Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• , size and magnetic nature enables them to kill microorganisms through the application of an external magnetic field, resulting in an increase of the therapeutic antimicrobial properties, especially when compared to conventional antimicrobial compounds [136]. Ferromagnetic nanoparticles are probably the

• -volume ratio, increasing the surface of the atoms [19]. In addition, when a magnetic field is applied the magnetic moments of these ferromagnetic FeO NPs become aligned. The surface of the SPIONs can be modified to specifically improve their functionality as antimicrobial compounds by increasing their

• modification, intrinsic properties and the type of targeted microorganism [18]. A special category of metallic NPs is superparamagnetic iron-oxide nanoparticles (SPIONs) (e.g., magnetite (Fe3O4) and maghemite (γ-Fe2O3) NPs) whose antimicrobial activity increases upon the application of an external magnetic

Transient coating of γ-Fe₂O₃ nanoparticles with glutamate for its delivery to and removal from brain nerve terminals

• Konstantin Paliienko,
• Artem Pastukhov,
• Michal Babič,
• Daniel Horák,
• Olga Vasylchenko and
• Tatiana Borisova

Beilstein J. Nanotechnol. 2020, 11, 1381–1393, doi:10.3762/bjnano.11.122

• identified. Glutamate-coated γ-Fe2O3 nanoparticles can be used for glutamate delivery to the nervous system or for glutamate adsorption (but with lower effectiveness) in stroke, brain trauma, epilepsy, and cancer treatment following by its subsequent removal using a magnetic field. γ-Fe2O3 nanoparticles with

• concentrations were mixed with abovementioned components along with different amounts of γ-Fe2O3 nanoparticles also added to the probe. The incubation time was 5 min in the salt solutions and 30 min in blood plasma or albumin. After that a magnetic field was applied or the nanoparticles were sedimented in a

• -[14C]glutamate, the γ-Fe2O3 nanoparticles were isolated from the incubation medium using a magnetic field (250 mT, gradient 5.5 Т/m). Alternatively, the nanoparticles were sedimented in a microcentrifuge (10 min at 13,000g). After removal of the nanoparticles from the incubation media, they were washed

Controlling the proximity effect in a Co/Nb multilayer: the properties of electronic transport

• Sergey Bakurskiy,
• Mikhail Kupriyanov,
• Nikolay V. Klenov,
• Igor Soloviev,
• Andrey Schegolev,
• Roman Morari,
• Yury Khaydukov and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1336–1345, doi:10.3762/bjnano.11.118

• distribution appears in the screening of F-layers in multilayer structures from an outer magnetic field due to the Meissner effect. The inner F-layers are strongly screened while the opposite is observed for the outer layers. This means that the remagnetization of the layers in an increasing homogeneous

• external magnetic field do not occur simultaneously, but instead gradually from the outer to the inner layers of the structure. The calculated distribution of the anomalous Green’s function, F, allows for the estimation of the screening properties of the hybrid structure. The spatial distribution of the

• changes in the temperature or in the applied magnetic field [9] can significantly change (from zero to relatively large values) the kinetic inductance of thin s-layers in the hybrid structures studied in this work. Experimental results The next step was to experimentally verify the significant changes

Magnetohydrodynamic stagnation point on a Casson nanofluid flow over a radially stretching sheet

• Ganji Narender,
• Kamatam Govardhan and
• Gobburu Sreedhar Sarma

Beilstein J. Nanotechnol. 2020, 11, 1303–1315, doi:10.3762/bjnano.11.114

• article proposes a numerical model to investigate the impact of the radiation effects in the presence of heat generation/absorption and magnetic field on the magnetohydrodynamics (MHD) stagnation point flow over a radially stretching sheet using a Casson nanofluid. The nonlinear partial differential

• transfer are examined. The coordinate system is chosen such that the r-axis is along the direction of the flow whereas the z-axis is perpendicular to the flow direction (Figure 1). The velocity of the outer flow is designated as Ue and the direction of the uniform magnetic field is chosen to be normal to

