Electron interactions with the heteronuclear carbonyl precursor H₂FeRu₃(CO)₁₃ and comparison with HFeCo₃(CO)₁₂: from fundamental gas phase and surface science studies to focused electron beam induced deposition

• Ragesh Kumar T P,
• Paul Weirich,
• Lukas Hrachowina,
• Marc Hanefeld,
• Ragnar Bjornsson,
• Helgi Rafn Hrodmarsson,
• Sven Barth,
• D. Howard Fairbrother,
• Michael Huth and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2018, 9, 555–579, doi:10.3762/bjnano.9.53

• ; focused electron beam induced deposition; heteronuclear FEBID precursors; surface science; Introduction Direct-write technologies using electron beams for nanostructure deposition can surpass the limitations of standard lithography techniques, such as the growth of three-dimensional nanostructures with

• such as magnetism at the nanoscale. Magnetic nanostructures are fundamental building blocks for applications in data storage and processing as well as the potential successor technologies based on magnonics [67] and spintronics [68] combined with high integration density relying on 3D nanostructure

Single-step process to improve the mechanical properties of carbon nanotube yarn

• Maria Cecilia Evora,
• Xinyi Lu,
• Nitilaksha Hiremath,
• Nam-Goo Kang,
• Kunlun Hong,
• Roberto Uribe,
• Gajanan Bhat and
• Jimmy Mays

Beilstein J. Nanotechnol. 2018, 9, 545–554, doi:10.3762/bjnano.9.52

• high-performance carbon fibers. The reasons for the lower tensile strength compared to carbon fibers are believed to be defects and an inhomogeneous nanostructure, very weak interactions between CNTs, and the packing of CNT bundles [17][18]. It is still a challenge to develop a method that can produce

Green synthesis of fluorescent carbon dots from spices for in vitro imaging and tumour cell growth inhibition

• Nagamalai Vasimalai,
• Vânia Vilas-Boas,
• Juan Gallo,
• María de Fátima Cerqueira,
• Mario Menéndez-Miranda,
• José Manuel Costa-Fernández,
• Lorena Diéguez,
• Begoña Espiña and
• María Teresa Fernández-Argüelles

Beilstein J. Nanotechnol. 2018, 9, 530–544, doi:10.3762/bjnano.9.51

• %, respectively, whereas there was no significant growth inhibition to non-cancerous cells. Our preliminary results showed that this effect might be attributed to the presence of active molecules within the C-dot nanostructure, and more studies should be performed to understand the mechanism of action. Although

Sugarcane juice derived carbon dot–graphitic carbon nitride composites for bisphenol A degradation under sunlight irradiation

• Lan Ching Sim,
• Jing Lin Wong,
• Chen Hong Hak,
• Jun Yan Tai,
• Kah Hon Leong and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2018, 9, 353–363, doi:10.3762/bjnano.9.35

• great support to attach with CDs. After incorporating the CDs, the CD/g-C3N4 composites exhibited a more packed and agglomerated morphological nanostructure compared to that of pure g-C3N4. A similar observation was reported in our previous research [28], showing that the clustered effect was attributed

Review: Electrostatically actuated nanobeam-based nanoelectromechanical switches – materials solutions and operational conditions

• Liga Jasulaneca,
• Jelena Kosmaca,
• Raimonds Meija,
• Jana Andzane and
• Donats Erts

Beilstein J. Nanotechnol. 2018, 9, 271–300, doi:10.3762/bjnano.9.29

• continuum-based theories may occur. For instance, for cantilevered resonating nanostructures, continuum mechanics predictions fail when the cross-sectional area of the nanostructure is on the order of tens of lattice constants [3]. At this level, quantum effects, crystalline perfection, surface and

• contact area [8][10][11][54], observe the electrical breakdown mechanism for a single nanostructure [55][56][57][58], and investigate the dynamic processes occurring in the switch nanocontact [54]. The durability of a NEM switch strongly depends on the evolution of the contact between the switching

• [110]; (3) Young’s modulus shows almost no dependence on the diameter of metal nanowires, for example, for Au [111]. The change of the Young’s modulus can be explained by an increased influence of the surface atoms on the overall elastic behaviour of the nanostructure at sizes below a few nanometres

Dopant-stimulated growth of GaN nanotube-like nanostructures on Si(111) by molecular beam epitaxy

• Alexey D. Bolshakov,
• Alexey M. Mozharov,
• Georgiy A. Sapunov,
• Igor V. Shtrom,
• Nickolay V. Sibirev,
• Vladimir V. Fedorov,
• Evgeniy V. Ubyivovk,
• Maria Tchernycheva,
• George E. Cirlin and
• Ivan S. Mukhin

