Ion-induced surface reactions and deposition from Pt(CO)₂Cl₂ and Pt(CO)₂Br₂

• Mohammed K. Abdel-Rahman,
• Patrick M. Eckhert,
• Atul Chaudhary,
• Johnathon M. Johnson,
• Jo-Chi Yu,
• Lisa McElwee-White and
• D. Howard Fairbrother

Beilstein J. Nanotechnol. 2024, 15, 1427–1439, doi:10.3762/bjnano.15.115

• ability of data acquired from fundamental UHV surface science studies to provide insights that can be used to better understand the interactions between ions and precursors during IBID from inorganic precursors. Keywords: deposition; ion beam; nanostructure; organometallic; precursor; Introduction

Various CVD-grown ZnO nanostructures for nanodevices and interdisciplinary applications

• The-Long Phan,
• Le Viet Cuong,
• Vu Dinh Lam and
• Ngoc Toan Dang

Beilstein J. Nanotechnol. 2024, 15, 1390–1399, doi:10.3762/bjnano.15.112

• second type of nanostructure has a shape which resembles that of matches or drumsticks, which was mixed with several hexagonal prism-shaped nanorods, named M in Figure 2c. We also collected images of nanopencils, named P1 and P2 in Figure 3d,e, which have hexagonal prism-shaped bodies with sharp tips

New design of operational MEMS bridges for measurements of properties of FEBID-based nanostructures

• Bartosz Pruchnik,
• Krzysztof Kwoka,
• Ewelina Gacka,
• Dominik Badura,
• Piotr Kunicki,
• Andrzej Sierakowski,
• Paweł Janus,
• Tomasz Piasecki and
• Teodor Gotszalk

Beilstein J. Nanotechnol. 2024, 15, 1273–1282, doi:10.3762/bjnano.15.103

• nanostructure. Keywords: FEBID; MEMS; MEMS bridge; nanowires; opMEMS; Introduction Nanoelectronics is the fastest developing branch of modern electronic technology. Reduced dimensions allow for lower power consumption of the circuit and higher operating speeds [1][2]. Even more advantages (e.g., developed

• for the desired MEMS measurement platforms are as follows: They should be dimensionally compatible with the nanostructure to be tested and allow for actuation with an embedded actuation mechanism. To operate, MEMS platforms require auxiliary equipment such as a scanning electron microscope (SEM) or

• nanomodification. Finally, we show results of resistance measurements of a free-standing FEBID nanostructure deposited across the RoI of a LiS-embedded opMEMS bridge. Materials and Methods Design of opMEMS bridges The opMEMS were fabricated on an undoped ⟨110⟩ silicon substrate on which a 40 nm silicon nitride

A low-kiloelectronvolt focused ion beam strategy for processing low-thermal-conductance materials with nanoampere currents

• Annalena Wolff,
• Nico Klingner,
• William Thompson,
• Yinghong Zhou,
• Jinying Lin and
• Yin Xiao

Beilstein J. Nanotechnol. 2024, 15, 1197–1207, doi:10.3762/bjnano.15.97

• heating effects that lead to noticeable changes in nanostructure deposition geometry during FEBID processes have recently been published [19]. These approaches, a thorough understanding of the parameters that govern the beam-induced heat damage as well as open source software, would also be beneficial for

Quantum-to-classical modeling of monolayer Ge₂Se₂ and its application in photovoltaic devices

• Anup Shrivastava,
• Shivani Saini,
• Dolly Kumari,
• Sanjai Singh and
• Jost Adam

Beilstein J. Nanotechnol. 2024, 15, 1153–1169, doi:10.3762/bjnano.15.94

• Technology, Allahabad, Uttar Pradesh, India Department of Electrical Engineering, Indian Institute of Technology, Patna, India Center for Interdisciplinary Nanostructure Science and Technology (CINSaT), University of Kassel, Kassel, Germany 10.3762/bjnano.15.94 Abstract Since the discovery of graphene in

Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• carriers prior to their participation in reactions significantly reduces the efficiency of methane oxidation reactions [23][24]. To address these issues of TiO2 nanomaterials, many scientists have developed TiO2-based nanostructure composites as advanced photocatalysts [25][26][27][28][29][30]. The

• that the superior wettability of TiO2/SiNWs (hydrophilic surfaces) compared to TiO2/glass (hydrophobic surfaces) enables partial adsorption of water molecules, which facilitates the generation of radicals necessary for photocatalytic reactions. Furthermore, the TiO2 nanostructure and p-type SiNWs are

A review on the structural characterization of nanomaterials for nano-QSAR models

• Salvador Moncho,
• Eva Serrano-Candelas,
• Jesús Vicente de Julián-Ortiz and
• Rafael Gozalbes

Beilstein J. Nanotechnol. 2024, 15, 854–866, doi:10.3762/bjnano.15.71

• their aggregates on their toxicity has been recently reviewed [13]. From now, we will use the label “nanostructure” to refer to these properties, in comparison with the term “structure” referring to the chemical composition. The nanostructural differences among nanoparticles can be defined by different

• means: (i) direct measurements of their structure (e.g., their size), (ii) comparison of their physical properties that depend on size/nanostructure, and (iii) consideration of differences in their preparation. Another particularity of NMs is their chemical composition, as they could exhibit complex

• related to the external part (shell or surface) and/or the substituents or ligands attached to it ((b) in Figure 3), and those that directly reflect the nanostructure of the nanoform (including factors such as size, aspect ratio, or surface area, (c) in Figure 3). (ii) Descriptors that codify experimental

Elastic modulus of β-Ga₂O₃ nanowires measured by resonance and three-point bending techniques

• Annamarija Trausa,
• Sven Oras,
• Sergei Vlassov,
• Mikk Antsov,
• Tauno Tiirats,
• Andreas Kyritsakis,
• Boris Polyakov and
• Edgars Butanovs

Beilstein J. Nanotechnol. 2024, 15, 704–712, doi:10.3762/bjnano.15.58

• variations in reported nanostructure moduli. The mean elastic modulus of 34.5 and 75.8 GPa were obtained from resonance and three-point bending methods, respectively, which is significantly lower than the bulk value. Furthermore, the measured elastic moduli values indicate the need for finely controllable β

• reasons for the scattering of the measured elastic modulus values. Secondly, since the elastic modulus depends so intricately on the dimensions of the nanostructure (height is raised to the third power for three-point bending, width to the second power, and length to the fourth power for resonance

• error to the calculations which should be minimised via a thorough study of each individual nanostructure geometry [29]. The magnitude of the geometrical measurement error typically increases significantly for smaller NWs, since the relative measurement error is becoming comparable to the absolute value

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• formation of doped, compounded, and encapsulated nanoparticles. It will be shown how the choice of solvent, synthesis method, and laser parameters influence the nanostructure formation as well as the amount and chain length of the generated polyyne by-products. Finally, theoretical approaches to address the

Potential of a deep eutectic solvent in silver nanoparticle fabrication for antibiotic residue detection

• Le Hong Tho,
• Bui Xuan Khuyen,
• Ngoc Xuan Dat Mai and
• Nhu Hoa Thi Tran

Beilstein J. Nanotechnol. 2024, 15, 426–434, doi:10.3762/bjnano.15.38

• the nanostructure and surface morphology of the nanoparticles, as well as the elemental distribution of silver on the substrate, a S4800 field-emission scanning electron microscope purchased from Hitachi, Japan, and an M4 TORNADOPlus Micro X-ray fluorescence spectrometer with a Rh tube at 30 W micro

Modulated critical currents of spin-transfer torque-induced resistance changes in NiCu/Cu multilayered nanowires

• Mengqi Fu,
• Roman Hartmann,
• Julian Braun,
• Sergej Andreev,
• Torsten Pietsch and
• Elke Scheer

