Si/Ge intermixing during Ge Stranski–Krastanov growth

• Alain Portavoce,
• Khalid Hoummada,
• Antoine Ronda,
• Dominique Mangelinck and
• Isabelle Berbezier

Beilstein J. Nanotechnol. 2014, 5, 2374–2382, doi:10.3762/bjnano.5.246

• concentration reaching ≈15 atom % in the rest of the island. The composition of Ge islands depends on the growth conditions. Ge islands exhibiting a Si-rich core were shown to correspond to growth conditions allowing for near-equilibrium states to be reached, which is more typical for the case of chemical vapor

• deposition [34]. Ge islands exhibiting a Ge-rich core were shown to be related to growth conditions promoting far-from-equilibrium states, controlled by kinetic processes, which is more typical for the case of MBE growth [34]. Equilibrium is reached through free energy minimization, taking into account the

Gas sensing properties of nanocrystalline diamond at room temperature

• Marina Davydova,
• Pavel Kulha,
• Alexandr Laposa,
• Karel Hruska,
• Pavel Demo and
• Alexander Kromka

Beilstein J. Nanotechnol. 2014, 5, 2339–2345, doi:10.3762/bjnano.5.243

• of the NCD sensor is discussed. Finally, a simulation of the distribution of the current density of H-terminated NCD is presented. Results and Discussion Hot plasma microwave PECVD system Microwave plasma chemical vapor deposition is a well-established process for the fast growth of high quality

• growth proceeded in two steps: first, seeding for 1, 2, 5 or 40 min, followed by treatment by with microwave plasma-enhanced chemical vapor deposition (PECVD). The diamond layers were grown either by focused microwave PECVD (Aixtron P6, named as “hot plasma”) or pulsed-linear antenna microwave PECVD

Sequence-dependent electrical response of ssDNA-decorated carbon nanotube, field-effect transistors to dopamine

• Hari Krishna Salila Vijayalal Mohan,
• Jianing An and
• Lianxi Zheng

Beilstein J. Nanotechnol. 2014, 5, 2113–2121, doi:10.3762/bjnano.5.220

• repeated-ssDNA-decorated SWCNT FETs to DA, in the presence and absence of UA. Experimental SWCNT growth and FET fabrication Long, individual SWCNTs were grown on n+-doped Si capped by 1 µm of SiO2, thermally grown via chemical vapor deposition (CVD) using 0.01 M FeCl3 ethanol solution as the catalytic

Effect of channel length on the electrical response of carbon nanotube field-effect transistors to deoxyribonucleic acid hybridization

• Hari Krishna Salila Vijayalal Mohan,
• Jianing An,
• Yani Zhang,
• Chee How Wong and
• Lianxi Zheng

Beilstein J. Nanotechnol. 2014, 5, 2081–2091, doi:10.3762/bjnano.5.217

• chemical vapor deposition (CVD) process at 950 ºC was utilized to grow SWCNTs, in which 0.01 M FeCl3 ethanol solution was used as the catalytic precursor similar to our previous works [22][23]. Fabrication of SWCNT-based FETs We prepared three types of SWCNT-based FETs with different channel lengths, L

Cathode lens spectromicroscopy: methodology and applications

• T. O. Menteş,
• G. Zamborlini,
• A. Sala and
• A. Locatelli

Beilstein J. Nanotechnol. 2014, 5, 1873–1886, doi:10.3762/bjnano.5.198

• vapor deposition (CVD) technique. CVD utilizes transition metal catalysts as a means to promote the dissociative adsorption of gases such as ethylene or methane, which can readily deliver the carbon atoms required for island nucleation and growth. LEEM is widely employed to image the growth process; the

• peak photoelectron current in XPEEM. SPELEEM studies of graphene epilayers LEEM has found ample use in graphene research with its high structural sensitivity and video acquisition rate allowing for dynamic measurements of film growth. In such experiments, graphene is typically obtained by the chemical

