A review on nanostructured silver as a basic ingredient in medicine: physicochemical parameters and characterization

• Gabriel M. Misirli,
• Kishore Sridharan and
• Shirley M. P. Abrantes

Beilstein J. Nanotechnol. 2021, 12, 440–461, doi:10.3762/bjnano.12.36

• }, {100}, and possibly {110} exposed facets in AgNPs are different not only in the densities of the surface atoms, but also in their electronic structure, bonding, and chemical reactivity [34][35][36]. Figure 2 depicts these surfaces (facets) more clearly. Agnihotri et al. studied the bactericidal

• activity against E. coli, Bacillus subtilis, and Staphylococcus aureus of spherical AgNPs of various sizes and concluded that their effectiveness increased with decreasing size, regardless of the bacterial strains [43]. On the other hand, studies indicate that the reactivity and antibacterial activity of

The impact of molecular tumor profiling on the design strategies for targeting myeloid leukemia and EGFR/CD44-positive solid tumors

• Nikola Geskovski,
• Nadica Matevska-Geshkovska,
• Simona Dimchevska Sazdovska,
• Marija Glavas Dodov,
• Kristina Mladenovska and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2021, 12, 375–401, doi:10.3762/bjnano.12.31

• -selectin thioaptamer ligand (ESTA), which binds to E-selectin with high affinity and at the same time expresses minimal cross-reactivity to other selectin family members [36]. The formulation demonstrated an eightfold increase in the BM localization of the encapsulated liposomes, relative to the equivalent

Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition

• Cristiano Glessi,
• Aya Mahgoub,
• Cornelis W. Hagen and
• Mats Tilset

Beilstein J. Nanotechnol. 2021, 12, 257–269, doi:10.3762/bjnano.12.21

• , and decompose in a clean manner to the desired products. Furthermore, it should be inexpensive and easy to prepare, non-toxic, and easy to store and handle [17]. The choice of such molecules requires a compromise to be made between volatility, stability, and reactivity induced by electron irradiation

Extended iron phthalocyanine islands self-assembled on a Ge(001):H surface

• Rafal Zuzak,
• Marek Szymonski and
• Szymon Godlewski

Beilstein J. Nanotechnol. 2021, 12, 232–241, doi:10.3762/bjnano.12.19

• the passivation of semiconducting materials, which removes surface dangling bonds and significantly reduces surface reactivity, may also provide a sufficiently insulating layer for an efficient decoupling of molecular structures from the substrate influence. Among such surfaces, hydrogen-passivated Si

TiO_x/Pt₃Ti(111) surface-directed formation of electronically responsive supramolecular assemblies of tungsten oxide clusters

• Marco Moors,
• Yun An,
• Agnieszka Kuc and
• Kirill Yu. Monakhov

Beilstein J. Nanotechnol. 2021, 12, 203–212, doi:10.3762/bjnano.12.16

• field-triggered electronic manipulation of nanoscopic W3O9 clusters. Depending on the operating conditions, two different stable oxide phases, z’-TiOx and w’-TiOx, were produced. These phases show a strong effect on the adsorption characteristics and reactivity of W3O9 clusters, which are formed as a

• titanium oxide layers grown on a Pt3Ti(111) surface. The given case study with the nanoscopic W3O9 clusters as the main components of tungsten trioxide vapor, which have been evidenced by mass spectrometric studies [9][10], showcases remarkable TiOx/Pt3Ti(111)-directed reactivity of W3O9 to hierarchical

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• structure. After the etching process, MXenes have a great number of active groups, such as –OH and =O, which results in superior hydrophilicity, chemical reactivity, and large contact area. This implies a potential of MXenes for the use in supercapacitors [16][18][19][22][23][28]. Moreover, MXenes can be

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core–shell nanostructures for photocatalytic activity

• Bridget K. Mutuma,
• Xiluva Mathebula,
• Isaac Nongwe,
• Bonakele P. Mtolo,
• Boitumelo J. Matsoso,
• Rudolph Erasmus,
• Zikhona Tetana and
• Neil J. Coville

Beilstein J. Nanotechnol. 2020, 11, 1834–1846, doi:10.3762/bjnano.11.165

• surface [23]. Thus, silica-based core–shell nanocomposites offer added advantages of manipulating the pore structure, surface area, morphology, and catalyst reactivity [28]. Unlike the metal oxide–metal oxide composites, the use of metal oxide core@metal nanocomposites as dopants for titania

