Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• temperature and reactivity. With broad applications in therapy [22][23], laser combined imaging, solar vapour generation [24], and biosensors [25], the global market for PT devices is expected to be a multimillion dollar enterprise by 2025 [26]. This review will focus on concepts such as the theoretical

Solvent-induced assembly of mono- and divalent silica nanoparticles

• Bin Liu,
• Etienne Duguet and
• Serge Ravaine

Beilstein J. Nanotechnol. 2023, 14, 52–60, doi:10.3762/bjnano.14.6

• -controlled step-growth polymerization, in which the reactivity of the patches is independent of the chain length [38]. At longer times (t > 2 h), one can observe that no longer varies linearly with time (Figure 6b). The polymerization of 2-PSN seems to follow a different pathway that is, most likely, a

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• constants and the half-lives are summarized in Table 2. Significant differences in reactivity were observed for phenol and DBMP. The dissociation constant (pKa) of DBMP is approx. 7.21, hence, almost 90% of the DBMP was dissociated at pH 8, while phenol was mainly (98%) undissociated (Figure 3). The high

• the given reaction conditions (89% of DBMP was dissociated vs only 13% of phenol). The presence of hydroxyl radicals in the solution and a higher reactivity of phenoxide ions compared to that of undissociated forms contributed to a higher degradation efficiency of DBMP in ozonolysis. DBMP is easier to

Hydroxyapatite–bioglass nanocomposites: Structural, mechanical, and biological aspects

• Olga Shikimaka,
• Mihaela Bivol,
• Bogdan A. Sava,
• Marius Dumitru,
• Christu Tardei,
• Beatrice G. Sbarcea,
• Daria Grabco,
• Constantin Pyrtsac,
• Daria Topal,
• Andrian Prisacaru,
• Vitalie Cobzac and
• Viorel Nacu

Beilstein J. Nanotechnol. 2022, 13, 1490–1504, doi:10.3762/bjnano.13.123

• glass in the HA-BG composites may stimulate the transformation of HA into tricalcium phosphate (TCP) during the sintering at high temperatures, inducing more reactivity of the material in the physiologic environment [4][20]. The HA-TCP transformation can be controlled through the glass fraction and the

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• /storage due to their reactivity, surface area, and advantageous features compared to their bulk counterparts [2][3][4]. In recent years, many efforts have increased the photocatalytic performance. However, the relative photocatalytic performance is still deficient, and it does not fulfil the criteria for

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• surfaces. This is attributed to the stronger Ti–Cl bonds in TiCl4 compared to Ti–N bonds in Ti(DMA)4. Ti(DMA)4 also shows high reactivity to the organics compared to TiCl4. Double reactions of EG and GL with the TiCl3 species from TiCl4 and TiDMA species from Ti(DMA)4 are also explored to better understand

• Ti–N bond compared to the Ti–Cl bond and hence a higher reactivity for the Ti(DMA)4 precursor towards the surface and towards the co-reactant is expected. In addition, due to the bulky DMA ligands of Ti(DMA)4, the “reservior” effect, which is very common for small molecules such as TiCl4 [30], DEZ

• , respectively. The results are attributed the higher reactivity of the OH group with TiCl4 in comparison to the NH2 group and the higher tendency of the heterobifunctional organic precursor to orientate in an upright configuration and avoid unwanted double reactions on the surface [42]. TiCl4 was also coupled

Recent advances in green carbon dots (2015–2022): synthesis, metal ion sensing, and biological applications

• Aisha Kanwal,
• Naheed Bibi,
• Sajjad Hyder,
• Arif Muhammad,
• Hao Ren,
• Jiangtao Liu and
• Zhongli Lei

Beilstein J. Nanotechnol. 2022, 13, 1068–1107, doi:10.3762/bjnano.13.93

Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media

• Iyyappan Madakannu,
• Indrajit Patil,
• Bhalchandra Kakade and
• Kasibhatta Kumara Ramanatha Datta

Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89

• effects, and carbon monoxide poisoning [16][17]. The electrocatalytic reactivity (mechanism and kinetics) of silver has similarities to that of Pt regarding the ORR performance, with considerably high onset potential, half-wave potential, current density, and number of transferred electrons. The important

DNA aptamer selection and construction of an aptasensor based on graphene FETs for Zika virus NS1 protein detection

• Nathalie B. F. Almeida,
• Thiago A. S. L. Sousa,
• Viviane C. F. Santos,
• Camila M. S. Lacerda,
• Thais G. Silva,
• Rafaella F. Q. Grenfell,
• Flavio Plentz and
• Antero S. R. Andrade

Beilstein J. Nanotechnol. 2022, 13, 873–881, doi:10.3762/bjnano.13.78

• where more than one flavivirus co-circulates and YFV vaccination is mandatory. The traditional serological approaches present relatively high antigenic cross-reactivity. Molecular techniques have been successfully applied for flavivirus infection diagnosis offering the advantages of speed, sensitivity

• detection. Results and Discussion A simple, economical, sensitive, and specific diagnostic test is required to help to control flavivirus infections. The serological approaches currently available are limited due to the cross-reactivity between the members of the Flavivirus genus. Molecular diagnosis

