Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• , photoinduced demagnetization component following a subpicosecond one; the former vanishes at low temperatures only in the x = 0.080 sample. We argue that the 10 ps timescale demagnetization originates most probably from the diffusive transport of d electrons under the condition of nanoscale magnetic

• of 10 ps can be estimated as 10−9 m/10−11 s = 100 m/s. For the conventional spin diffusion, the spin memory length is where is the diffusion coefficient, τs is the Elliott–Yafet spin-relaxation time [46][47], τ is the charge transport relaxation time, and vF is the Fermi velocity. For the purpose

• ferromagnetic metals was a subject of interest in magnetic nanostructures [50][51][52] and had a value of about 3 × 105 m/s. Being stronger localized in the narrower 4d bands [44], the itinerant 4d electrons must have a lower velocity, say 105 m/s. Then, with the transport time τ ≈ 10−14 s and the electron-spin

Hierachical epicuticular wax coverage on leaves of Deschampsia antarctica as a possible adaptation to severe environmental conditions

• Elena V. Gorb,
• Iryna A. Kozeretska and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2022, 13, 807–816, doi:10.3762/bjnano.13.71

• Bay) to 400 mm per year (South Shetland Islands) [26]. In general, a continuous epicuticular wax layer is known to serve as an transport barrier limiting the uncontrolled water loss in plants [38][41]. The presence of a thick wax coverage has been considered as one of typical xeromorphic features (i.e

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• , which are important for increase the density of active sites for catalysis and energy storage. However, they are too narrow for the transport of small molecules, hindering fast mass transport. Forming additional porous textures in monocrystalline coordination polymers can perfectly solve this problem by

A nonenzymatic reduced graphene oxide-based nanosensor for parathion

• Sarani Sen,
• Anurag Roy,
• Ambarish Sanyal and
• Parukuttyamma Sujatha Devi

Beilstein J. Nanotechnol. 2022, 13, 730–744, doi:10.3762/bjnano.13.65

• , enhanced electron transport facility, excellent mechanical, thermal, and electrical stability [11][25][26][27]. The electronic structure and surface physicochemistry of graphene are beneficial for electron transfer. Several graphene-based nanocomposites based on complex synthesis processes are reported as

• graphite nature of GO. This confirms that the oxygen functional groups were removed from the graphene layers by electrochemical reduction of GO, decreasing the interspacing distance between graphene layers which facilitates electron transport. Thus, the conductivity of ERGO was enhanced compared to that of

Modeling a multiple-chain emeraldine gas sensor for NH₃ and NO₂ detection

• Hana Sustkova and
• Jan Voves

Beilstein J. Nanotechnol. 2022, 13, 721–729, doi:10.3762/bjnano.13.64

• , as seen in the I–V characteristic obtained through the extended Hückel method, in the saturated part, ballistic charge carrier transport of one particle takes place. Thus, for the relative resistance change data, only the initial part of the I–V diagram was taken into account. Also, the numerical

Direct measurement of surface photovoltage by AC bias Kelvin probe force microscopy

• Masato Miyazaki,
• Yasuhiro Sugawara and
• Yan Jun Li

Beilstein J. Nanotechnol. 2022, 13, 712–720, doi:10.3762/bjnano.13.63

• ) because of the need for consecutive measurements in darkness and under illumination. Thus, AC-KPFM and classical KPFM measure the SPV derived from different origins, such as charge recombination (nanoseconds to milliseconds) [60], ion transport (milliseconds to seconds) [61], and surface chemical

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• -dependent scattering. In contrast, we treat spin mixing of arbitrary strength exactly. The distribution of spin mixing angles (δφn, n is the channel index) along the transport channels is the only unknown in the theory. This distribution can be probed directly in a fully electronic experiment, measuring the

Comparative molecular dynamics simulations of thermal conductivities of aqueous and hydrocarbon nanofluids

• Adil Loya,
• Antash Najib,
• Fahad Aziz,
• Asif Khan,
• Guogang Ren and
• Kun Luo

Beilstein J. Nanotechnol. 2022, 13, 620–628, doi:10.3762/bjnano.13.54

• that a local micro-convection is induced in the base fluid due to the Brownian motion of nanoparticles, which increases both mixing and heat transport within the nanofluid [16][17]. Later, several studies demonstrated that interactions between liquid atoms and nanoparticles (i.e., a liquid adsorption