Beilstein J. Nanotechnol. 2018, 9, 146–154, doi:10.3762/bjnano.9.17

• the study, we introduce a new dopant-stimulated method for GaN nanotube-like nanostructure synthesis using a high-intensity Si flux. Transmission electron microscopy was used to investigate the morphological features of the GaN nanostructures. The synthesized structures have a hexagonal cross-section

• and possess high crystal quality. We propose a theoretical model of the novel nanostructure formation which includes the role of the dopant Si. Some of the Si-doped samples were studied with the photoluminescence (PL) technique. The analysis of the PL spectra shows that the highest value of donor

• efficiency of over 20% in such a simple SC [9]. The development of controllable methods of GaN nanostructure growth and doping on Si substrates opens up new possibilities for integration of III–V materials with established CMOS technology. The latter issue represents one of the bottlenecks of modern opto

Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition

• Ziyan Warneke,
• Markus Rohdenburg,
• Jonas Warneke,
• Janina Kopyra and
• Petra Swiderek

Beilstein J. Nanotechnol. 2018, 9, 77–90, doi:10.3762/bjnano.9.10

• deposition; nanostructure purification; platinum precursor; Introduction Focused electron beam induced deposition (FEBID) produces solid nanomaterials with size down to the sub-10 nm regime by decomposing precursor molecules adsorbed on a surface under a tightly focused high-energy electron beam [1

• obtain insight into some mechanistic aspects of the water-assisted purification process. Our results provide a fundament for the molecular understanding and rational control of FEBID nanostructure purification using water as process gas [12] with additional implications for the stability of the

• precursor were thus deposited on the surface so that the resulting deposit had an estimated thickness in the range of a typical FEBID nanostructure [12]. This deposit was then used for a desorption experiment to study the reactions occuring during a water-assisted purification process (Figure 8). We note

Gas-sensing behaviour of ZnO/diamond nanostructures

• Marina Davydova,
• Alexandr Laposa,
• Jiri Smarhak,
• Alexander Kromka,
• Neda Neykova,
• Josef Nahlik,
• Jiri Kroutil,
• Jan Drahokoupil and
• Jan Voves

Beilstein J. Nanotechnol. 2018, 9, 22–29, doi:10.3762/bjnano.9.4

• cell electrodes, light emitting devices, quantum dots and gas sensors [5][6][7][8][9][10][11][12][13]. The improvement in response of metal-oxide sensors has been observed by several authors, due to the formation of isolated functional layers on the one-dimensional nanostructure surface using metal

Facile synthesis of silver/silver thiocyanate (Ag@AgSCN) plasmonic nanostructures with enhanced photocatalytic performance

• Xinfu Zhao,
• Dairong Chen,
• Abdul Qayum,
• Bo Chen and
• Xiuling Jiao

Beilstein J. Nanotechnol. 2017, 8, 2781–2789, doi:10.3762/bjnano.8.277

• 84% oxytetracycline was degraded in 60 min in the fifth cycle, and the efficiency was almost the same as for the first cycle. Further investigations revealed that after five cyclic experiments, the microstructure of Ag@AgSCN had no obvious changes except a somewhat smoother Ag@AgSCN nanostructure

• content of Ag in Ag@AgSCN nanostructures can be controlled by simply adjusting the irradiation time of the UV light. The catalytic performance of the nanostructure was evaluated by degradation of oxytetracycline under visible-light irradiation. The Ag@AgSCN nanostructures showed high photocatalytic

• -Elmer Lambda-35 UV–vis spectrometer. (a) XRD patterns of Ag@AgSCN nanostructures with different molar ratios of Ag to AgSCN. An (b) SEM image and (c) SAED pattern of the Ag@AgSCN nanostructure (sample M2). (a) UV–vis diffuse reflectance spectra of M0, M1, M2, M3, M4, M5. (b) Kubelka–Munk plots of M0 and

Enhanced photoelectrochemical water splitting performance using morphology-controlled BiVO₄ with W doping

• Xin Zhao and
• Zhong Chen

Beilstein J. Nanotechnol. 2017, 8, 2640–2647, doi:10.3762/bjnano.8.264

• % increase). Keywords: bismuth vanadate; charge separation; nanostructure; photoelectrochemical water splitting; Introduction Solar hydrogen generation is one of the most promising approaches to create clean energy and to overcome the environmental problems associated with use of conventional fossil fuels