Donor–acceptor graphene-based hybrid materials facilitating photo-induced electron-transfer reactions

• Anastasios Stergiou,
• Georgia Pagona and
• Nikos Tagmatarchis

Beilstein J. Nanotechnol. 2014, 5, 1580–1589, doi:10.3762/bjnano.5.170

• exhibiting unique mechanical [1] and electronic properties [2] and can be described as one of the most extensively examined materials of recent years [3][4]. Diverse approaches have been developed to obtain graphene sheets, including the mechanical cleavage of graphite [3], chemical vapor deposition on metal

Fringe structures and tunable bandgap width of 2D boron nitride nanosheets

• Peter Feng,
• Muhammad Sajjad,
• Eric Yiming Li,
• Hongxin Zhang,
• Jin Chu,
• Ali Aldalbahi and
• Gerardo Morell

Beilstein J. Nanotechnol. 2014, 5, 1186–1192, doi:10.3762/bjnano.5.130

• either chemical-solution-derived method or a chemical vapor deposition (CVD) process. Many excellent results have been reported [6][7][8][9]. Systematic and comprehensive reviews of two-dimensional (2D) boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene have been

Electron-beam induced deposition and autocatalytic decomposition of Co(CO)₃NO

• Florian Vollnhals,
• Martin Drost,
• Fan Tu,
• Esther Carrasco,
• Andreas Späth,
• Rainer H. Fink,
• Hans-Peter Steinrück and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2014, 5, 1175–1185, doi:10.3762/bjnano.5.129

• and film growth, i.e., chemical vapor deposition (CVD) [24]. For Co(CO)3NO, EBID was found up to about 393 K, followed by seeded growth up to about 403 K and spontaneous decomposition at higher temperatures. In the EBID regime, increasing the temperature from 293 to 323 K lowered the carbon content by

Nanocavity crossbar arrays for parallel electrochemical sensing on a chip

• Enno Kätelhön,
• Dirk Mayer,
• Marko Banzet,
• Andreas Offenhäusser and
• Bernhard Wolfrum

Beilstein J. Nanotechnol. 2014, 5, 1137–1143, doi:10.3762/bjnano.5.124

• . Afterwards, the top electrodes are fabricated from an electron-beam evaporated stack of chromium/platinum/titanium stack of the thicknesses 7/50/7 nm. Subsequently, a passivation composed of alternating layers. SiO2/Si3N4/SiO2 is deposited via plasma enhanced chemical vapor deposition [38]. In the next step

Methods for rapid frequency-domain characterization of leakage currents in silicon nanowire-based field-effect transistors

• Tomi Roinila,
• Xiao Yu,
• Jarmo Verho,
• Tie Li,
• Pasi Kallio,
• Matti Vilkko,
• Anran Gao and
• Yuelin Wang

Beilstein J. Nanotechnol. 2014, 5, 964–972, doi:10.3762/bjnano.5.110

• of the authors. The number of studies considering frequency-domain measurements of SiNW FETs is very low. The authors in [9] applied low-frequency noise spectroscopy (LFNS), and characterized generation–recombination centers in silicon nanowires grown by using chemical vapor deposition. Their aim was

Gas sensing with gold-decorated vertically aligned carbon nanotubes

• Prasantha R. Mudimela,
• Mattia Scardamaglia,
• Oriol González-León,
• Nicolas Reckinger,
• Rony Snyders,
• Eduard Llobet,
• Carla Bittencourt and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2014, 5, 910–918, doi:10.3762/bjnano.5.104

• Institute for Materials Science and Engineering, University of Mons, Mons, Belgium MINOS-EMaS, Universitat Rovira i Virgili, Tarragona, Spain 10.3762/bjnano.5.104 Abstract Vertically aligned carbon nanotubes of different lengths (150, 300, 500 µm) synthesized by thermal chemical vapor deposition and