• distributions. For high values for Ha, the fluid velocity decreases while the temperature and concentration of the fluid increase. This stems from the fact that an opposing force generated by the magnetic field, generally referred to as the Lorentz force, reduces the fluid motion, resulting in a reduction in

Proximity effect in [Nb(1.5 nm)/Fe(x)]₁₀/Nb(50 nm) superconductor/ferromagnet heterostructures

• Yury Khaydukov,
• Sabine Pütter,
• Laura Guasco,
• Roman Morari,
• Gideok Kim,
• Thomas Keller,
• Anatolie Sidorenko and
• Bernhard Keimer

Beilstein J. Nanotechnol. 2020, 11, 1254–1263, doi:10.3762/bjnano.11.109

• experiments we applied a magnetic field in-plane and normal to the sample plane. Data were fitted to models using the exact solutions of the Schrödinger equation as described in our prior works [13][40][41]. For the transport experiment we used the device depicted in Figure 1b. The device consists of four

• in this work we used it ex situ. For the measurements we used an ac current with an amplitude of 100–200 μA. In the experiment we measured the resistance of the samples as a function of the temperature T and the magnetic field H, which was applied parallel to the sample surface. Before every H scan

• cooling to T = 8.2 K. Below this temperature a decrease of the magnetic moment due to the Meissner effect is observed. Polarized neutron reflectometry Figure 5a shows reflectivity curves measured on sample s3 at a temperature of T = 13 K in a magnetic field of H = 4.5 kOe. The curves are characterized by

Ultrasensitive detection of cadmium ions using a microcantilever-based piezoresistive sensor for groundwater

• Dinesh Rotake,
• Anand Darji and
• Nitin Kale

Beilstein J. Nanotechnol. 2020, 11, 1242–1253, doi:10.3762/bjnano.11.108

• only on absorption and fluorescence change and need dynamic acquisition [23]. A magnetic field powered pressure sensor proposed by Khan et al. [24] is capable of measuring pressure in the range of kilopascals but the suitability for the very low pressure caused by HMIs needs to be examined. A reduced

Magnetic-field-assisted synthesis of anisotropic iron oxide particles: Effect of pH

• Andrey V. Shibaev,
• Petr V. Shvets,
• Darya E. Kessel,
• Roman A. Kamyshinsky,
• Anton S. Orekhov,
• Sergey S. Abramchuk,
• Alexei R. Khokhlov and
• Olga E. Philippova

Beilstein J. Nanotechnol. 2020, 11, 1230–1241, doi:10.3762/bjnano.11.107

• University, Albert-Einstein-Allee 11, 89069 Ulm, Germany 10.3762/bjnano.11.107 Abstract The synthesis of magnetite (Fe3O4) nanorods using reverse co-precipitation of Fe3+ and Fe2+ ions in the presence of a static magnetic field is reported in this work. The phase composition and crystal structure of the

• properties and a larger length-scale of the locally induced magnetic field in comparison to nanospheres with a similar volume, providing an enhanced MRI contrast [11][19][23], higher specific adsorption rate in magnetic hyperthermia [13], and better separation efficiency in magnetic separation of immune

• oxide. It consists of co-precipitating Fe3+ and Fe2+ ions upon exposure to an external magnetic field, which is used as a template for directional nanoparticle growth. Note that in the absence of a magnetic field, the same reagents yield spherical nanoparticles [30]. Hence, one can conclude that the

Influence of the magnetic nanoparticle coating on the magnetic relaxation time

• Mihaela Osaci and
• Matteo Cacciola

Beilstein J. Nanotechnol. 2020, 11, 1207–1216, doi:10.3762/bjnano.11.105

• Langevin dynamics method was applied based on the effective Verlet-type algorithm. The Néel magnetic relaxation time was obtained via the Coffey method in an oblique magnetic field, adapted to the local magnetic field on a nanoparticle. Keywords: colloidal system; effective Verlet-type algorithm; magnetic

• . Upon reaching the tumour, the magnetic nanoparticles are locally subjected to an alternating magnetic field, generating heat that kills the cancer cells [1]. The heat is generated due to two phenomena: Néel relaxation (an internal phenomenon driven by the rotation of the particle magnetic moment inside

