Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• Molybdenum substrates that were placed at the very beginning of the second part of the furnace were covered by a deposit (Figure 1a) containing chromium, germanium, and oxygen (Supporting Information File 1, Figure S1). The [Cr]/[Ge] atomic ratio was in the range of 1:(8–12). From a granular-like surface

• directly contact an as-grown single NW was developed. This method allowed us to measure the conductivity between the molybdenum substrate and the point of contact of the tungsten tip with the NW. To limit the contact resistance between the tungsten tip and the NW, the tip was soldered to the NW with a

• first part of the furnace. The Cr(acac)3 vapor in a continuous flow (3 sccm) of germane (GeH4) at 250 Pa was transported to the second part of the furnace where pyrolysis took place at 500 °C over molybdenum substrates. X-ray photoelectron spectrometry (XPS, Kratos ESCA 3400 with a base pressure below

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• nanocrystals [50], molybdenum trioxide [21], manganese dioxide [51], and vanadium carbide nanoparticles [12]. For instance, the electrocatalytic performance of cobalt nanoparticles (CoNPs) was reported by Zhang et al. [45] who studied a cathode comprising hollow carbon nanospheres. The cathode displayed a

• -workers [21]. Molybdenum trioxide prevents polysulfides from migrating due to its electrocatalytic and chemical sequestrant character. Therefore, a cycling stability of 2000 cycles was achieved. In the same way, a cathode with high capacity retention of 96.2% after 2000 cycles was presented by Tang and co

Prediction of Co and Ru nanocluster morphology on 2D MoS₂ from interaction energies

• Cara-Lena Nies and
• Michael Nolan

Beilstein J. Nanotechnol. 2021, 12, 704–724, doi:10.3762/bjnano.12.56

• . Based on this understanding, we propose Co on MoS2 as a suitable candidate for advanced interconnects, while Ru on MoS2 is more suited to catalysis applications. Keywords: cobalt (Co); 2D materials; molybdenum disulfide (MoS2); ruthenium (Ru); thin film nucleation; Introduction Layered materials that

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• to preferential sputtering of sulfur, increasing the relative amount of molybdenum in the material. Finally, at even higher doses, insulating behavior re-emerged, presumed to be due to excessive material removal by sputtering. In related work, a nearest-neighbor hopping mechanism mediated by the

• irradiation in the HIM, this time using a defocused beam to irradiate larger areas, has also been used to generate defects in exfoliated flakes of molybdenum dichalcogenides (MoS2 and MoSe2) to activate the catalytic activity of the basal planes of the crystal for hydrogen evolution reactions [69]. Thermal

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

Free and partially encapsulated manganese ferrite nanoparticles in multiwall carbon nanotubes

• Saja Al-Khabouri,
• Salim Al-Harthi,
• Toru Maekawa,
• Mohamed E. Elzain,
• Ashraf Al-Hinai,
• Ahmed D. Al-Rawas,
• Abbsher M. Gismelseed,
• Ali A. Yousif and
• Myo Tay Zar Myint

Beilstein J. Nanotechnol. 2020, 11, 1891–1904, doi:10.3762/bjnano.11.170

• removal of harmful pollutants [8], carbon nanotubes decorated with molybdenum disulfide are used in microbial fuel cells [9] and photoelectric detectors [10], supercapacitor electrodes use binary metal oxide/multiwall carbon nanotubes (MWCNTs) [11], among other numerous recently developed applications [12

Self-standing heterostructured NiC_x-NiFe-NC/biochar as a highly efficient cathode for lithium–oxygen batteries

• Shengyu Jing,
• Xu Gong,
• Shan Ji,
• Linhui Jia,
• Bruno G. Pollet,
• Sheng Yan and
• Huagen Liang

Beilstein J. Nanotechnol. 2020, 11, 1809–1821, doi:10.3762/bjnano.11.163

• [26]. For instance, molybdenum/tungsten carbide with a well-defined nanostructure was synthesized via a hydrothermal method, and the obtained metal carbide catalyst yielded a high capacity in lithium–oxygen batteries [15]. Also, titanium carbide was synthesized by Bruce et al. as cathode material for

Effect of localized helium ion irradiation on the performance of synthetic monolayer MoS₂ field-effect transistors

• Jakub Jadwiszczak,
• Pierce Maguire,
• Conor P. Cullen,
• Georg S. Duesberg and
• Hongzhou Zhang

Beilstein J. Nanotechnol. 2020, 11, 1329–1335, doi:10.3762/bjnano.11.117

• study of the electrical performance of chemically synthesized monolayer molybdenum disulfide (MoS2) field-effect transistors irradiated with a focused helium ion beam as a function of increasing areal irradiation coverage. We determine an optimal coverage range of approx. 10%, which allows for the