• dynamic simulations with EAM and the Dreiding force field to investigate different properties of thermal transport of water/CuO nanofluids. They calculated similar thermal conductivity values for water from 303–323 K, as in our case (i.e., 0.59–0.66 W·m−1·K−1, respectively). Then they added CuO

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• is associated with the reduction of I3− at the cathode (CE/electrolyte), while the second one in the low-frequency region is attributed to electron transport in the TiO2 film in the back reaction at the TiO2/electrolyte interface (TiO2/dye/electrolyte). EIS data were fitted using an equivalent

Design and characterization of polymeric microneedles containing extracts of Brazilian green propolis

• Camila Felix Vecchi,
• Rafaela Said dos Santos,
• Jéssica Bassi da Silva and
• Marcos Luciano Bruschi

Beilstein J. Nanotechnol. 2022, 13, 503–516, doi:10.3762/bjnano.13.42

• epidermis, and are later removed [6][14]. The application of MNs creates a transport pathway for the delivery of molecules, crossing external barriers that limit the introduction of molecules into the target tissue. Furthermore, MNs are very versatile and are considered less painful, less harmful, and more

• gastrointestinal one. Despite the great therapeutic potential, the use of this pathway is limited by the low permeation of molecules through the stratum corneum, the outermost layer of the skin, which works as a barrier, blocking the transport of drugs through the subcutaneous tissue. To overcome this difficulty

Ethosomal (−)-epigallocatechin-3-gallate as a novel approach to enhance antioxidant, anti-collagenase and anti-elastase effects

• Çiğdem Yücel,
• Gökçe Şeker Karatoprak,
• Sena Yalçıntaş and
• Tuğba Eren Böncü

Beilstein J. Nanotechnol. 2022, 13, 491–502, doi:10.3762/bjnano.13.41

• solution form of EGCG for the transdermal delivery of EGCG. The parameters considered were antioxidant and enzymes inhibition effects, transport properties across cell monolayers, and better stability profiles. These evident effects of EGCG via ethosomal formulations might help to optimize the targeting of

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• create ultrathin carbon nanomembranes (CNMs) [25][26]. Depending on the precursor molecules and the exposure conditions, thickness [27], mechanical stiffness [28], and electronic transport characteristics [29][30] of CNMs can be tailored. Carbon nanomembranes have been applied as electron microscopy

Tunable superconducting neurons for networks based on radial basis functions

• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Igor I. Soloviev,
• Mikhail Yu. Kupriyanov,
• Maxim V. Tereshonok and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2022, 13, 444–454, doi:10.3762/bjnano.13.37

• layers supports the superconducting order parameter and increases the efficiency of the spin valve effect [58]. Here, we propose a development of this approach, allowing one to significantly increase the effective variations in the kinetic inductance. We study proximity effect and electronic transport in

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

• Ali Javed,
• Felix Steinke,
• Stephan Wöhlbrandt,
• Hana Bunzen,
• Norbert Stock and
• Michael Tiemann

Beilstein J. Nanotechnol. 2022, 13, 437–443, doi:10.3762/bjnano.13.36

• of covalent bonds and hydrogen bonds between adjacent molecules, without mass transport [25]. For bulk liquid water, this is known as the Grotthuß mechanism, with reported activation energy values of 0.10–0.11 eV [26][27]. In the materials studied here, proton hopping can occur between H2O/H3O+ and

• conduction occurs by mass transport (i.e., by cation diffusion of, e.g., H3O+), activation energies higher than 0.4 eV are expected [28]. This mechanism seems to dominate the additional conduction mode in the non-activated Mg-CP sample, where an activation energy of 0.64 eV is observed. This is consistent

A broadband detector based on series YBCO grain boundary Josephson junctions

• Egor I. Glushkov,
• Alexander V. Chiginev,
• Leonid S. Kuzmin and
• Leonid S. Revin

Beilstein J. Nanotechnol. 2022, 13, 325–333, doi:10.3762/bjnano.13.27

• of magnitude [34][35]. It does not take into account the increase in output noise due to the influence of low-frequency noise spectra of the critical current fluctuations δIc and normal resistance fluctuations δRN associated with the transport mechanisms of the Cooper pairs and quasiparticles