• values of ηsep and ηinj of the planar and porous W-doped BiVO4 are shown in Figure 5b and 5c. ηsep at 1.23 V vs RHE of the planar and porous W-doped BiVO4 are, respectively, 41% and 47%, representing a 14% increase by the nanostructure formation. ηinj at 1.23 V vs RHE of the planar and porous W-doped

• BiVO4 are, respectively, 55% and 66%, corresponding to a 20% increase by the nanostructure formation. It has been reported that porous structures can shorten the hole diffusion distance to the surface and, thus, enhance the charge separation efficiency close to 60% at 1.23 V vs RHE [12]. Our finding is

Localized growth of carbon nanotubes via lithographic fabrication of metallic deposits

• Fan Tu,
• Martin Drost,
• Imre Szenti,
• Janos Kiss,
• Zoltan Kónya and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2017, 8, 2592–2605, doi:10.3762/bjnano.8.260

• , hindering the coalescence of Fe nanoparticles, resulting in more active sites for CNT nucleation [28][29][30]. A peculiar lift-up of the CNT nanostructure was also observed for the first time. Based on energy dispersive X-ray (EDX) spectroscopy and SEM data, the corresponding mechanism is also discussed

• directly contribute to the CNT growth for example by catalytic carbon source dissociation [30]. As depicted in Figure 6f, a spatially well-defined 4 × 4 µm2 CNT nanostructure with high density was synthesized, indicating the possibility to produce CNT forest structures by further exploring the experimental

• accelerating voltage in keV and ρ is the density of the detected sample. Considering the thickness of Fe nanostructure is approximately ≈30 nm, one can expect ≈1.6% Fe signal, which is below the detection limit of the method [45]. In additional experiments on other samples, the fabrication of CNT forests and

Direct writing of gold nanostructures with an electron beam: On the way to pure nanostructures by combining optimized deposition with oxygen-plasma treatment

• Domagoj Belić,
• Mostafa M. Shawrav,
• Emmerich Bertagnolli and
• Heinz D. Wanzenboeck

Beilstein J. Nanotechnol. 2017, 8, 2530–2543, doi:10.3762/bjnano.8.253

• and/or sufficiently long DT lead to an increase of the Au content in the deposits. However, setting too small PPS and too long DT drastically increased the total deposition time to a few hours, even for a relatively small planar nanostructure having an area of a few square micrometers. Thus the PPS

• the main planar nanostructure, with more material deposited in the SSA direction, clearly indicating a shadowing effect. This likely occurred due to scattering of primary electrons on already deposited material, which resulted with favoured generation of secondary electrons in front of the deposit (as

• , the shape of the deposit was largely preserved, but more importantly, the EDX analysis showed an increase in Au content throughout the nanostructure. The enhancement factor (EF) was considerably larger on the initially Au-poor, “end” side (EF ≈ 4), while the initially Au-rich “beginning” side saw only

Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals

• Somi Kang,
• Sean E. Lehman,
• Matthew V. Schulmerich,
• An-Phong Le,
• Tae-woo Lee,
• Stephen K. Gray,
• Rohit Bhargava and
• Ralph G. Nuzzo

Beilstein J. Nanotechnol. 2017, 8, 2492–2503, doi:10.3762/bjnano.8.249

• a metal nanostructure (localized surface plasmons). The attributes of these excitations are highly sensitive to local refractive index changes, which in turn allow for their exploitation in chemical and biological sensing [7][8][9]. In this way, surface plasmonic resonance (SPR) sensors are

• frequencies. A ≈5 nm titanium dioxide adhesion layer was deposited using atomic layer deposition (Cambridge nanotech) on the embossed SOG nanostructure followed by deposition of a ≈50 nm metallic film (Au, Ag or both) via one of the various methods. Sputter deposition in a 5 mTorr argon atmosphere (AJA

Au nanostructure fabrication by pulsed laser deposition in open air: Influence of the deposition geometry

• Rumen G. Nikov,
• Anna Og. Dikovska,
• Nikolay N. Nedyalkov,
• Georgi V. Avdeev and
• Petar A. Atanasov

Beilstein J. Nanotechnol. 2017, 8, 2438–2445, doi:10.3762/bjnano.8.242

• water drop (Vd = 2 μL) with respect to the underlying substrate surface. Results and Discussion Nanostructure formation We present the general aspects of the nanostructure fabrication process using geometry 4 as an example, where the samples were deposited using a standard on-axis configuration