A catechol biosensor based on electrospun carbon nanofibers

• Dawei Li,
• Zengyuan Pang,
• Xiaodong Chen,
• Lei Luo,
• Yibing Cai and
• Qufu Wei

Beilstein J. Nanotechnol. 2014, 5, 346–354, doi:10.3762/bjnano.5.39

• development, various methods used for CNFs preparation are established, such as arc-discharge [21], laser ablation [22], chemical vapor deposition (CVD) methods [23]. Electrospinning, which is known as a facile and convenient process, can produce nanofibers or microfibers with different diameters while using

Tensile properties of a boron/nitrogen-doped carbon nanotube–graphene hybrid structure

• Kang Xia,
• Haifei Zhan,
• Ye Wei and
• Yuantong Gu

Beilstein J. Nanotechnol. 2014, 5, 329–336, doi:10.3762/bjnano.5.37

• in the fields of mechanics, photology, electronics and bio-sensing [1][2]. Through the chemical vapor deposition (CVD) method, a graphene–nanotube hybrid structure (GNHS) has been synthesized recently [3][4][5], which evidently demonstrates an improved performance for the application as field

Modeling and optimization of atomic layer deposition processes on vertically aligned carbon nanotubes

• Nuri Yazdani,
• Vipin Chawla,
• Eve Edwards,
• Vanessa Wood,
• Hyung Gyu Park and
• Ivo Utke

Beilstein J. Nanotechnol. 2014, 5, 234–244, doi:10.3762/bjnano.5.25

• functionalization [19][20][21][22][23][24]. In practice, however, chemical vapor deposition (CVD) grown CNTs are prone to a sufficient density of surface defect sites to allow for the nucleation of the ceramic at discrete points along the surface of the CNT. The ceramic then grows from these nucleation sites until

• dioxide and aluminum oxide. To synthesize our VACNTs, a 3-nm-thick catalyst layer of iron on top of a 20-nm-thick layer of aluminum is deposited through electron beam evaporation onto a silicon wafer. The VACNTs are then grown by chemical vapor deposition in a cold-wall CVD system. The catalyst-covered

Cyclic photochemical re-growth of gold nanoparticles: Overcoming the mask-erosion limit during reactive ion etching on the nanoscale

• Burcin Özdemir,
• Axel Seidenstücker,
• Alfred Plettl and
• Paul Ziemann

Beilstein J. Nanotechnol. 2013, 4, 886–894, doi:10.3762/bjnano.4.100

• were prepared on top of the previously fabricated Au NP by chemical vapor deposition (CVD) rather than immersion of the silica substrates into OTMS solutions. Like immersion the much faster CVD method results in selective reactions of the methoxysilane functional groups with the silanol groups of the

• transferring the loaded inverse micelles onto the SiO2-substrate surface. In order to reduce the precursor into metallic Au and to completely remove the polymeric species, substrates were treated in H2-plasma (90 min at 160 W, Technics Plasma 100-E, Munich). Chemical vapor deposition of OTMS onto Au decorated

Synthesis of boron nitride nanotubes from unprocessed colemanite

• Saban Kalay,
• Zehra Yilmaz and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2013, 4, 843–851, doi:10.3762/bjnano.4.95

• yield, low cost and pure BNNTs. Keywords: boron nitride nanotube; chemical vapor deposition; colemanite; synthesis; Introduction Colemanite (Ca2B6O11·5H2O) is one of the most important compounds of more than 200 different boron ores. All boron ores include boron oxide (B2O3) at varying percentages in

• BNNTs are more toxic than CNTs [13]. The first BNNTs were synthesized by Chopra et al. with the arc-discharge method [14]. Later, the use of chemical vapor deposition (CVD), laser ablation, ball milling, a template-assisted process, and displacement reactions were reported for the synthesis [15][16][17

Surface passivation and optical characterization of Al₂O₃/a-SiC_x stacks on c-Si substrates