• materials; Introduction Layered two-dimensional (2D) semiconductors have come to the fore in recent years as promising candidates for the implementation of flexible, transparent, and low-power electronics. In particular, transition metal dichalcogenides (TMDs), such as molybdenum disulfide (MoS2), have

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

• Mykola Borzenkov,
• Piersandro Pallavicini,
• Angelo Taglietti,
• Laura D’Alfonso,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

• NIR-photothermal ablation (>99.99%) of S. aureus both in biofilms and in infected tissues [98]. Molybdenum oxide nanoparticles display a strong absorption in the NIR region, originating from the intervalence charge-transfer transition between the Mo5+ and Mo6+ states [99]. Ag nanocubes supported on

Monolayers of MoS₂ on Ag(111) as decoupling layers for organic molecules: resolution of electronic and vibronic states of TCNQ

• Asieh Yousofnejad,
• Gaël Reecht,
• Nils Krane,
• Christian Lotze and
• Katharina J. Franke

Beilstein J. Nanotechnol. 2020, 11, 1062–1071, doi:10.3762/bjnano.11.91

• the modes with strong electron–phonon coupling. Keywords: decoupling layer; molybdenum disulfide (MoS2); scanning tunneling microscopy, tetracyanoquinodimethane (TCNQ); vibronic states; Introduction When molecules are adsorbed on metal surfaces, their electronic states are strongly perturbed by

Epitaxial growth and superconducting properties of thin-film PdFe/VN and VN/PdFe bilayers on MgO(001) substrates

• Wael M. Mohammed,
• Igor V. Yanilkin,
• Amir I. Gumarov,
• Airat G. Kiiamov,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2020, 11, 807–813, doi:10.3762/bjnano.11.65

• was 20 cm, and the deposition rate was 0.2 nm/min. To grow heterostructures, the samples on the molybdenum holder were moved without breaking vacuum via the UHV transfer line between the MBE and MS deposition chambers as well as the analysis chamber (SPECS, Germany). To perform a comparative study

Exfoliation in a low boiling point solvent and electrochemical applications of MoO₃

• Matangi Sricharan,
• Bikesh Gupta,
• Sreejesh Moolayadukkam and
• H. S. S. Ramakrishna Matte

Beilstein J. Nanotechnol. 2020, 11, 662–670, doi:10.3762/bjnano.11.52

• mV·s−1. Keywords: 2-butanone; liquid-phase exfoliation; low-boiling point solvent; molybdenum trioxide (MoO3); supercapacitors; Introduction The advent of graphene has opened a new area of research in the field of two-dimensional materials [1]. The extraordinary properties of graphene have led

• layered materials, molybdenum oxide (MoO3) has gained special attention because of its numerous applications in electronics, catalysis, electrochemistry, solar cells and gas sensors [6]. Monolayered and few-layered MoO3 has been reported to have better properties than the bulk material [7]. Thus, it is

• boiling point, such as isopropyl alcohol (IPA) [5]. Alternative approaches for obtaining MoO3 dispersions in low boiling point solvents have also been reported. For instance, Alsaif et al. have exfoliated MoO3 in mixtures of water and alcohols (methanol, ethanol, IPA) [12]. In these dispersions molybdenum

DFT calculations of the structure and stability of copper clusters on MoS₂

• Cara-Lena Nies and
• Michael Nolan

Beilstein J. Nanotechnol. 2020, 11, 391–406, doi:10.3762/bjnano.11.30

• character of Cu nanoclusters is preserved. Keywords: copper (Cu); density functional theory (DFT); 2D materials; molybdenum disulfide (MoS2); thin film nucleation; Introduction Since the successful exfoliation of monolayers of graphene by Novoselov et al., 2D materials have gained a large interest in a

Design and facile synthesis of defect-rich C-MoS₂/rGO nanosheets for enhanced lithium–sulfur battery performance

• Chengxiang Tian,
• Juwei Wu,
• Zheng Ma,
• Bo Li,
• Pengcheng Li,
• Xiaotao Zu and
• Xia Xiang

Beilstein J. Nanotechnol. 2019, 10, 2251–2260, doi:10.3762/bjnano.10.217

• construction of other high-performance metal disulfide electrodes for electrochemical energy storage. Keywords: annealing; double modification; high-performance electrodes; lithium–sulfur battery; molybdenum disulfide (MoS2); reduced graphene oxide (rGO); Introduction Lithium–sulfur (Li–S) batteries have

Improvement of the thermoelectric properties of a MoO₃ monolayer through oxygen vacancies