• the particle) and Brown relaxation (an external phenomenon driven by the rotation of the nanoparticle along the magnetic moment). Both internal and external sources of friction lead to a delay in the orientation of the particle magnetic moment in the direction of the applied magnetic field, thus

3D superconducting hollow nanowires with tailored diameters grown by focused He⁺ beam direct writing

• Rosa Córdoba,
• Alfonso Ibarra,
• Dominique Mailly,
• Isabel Guillamón,
• Hermann Suderow and
• José María De Teresa

Beilstein J. Nanotechnol. 2020, 11, 1198–1206, doi:10.3762/bjnano.11.104

• is present along the whole nanowire length. Moreover, these nanowires become superconducting at 6.8 K and show high values of critical magnetic field and critical current density. Consequently, these 3D nano-objects could be implemented as components in the next generation of electronics, such as

• magnetic field (µ0Hc2(0)) up to 9.5 T [14][15][16]. Alternatively, in combination with Nb(NMe2)3(N-t-Bu), Ga+ FIBID yielded NbC wires with a broadened Tc range from 4 to 11 K [18]. One significant limitation is that 3D elements below 100 nm in diameter cannot be obtained with Ga+ FIBID, mainly due to the

• Ti pads. Finally, we made four-point-probe electrical measurements at low temperature (down to 0.5 K) and under a magnetic field perpendicular to the substrate plane (up to 9 T). The NWs change from the normal to the superconducting state at Tc (0.5RN) values between 5.45 and 6.78 K (Figure 6a and

Applications of superparamagnetic iron oxide nanoparticles in drug and therapeutic delivery, and biotechnological advancements

• Maria Suciu,
• Corina M. Ionescu,
• Alexandra Ciorita,
• Septimiu C. Tripon,
• Dragos Nica,
• Hani Al-Salami and
• Lucian Barbu-Tudoran

Beilstein J. Nanotechnol. 2020, 11, 1092–1109, doi:10.3762/bjnano.11.94

• behave like one magnetic unit, rotating in the presence of a magnetic field without retaining the magnetism after the magnetic field is removed [17]. This property makes SPIONs good candidates for MRI, and also for a type of thermic treatment of cancer, called localized hyperthermia. There are also other

• pool (ferritin and transferrin) for normal metabolic activities [20]. In localized hyperthermia, SPIONs generate heat by constantly aligning to an alternating magnetic field. This heat is rapidly transferred to the surrounding cancerous tissue in which proteins denature and, consequently, cells become

• alternating magnetic field [30]. Currently, it is used only as an alternative therapy and nearly always in combination with other therapies [34]. Results have shown that even non-magnetic hyperthermia (water-bath method) using SPIONs has cytotoxic effects [35]. Many studies focus on the potential of SPIONs as

Wet-spinning of magneto-responsive helical chitosan microfibers

• Dorothea Brüggemann,
• Johanna Michel,
• Naiana Suter,
• Matheus Grande de Aguiar and
• Michael Maas

Beilstein J. Nanotechnol. 2020, 11, 991–999, doi:10.3762/bjnano.11.83

• . This strategy is based on wet-spinning of magnetic fibers, which are collected on a rotating needle controlled by an external magnetic field with a predefined helical geometry. The fibers were characterized regarding their morphology, microstructure, magnetization and mechanical characteristics. These

• flat as a result of their soft nature during the winding process (Figure 3A). This appearance resembled the morphology of helical alginate microfibers, where fiber shaping was achieved by micromanipulation in a magnetic field [47]. In comparison to the aforementioned work [47] and also to the 3D

• obtained at a magnetic field strength of 40 × 103 Gs using 72 points per loop with a scan speed of 10 s per point. The range covered during the hysteresis scan was between +22 × 103 Oe and −22 × 103 Oe. During the scans, the magnetic field was measured with a FCM-10 control module and the magnetization

Effect of magnetic field, heat generation and absorption on nanofluid flow over a nonlinear stretching sheet

