Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• functionalized MOx NFs with superior sensitivity and fast response in a high humidity environment (95% relative humidity (RH)). WO3 NFs functionalized by RuO2 [189] and Rh2O3 [106] NPs show improved response toward acetone at 350 °C. The fibers have an average diameter in the range 250–300 nm with no significant

Know your full potential: Quantitative Kelvin probe force microscopy on nanoscale electrical devices

• Amelie Axt,
• Ilka M. Hermes,
• Victor W. Bergmann,
• Niklas Tausendpfund and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2018, 9, 1809–1819, doi:10.3762/bjnano.9.172

• Asylum research MFP3D SFM in a nitrogen glovebox (level of humidity below 1%) for all experiments. The typical resonance frequency of the cantilevers (Bruker Model:SCM-PIT-V2) was ≈75 kHz, spring constant of 3 N/m, a tip radius of 25 nm and a tip height of 10 to 15 μm. The typical length of the

Direct AFM-based nanoscale mapping and tomography of open-circuit voltages for photovoltaics

• Katherine Atamanuk,
• Justin Luria and
• Bryan D. Huey

Beilstein J. Nanotechnol. 2018, 9, 1802–1808, doi:10.3762/bjnano.9.171

• property mapping is especially beneficial for specimens sensitive to their environment, as is common for many photovoltaics in the presence of oxygen or humidity [19]. Along these lines, direct measurements of VOC* during exposure to acetic acid are ongoing for Si solar cells to correlate any changes in

Preparation of micro/nanopatterned gelatins crosslinked with genipin for biocompatible dental implants

• Reika Makita,
• Tsukasa Akasaka,
• Seiichi Tamagawa,
• Yasuhiro Yoshida,
• Saori Miyata,
• Hirofumi Miyaji and
• Tsutomu Sugaya

Beilstein J. Nanotechnol. 2018, 9, 1735–1754, doi:10.3762/bjnano.9.165

• , but not as a main focus [38][39][51][52]. The crosslinking reaction of gelatin is controlled by the reaction time, the temperature, and humidity. In this study, we used 20 wt % gelatin as an optimal concentration for the gelatin solution, because a concentration of 30 wt % gelatin produced a solution

• an atmosphere with 100% humidity to avoid drying out and incubated for 3 days at 37 °C. The molds were then dried for 3 days at normal humidity at 37 °C. The molds were then stored at −18 °C to harden the gelatin prior to demolding. Demolding was achieved by carefully peeling off the PDMS mold from

• was gently pressed onto the gelatin/genipin mixture. We found that it was important that the viscosity of the solution not be too high, as excessive cross-linking can occur (Figure 11a). In order for continuous crosslinking to occur, the mixture was incubated at 100% humidity in order to avoid drying

Nanoscale electrochemical response of lithium-ion cathodes: a combined study using C-AFM and SIMS

• Jonathan Op de Beeck,
• Nouha Labyedh,
• Alfonso Sepúlveda,
• Valentina Spampinato,
• Alexis Franquet,
• Thierry Conard,
• Philippe M. Vereecken,
• Wilfried Vandervorst and
• Umberto Celano

Beilstein J. Nanotechnol. 2018, 9, 1623–1628, doi:10.3762/bjnano.9.154

• the reproducibility and quantitative interpretation of C-AFM [17]. At the same time, we do not expect the high-vacuum environment to be completely free from humidity. Therefore, in these measurements the formation of any Li composites such as Li2O and Li2CO3 cannot be excluded as also considered by

Evaluation of replicas manufactured in a 3D-printed nanoimprint unit

• Manuel Caño-García,
• Morten A. Geday,
• Manuel Gil-Valverde,
• Xabier Quintana and
• José M. Otón

Beilstein J. Nanotechnol. 2018, 9, 1573–1581, doi:10.3762/bjnano.9.149

• procedure was the same, some variables such as room temperature or humidity were not controlled. As a result, some variability between batches was observed, frequently larger than the variability within a single batch. Occasionally, this issue leads to apparently biased measurements, e.g., the back angle of