Electron beam-induced deposition of platinum from Pt(CO)₂Cl₂ and Pt(CO)₂Br₂

• Aya Mahgoub,
• Hang Lu,
• Rachel M. Thorman,
• Konstantin Preradovic,
• Titel Jurca,
• Lisa McElwee-White,
• Howard Fairbrother and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2020, 11, 1789–1800, doi:10.3762/bjnano.11.161

• is more volatile than the chloride (vide infra), facilitating delivery to the substrate, although a study of the electron-induced reactivity of (η3-C3H5)Ru(CO)3Br and (η3-C3H5)Ru(CO)3Cl under UHV conditions demonstrated that the response of the halides to electron flux was similar for both compounds

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• activity can result in the development of novel antimicrobial substances. Specifically, metal-based nanoparticles have attracted much interest due to their broad effectiveness against pathogenic microorganisms due to their high surface area and high reactivity. The aim of this review was to explore the

Atomic defect classification of the H–Si(100) surface through multi-mode scanning probe microscopy

• Jeremiah Croshaw,
• Thomas Dienel,
• Taleana Huff and
• Robert Wolkow

Beilstein J. Nanotechnol. 2020, 11, 1346–1360, doi:10.3762/bjnano.11.119

• apparent contrast of the hydrogen atoms with the surrounding surface. Previous studies have identified the two contrasts as resulting from differing chemical reactivity of different functionalizing apex atoms [38], where the dark contrast image corresponds to a Si-terminated tip [39][40][41] and the bright

• contrast image corresponds to an H-terminated tip [39][40]. The transition between the two modes through the loss of H-functionalization of the tip (by capping a surface dangling bond [40]) can be seen in Supporting Information File 1, Figure S4. This differing chemical reactivity is seen in Figure 1j

• , where the height-dependent frequency shift spectra (Δf(z)) taken above select positions on the surface (see Figure 1g,h for positions), shows significantly different character for each tip termination. To highlight the termination-dependent reactivity, frequency shift difference spectra [42] were

Role of redox-active axial ligands of metal porphyrins adsorbed at solid–liquid interfaces in a liquid-STM setup

• Thomas Habets,
• Sylvia Speller and
• Johannes A. A. W. Elemans

Beilstein J. Nanotechnol. 2020, 11, 1264–1271, doi:10.3762/bjnano.11.110

• insights into reactivity at the single-molecule scale, some mechanistic aspects still remained unclear. For instance, the reduction of the Mn(III) porphyrin to a Mn(II) porphyrin also involves the dissociation of the axially coordinating Cl ligand from the metal center, and it is as yet unclear what the

• their reactivity. Our proposal of redox reactions is supported by the observation that the magnitude of the current increases with an increasing concentration of Mn(III)TUPCl in the supernatant solution. Typically, Faradaic currents depend linearly on the concentration of the redox-active species, and

• of the chloride counterion for the redox reactivity of MnTUPCl. To investigate the influence of the nature of the used electrodes, we varied the sample surfaces (HOPG and Au(111)) and the tip material (Pt90Ir10, Au and W). A summary of these experiments is given in Table 1. Additional currents were

Hybridization vs decoupling: influence of an h-BN interlayer on the physical properties of a lander-type molecule on Ni(111)

• Maximilian Schaal,
• Takumi Aihara,
• Marco Gruenewald,
• Felix Otto,
• Jari Domke,
• Roman Forker,
• Hiroyuki Yoshida and
• Torsten Fritz

Beilstein J. Nanotechnol. 2020, 11, 1168–1177, doi:10.3762/bjnano.11.101

• chemical reactivity (prone to oxidation) and a strong hybridization with the organic molecules [41]. In contrast to these traditional low work function materials, h-BN on Ni(111) is chemically inert, and we showed that organic molecules like DBP are decoupled from the metal surface which makes this system

Straightforward synthesis of gold nanoparticles by adding water to an engineered small dendrimer

• Sébastien Gottis,
• Régis Laurent,
• Vincent Collière and
• Anne-Marie Caminade

Beilstein J. Nanotechnol. 2020, 11, 1110–1118, doi:10.3762/bjnano.11.95

• nanoparticle synthesis due to the reactivity of this linkage [37][38][39] and due to its ability to complex metals, especially gold(I), with the sulfur atom [40][41]. A recent theoretical work demonstrated that the highest occupied molecular orbital of a small dendrimer containing the P=N–P=S linkage is