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• of gold nanoparticles and contacted by nanoelectrodes. The resulting small-area nanodevices were thoroughly electrically characterized as a function of temperature and light exposure. Differences in the resulting device conductance could be attributed to the device design and the respective transport

• makes them superior candidates for charge transport studies and functional nanodevices [16][17][18]. Using TP-based ligands and a reactive Ru precursor, we recently succeeded to establish a room-temperature method to grow Ru-TP supramolecular wires by sequential reaction [19]. The stepwise wire growth

• constituting building blocks. For this purpose, the transport properties of the redox-active Ru(TP)2-complexes are studied under electrical or optical triggering in Ru(TP)2-complex wire devices and in Ru(MPTP)2–AuNP devices. Both devices are based on the same nanoelectrode design and are composed of analogous

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• predominantly point defects, that is, defects associated with one lattice point, such as cation or oxygen ion vacancies. OVs determine the physical and chemical properties of metal oxides. Figure 4a shows the natural crystal structure of SnO2 synthesized by vapor transport [48]. The (110) plane of rutile SnO2

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• to conventional diode discharges. In turn, lowering the working pressure while keeping a high discharge current density, that is, a few tens of millamperes per square centimeter, allows for increasing the target erosion rate and facilitates the transport of the sputtered atoms towards the substrate

• are expelled out of the surface, that is, sputtered. More information about the theory of ion-induced sputtering can be found in [8]. Ion–surface interaction and sputtering yield data can be calculated using codes such as SRIM [35] and TRYDIN [36], while transport of the sputtered species through the

• presence of a temperature gradient might influence the physicochemical properties of the host liquid and the transport of matter inside the liquid medium. It is possible to sputter two or more elements simultaneously by setting up the sputtering apparatuses identical to the one presented in Figure 3 with

Design aspects of Bi₂Sr₂CaCu₂O_8+δ THz sources: optimization of thermal and radiative properties

• Mikhail M. Krasnov,
• Natalia D. Novikova,
• Roger Cattaneo,
• Alexey A. Kalenyuk and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 1392–1403, doi:10.3762/bjnano.12.103

• dissipation power, Pgen, of the generator mesa. For the whisker-based device (c) a profound emission occurs at the step in the I–V marked in panel (a). For the crystal-based device (d) only a small monotonic increment of Rdet vs Pgen is observed, caused by gradual self-heating. Heat transport in a whisker

• -based device without electrodes. (a) A sketch of the device and (b) a cross section through the mesa (not to scale). (c–e) Calculated temperature distribution for the device in vacuum. (f–h) The same for the device in exchange He gas. Heat transport in a whisker-based device with an electrode. (a) A

• sketch of the device and (b) a cross section through the mesa (not to scale). (c–e) Calculated temperature distribution for the device in vacuum. (f–h) The same for the device in exchange He gas. Heat transport in a crystal-based device in vacuum (a) without electrodes, (b) with electrodes. The left

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• indicator for local changes of the defect chemistry, as it is directly related to the local Fermi level [20]. The defect chemistry of acceptor-doped ceria and the oxide ion/electronic transport within ceria single-phase materials and also for ceria-based dual-phase materials is well understood at

• expected to be in the spinel region rather than on another site of the ceria phase. Another possible explanation would be that enhanced charge transport by electrons occurs along the grain boundary. This has already been confirmed experimentally for similar composite materials [33]. In this case, an

• the sign of the polarization, it was observed in some cases that charge is obviously distributed along scratches on the surface, which were introduced by polishing. This underlines the hypothesis, that fast charge transport in ceria-based materials via the uppermost surface layers is still possible at

Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• diagram [2] and Gibb’s energies [3], were determined. In other works, the crystallographic phases Cr3Ge, Cr5Ge3, Cr11Ge8, CrGe, and Cr11Ge19 were synthetized using chemical vapor transport [4]. Also, Cr11Ge19 in the form of large single crystals was obtained using a two-zone vertical gradient freeze