• Santoshi Misra and
• Govardhan Kamatam

Beilstein J. Nanotechnol. 2020, 11, 976–990, doi:10.3762/bjnano.11.82

• the influence of varied dimensionless parameters has been the focus of research in contemporary times. This work models the effect of magnetic field, heat generation and absorption parameter in a steady, laminar, two-dimensional boundary layer flow of a nanofluid over a permeable stretching sheet at a

• –corrector method is employed to solve the equations. The impact of the dimensionless parameters, including the Brownian motion, thermophoresis, magnetic field, heat generation and absorption parameters, on the velocity, temperature and nanoparticle concentration of fluid flow are analysed systematically

• . Keywords: Brownian motion; heat generation and absorption; magnetic field; nanofluid; thermophoresis; Introduction The study of magnetohydrodynamic problems, such as nanofluid flow over a permeable stretching sheet, has recently become relevant due to potential applications in various fields of science

A Josephson junction based on a highly disordered superconductor/low-resistivity normal metal bilayer

• Pavel M. Marychev and
• Denis Yu. Vodolazov

Beilstein J. Nanotechnol. 2020, 11, 858–865, doi:10.3762/bjnano.11.71

• NbN/Al, NbN/Ag and MoN/Ag bilayers. Namely, the suppression of the critical temperature of the SN bilayer is smaller while the change in magnetic field penetration depth of the SN bilayer is larger than the Usadel model predicts. Therefore, the present results should be considered only as a route for

• Equation 12). SN-S-SN junctions made of a NbN/Al bilayer have been fabricated recently [26] and indications of the Josephson effect (the presence of Shapiro steps and a Fraunhofer-like dependence of the critical current on the magnetic field) have been observed. But due to not optimized parameters (dS = dc

Epitaxial growth and superconducting properties of thin-film PdFe/VN and VN/PdFe bilayers on MgO(001) substrates

• Wael M. Mohammed,
• Igor V. Yanilkin,
• Amir I. Gumarov,
• Airat G. Kiiamov,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2020, 11, 807–813, doi:10.3762/bjnano.11.65

• . Saturation magnetization Ms(T) as a function of the temperature of the Pd0.96Fe0.04/VN (green symbols) and VN/Pd0.92Fe0.08 (red symbols) heterostructures measured in a magnetic field of 200 Oe. Temperature dependence of the electrical resistance of the VN film and the Pd0.96Fe0.04/VN and VN/Pd0.92Fe0.08

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• ) characterization and generation using ions, electrons or other irradiation methods, the observation of ensemble paramagnetic properties and their optically detected magnetic resonance by applying a high magnetic field until the isolation of single defects and eventually their optical spin coherent control. Weber

Observation of unexpected uniaxial magnetic anisotropy in La_2/3Sr_1/3MnO₃ films by a BaTiO₃ overlayer in an artificial multiferroic bilayer

• John E. Ordóñez,
• Lorena Marín,
• Luis A. Rodríguez,
• Pedro A. Algarabel,
• José A. Pardo,
• Roger Guzmán,
• Luis Morellón,
• César Magén,
• Etienne Snoeck,
• María E. Gómez and
• Manuel R. Ibarra

Beilstein J. Nanotechnol. 2020, 11, 651–661, doi:10.3762/bjnano.11.51

• using the pulsed-laser deposition technique. We analyzed the films structurally through X-ray reciprocal space maps and high-angle annular dark field microscopy, and magnetically via thermal demagnetization curves and in-plane magnetization versus applied magnetic field loops at room temperature. Our

• geometric phase analysis (GPA) method on HAADF-STEM images. We magnetically analyzed samples by performing room-temperature polar plots of the remnant field, where we applied magnetic field on the plane of the sample along different directions. Results and Discussion Figure 1 displays RSMs taken around the

• each case. Figure 3 displays isothermal room temperature loops of the normalized magnetization (M(H)/Ms) as a function of the applied magnetic field for 27 nm thick LSMO films (plots to the left), and for BTO (140 nm)/LSMO (27 nm) bilayers (plots to the right) grown on STO (plots on the top), LSAT