Beilstein J. Nanotechnol. 2024, 15, 360–366, doi:10.3762/bjnano.15.32

• equipment and the expert support concerning its usage and data analysis provided by the Nanostructure Laboratory at the University of Konstanz. Funding This research was funded by the A. v. Humboldt Foundation and the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) through project numbers

Controllable physicochemical properties of WO_x thin films grown under glancing angle

• Rupam Mandal,
• Aparajita Mandal,
• Alapan Dutta,
• Rengasamy Sivakumar,
• Sanjeev Kumar Srivastava and
• Tapobrata Som

Beilstein J. Nanotechnol. 2024, 15, 350–359, doi:10.3762/bjnano.15.31

• in Figure S1a and Figure S1b (Supporting Information File 1), respectively, confirming the compact growth of the columnar nanostructures originating from the GLAD geometry [32]. Here, the higher thickness is presented only to demonstrate the columnar nanostructure formation in a clearer way. Based on

Vinorelbine-loaded multifunctional magnetic nanoparticles as anticancer drug delivery systems: synthesis, characterization, and in vitro release study

• Zeynep Özcan and
• Afife Binnaz Hazar Yoruç

Beilstein J. Nanotechnol. 2024, 15, 256–269, doi:10.3762/bjnano.15.24

• where the synthesized nanostructure was exposed to NIR light, SN38-loaded nanoparticles effectively suppressed tumor growth chemotherapeutically and photothermally [29]. This promising result highlights the potential of the PEGylation of PDA nanoparticles for advanced cancer treatment strategies

• %, indicating the superior efficacy of our synthesis method. Moreover, our drug-loaded nanostructures exhibit a saturization magnetization of Ms = 60.40 emu/g, highlighting enhanced magnetic properties compared to the cited study. This indicates that the nanostructure can be strongly manipulated under an

• PDA polymer was achieved through the Michael addition reaction, involving the thiol and carbonyl groups present in the SH-PEG structure [37][38]. Vinorelbine loading on PDA/Fe3O4 nanoparticles For loading vinorelbine tartrate into the nanostructure, 25 mg of PEGylation PDA/Fe3O4 nanoparticles (1 mg/mL

Ion beam processing of DNA origami nanostructures

• Leo Sala,
• Agnes Zerolová,
• Violaine Vizcaino,
• Alain Mery,
• Alicja Domaracka,
• Hermann Rothard,
• Philippe Boduch,
• Dominik Pinkas and
• Jaroslav Kocišek

Beilstein J. Nanotechnol. 2024, 15, 207–214, doi:10.3762/bjnano.15.20

• vacuum and in air, respectively. Slow- and medium-energy heavy ion irradiation results in the cutting of the nanostructures or crater formation with ion-induced damage in the 10 nm range around the primary ion track. In all these cases, the designed shape of the 2D origami nanostructure remains

• in the present context are works on the use of DNA origami nanostructures in top-down or bottom-up nanopatterning approaches [7][8][9][10]. So far, DNA origami has been proposed only as a resist or as a platform to precisely arrange nanostructure precursors in lithography [11][12][13]. Incorporating

• nanometer scale and the nanometric precision of DNA origami-based assembly open possibilities in more precise tuning and control of nanofabrication. Here we analyze the consequences of ion beam irradiation on 2D DNA origami nanotriangles deposited on Si as a model substrate and resulting nanostructure

Curcumin-loaded nanostructured systems for treatment of leishmaniasis: a review

• Douglas Dourado,
• Thayse Silva Medeiros,
• Éverton do Nascimento Alencar,
• Edijane Matos Sales and
• Fábio Rocha Formiga