• Gema López,
• Pablo R. Ortega,
• Cristóbal Voz,
• Isidro Martín,
• Mónica Colina,
• Anna B. Morales,
• Albert Orpella and
• Ramón Alcubilla

Beilstein J. Nanotechnol. 2013, 4, 726–731, doi:10.3762/bjnano.4.82

• (ALD) at 200 °C and were complemented with a layer of a-SiCx deposited by plasma-enhanced chemical vapor deposition (PECVD) to form anti-reflection coating (ARC) stacks with a total thickness of 75 nm. A comparative study has been carried out on polished and randomly textured wafers. We have

Evolution of microstructure and related optical properties of ZnO grown by atomic layer deposition

• Adib Abou Chaaya,
• Roman Viter,
• Mikhael Bechelany,
• Zanda Alute,
• Donats Erts,
• Anastasiya Zalesskaya,
• Kristaps Kovalevskis,
• Vincent Rouessac,
• Valentyn Smyntyna and
• Philippe Miele

Beilstein J. Nanotechnol. 2013, 4, 690–698, doi:10.3762/bjnano.4.78

• different deposition techniques such as sol–gel [18], chemical vapor deposition [19], electro-deposition [5][6][7], RF sputtering, and atomic layer deposition (ALD) [16][17]. It is well known that the optoelectronic properties of zinc oxide thin film [20][21] are strongly dependent on the structure [11][22

A nano-graphite cold cathode for an energy-efficient cathodoluminescent light source

• Alexander N. Obraztsov,
• Victor I. Kleshch and
• Elena A. Smolnikova

Beilstein J. Nanotechnol. 2013, 4, 493–500, doi:10.3762/bjnano.4.58

• appropriate phosphor materials. In this paper we propose a nano-graphite film material as a highly efficient cold cathode, which is able to produce high intensity electron beams without energy consumption. The nano-graphite film material was produced by using chemical vapor deposition techniques. Prototypes

• stability of the FE process is stems from the weak interaction between these atomic layers, which lead to their splitting and detachment under the action of the strong electric field. This problem is essentially eliminated in mesoporous nano-graphite film (NGF) material obtained by chemical vapor deposition

• obtained by chemical vapor deposition (CVD) from a hydrogen/methane gas mixture activated by a direct current discharge. The details of the used home-made CVD system and the corresponding process are described in [13][14]. For the cathode production pieces of Ni wire with 1 mm diameter were placed in a CVD

Functionalization of vertically aligned carbon nanotubes

• Eloise Van Hooijdonk,
• Carla Bittencourt,
• Rony Snyders and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2013, 4, 129–152, doi:10.3762/bjnano.4.14

• were the synthesis on a large scale, the reproducibility, and the control of the diameter and number of walls of the CNTs using different synthesis techniques such as arc discharge, laser ablation or chemical vapor deposition. After these issues had been addressed, the focus in carbon nanotube research

• aligned CNTs from acetylene chemical vapor deposition (CVD) catalyzed by iron nanoparticles embedded in mesoporous silica. In that work, the growth direction of not very straight, entangled-CNTs was related to the direction of the pores in the silica substrate, being perpendicular to the substrate surface

• if the pores were vertical. Later, in 1998, the synthesis of very straight, aligned multiwalled CNTs on nickel-coated glass at temperatures as low as 666 °C was obtained by Ren et al. [24] using plasma-enhanced hot-filament chemical vapor deposition (PE-HF-CVD). Reported in 1999 by Fan et al. [25], a

Low-dose patterning of platinum nanoclusters on carbon nanotubes by focused-electron-beam-induced deposition as studied by TEM

• Xiaoxing Ke,
• Carla Bittencourt,
• Sara Bals and
• Gustaaf Van Tendeloo

Beilstein J. Nanotechnol. 2013, 4, 77–86, doi:10.3762/bjnano.4.9

• studies of functionalized CNTs. Experimental CNTs supported on a TEM grid are used as the deposition target. The samples are prepared by using commercially available multiwalled carbon nanotubes (MWCNTs) produced by arc discharge or chemical vapor deposition (CVD). The CNTs powder is sonically dispersed