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

• Varsha Sharma and
• Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

• efforts were also made to release the payload under the exposure of external (modern) triggers such as laser light, ultrasound, magnetic field, enzymatic deformation and mechanical deformation. In the latter cases, the capsules were irreversibly ruptured and released the loaded molecules either in a burst

Nanoparticles based on the zwitterionic pillar[5]arene and Ag⁺: synthesis, self-assembly and cytotoxicity in the human lung cancer cell line A549

• Dmitriy N. Shurpik,
• Denis A. Sevastyanov,
• Pavel V. Zelenikhin,
• Pavel L. Padnya,
• Vladimir G. Evtugyn,
• Yuriy N. Osin and
• Ivan I. Stoikov

Beilstein J. Nanotechnol. 2020, 11, 421–431, doi:10.3762/bjnano.11.33

• echo (STE) bipolar gradient pulse pair (stebpgp1s) pulse sequence with 16 scans of 16 data points collected. The maximum gradient strength produced in the z direction was 5.35 G mm−1. The duration of the magnetic field pulse gradients (δ) was optimized for each diffusion time (Δ) in order to obtain a 2

High dynamic resistance elements based on a Josephson junction array

• Konstantin Yu. Arutyunov and
• Janne S. Lehtinen

Beilstein J. Nanotechnol. 2020, 11, 417–420, doi:10.3762/bjnano.11.32

• necessary, a small magnetic field, up to 0.05 T, was applied using small superconducting coils wound directly on the sample holder cap. Results and Discussion The ultimate goal of this work is to study the quantum dynamics of the QPSJ, a system dual to JJ [3], including the observation of Coulomb blockade

• the SQUID-based approach requires application of a finite magnetic field. Given that the electromagnetic horizon of our QPSJ is of the order of ≈100 μm [23][24][25], the corresponding high-impedance current biasing circuit should be of appropriate (small) dimensions. Thus the area of the SQUID is

• small, and hence a magnetic field corresponding to Φ/Φ0 → π/2 can easily reach the ≈10 mT range. At such a magnetic field, two undesirable effects might happen both with the biasing superconducting leads and with the QPSJ. Namely, the formation of Abrikosov vortices and a noticeable suppression of the

Nonequilibrium Kondo effect in a graphene-coupled quantum dot in the presence of a magnetic field

• Levente Máthé and
• Ioan Grosu

Beilstein J. Nanotechnol. 2020, 11, 225–239, doi:10.3762/bjnano.11.17

• value even at the Dirac point. The influence of the on-site Coulomb interaction and the magnetic field on the transport properties of the system shows a tendency similar to the previous results obtained for quantum dots connected to metallic electrodes. Most remarkably, we find that the Kondo resonance

• graphene-based quantum dot system provides a platform for potential applications of nanoelectronics. Furthermore, we also propose an experimental setup for performing measurements in order to verify our model. Keywords: graphene; Kondo effect; magnetic field; pseudogap Anderson model; quantum dot

• ][41][42][43][44][45] with the equation of motion (EOM) technique [46][47][48]. In our studies, a magnetic field is applied to the QD causing a Kondo resonance splitting, and a finite on-site Coulomb interaction (U) is considered resulting in a shift of the main QD energy level. Furthermore, an

Plasmonic nanosensor based on multiple independently tunable Fano resonances

• Lin Cheng,
• Zelong Wang,
• Xiaodong He and
• Pengfei Cao

Beilstein J. Nanotechnol. 2019, 10, 2527–2537, doi:10.3762/bjnano.10.243

• , the transmittance is almost zero, which is in good agreement with the situation of the dip inset in Figure 2a. Figure 3c–g corresponds to peaks 1–5, respectively. Figure 3c illustrates that the magnetic field energy of peak1 at 1077 nm is mainly concentrated on stub1, stub2 and the middle part of the

• cavity1 (red solid line) in the structure. Transmission spectra of the structure with (red solid line) and without (blue dashed line) cavity3, and (b) the distribution of normalized magnetic field |Hz| at 1320 nm with only stub1 inserted into the bus waveguide. The |Hz| distribution of the total compound

