa Mangalassery,
• Jai Prakash Gautam and
• Sri Ram Gopal Naraharisetty

Beilstein J. Nanotechnol. 2025, 16, 1302–1315, doi:10.3762/bjnano.16.95

• structuring offers a straightforward means to manipulate the functional and surface characteristics of substrates [10][11][12][13]. The applications span a broad spectrum, encompassing colorization control, self-cleaning surfaces, regulation of cell and bacterial films, antireflective surfaces, surface

Enhancing the photoelectrochemical performance of BiOI-derived BiVO₄ films by controlled-intensity current electrodeposition

• Huu Phuc Dang,
• Khanh Quang Nguyen,
• Nguyen Thi Mai Tho and
• Tran Le

Beilstein J. Nanotechnol. 2025, 16, 1289–1301, doi:10.3762/bjnano.16.94

• optimize the crystallinity, surface morphology, and electronic properties of the films. Subsequently, an electrochemical deposition method was developed to facilitate the uniform distribution of V2O5 among Bi–O–I flakes to homogeneously enhance the conversion reaction. The XRD pattern confirms the

• monoclinic scheelite BiVO4 structure with dominant (121) and (004) peaks. FESEM imaging revealed that the different deposition conditions influenced the surface morphologies of the BiOI and BiVO4 films. Photocurrent density measurements showed that BiVO4(326) achieved 1.2 mA·cm−2 at 1.23 V vs RHE

• charge carriers, which severely restrict its PEC performance [10][11][12]. Various strategies have been explored to overcome these challenges and optimize the structural, electronic, and surface properties of BiVO4 [13][14]. Hydrothermal synthesis has been used to produce highly crystalline BiVO4 films

Functional bio-packaging enhanced with nanocellulose from rice straw and cinnamon essential oil Pickering emulsion for fruit preservation

• Tuyen B. Ly,
• Duong D. T. Nguyen,
• Hieu D. Nguyen,
• Yen T. H. Nguyen,
• Bup T. A. Bui,
• Kien A. Le and
• Phung K. Le

Beilstein J. Nanotechnol. 2025, 16, 1234–1245, doi:10.3762/bjnano.16.91

• and enhanced food safety [30]. Results and Discussion Physicochemical properties FTIR spectroscopy (Figure 1a) was used to study the PVA/glycerol biopackaging (BP), NC-reinforced BP (rBP), and PE-CEO-containing rBP (rCBP) composite films. BP exhibited characteristic peaks at 3330 cm−1 (O–H stretching

• composite, delaying its decomposition [24]. CEO did not significantly alter the thermal degradation pattern, confirming that its incorporation did not compromise the thermal stability of the samples. These findings indicate that PVA-NC films are thermally suitable for applications like food packaging, where

• moderate temperature resistance is required. Figure 1c illustrates the mechanical properties of biopackaging films, including tensile strength and elongation at break. The incorporation of NC significantly enhances the tensile strength of the films by more than 40%, reaching 31.06 MPa, due to the

Hydrogels and nanogels: effectiveness in dermal applications

• Jéssica da Cruz Ludwig,
• Diana Fortkamp Grigoletto,
• Daniele Fernanda Renzi,
• Wolf-Rainer Abraham,
• Daniel de Paula and
• Najeh Maissar Khalil

Beilstein J. Nanotechnol. 2025, 16, 1216–1233, doi:10.3762/bjnano.16.90

• hydrogel films, drying for four days at room temperature and storage in a desiccator is required [94]. In the method described by Gao et al. (2018), PVA 15% w/v is added into water and stirred at 95 °C until complete dissolution [55]. The freeze/thaw cycle was carried out at −20 °C and room temperature and

• through the oxidative coupling of catechol groups using a hydrogen peroxide/horseradish peroxidase (H2O2/HRP) catalytic system [41]. The addition of the antibiotic doxycycline provided the hydrogels with antimicrobial activity to treat infected full-thickness defect wounds. Flexible films composed of

• guanosine quartet hydrogels loaded with recombinant human-sourced collagen can be wrapped onto the skin surface. These films can supply collagen deposition for the wound by recruiting macrophages and fibroblasts and eventually inducing their proliferation and migration [42]. In the study by Zhao et al

Transfer function of an asymmetric superconducting Gauss neuron

• Fedor A. Razorenov,
• Aleksander S. Ionin,
• Nikita S. Shuravin,
• Liubov N. Karelina,
• Mikhail S. Sidel’nikov,
• Sergey V. Egorov and
• Vitaly V. Bol’ginov

Beilstein J. Nanotechnol. 2025, 16, 1160–1170, doi:10.3762/bjnano.16.85

• slightly different shapes, which allows them to be distinguished during the initial analysis of experimental data. In recent years, a number of superconducting devices have been proposed based on very thin superconducting films whose kinetic inductance may be comparable to the magnetic one [11][25][26