Beilstein J. Nanotechnol. 2024, 15, 37–50, doi:10.3762/bjnano.15.4

• : 190.3 ± 3.19 and IC50 value of the curc-free: 243.56 ± 2.89 μg/mL) corroborating the improvements in the leishmanicidal response after entrapment of curc in the nanostructure. This biological performance was also observed in artemether-NLC against L.infantum. Nanostructured lipid carriers conferred an

• IC50 values of 0.15 ± 0.08, 0.09 ± 0.07, and 0.07 ± 0.04 μM and selectivity index (SI) of 80, 255, and 314, respectively. In addition to the influence of the nanostructure, sugar promotes greater internalization of these nanoparticles due to the mannose receptors on the surface of macrophages [111

• ]. Pentamidine-loaded nanoparticles also showed great results due to the nanostructure. Free pentamidine and Pentamidine-NPs were administered orally in an in vivo experimental model of mice infected with visceral leishmaniasis. Only the nanoencapsulated drug showed a significant reduction in the relative weight

Nanotechnological approaches in the treatment of schistosomiasis: an overview

• Lucas Carvalho,
• Michelle Sarcinelli and
• Beatriz Patrício

Beilstein J. Nanotechnol. 2024, 15, 13–25, doi:10.3762/bjnano.15.2

• nanoparticles, nanostructure lipid carriers, nanoemulsions, nanocrystals, solid lipid nanoparticles, polymeric nanoparticles, noisomes, and others. Percentage of administration routes used in the 65 selected articles. The routes were: oral, subcutaneous, or intramuscular. In some cases, this information was

TEM sample preparation of lithographically patterned permalloy nanostructures on silicon nitride membranes

• Joshua Williams,
• Michael I. Faley,
• Joseph Vimal Vas,
• Peng-Han Lu and
• Rafal E. Dunin-Borkowski

Beilstein J. Nanotechnol. 2024, 15, 1–12, doi:10.3762/bjnano.15.1

• submicrometer apertures were milled on SiN membranes using a focused ion beam. Furthermore, we have developed a new TEM sample preparation method, where we fabricated Py nanostructures on a bulk substrate with a SiN buffer layer and etched the substrate to create a thin SiN membrane under the Py nanostructure

• , we initially fabricated the nanostructures on a 200 µm thick Si substrate with 100 nm thick SiN buffer layers on both sides. The buffer layers were deposited with low-pressure CVD to ensure stress-free films. The fabrication process is shown in Figure 10. First, we made the nanostructure using lift

• -off or IBE methods on the bulk substrate. Then we protected the nanostructure with a resist and patterned AZ®5214E resist on the back side of the substrate using the image reversal technique. A window in the SiN buffer layer was prepared by ion beam etching through the aperture in the mask of AZ®5214E

Determination of the radii of coated and uncoated silicon AFM sharp tips using a height calibration standard grating and a nonlinear regression function

• Perawat Boonpuek and
• Jonathan R. Felts

Beilstein J. Nanotechnol. 2023, 14, 1200–1207, doi:10.3762/bjnano.14.99

• measured using a tip characterizer and tip qualification or standard calibration grating. In one of those studies, the tip geometry was determined by using a well-known sharp-edged silicon structure, which included height patterns with a certified pitch on a nanostructure plate [10]. Three types of AFM

• mode with very light loading (0.01 nN) to prevent the tips from wear. The noise effect was not considered here, because the measurement was conducted inside the hood of a MFP-3D Origin (Asylum Research) with noise filter system. Considering the geometry of the nanostructure and the scanline signal

A combined gas-phase dissociative ionization, dissociative electron attachment and deposition study on the potential FEBID precursor [Au(CH₃)₂Cl]₂

• Elif Bilgilisoy,
• Ali Kamali,
• Thomas Xaver Gentner,
• Gerd Ballmann,
• Sjoerd Harder,
• Hans-Peter Steinrück,
• Hubertus Marbach and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2023, 14, 1178–1199, doi:10.3762/bjnano.14.98

Hierarchically patterned polyurethane microgrooves featuring nanopillars or nanoholes for neurite elongation and alignment