• Wenwen Zheng,
• Wei Cao,
• Ziyu Wang,
• Huixiong Deng,
• Jing Shi and
• Rui Xiong

Beilstein J. Nanotechnol. 2019, 10, 2031–2038, doi:10.3762/bjnano.10.199

• calculations; molybdenum trioxides; MoO3 monolayer; oxygen vacancies; thermoelectric properties; Introduction Thermoelectric materials that can directly convert temperature gradients to voltage gradients and vice versa provide a valid strategy to mitigate the global energy crisis. Owing to the unique ability

• and fuel cells [5]. Meanwhile, the thermoelectric application of TMO-based materials has been explored and their poor efficiency is still the major difficulty [6]. Among the TMOs, layered molybdenum trioxide (MoO3) has attracted attention as a potential electrode material in electrochemical products

• atoms, that are connected to different molybdenum atoms, as indicated by different colors in Figure 1a. The relaxed lattice constants of the MoO3 monolayer are a = 3.68 Å and b = 3.93 Å, which are similar to the bulk experimental data of 3.70 and 3.96 Å [30]. In Figure 1b, we give the electronic band

Flexible freestanding MoS₂-based composite paper for energy conversion and storage

• Florian Zoller,
• Jan Luxa,
• Thomas Bein,
• Dina Fattakhova-Rohlfing,
• Daniel Bouša and
• Zdeněk Sofer

Beilstein J. Nanotechnol. 2019, 10, 1488–1496, doi:10.3762/bjnano.10.147

• devices where high flexibility and mechanical strength are desired. Keywords: flexible composites; hydrogen evolution reaction (HER); lithium ion batteries (LIBs); molybdenum disulfide; nanoarchitectonics; supercapacitors; Introduction The world’s growing population has a nearly ever-increasing demand

• extend their application to large energy storage systems or to the electromobility sector, an improvement in the energy storage capacity is necessary. Layered dichalcogenide materials such as molybdenum sulfide (MoS2) are promising candidates for the replacement of the commercial anode material graphite

Kelvin probe force microscopy of the nanoscale electrical surface potential barrier of metal/semiconductor interfaces in ambient atmosphere

• Petr Knotek,
• Tomáš Plecháček,
• Jan Smolík,
• Petr Kutálek,
• Filip Dvořák,
• Milan Vlček,
• Jiří Navrátil and
• Čestmír Drašar

Beilstein J. Nanotechnol. 2019, 10, 1401–1411, doi:10.3762/bjnano.10.138

• crystals of 10–20 mm in length, 3–6 mm in width and up to 3 mm in thickness [31]. The surface of freshly cleaved layered Bi2Se3 single crystals was used as a substrate. The samples for the AFM measurement, Au nanoparticles (NPs) and thin films of gold or molybdenum, were prepared via DC sputtering in a SEM

Alloyed Pt₃M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction

• Stéphane Louisia,
• Yohann R. J. Thomas,
• Pierre Lecante,
• Marie Heitzmann,
• M. Rosa Axet,
• Pierre-André Jacques and
• Philippe Serp

Beilstein J. Nanotechnol. 2019, 10, 1251–1269, doi:10.3762/bjnano.10.125

• performed on a diffractometer dedicated to pair distribution function (PDF) analyses: graphite-monochromatized molybdenum radiation (0.07169 nm), solid state detection and low background setup. The samples were sealed in Lindemann glass capillaries (diameter 1.5 mm). The MEA cross-sections were prepared by

Tungsten disulfide-based nanocomposites for photothermal therapy

• Tzuriel Levin,
• Hagit Sade,
• Rina Ben-Shabbat Binyamini,
• Maayan Pour,
• Iftach Nachman and
• Jean-Paul Lellouche

Beilstein J. Nanotechnol. 2019, 10, 811–822, doi:10.3762/bjnano.10.81

• latter group, nanostructures of metals [38], metal oxides (including iron oxides) [39], and metal chalcogenides [40][41] were studied. Tungsten oxides [42] and molybdenum oxides [43] were studied, as well as their disulfides. The disulfides were tested mainly in the forms of nanosheets [44], nanoflakes

Trapping polysulfide on two-dimensional molybdenum disulfide for Li–S batteries through phase selection with optimized binding

• Sha Dong,
• Xiaoli Sun and
• Zhiguo Wang

Beilstein J. Nanotechnol. 2019, 10, 774–780, doi:10.3762/bjnano.10.77

• batteries. Keywords: Li–S batteries; molybdenum disulfide; phase transformation; Introduction To satisfy the increasing demand for high-capacity energy storage systems, rechargeable lithium–sulfur (Li–S) batteries have attracted much attention in recent years due to a high theoretical specific energy