• and is the same as found in biological samples. To obtain aptamers specific for the ZIKV NS1 protein, counterselections with NS1 proteins of DENV (serotypes 1, 2, 3, and 4) and YFV were included. Carrying out counterselections with homologous proteins is advantageous to avoid cross-reactivity. By this

Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• increase of the interfacial energy as a function of the temperature, which can be explained by the reactivity between SiOx and Ga and the occurrence of chemical segregation at the liquid alloy surface. Keywords: atomic force microscopy (AFM); interfacial energy; liquid alloy; Introduction Recently, room

• could be tuned by texturing the substrate surface. The wetting of gallium-based liquid alloys is thus complex and depends on the stability of the oxide at the liquid–substrate interface, the reactivity with the substrate material, and the substrate topography. In this work, we applied atomic force

• depend on the chemistry of the asperities. Furthermore, we observe a weak increase of the interfacial energy as a function of the temperature. We discuss our results based on the reactivity between SiOx and Ga and the occurrence of chemical segregation at the liquid alloy surface. Experimental We

Optimizing PMMA solutions to suppress contamination in the transfer of CVD graphene for batch production

• Chun-Da Liao,
• Andrea Capasso,
• Tiago Queirós,
• Telma Domingues,
• Fatima Cerqueira,
• Nicoleta Nicoara,
• Jérôme Borme,
• Paulo Freitas and
• Pedro Alpuim

Beilstein J. Nanotechnol. 2022, 13, 796–806, doi:10.3762/bjnano.13.70

• stability and impermeability to gases and liquids. In contrast, the surrounding exposed areas of the Cu foil surface exhibited high reactivity and were readily oxidized to copper oxides with a noticeable color change. The apparent color contrast between the oxidized and non-oxidized Cu surfaces made the

Hierarchical Bi₂WO₆/TiO₂-nanotube composites derived from natural cellulose for visible-light photocatalytic treatment of pollutants

• Zehao Lin,
• Zhan Yang and
• Jianguo Huang

Beilstein J. Nanotechnol. 2022, 13, 745–762, doi:10.3762/bjnano.13.66

• method for the reduction of Cr(VI) into Cr(III) due to its high efficiency, energy-saving, and nonpolluting advantages [4]. Among the various photocatalysts, traditional titania (TiO2) photocatalysts have received great attention due to their high reactivity, excellent stability, and nontoxicity [5][6][7

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• found that nps smaller than 100 nm produce more ROS due to their higher surface area [29]. Properties of nps such as surface charge density and zeta potential are influential in determining their reactivity, agglomeration properties, interaction with cells, stability in complex media, and adsorption of

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

Biocompatibility and cytotoxicity in vitro of surface-functionalized drug-loaded spinel ferrite nanoparticles

• Sadaf Mushtaq,
• Khuram Shahzad,
• Tariq Saeed,
• Anwar Ul-Hamid,
• Bilal Haider Abbasi,
• Nafees Ahmad,
• Waqas Khalid,
• Muhammad Atif,
• Zulqurnain Ali and
• Rashda Abbasi

Beilstein J. Nanotechnol. 2021, 12, 1339–1364, doi:10.3762/bjnano.12.99

• , magnetite NPs have some serious limitations, such as chemical reactivity, rapid oxidation, particle agglomeration, and high surface energy which may affect their biocompatibility and performance [11]. Moreover, they have low magnetization at a smaller size and the presence of iron has been associated with

Identifying diverse metal oxide nanomaterials with lethal effects on embryonic zebrafish using machine learning

• Richard Liam Marchese Robinson,
• Haralambos Sarimveis,
• Philip Doganis,
• Xiaodong Jia,
• Marianna Kotzabasaki,
• Christiana Gousiadou,
• Stacey Lynn Harper and
• Terry Wilkins

Beilstein J. Nanotechnol. 2021, 12, 1297–1325, doi:10.3762/bjnano.12.97

• characteristics related to intermolecular interactions, which could affect agglomeration or uptake by cells, and reactivity, which could trigger toxicity. (Dummy values, lower than the minimum of observed values, were inserted where the corresponding coating was absent, in keeping with recommended practice [45

pH-driven enhancement of anti-tubercular drug loading on iron oxide nanoparticles for drug delivery in macrophages

• Karishma Berta Cotta,
• Sarika Mehra and
• Rajdip Bandyopadhyaya

Beilstein J. Nanotechnol. 2021, 12, 1127–1139, doi:10.3762/bjnano.12.84

• aqueous solution to Fe present on the surface of the nanoparticles. Such Fe–OH associations are often found on iron oxide nanoparticles due to their high reactivity [28][35]. Characteristic peaks for NOR observed at 1258 cm−1, 1615 cm−1, 1734 cm−1, 2852 cm−1 and 3418 cm−1 in Figure 2f are indicative of

Use of nanosystems to improve the anticancer effects of curcumin

• Andrea M. Araya-Sibaja,
• Norma J. Salazar-López,
• Krissia Wilhelm Romero,
• José R. Vega-Baudrit,
• J. Abraham Domínguez-Avila,
• Carlos A. Velázquez Contreras,
• Ramón E. Robles-Zepeda,
• Mirtha Navarro-Hoyos and
• Gustavo A. González-Aguilar