• Lester Uy Vinzons,
• Guo-Chung Dong and
• Shu-Ping Lin

Beilstein J. Nanotechnol. 2023, 14, 1157–1168, doi:10.3762/bjnano.14.96

• , the question arises: Can discrete structures be combined with continuous structures for possible synergistic effects? Indeed, several studies have fabricated hierarchical discrete nanostructures on continuous microstructures in order to better mimic the micro- and the nanostructure of the native nerve

• ), indicating dominance of the nanostructure properties in this direction. In contrast, the CA values were higher and remained quite close to each other in magnitude even after O2 plasma treatment, signifying the dominance of the microgroove properties in this orientation. Despite the relatively high CA

Density functional theory study of Au-fcc/Ge and Au-hcp/Ge interfaces

• Olga Sikora,
• Małgorzata Sternik,
• Benedykt R. Jany,
• Franciszek Krok,
• Przemysław Piekarz and
• Andrzej M. Oleś

Beilstein J. Nanotechnol. 2023, 14, 1093–1105, doi:10.3762/bjnano.14.90

• candidate for the observed nanostructure. However, a detailed analysis of the scattered intensity of atomic columns [23] suggests that the rows of Au atoms are located directly above the rows of Ge atoms. We therefore built variant D of the heterostructure, with 102 atoms (42 Ge and 60 Au), and the

Properties of tin oxide films grown by atomic layer deposition from tin tetraiodide and ozone

• Kristjan Kalam,
• Peeter Ritslaid,
• Tanel Käämbre,
• Aile Tamm and
• Kaupo Kukli

Beilstein J. Nanotechnol. 2023, 14, 1085–1092, doi:10.3762/bjnano.14.89

• have been studied from many perspectives. For example, one can mention anodes for Li-ion batteries [1], gas sensors [2], catalytic activities [3], and stable buffer [4] or base [5] layers in solar cells. More applications can be found, when SnO2 is considered as constituent of a nanostructure or a

Exploring internal structures and properties of terpolymer fibers via real-space characterizations

• Michael R. Roenbeck and
• Kenneth E. Strawhecker

Beilstein J. Nanotechnol. 2023, 14, 1004–1017, doi:10.3762/bjnano.14.83

• through real-space mapping. Complementing these full-fiber scans, high-resolution topography and stiffness maps on smaller fiber subdomains were also obtained to study the nanostructure of Technora®. From detailed topography maps, we found that the well-aligned surface features observed on the full

• findings provide quantitative details about the branched network of fibrils that defines the nanostructure of Technora®. Technora® vs Kevlar® K29 To further highlight the unique internal nanostructure of Technora®, we compare topography and stiffness maps of Technora® to the more widely studied Kevlar® K29

• contextualize several aspects related to our findings. First, we describe how this real-space characterization provides new information about the Technora® fiber nanostructure. We then focus on fiber microstructures, highlighting how this technique expands upon conclusions from previous studies. Lastly, we

Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• interpret and can be calculated quickly without the involvement of expert personnel. These descriptors simplify the nanostructure property calculation and determine the nanoscale interactions without much computational intervention. The use of such descriptors saves time; the descriptors are also cost

Biomimetics on the micro- and nanoscale – The 25th anniversary of the lotus effect

• Matthias Mail,
• Kerstin Koch,
• Thomas Speck,
• William M. Megill and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 850–856, doi:10.3762/bjnano.14.69

• paper “The origin of black and white coloration of the Asian tiger mosquito Aedes albopictus (Diptera, Culicidae)” analysed the reflectance spectra of the white scales as well as the micro- and nanostructure of the black and white scales on the tarsi of A. albopictus. The results show that the white

• colour is produced by the hierarchical micro- and nanostructure of the surface. The reflection of light depends on the angle of incidence. In addition to superhydrophobicity, these results suggest that the scales have another function – their hierarchical structures produce the brilliant white colour