• coupling distance t2 of cavity3 and (e) three specific values of θ. (f) The dependence of the transmission of peak5 on θ. Schematic diagram of cavity3 with different tilt angles θ, (a) θ = 0°, (b) θ = −20°. (c) The distribution of the magnetic field Hz at θ = −20°. (a) Transmission spectra for different

Label-free highly sensitive probe detection with novel hierarchical SERS substrates fabricated by nanoindentation and chemical reaction methods

• Jingran Zhang,
• Tianqi Jia,
• Yongda Yan,
• Li Wang,
• Peng Miao,
• Yimin Han,
• Xinming Zhang,
• Guangfeng Shi,
• Yanquan Geng,
• Zhankun Weng,
• Daniel Laipple and
• Zuobin Wang

Beilstein J. Nanotechnol. 2019, 10, 2483–2496, doi:10.3762/bjnano.10.239

• . The definitions of the geometrical parameters are provided, where E(x), H(y) and K(z) are the electric field, magnetic field, and direction of light propagation, respectively. The electric field intensity is 2.19 V/m, and the radius of the Ag nanoparticle is 100 nm, as computed in air as shown in

Self-assembly of a terbium(III) 1D coordination polymer on mica

• Quentin Evrard,
• Giuseppe Cucinotta,
• Felix Houard,
• Guillaume Calvez,
• Yan Suffren,
• Carole Daiguebonne,
• Olivier Guillou,
• Andrea Caneschi,
• Matteo Mannini and
• Kevin Bernot

Beilstein J. Nanotechnol. 2019, 10, 2440–2448, doi:10.3762/bjnano.10.234

• sample is similar to that of crystalline bulk [Tb(hfac)3·2H2O]n. Namely, two maxima of X″ are observed, which however differently depend on the static magnetic field applied (Figure S3 and Figure S4, Supporting Information File 1) probably due to a partial loss of the magnetic anisotropy of TbIII upon

pH-Controlled fluorescence switching in water-dispersed polymer brushes grafted to modified boron nitride nanotubes for cellular imaging

• Saban Kalay,
• Yurij Stetsyshyn,
• Volodymyr Donchak,
• Khrystyna Harhay,
• Ostap Lishchynskyi,
• Halyna Ohar,
• Yuriy Panchenko,
• Stanislav Voronov and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2019, 10, 2428–2439, doi:10.3762/bjnano.10.233

• nanomaterials [1][2][3][4][5] to generate novel structures with tunable properties through external stimuli such as pH, temperature, light, and magnetic field [6][7][8][9][10]. Among other nanomaterials, significant research effort has been dedicated to the use of nanotubes [1][2][3][4][6][7][11][12][13][14][15

Deterministic placement of ultra-bright near-infrared color centers in arrays of silicon carbide micropillars

• Stefania Castelletto,
• Abdul Salam Al Atem,
• Faraz Ahmed Inam,
• Hans Jürgen von Bardeleben,
• Sophie Hameau,
• Ahmed Fahad Almutairi,
• Gérard Guillot,
• Shin-ichiro Sato,
• Alberto Boretti and
• Jean Marie Bluet

Beilstein J. Nanotechnol. 2019, 10, 2383–2395, doi:10.3762/bjnano.10.229

• isotopically pure SiC to δB ≈ 10nT/√Hz [51][52]. By increasing the photoemission collection efficiency (C) of the color centers and the number of emitters (N), as for example in micropillars, the magnetic field sensitivity can be dramatically improved to reach magnetic sensing resolution of δB ≈ 10nT/√(C·N·Hz

• attenuation of X-ray or coherent neutron scattering [23][24]. The DWF can be estimated as the ratio of the ZPL PL emission, compared to the total PL emission, which is the combination of the ZPL PL emission and the phonon-broadened PL. The ZFS refers to the lifting of degeneracy in the absence of a magnetic

• field. Unpaired electrons interact to give two or more energy states [25]. ODMR is a technique to optically pump the electron spin state of a crystal defect for spin initialization and readout [26]. There are over 200 polymorphs of SiC, and the most relevant are cubic SiC (3C) and hexagonal (4H and 6H