Tailoring polarization and magnetization of absorbing terahertz metamaterials using a cut-wire sandwich structure

• Hadi Teguh Yudistira,
• Shuo Liu,
• Tie Jun Cui and
• Han Zhang

Beilstein J. Nanotechnol. 2018, 9, 1437–1447, doi:10.3762/bjnano.9.136

• measurements were conducted in a nitrogen environment (humidity less than 1%) at 25 °C. We first recorded the waveform reflected from an opaque gold film as reference for the reflection. For the transmission reference, we recorded the waveform transmitted without any sample. Figure 8a–c presents the measured

Electrostatic force spectroscopy revealing the degree of reduction of individual graphene oxide sheets

• Yue Shen,
• Ying Wang,
• Yuan Zhou,
• Chunxi Hai,
• Jun Hu and
• Yi Zhang

Beilstein J. Nanotechnol. 2018, 9, 1146–1155, doi:10.3762/bjnano.9.106

• ambient temperature, and uses a compressor and a humidifier to control the humidity of the environment. In order to eliminate the influence of noise from the system, the temperature and humidity generator are physically separated from the AFM. The humidity generator and the AFM are connected with

• adiabatic hoses, forming the gas transmission loop. The temperature fluctuations were below 0.2 °C and the error of humidity control was about 2% relative humidity (RH). To avoid influences on EFM or SPFM imaging from the dielectric constant change of the mica substrate, all the SPM-based operations were

• carried out under room temperature at 23 °C and at a relative humidity of 15% in order to ensure constant substrate surface properties (especially regarding the dielectric constant of the mica surface) [20]. In all the SPM operations, the NSC18/Ti-Pt (MikroMasch Co.) tip was used, which employed a silicon

Imaging of viscoelastic soft matter with small indentation using higher eigenmodes in single-eigenmode amplitude-modulation atomic force microscopy

• Miead Nikfarjam,
• Enrique A. López-Guerra,
• Santiago D. Solares and
• Babak Eslami

Beilstein J. Nanotechnol. 2018, 9, 1116–1122, doi:10.3762/bjnano.9.103

• deformational timescale in our studies (previous studies have quantified the dependence of characteristic times on the molecular weight for polystyrene [30]). In order to ensure a homogenous surface, the relative humidity was controlled to be approximately 30% during the spin-coating process. A portion of the

Scanning speed phenomenon in contact-resonance atomic force microscopy

• Christopher C. Glover,
• Jason P. Killgore and
• Ryan C. Tung

Beilstein J. Nanotechnol. 2018, 9, 945–952, doi:10.3762/bjnano.9.87

• cyanoacrylate. A razor blade was then used to cleave the sample, leaving behind a pristine sample surface. The sample was placed in a closed AFM flow-cell with an integrated relative humidity sensor. A cantilever with spring constant kL = 1.7 ± 0.2 N/m and first free resonance = 61.85 ± 0.1 kHz was mounted to

• eigenmode placed further constraints on the selection of the cantilever. A gas mixing apparatus was used to mix streams of dry and saturated N2 to achieve various levels of relative humidity in the cell. The cantilever was brought into contact with the sample at 100 nN and 300 nN. The NIST SPRITE circuit

• indented into a mica surface with a force of 100 nN in an environment with a relative humidity (RH) of 41% and scanned in a direction orthogonal to the long axis of the cantilever (scan angle of 90°). The resulting in-contact natural frequencies of the cantilever are measured while the tip is moved across

Bioinspired self-healing materials: lessons from nature

• Joseph C. Cremaldi and
• Bharat Bhushan

Beilstein J. Nanotechnol. 2018, 9, 907–935, doi:10.3762/bjnano.9.85

Nanoscale mapping of dielectric properties based on surface adhesion force measurements