Beilstein J. Nanotechnol. 2021, 12, 1047–1062, doi:10.3762/bjnano.12.78

• is distributed within a polymeric matrix (i.e., surrounded by the polymer) they are referred to as nanocapsules. Alternatively, if the drug is homogeneously dispersed in the polymeric matrix they are called nanospheres [78][79]. Their main advantages include their reactivity, surface area, stability

Revealing the formation mechanism and band gap tuning of Sb₂S₃ nanoparticles

• Maximilian Joschko,
• Franck Yvan Fotue Wafo,
• Christina Malsi,
• Danilo Kisić,
• Ivana Validžić and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 1021–1033, doi:10.3762/bjnano.12.76

• compound, the highest reactivity was reached. However, TMS is toxic and also costly compared to the widely used elemental sulfur, limiting a broad use in the preparation of Sb2S3 materials [19]. Li et al. have performed mechanistic studies on the temperature dependency of Sb2S3 nanoparticles in the range

• application. In the present work, a hot-injection approach at a moderate temperature (150 °C) is presented. The reaction was analyzed in the time sections from 30 s to 30 h. The precursor S-OlAm was selected to achieve a high reactivity while avoiding toxic substances such as TMS. A relatively low injection

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• this technology has currently developed and where future research could be directed at. Review Conventional sulfur–carbon cathode materials Sulfur–carbon composites are the most widely studied cathode materials because carbon increases the cathode conductivity and also improves the reactivity of sulfur

• cathode is reported to display a capacity of 153 mAh·g−1 after 500 cycles at 1C [39], while the latter has 257 mAh·g−1 after 200 cycles at 1C [40]. This problem is a consequence of the low sulfur content of the polymer, which is usually less than 50 wt % and the limited redox reactivity of sulfur [38][41

• ]. In order to overcome the consequences of the limited reactivity, a small amount of selenium can be added to the cathode and uniformly distributed through selenium–sulfur bonds. A significant improvement in redox reaction kinetics is achieved since selenium has a higher conductivity than sulfur and

Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• layer; molecular self-assembly; scanning probe microscopy; surface science; Over the past two decades, organic molecules adsorbed on atomically defined metal surfaces have been intensively studied to obtain an in-depth understanding of their self-assembly behavior, on-surface reactivity, as well as

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• oxide nanoparticles [28]. Numerous indispensable parameters including surface tension, polarity, viscosity, and hydrogen bonding have an important influence on the reactivity of species. Also, the formation of nanostructures is governed by the mass transport properties of the DES components. It is also

Impact of GaAs(100) surface preparation on EQE of AZO/Al₂O₃/p-GaAs photovoltaic structures

• Piotr Caban,
• Rafał Pietruszka,
• Jarosław Kaszewski,
• Monika Ożga,
• Bartłomiej S. Witkowski,
• Krzysztof Kopalko,
• Piotr Kuźmiuk,
• Katarzyna Gwóźdź,
• Ewa Płaczek-Popko,
• Krystyna Lawniczak-Jablonska and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 578–592, doi:10.3762/bjnano.12.48

• [3]. Due preparation of the substrate, seems to be one of the most important aspects here as the oxide-based states of the GaAs surface are known to adversely affect device performance. Thus, in this present work we focus on the methods to limit their role. Reactivity of the surface of gallium

Influence of electrospray deposition on C₆₀ molecular assemblies

• Antoine Hinaut,
• Sebastian Scherb,
• Sara Freund,
• Zhao Liu,
• Thilo Glatzel and
• Ernst Meyer

Beilstein J. Nanotechnol. 2021, 12, 552–558, doi:10.3762/bjnano.12.45

• reactivity of the surface, the presence of defects, already reported [37] and visible as small holes, should be noted. C60 on the surface can easily be identified as large bright areas corresponding to monolayer islands. These islands show irregular contour paths without preferential orientation as well as

The preparation temperature influences the physicochemical nature and activity of nanoceria

• Robert A. Yokel,
• Wendel Wohlleben,
• Johannes Georg Keller,
• Matthew L. Hancock,
• Jason M. Unrine,
• D. Allan Butterfield and
• Eric A. Grulke

Beilstein J. Nanotechnol. 2021, 12, 525–540, doi:10.3762/bjnano.12.43

• from partial nanoceria dissolution led to less cellular protein carbonyl formation, attributed to an increased amount of surface Ce3+ species. Surface reactivity was greater for the solvothermally synthesized nanoceria, which had more Ce3+ species at the surface. The results show that temperature

• applications), the influence of carboxylic acids and immobilized phosphate on their dissolution, the influence of nanoceria after partial dissolution on a selected biological effect, and the surface reactivity. Based on reports of very limited NM-212 dissolution and physicochemical differences between

• of nanoceria dissolution on its biological identity was assessed as the protein carbonyl level in response to partially dissolved nanoceria. The catalytic potential was assessed using a reactivity assay. Experimental Materials NM-211 and NM-212 were obtained from the European Commission Joint