• procedure described in the Experimental section. The nanoparticles and aggregates produced in the ablated plasma led to the formation of a chain-like nanostructure on the substrate. SAED electron diffraction patterns of the nanostructure are also shown in Figure 1b. The interplanar distance from the main

• are arranged along the (111) reflection plane of Au, which possesses the lowest surface-free energy. This crystallite alignment leads to the chain-like nanostructure formation on the substrate, as shown in Figure 1b. The XPS analysis of the as-deposited Au nanostructure is presented in Figure 3. The

Comparing postdeposition reactions of electrons and radicals with Pt nanostructures created by focused electron beam induced deposition

• Julie A. Spencer,
• Michael Barclay,
• Miranda J. Gallagher,
• Robert Winkler,
• Ilyas Unlu,
• Yung-Chien Wu,
• Harald Plank,
• Lisa McElwee-White and
• D. Howard Fairbrother

Beilstein J. Nanotechnol. 2017, 8, 2410–2424, doi:10.3762/bjnano.8.240

• demonstrated great potential in the field of nanostructure fabrication [1][2][3][4]. In FEBID, a volatile organometallic precursor is introduced into a vacuum chamber (typically a modified scanning electron microscope (SEM)) and irradiated by a focused electron beam [2][3]. The precursor decomposes under

• electron beam irradiation, with non-volatile product species being incorporated into the growing deposit. The size and shape of the nanostructure are controlled by manipulation of the electron beam (focusing ability and patterning capabilities), which allows an almost unlimited array of three-dimensional

• impact the shape integrity of the deposits by producing voids, cracks or other unwanted side effects [5][9][10][14][15]. An ideal purification strategy in FEBID is one that removes all of the organic impurities to leave behind a compact, high-fidelity metal nanostructure, whose shape is unchanged as

Increasing the stability of DNA nanostructure templates by atomic layer deposition of Al₂O₃ and its application in imprinting lithography

• Hyojeong Kim,
• Kristin Arbutina,
• Anqin Xu and
• Haitao Liu

Beilstein J. Nanotechnol. 2017, 8, 2363–2375, doi:10.3762/bjnano.8.236

• Hyojeong Kim Kristin Arbutina Anqin Xu Haitao Liu Department of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, Pennsylvania 15260, United States of America 10.3762/bjnano.8.236 Abstract We present a method to increase the stability of DNA nanostructure templates through

• resistive to UV/O3 oxidation. The ALD-coated DNA templates were used for a direct pattern transfer to poly(L-lactic acid) films. Keywords: aluminium oxide (Al2O3); atomic layer deposition; DNA nanostructure; nanofabrication; nanoimprint lithography; pattern transfer; polymer stamp; replica molding

• ; Introduction In 1982, Seeman et al. first introduced the idea of utilizing DNA to build a mechanically robust nanostructure [1]. Since then, the field of structural DNA nanotechnology has evolved remarkably from immobile Holliday junctions to complex shapes fabricated from single-stranded tiles [2][3]. Through

Surfactant-induced enhancement of droplet adhesion in superhydrophobic soybean (Glycine max L.) leaves

• Oliver Hagedorn,
• Ingo Fleute-Schlachter,
• Hans Georg Mainx,
• Viktoria Zeisler-Diehl and
• Kerstin Koch

Beilstein J. Nanotechnol. 2017, 8, 2345–2356, doi:10.3762/bjnano.8.234

• and five variations of nonionic surfactants) have been investigated. The leaf surface structures show a hierarchical organization, built up by convex epidermal cells (microstructure) and superimposed epicuticular platelet-shaped wax crystals (micro- to nanostructure). Chemical analysis of the

Molecular dynamics simulations of nanoindentation and scratch in Cu grain boundaries

• Shih-Wei Liang,
• Ren-Zheng Qiu and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2017, 8, 2283–2295, doi:10.3762/bjnano.8.228

• and adhesion when a probe touches the substrate) between Ni (probe) and Au (thin film substrate) under nanoindentation conditions using MD simulations. Moreover, Mulliah et al. [18] analyzed the friction coefficient, the dislocation, and related parameters of the nanostructure under nanoscratch

Hydrothermal synthesis of ZnO quantum dot/KNb₃O₈ nanosheet photocatalysts for reducing carbon dioxide to methanol

• Xiao Shao,
• Weiyue Xin and
• Xiaohong Yin

Beilstein J. Nanotechnol. 2017, 8, 2264–2270, doi:10.3762/bjnano.8.226

• excellent nonlinear optical, piezoelectric, ferroelectric, ionic conductivity, selective-ion exchange and photocatalytic properties [6][7][8][9]. Zhang et al. prepared K4Nb6O17 with a sheet-like nanostructure by hydrothermal synthesis and found its photocatalytic activity for degrading acidic red G to be