Direct observation of the CVD growth of monolayer MoS₂ using in situ optical spectroscopy

• Claudia Beatriz López-Posadas,
• Yaxu Wei,
• Wanfu Shen,
• Daniel Kahr,
• Michael Hohage and
• Lidong Sun

Beilstein J. Nanotechnol. 2019, 10, 557–564, doi:10.3762/bjnano.10.57

• dichalcogenide (2D TMDC) materials. However, it is very challenging to carry out such studies during chemical vapor deposition (CVD). Here, we report the first, real time, in situ study of the CVD growth of 2D TMDCs. More specifically, the CVD growth of a molybdenum disulfide (MoS2) monolayer on sapphire

• spectroscopy; molybdenum disulfide (MoS2) monolayer; two-dimensional transition-metal dichalcogenides (2D TMDC); Introduction Two-dimensional transition metal dichalcogenide (2D TMDC) materials have drawn wide attention because of their fascinating physical and chemical properties [1][2][3][4][5][6]. Given

• is sketched in Figure 3a. High purity MoO3 powder is used as the precursor for molybdenum, whereas the sulfur is supplied by vaporizing solid sulfur. High purity Ar was used as a carrier gas and a flow rate of 150 sccm was maintained during the whole process. The air in the reactor was evacuated

Mo-doped boron nitride monolayer as a promising single-atom electrocatalyst for CO₂ conversion

• Qianyi Cui,
• Gangqiang Qin,
• Weihua Wang,
• Lixiang Sun,
• Aijun Du and
• Qiao Sun

Beilstein J. Nanotechnol. 2019, 10, 540–548, doi:10.3762/bjnano.10.55

• high cost and has limits to its practical application. Above all, molybdenum as a non-noble-metal doped on BN monolayers presents both great performance in this theoretical study and is practically feasible for future experimental research. Although the energy input for the last step is possibly

Choosing a substrate for the ion irradiation of two-dimensional materials

• Egor A. Kolesov

Beilstein J. Nanotechnol. 2019, 10, 531–539, doi:10.3762/bjnano.10.54

• atoms in WS2 [19] to almost 32 eV for molybdenum in MoS2 [18] (this range includes values of ≈5–7 eV for S and Se in 2D TMDs [18][19] and ≈22–23 eV in graphene [20][21][22]). However, in [1] it was shown that, except for participating in the defect formation in adsorbed monolayers, the substrate can

Femtosecond laser-assisted fabrication of chalcopyrite micro-concentrator photovoltaics

• Franziska Ringleb,
• Stefan Andree,
• Berit Heidmann,
• Jörn Bonse,
• Katharina Eylers,
• Owen Ernst,
• Torsten Boeck,
• Martina Schmid and
• Jörg Krüger

Beilstein J. Nanotechnol. 2018, 9, 3025–3038, doi:10.3762/bjnano.9.281

• state of the art. The electric back contact (molybdenum) covered with the highly-efficient light-absorber (CIGSe) on top is deposited on a carrier material (glass). A buffer layer (CdS), a window layer consisting of an intrinsic ZnO layer (ZnO) and an aluminum-doped ZnO layer (Al:ZnO) as transparent

• and opportunities of the novel approaches to realize this cell concept. The first approach for microabsorber fabrication summarized here is based on the growth of metallic precursors (indium islands) on laser-structured substrates (molybdenum on glass) by means of physical vapor deposition (nucleation

• approach). The second method presented is based on laser-induced forward transfer (LIFT). In this method, laser radiation is used to transfer parts of a donor film (copper, indium, gallium) from a transparent carrier medium (glass) to an acceptor substrate (molybdenum on glass) in a spatially controlled

Site-controlled formation of single Si nanocrystals in a buried SiO₂ matrix using ion beam mixing

• Xiaomo Xu,
• Thomas Prüfer,
• Daniel Wolf,
• Hans-Jürgen Engelmann,
• Lothar Bischoff,
• René Hübner,
• Karl-Heinz Heinig,
• Wolfhard Möller,
• Stefan Facsko,
• Johannes von Borany and
• Gregor Hlawacek

Beilstein J. Nanotechnol. 2018, 9, 2883–2892, doi:10.3762/bjnano.9.267

• ) irradiation was performed using a helium ion microscope (HIM) [24][32] (ORION NanoFab, Carl Zeiss). Ne+ ions with an energy of 25 keV were used for ion beam mixing and imaging with either He or Ne was kept to a minimum to avoid additional unintentional damage and mixing. A 10 μm molybdenum aperture was used