• , where is the magnetic part of total inductance Lout. Therefore, the use of ultrathin superconducting films is not a promising approach for implementing a superconducting Gauss neuron. C. Input asymmetry One more possible type of asymmetry is related to the unequal input signal supply to the neuron’s

Crystalline and amorphous structure selectivity of ignoble high-entropy alloy nanoparticles during laser ablation in organic liquids is set by pulse duration

• Robert Stuckert,
• Felix Pohl,
• Oleg Prymak,
• Ulrich Schürmann,
• Christoph Rehbock,
• Lorenz Kienle and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2025, 16, 1141–1159, doi:10.3762/bjnano.16.84

Influence of ion beam current on the structural, optical, and mechanical properties of TiO₂ coatings: ion beam-assisted vs conventional electron beam evaporation

• Agata Obstarczyk and
• Urszula Wawrzaszek

Beilstein J. Nanotechnol. 2025, 16, 1097–1112, doi:10.3762/bjnano.16.81

• occurred for all coatings. In particular, an increase in ion beam current led to a reduction in crystallite size by approximately 30% compared to coatings prepared by conventional EBE process. The average anatase crystallite size for annealed films was in the range of 30.8 to 43.5 nm. A detailed SEM

• analysis of surface morphology and cross sections revealed that the TiO2 films prepared by IBAD had smaller, rounded grains and were denser compared to those deposited by EBE. Optical properties showed high transparency of 77–83% in the visible wavelength range for all as-prepared thin films. However

• , annealing caused a decrease of the transparency level by 32% for films deposited by EBE, while for films from the IBAD process the decrease was less than 10%. The use of an ion gun increased the hardness of the TiO2 films from 2.4 to 3.5 GPa (Iibg = 4 A). Although a similar relationship was observed for

Single-layer graphene oxide film grown on α-Al₂O₃(0001) for use as an adsorbent

• Shiro Entani,
• Mitsunori Honda,
• Masaru Takizawa and
• Makoto Kohda

Beilstein J. Nanotechnol. 2025, 16, 1082–1087, doi:10.3762/bjnano.16.79

• ions from aqueous solutions. In order to realize its application use, it is necessary to form large-area GO films with well-controlled thickness. However, the conventional methods for the fabrication of such tailored GO films present considerable challenges. Conventionally, GO films are obtained by a

• drop-casting technique, wherein GO flakes dispersed in a solvent are cast onto a substrate [16][17]. This technique does not allow for the control of number of layers. Consequently, studies have been conducted to synthesize large-area and single-layer GO (SLGO) films. As mentioned above, GO films have

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

• molecules and their two-dimensional films. The structure and quality of the films are pivotal parameters for any molecular electronics application, thus making them indispensable for the development of nanoscale electronic devices. In particular, these findings on the controlled self-assembly of

• . Additionally, they can be employed as precursors to produce CaFe2O4 thin films upon calcination. The resulting transparent solution is coated and subjected to calcination/annealing to form mesoporous thin films. The mesoporous films display excellent performance in the oxygen evolution reaction. It would be

• presented an overview of research activities utilizing azobenzene-containing monolayers and liquid crystal polymer films [243]. The linking of azobenzene molecules to liquid crystal and polymer systems has enabled the realization of a number of fascinating new motional functions. The use of photostimulation

Multifunctional properties of bio-poly(butylene succinate) reinforced with multiwalled carbon nanotubes

• Volodymyr Krasinskyi,
• Krzysztof Bajer,
• Ludmila Dulebova,
• Nickolas Polychronopoulos,
• Oksana Krasinska and
• Daniel Kaczor

Beilstein J. Nanotechnol. 2025, 16, 1014–1024, doi:10.3762/bjnano.16.76

• wettability of films based on the nanocomposite is 7 mN·m−1 higher than that of the original PBS (52 versus 45 mN·m−1). This indicates that PBS/CNT_0.5 films will not require additional activation before applying paints, adhesives, or coatings. The addition of CNTs also affects the density of PBS

• packaging, which typically require elongation at break in the range of 100–600% and Young’s modulus between 200 and 700 MPa [25]. Potential applications include stretch sleeves, flexible lids, and barrier films, where controlled deformation and improved wear resistance are desired. Rheological analysis

• temperatures of the Plasti-Corder LabStation extruder (Brabender, Duisburg, Germany) were set to 150, 160, and 170 °C, with the die head at 175 °C. The screw speed was 60 rpm, the cooling roll was set to 70 °C, and the rotational speed was 12 min−1. As a result of the films being freely cast onto the cooling

Time-resolved probing of laser-induced nanostructuring processes in liquids

• Maximilian Spellauge,
• David Redka,
• Mianzhen Mo,
• Changyong Song,
• Heinz Paul Huber and
• Anton Plech

Beilstein J. Nanotechnol. 2025, 16, 968–1002, doi:10.3762/bjnano.16.74