Effect of normal load and roughness on the nanoscale friction coefficient in the elastic and plastic contact regime

• Aditya Kumar,
• Thorsten Staedler and
• Xin Jiang

Beilstein J. Nanotechnol. 2013, 4, 66–71, doi:10.3762/bjnano.4.7

• vapor deposition (Balzer BAS 450) utilizing a gas mixture of argon and acetylene at a bias voltage of −950 and −350 V, respectively. Topographical characterization: The surface morphology was characterized by atomic force microscopy (AFM, Park Systems Corp. XE-100). Noncontact AFM was used to obtain

• nanoindentation-based scratch test with linearly increasing load. Experimental Samples: As mentioned above, fused silica and DLC were chosen as sample materials. The fused silica was provided as a standard sample by Hysitron Inc. The DLC samples, 1µm thick films on Si(100) wafer, were synthesized by chemical

Diamond nanophotonics

• Katja Beha,
• Helmut Fedder,
• Marco Wolfer,
• Merle C. Becker,
• Petr Siyushev,
• Mohammad Jamali,
• Anton Batalov,
• Christopher Hinz,
• Jakob Hees,
• Lutz Kirste,
• Harald Obloh,
• Etienne Gheeraert,
• Boris Naydenov,
• Ingmar Jakobi,
• Florian Dolde,
• Sébastien Pezzagna,
• Daniel Twittchen,
• Matthew Markham,
• Daniel Dregely,
• Harald Giessen,
• Jan Meijer,
• Fedor Jelezko,
• Christoph E. Nebel,
• Rudolf Bratschitsch,
• Alfred Leitenstorfer and
• Jörg Wrachtrup

Beilstein J. Nanotechnol. 2012, 3, 895–908, doi:10.3762/bjnano.3.100

• incorporate color centers based on nickel and tungsten, in situ into diamond using microwave-plasma-enhanced chemical vapor deposition. The fabrication of silicon–vacancy centers in nanodiamonds by microwave-plasma-enhanced chemical vapor deposition is discussed in addition. Keywords: CVD diamond doping

• direct synthesis of diamond crystals by microwave plasma enhanced chemical vapor deposition (MWPECVD) offers an alternative route to integrate color centers and was investigated in addition to ion implantation [19][20]. We deposited single-crystal diamond layers of high phase and structural purity by

Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers

• Abdel-Aziz El Mel,
• Jean-Luc Duvail,
• Eric Gautron,
• Wei Xu,
• Chang-Hwan Choi,
• Benoit Angleraud,
• Agnès Granier and
• Pierre-Yves Tessier

Beilstein J. Nanotechnol. 2012, 3, 846–851, doi:10.3762/bjnano.3.95

• ) wrapping the nanowires could be considered as an outstanding shield protecting the metal cores against oxidation. Core–shell nanowires consisting of metal cores and graphene stacking shells, also known as metal-filled carbon nanotubes, are in general produced by chemical vapor deposition (CVD) [20][21][22

Influence of the diameter of single-walled carbon nanotube bundles on the optoelectronic performance of dry-deposited thin films

• Kimmo Mustonen,
• Toma Susi,
• Antti Kaskela,
• Patrik Laiho,
• Ying Tian,
• Albert G. Nasibulin and
• Esko I. Kauppinen

Beilstein J. Nanotechnol. 2012, 3, 692–702, doi:10.3762/bjnano.3.79

• comparison between the performances of SWCNT networks from chemical vapor deposition (CVD), HiPCO, laser ablation, and arc discharge sources; although, again involving liquid suspensions [15]. While these initial studies have been steps in the right direction, the damage induced by sample preparation and the