A new photodetector structure based on graphene nanomeshes: an ab initio study

• Babak Sakkaki,
• Hassan Rasooli Saghai,
• Ghafar Darvish and
• Mehdi Khatir

Beilstein J. Nanotechnol. 2020, 11, 1036–1044, doi:10.3762/bjnano.11.88

•  1, from the A4Z6-6 and A4A4-6 supercells six carbon atoms (one hexagon) were removed, and from the A4Z6-24 supercell 24 carbon atoms were removed. Note that the creation of these holes in the graphene lattice leaves dangling bonds on carbon atoms at the edges and increases the reactivity of these

Microwave-induced electric discharges on metal particles for the synthesis of inorganic nanomaterials under solvent-free conditions

• Vijay Tripathi,
• Harit Kumar,
• Anubhav Agarwal and
• Leela S. Panchakarla

Beilstein J. Nanotechnol. 2020, 11, 1019–1025, doi:10.3762/bjnano.11.86

• of CuF/CuF2 nanorods. The reactivity of Cu with sulfur is higher than that with fluorine as soft–soft interactions between Cu and S dominate the product stability compared to soft–hard interactions between Cu and F. The XRD pattern in Figure 4a confirms the hexagonal covellite structure of CuS. The

• fluorides depending on the reactivity. Cu and Ni, in the presence of graphite and /or g-C3N4 and the absence of sulfur produce metallic nanoparticles. This might be due to the reducing capability of carbon at high temperatures preventing the metals from getting oxidized. When sulfur is used in the reaction

• mixture along with g-C3N4, sulfur helps to produce carbon nanotubes instead of carbon nanospheres. The reactivity of sulfur with the end caps of nanotubes does not allow the carbon nanotubes to close. These amorphous carbon nanotubes help as a template to intercalate metal fluorides/metal sulfides. As the

Three-dimensional solvation structure of ethanol on carbonate minerals

• Hagen Söngen,
• Ygor Morais Jaques,
• Peter Spijker,
• Christoph Marutschke,
• Stefanie Klassen,
• Ilka Hermes,
• Ralf Bechstein,
• Lidija Zivanovic,
• John Tracey,
• Adam S. Foster and
• Angelika Kühnle

Beilstein J. Nanotechnol. 2020, 11, 891–898, doi:10.3762/bjnano.11.74

• between a mineral and its environment takes place at the interface, the interfacial structure is of fundamental importance for gaining molecular-level understanding of the mineral reactivity. In the presence of water, the hydration structure at the interface needs to be known. With the advent of high

Templating effect of single-layer graphene supported by an insulating substrate on the molecular orientation of lead phthalocyanine

• K. Priya Madhuri,
• Abhay A. Sagade,
• Pralay K. Santra and
• Neena S. John

Beilstein J. Nanotechnol. 2020, 11, 814–820, doi:10.3762/bjnano.11.66

• transparency disappears with an increasing number of graphene layers, and the wettability approaches that of graphite. The underlying support substrate is reported to even influence the chemical reactivity of a monolayer of graphene [15]. Most of the orientation studies of MPc on graphene deal with planar MPc

Comparison of fresh and aged lithium iron phosphate cathodes using a tailored electrochemical strain microscopy technique

• Matthias Simolka,
• Hanno Kaess and
• Kaspar Andreas Friedrich

Beilstein J. Nanotechnol. 2020, 11, 583–596, doi:10.3762/bjnano.11.46

• additional mechanical (stiffness, elasticity), electrical (conductivity, surface potential), electrochemical (reactivity, mobility and activity), mechanoelectrical (piezoelectricity) and chemical (chemical bonding) material properties. In situ AFM imaging of the sample topography is often used to study the

Rational design of block copolymer self-assemblies in photodynamic therapy

• Maxime Demazeau,
• Laure Gibot,
• Anne-Françoise Mingotaud,
• Patricia Vicendo,
• Clément Roux and
• Barbara Lonetti

Beilstein J. Nanotechnol. 2020, 11, 180–212, doi:10.3762/bjnano.11.15

• PDT. Block copolymer nanoassemblies offer the unique possibility to protect the photosensitizer in a hydrophobic environment (as described in Figure 3) and to prevent the aggregation. At the same time, they improve the biodistribution, pharmacokinetics and photochemical reactivity of the

Fabrication of Ag-modified hollow titania spheres via controlled silver diffusion in Ag–TiO₂ core–shell nanostructures

• Bartosz Bartosewicz,
• Malwina Liszewska,
• Bogusław Budner,
• Marta Michalska-Domańska,
• Krzysztof Kopczyński and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2020, 11, 141–146, doi:10.3762/bjnano.11.12