Vapor-based polymers: from films to nanostructures

• Meike Koenig and
• Joerg Lahann

Beilstein J. Nanotechnol. 2017, 8, 2219–2220, doi:10.3762/bjnano.8.221

• desired nanostructures. This combination of a conductive polymer with a hydrogel in a single nanostructure shows potential for the use in humidity sensors. Without the need for additives or solvents, a high purity of the resulting film is ensured, which is of paramount importance in the area of electronic

Evaluating the toxicity of TiO₂-based nanoparticles to Chinese hamster ovary cells and Escherichia coli: a complementary experimental and computational approach

• Alicja Mikolajczyk,
• Natalia Sizochenko,
• Ewa Mulkiewicz,
• Anna Malankowska,
• Michal Nischk,
• Przemyslaw Jurczak,
• Seishiro Hirano,
• Grzegorz Nowaczyk,
• Adriana Zaleska-Medynska,
• Jerzy Leszczynski,
• Agnieszka Gajewicz and
• Tomasz Puzyn

Beilstein J. Nanotechnol. 2017, 8, 2171–2180, doi:10.3762/bjnano.8.216

• nanoparticles, to model their quantitative nanostructure–toxicity relationships and to reveal the toxicity mechanism. In this context, toxicity tests for surface-modified TiO2-based nanoparticles were performed in vitro, using Gram-negative bacteria Escherichia coli and Chinese hamster ovary (CHO-K1) cells. The

Modelling focused electron beam induced deposition beyond Langmuir adsorption

• Dédalo Sanz-Hernández and
• Amalio Fernández-Pacheco

Beilstein J. Nanotechnol. 2017, 8, 2151–2161, doi:10.3762/bjnano.8.214

• account of FEBID at the molecular level [27]. A key ingredient to much of this recent progress is the FEBID continuum model [25], which describes the time evolution of adsorbate concentration on a substrate as a function of the various processes comprising FEBID. This model describes nanostructure

Systematic control of α-Fe₂O₃ crystal growth direction for improved electrochemical performance of lithium-ion battery anodes

• Nan Shen,
• Miriam Keppeler,
• Barbara Stiaszny,
• Holger Hain,
• Filippo Maglia and
• Madhavi Srinivasan

Beilstein J. Nanotechnol. 2017, 8, 2032–2044, doi:10.3762/bjnano.8.204

• α-Fe2O3 nanoparticles (e.g. nanorods with hexagonal structure, electrospun nanorods, and nanowires) or other morphologies (e.g. nanotubes, flower-like nanostructure, spindles, and hollow spheres) showed a notable electrochemical performance in the interaction with lithium. The results are also

Freestanding graphene/MnO₂ cathodes for Li-ion batteries

• Şeyma Özcan,
• Aslıhan Güler,
• Tugrul Cetinkaya,
• Mehmet O. Guler and
• Hatem Akbulut

Beilstein J. Nanotechnol. 2017, 8, 1932–1938, doi:10.3762/bjnano.8.193

• nanostructure composed of uniform nanowires have 1–2 μm length and 40–60 nm average diameter. β-MnO2 (Figure 1b) shows that the as-prepared β-MnO2 sample has a nanorod structure with 0.5–1 μm length and 20–40 nm average diameter. The γ-MnO2 (Figure 1c) exhibits an urchin-like structure with 0.5–1 μm average

Near-infrared-responsive, superparamagnetic Au@Co nanochains

• Varadee Vittur,
• Arati G. Kolhatkar,
• Shreya Shah,
• Irene Rusakova,
• Dmitri Litvinov and
• T. Randall Lee

Beilstein J. Nanotechnol. 2017, 8, 1680–1687, doi:10.3762/bjnano.8.168

• average outer diameter of 75 ± 3 nm, in close contact with each other; the shell is rough, with a typical thickness of about 14 ± 6 nm. Moreover, some pinholes were observed in the wall of the bimetallic nanochains, indicating the formation of a hollow nanostructure as shown in Figure 2c. Figure 3

• the hollow nanostructure. As noted above, PVP is widely used as a colloidal stabilizer to inhibit the aggregation of metal nanoparticles such as gold [49][50][51][52], silver [53][54], platinum [55][56][57], palladium [46][57][58][59], nickel [60][61], and cobalt [62][63]. To verify this hypothesis in