• Ying Wang,
• Yue Shen,
• Xingya Wang,
• Zhiwei Shen,
• Bin Li,
• Jun Hu and
• Yi Zhang

Beilstein J. Nanotechnol. 2018, 9, 900–906, doi:10.3762/bjnano.9.84

• conventional AFM modes, which is attributed to the larger tip–sample distance [30]. Moreover, in ambient electrical AFM scanning, relative humidity usually has a strong impact on image resolution and contrast [31][32]. We propose that fast mapping of the local dielectric distribution on a sample surface can be

• 18–25 °C, and relative humidity (RH) 35–60%) (Figure 2a,c). However, the contrast of the corresponding adhesion images increases significantly (Figure 2b,d). When the tip bias was lowered back to 0 V, both height and adhesion images returned to the original state before the dc voltage was applied

• at 150 nm, the Z-piezo oscillation frequency at 2.0 kHz, and the scan rate at 1 Hz. Voltage to the tip was applied using the scan parameter “tip bias”. All AFM experiments were conducted under ambient conditions at a room temperature of 18–25 °C and relative humidity of 35–60%. AFM images of the

Effect of annealing treatments on CeO₂ grown on TiN and Si substrates by atomic layer deposition

• Silvia Vangelista,
• Rossella Piagge,
• Satu Ek and
• Alessio Lamperti

Beilstein J. Nanotechnol. 2018, 9, 890–899, doi:10.3762/bjnano.9.83

• annealed at 300 °C we found out that this mild annealing does not induce any significant change in the film thickness, roughness and density of CeO2. However, it is effective in the removal of the humidity absorbed at the surface, detected in the as-deposited samples only [8]. On the other side, when

Comparative study of antibacterial properties of polystyrene films with TiO_x and Cu nanoparticles fabricated using cluster beam technique

• Vladimir N. Popok,
• Cesarino M. Jeppesen,
• Peter Fojan,
• Anna Kuzminova,
• Jan Hanuš and
• Ondřej Kylián

Beilstein J. Nanotechnol. 2018, 9, 861–869, doi:10.3762/bjnano.9.80

• sequential cycles and every type of sample are shown in Table 1. It can be seen that the ratio is stable within approximately ±15% from cycle to cycle. The deviations can be related to small changes in the experimental conditions, for example, variations of temperature and humidity, which are difficult to

Noble metal-modified titania with visible-light activity for the decomposition of microorganisms

• Maya Endo,
• Zhishun Wei,
• Kunlei Wang,
• Baris Karabiyik,
• Kenta Yoshiiri,
• Paulina Rokicka,
• Bunsho Ohtani,
• Agata Markowska-Szczupak and
• Ewa Kowalska

Beilstein J. Nanotechnol. 2018, 9, 829–841, doi:10.3762/bjnano.9.77

• the dark). Accordingly, it is proposed that silver-modified samples are more promising as antibacterial agents, due to high efficiency (both in the dark and under vis irradiation) as well as the lower price of silver. Antifungal activity of plasmonic photocatalysts High humidity, positive temperature

A review of carbon-based and non-carbon-based catalyst supports for the selective catalytic reduction of nitric oxide

• Shahreen Binti Izwan Anthonysamy,
• Syahidah Binti Afandi,
• Mehrnoush Khavarian and
• Abdul Rahman Bin Mohamed

Beilstein J. Nanotechnol. 2018, 9, 740–761, doi:10.3762/bjnano.9.68

• problem, which affects the natural characteristics of the atmosphere (gaseous constituents, water vapour that determines humidity and ozone layer) and adversely impacts the environment and human health. Nitrogen oxides (NOx, x = 1, 2) are irritant gases that cause problems such as photochemical smog

Synthesis and characterization of two new TiO₂-containing benzothiazole-based imine composites for organic device applications