• CSNs. This is likely due to much lower reactivity of Au compared to Ag. Ag–TiO2 nanostructures at an intermediate and the final stage of thermal modification are shown in SEM images in Figure 1 and Figure 2B–E. The SEM images in Figure 1 clearly indicate the titania shell, the Ag core and products of

Fully amino acid-based hydrogel as potential scaffold for cell culturing and drug delivery

• Dávid Juriga,
• Evelin Sipos,
• Orsolya Hegedűs,
• Gábor Varga,
• Miklós Zrínyi,
• Krisztina S. Nagy and
• Angéla Jedlovszky-Hajdú

Beilstein J. Nanotechnol. 2019, 10, 2579–2593, doi:10.3762/bjnano.10.249

• matrix. The PSI-0CYS-LYS gel shows a significantly higher swelling degree at every pH value due to the smaller reactivity of the amine groups in LYS, which leads to a lower amount of cross-links [21]. Regarding the mass swelling degree of the PASP-based hydrogels, two groups can be observed which differ

• in the ratio of the LYS and the CYS cross-linkers (Figure 2b). The gels with a lower ratio of LYS cross-links (100, 80 and 60CYS-LYS) have a lower swelling degree than the gels with higher LYS concentration (40, 20 and 0CYS-LYS) at every pH value, which also proves the lower reactivity of LYS. The

• * [21]. This indicates that a larger amount of CYS molecules reacts with two amine groups cross-linking the polymer chains. The strong electron withdrawing character of the carboxyl group of the amino-acid group decreases the electron density of the alpha amine group, resulting in a weaker reactivity of

Multiwalled carbon nanotube based aromatic volatile organic compound sensor: sensitivity enhancement through 1-hexadecanethiol functionalisation

• Nadra Bohli,
• Meryem Belkilani,
• Juan Casanova-Chafer,
• Eduard Llobet and
• Adnane Abdelghani

Beilstein J. Nanotechnol. 2019, 10, 2364–2373, doi:10.3762/bjnano.10.227

• decoration of MWCNTs Prior to their deposition on the interdigitated electrode surface, the MWCNTs were treated by oxygen plasma to create oxygen vacancies on the walls of the CNTs in order to enhance their surface reactivity [14][15]. The detailed description of the experimental steps undertaken is

Use of data processing for rapid detection of the prostate-specific antigen biomarker using immunomagnetic sandwich-type sensors

• Camila A. Proença,
• Tayane A. Freitas,
• Thaísa A. Baldo,
• Elsa M. Materón,
• Flávio M. Shimizu,
• Gabriella R. Ferreira,
• Frederico L. F. Soares,
• Ronaldo C. Faria and
• Osvaldo N. Oliveira Jr.

Beilstein J. Nanotechnol. 2019, 10, 2171–2181, doi:10.3762/bjnano.10.210

• immobilized on the electrode surface. Also, the monoclonal antibody provides high specificity to a single epitope, which is reflected in a low cross-reactivity. A comparison of various sandwich-type immunosensors and immunoassays for detection of PSA in the literature is presented in Table 1. Repeatability is

Improved adsorption and degradation performance by S-doping of (001)-TiO₂

• Xiao-Yu Sun,
• Xian Zhang,
• Xiao Sun,
• Ni-Xian Qian,
• Min Wang and
• Yong-Qing Ma

Beilstein J. Nanotechnol. 2019, 10, 2116–2127, doi:10.3762/bjnano.10.206

• − radicals with high reactivity. Experimental (×) and calculated (—) X-ray powder diffraction patterns of 1-S0 (a) and 2-S2 (b). Peak positions are shown as small markers (|). The lower trace represents the difference between the calculated and experimental data. TEM images (a–c) and HRTEM images (d–f) for 1

Novel hollow titanium dioxide nanospheres with antimicrobial activity against resistant bacteria

• Carol López de Dicastillo,
• Cristian Patiño,
• María José Galotto,
• Yesseny Vásquez-Martínez,
• Claudia Torrent,
• Daniela Alburquenque,
• Alejandro Pereira and
• Juan Escrig

Beilstein J. Nanotechnol. 2019, 10, 1716–1725, doi:10.3762/bjnano.10.167

• infections both in developed and developing countries worldwide [1]. Thus, the search for new alternatives against microbial incidence has become an important challenge. In this context, nanoparticles (NPs) have become of great interest to researchers because of their high reactivity against both Gram