• /filled nanoscale cables suitable for medicinal magnetic transport. Experimental CrGex deposits were synthetized using CVD. In a custom-made twin furnace (Supporting Information File 1, Figure S12), chromium(III) acetylacetonate powder (Sigma-Aldrich, 99.99%) was heated to 110 °C and evaporated in the

Nonmonotonous temperature dependence of Shapiro steps in YBCO grain boundary junctions

• Leonid S. Revin,
• Dmitriy V. Masterov,
• Alexey E. Parafin,
• Sergey A. Pavlov and
• Andrey L. Pankratov

Beilstein J. Nanotechnol. 2021, 12, 1279–1285, doi:10.3762/bjnano.12.95

• analysis of the transport properties, the best structure was selected and located at the center of a Si lens for efficient detection. The sample was mounted into a dry cryostat allowing for measurements in a wide temperature range from helium temperatures to ≈80 K. An external gigahertz signal was fed

• through an optical window with IR filters using a semiconductor synthesizer with a multiplier (70–78 GHz) or using a backward wave oscillator (230–370 GHz). The JJ transport properties and the response were characterized by a precise Keithley low-noise current source and nanovoltmeter using a standard 4

Electrical, electrochemical and structural studies of a chlorine-derived ionic liquid-based polymer gel electrolyte

• Ashish Gupta,
• Amrita Jain,
• Manju Kumari and
• Santosh K. Tripathi

Beilstein J. Nanotechnol. 2021, 12, 1252–1261, doi:10.3762/bjnano.12.92

• predominantly crystalline PVdF phase and an amorphous HFP phase, which provides necessary mechanical strength and good ion transport matrix. Magnesium-based electrochemical devices are emerging as an alternative to lithium-based devices [26][27][28][29][30]. Magnesium can be an alternative due to its

• polymer gel electrolytes (log σ as a function of 1000/T). From the plot, it can be seen that the thermal dependence of the conductivity follows the Vogel–Tammann–Fulcher (VTF) equation, which is commonly used to explain the ion transport in amorphous polymer electrolytes [36][37]: where A is a constant

• that shows the conductivity at an infinitely high temperature, the parameter B is the pseudo-activation energy and it is related to the critical free volume for ion transport, and T0 is a reference temperature, also called equilibrium glass transition temperature, which has a value close to the Tg

A review on slip boundary conditions at the nanoscale: recent development and applications

• Ruifei Wang,
• Jin Chai,
• Bobo Luo,
• Xiong Liu,
• Jianting Zhang,
• Min Wu,
• Mingdan Wei and
• Zhuanyue Ma

Beilstein J. Nanotechnol. 2021, 12, 1237–1251, doi:10.3762/bjnano.12.91

• applied to solve problems associated with macroscopic flows [2][3][4][5]. However, in the field of fluid transport at the micro-/nanoscale, the problem is not that simple and a possible deviation from the classical hypothesis may take place, resulting in liquid slippage at solid surfaces [6][7][8][9]. In

• and fabrication of nanofluidic devices. In addition, understanding the slip flow behavior in nanoporous media is also of great significance in the field of development of shale reservoirs [22]. The shale oil transport could be enhanced due to the positive slip length compared with that of the no-slip

• transport model [16]. Moreover, increasing the slip length can also raise the energy conversion efficiency from mechanical to electrical energy of the nanofluidic devices due to the reduction of flow resistance. For instance, it was shown that a slip length of 50 nm could increase the efficiency of energy

Impact of electron–phonon coupling on electron transport through T-shaped arrangements of quantum dots in the Kondo regime

• Patryk Florków and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2021, 12, 1209–1225, doi:10.3762/bjnano.12.89

• ; polarons; quantum dots; Introduction As the dimension of a mesoscopic system decreases, interactions between electrons become more important and many-body resonances build up. As a consequence, new transport paths are opened. The key phenomenon of strong correlations is the Kondo effect, which arises from

• already a well-established branch of research. The attached objects act as scatterers for electron transmission through the quantum wire and allow one to tune its transport properties. In T-shaped systems, the interference of different conduction paths can lead to Fano antiresonance manifesting as a dip

• ultrafast sensors, actuators, and signal processing components. Of special interest are molecular systems because molecules due to their softness easily deform during tunneling processes, giving rise to excitation of local phonon modes. The polaronic transport through molecular systems has been recently