• Anna Różycka,
• Agnieszka Iwan,
• Krzysztof Artur Bogdanowicz,
• Michal Filapek,
• Natalia Górska,
• Damian Pociecha,
• Marek Malinowski,
• Patryk Fryń,
• Agnieszka Hreniak,
• Jakub Rysz,
• Paweł Dąbczyński and
• Monika Marzec

Beilstein J. Nanotechnol. 2018, 9, 721–739, doi:10.3762/bjnano.9.67

• for SP1 and SP2 imines mixed with TiO2. Figure 8 shows POM textures of SP2 imine and SP2:TiO2 mixtures with different weight ratios 3:3, 3:2, 3:1, 3:0, taken after different periods of time under standard laboratory conditions (humidity about 50%, temperature about 24 °C). The investigated samples on

Tuning adhesion forces between functionalized gold colloidal nanoparticles and silicon AFM tips: role of ligands and capillary forces

• Sven Oras,
• Sergei Vlassov,
• Marta Berholts,
• Rünno Lõhmus and
• Karine Mougin

Beilstein J. Nanotechnol. 2018, 9, 660–670, doi:10.3762/bjnano.9.61

• interactions represent a major part of the molecular forces acting between both contact surfaces, however, the presence of water vapor (humidity rate of the order of 35%) in air, has a strong impact on these results via capillary forces. In ambient conditions a water mono-bilayer with thickness around 1 nm can

• bare solid, γSL is the interface energy between solid and liquid and γLV is the interface energy between liquid and vapour. This parameter shows the surface energy per unit area between the tip–liquid and substrate–liquid contacts. In the presence of humidity, Fadh is the sum of the direct adhesion Fss

• ° and θTL = 60° [36] are the static contact angles of the liquid on substrate (–NH2) and tip, respectively and γLV = 7.28 × 10−2 N/m is the liquid (water) surface tension. For the given values the capillary forces are around 7 nN. From Equation 2, it can be deduced that for the low humidity there is no

Nanoparticle delivery to metastatic breast cancer cells by nanoengineered mesenchymal stem cells

• Liga Saulite,
• Karlis Pleiko,
• Ineta Popena,
• Dominyka Dapkute,
• Ricardas Rotomskis and
• Una Riekstina

Beilstein J. Nanotechnol. 2018, 9, 321–332, doi:10.3762/bjnano.9.32

• . The cells were subsequently incubated for 24 and 48 h. After incubation, 10 µL of CCK8 reagent was added to each well, and the cells were incubated for 2 h at 37 °C in 5% CO2 and 90% humidity. The background signal controls containing QDs at all tested concentrations in the cell culture medium were

Review: Electrostatically actuated nanobeam-based nanoelectromechanical switches – materials solutions and operational conditions

• Liga Jasulaneca,
• Jelena Kosmaca,
• Raimonds Meija,
• Jana Andzane and
• Donats Erts

Beilstein J. Nanotechnol. 2018, 9, 271–300, doi:10.3762/bjnano.9.29

Humidity-dependent wound sealing in succulent leaves of Delosperma cooperi – An adaptation to seasonal drought stress

• Olga Speck,
• Mark Schlechtendahl,
• Florian Borm,
• Tim Kampowski and
• Thomas Speck

Beilstein J. Nanotechnol. 2018, 9, 175–186, doi:10.3762/bjnano.9.20

• were measured in terms of the relative bending angle over 55 minutes under various humidity conditions. The higher the relative air humidity, the lower the bending angle. Negative bending angles were found when a droplet of liquid water was applied to the wound. The statistical analysis revealed highly

• significant differences of the single main effects such as “humidity conditions in the wound region” and “time after wounding” and their interaction effect. The centripetal arrangement of five tissue layers with various thicknesses and significantly different mechanical properties might play an additional

• determine hydraulically driven effects, we have carried out analysis of the relative bending angle as a measure of the self-sealing efficiency under various humidity conditions and over time. Third, the obtained results are discussed not only regarding the self-sealing process as such, but also concerning

Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition

• Ziyan Warneke,
• Markus Rohdenburg,
• Jonas Warneke,
• Janina Kopyra and
• Petra Swiderek

Beilstein J. Nanotechnol. 2018, 9, 77–90, doi:10.3762/bjnano.9.10

• MeCpPtMe3 have a nanogranular structure, i.e., they consist of nanoscale Pt particles embedded in a carbonaceous matrix [12]. While FEBID-based PtC metal-matrix nanocomposites can serve, for instance, as transducing elements for humidity sensing [13], other applications call for high electrical conductivity

• carbonaceous matrix of nanogranular FEBID materials under humid conditions as relevant, for instance, in applications such as humidity sensing [13]. Results and Discussion Thermal reactions between intact MeCpPtMe3 and H2O In ALD processes for deposition of Pt performed at 100 °C and consisting of alternating

A robust AFM-based method for locally measuring the elasticity of samples

• Alexandre Bubendorf,
• Stefan Walheim,
• Thomas Schimmel and
• Ernst Meyer

Beilstein J. Nanotechnol. 2018, 9, 1–10, doi:10.3762/bjnano.9.1

• , pressure or humidity. Since its invention, the atomic force microscope (AFM) [4] has confirmed its value for locally determining nanomechanical properties, such as the Young’s modulus, of the sample surface. Initially, the measures were done qualitatively, with the cantilever operated in intermittent

• Young’s modulus of 500 MPa was used to determine parameter α(A1). The measurements were performed in non-dry air with a relative humidity of 36% at an ambient temperature of 27 °C. Results and Discussion Force–distance and frequency shift–distance curves Before starting the investigation of the sample

• quantitative determination of local elastic modulus of sample under ambient conditions (humidity and temperature). It combines the simplicity of the theoretical model developed by Herruzo et al. [7] for the determination of sample elasticity from 1 MPa to 3 GPa with a robust measuring method based on contact

Hyperthermic intracavitary nanoaerosol therapy (HINAT) as an improved approach for pressurised intraperitoneal aerosol chemotherapy (PIPAC): Technical description, experimental validation and first proof of concept

• Daniel Göhler,
• Stephan Große,
• Alexander Bellendorf,
• Thomas Albert Falkenstein,
• Mehdi Ouaissi,
• Jürgen Zieren,
• Michael Stintz and
• Urs Giger-Pabst

Beilstein J. Nanotechnol. 2017, 8, 2729–2740, doi:10.3762/bjnano.8.272

• intra-abdominal temperature by means of a temperature/humidity probe (XA Lufft; Lufft Mess- und Regeltechnik GmbH, Fellbach, Germany). In order to visualise the droplet deposition, HINAT-LAU was operated with an undiluted aqueous methylene blue solution (Toluidinblau; Dr. Franz Köhler Chemie GmbH

Dry adhesives from carbon nanofibers grown in an open ethanol flame

• Christian Lutz,
• Julia Syurik,
• C. N. Shyam Kumar,
• Christian Kübel,
• Michael Bruns and
• Hendrik Hölscher

Beilstein J. Nanotechnol. 2017, 8, 2719–2728, doi:10.3762/bjnano.8.271

• . Areas covered with 1D-CNs are limited to spots of the ethanol flame with nearly constant process conditions and a temperature in the range of 750 °C. Another limitation is the process stability, especially the environmental conditions. Humidity and temperature are critical factors for the successful

• find such 1D-CNs of different qualities on our samples, it should be mentioned that the quality of the resulting arrays obtained by the magnetic-field assisted growth in an ethanol flame, depends on the environmental conditions, i.e., temperature and humidity. Summarizing about 30 experiments conducted

• all over the year under different environmental conditions, we observed that a growth of CNFs is, in general, only successful at lower ambient lab temperatures and humidity as shown in Figure 5. We, therefore, assume that water condenses on the hygroscopic NiCl2·6H2O catalytic layer at elevated