Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• 1s orbital of carbon. We attribute these contributions (CO32−, C–C/C–H, and C–O) to contamination from the ambient. As mentioned above, we performed the XPS measurements on these liquid samples without prior Ar+-ion sputtering or further heating inside the vacuum chamber of the XPS instrument. Given

• that these contributions arose from contamination by the ambient, we excluded them from our calculations of the surface chemical composition. Figure 6 shows that the surface oxide on the melt mainly consists of gallium and tin oxides, with a minor contribution from indium oxide. After heating at 100 °C

Hierachical epicuticular wax coverage on leaves of Deschampsia antarctica as a possible adaptation to severe environmental conditions

• Elena V. Gorb,
• Iryna A. Kozeretska and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2022, 13, 807–816, doi:10.3762/bjnano.13.71

• . macrophylla Jebb and Cheek, N. mirabilis (Lour.) Druce, and N. rafflesiana Jack [16][17]. The waxy (slippery) zone located inside the pitchers is highly specialized for trapping and retaining of insect prey mainly due to contamination of attachment organs of insects [16], reduction of the real contact area

Optimizing PMMA solutions to suppress contamination in the transfer of CVD graphene for batch production

• Chun-Da Liao,
• Andrea Capasso,
• Tiago Queirós,
• Telma Domingues,
• Fatima Cerqueira,
• Nicoleta Nicoara,
• Jérôme Borme,
• Paulo Freitas and
• Pedro Alpuim

Beilstein J. Nanotechnol. 2022, 13, 796–806, doi:10.3762/bjnano.13.70

• as a supporting layer to (i) retain the integrity of graphene during the wet-etching bath required to dissolve the metallic substrate and (ii) provide mechanical stability when transferring graphene to the target substrates. During this process, two primary external sources of contamination need to

• metallic contamination from etchants such as FeCl3 can be substantially reduced by rinsing PMMA-coated graphene in DI water solution with 1–2% HCl [12]. Concerning the PMMA residues, several approaches were implemented to dissolve them, primarily by disrupting their chemical bonds. The chemical bond

• reliable transfer at a negligible contamination level, even without any post-treatment at high temperature. The supporting layer formed by spin coating presents high mechanical flexibility and strength for the transfer process and appears easy to dissolve afterward. We validated the impact of the optimized

Fabrication and testing of polymer microneedles for transdermal drug delivery

• Vahid Ebrahiminejad,
• Zahra Faraji Rad,
• Philip D. Prewett and
• Graham J. Davies

Beilstein J. Nanotechnol. 2022, 13, 629–640, doi:10.3762/bjnano.13.55

• required depth [18]. There should be no MN-induced skin contamination, for example, due to breakage of the tips, and zero toxicity demands medical-grade materials. Evaluation of MN mechanical strength requires an investigation of MN insertion characteristics and possible failure scenarios. During the

Detection and imaging of Hg(II) in vivo using glutathione-functionalized gold nanoparticles

• Gufeng Li,
• Shaoqing Li,
• Rui Wang,
• Min Yang,
• Lizhu Zhang,
• Yanli Zhang,
• Wenrong Yang and
• Hongbin Wang

Beilstein J. Nanotechnol. 2022, 13, 549–559, doi:10.3762/bjnano.13.46

• +, Co2+, Cu2+, Fe2+, Mg2+, Mn2+, Pb2+, Zn2+, Al3+, and Fe3+ (0.75 mM). Each solution of GNPs-GSH-Rh6G2/ion was prepared in spectral cuvettes that were carefully cleaned to avoid contamination. Fluorescence spectra were measured after mixing well to fully interact with the GNPs-GSH-RH6G2. All tests were

A non-enzymatic electrochemical hydrogen peroxide sensor based on copper oxide nanostructures

• Irena Mihailova,
• Vjaceslavs Gerbreders,
• Marina Krasovska,
• Eriks Sledevskis,
• Valdis Mizers,
• Andrejs Bulanovs and
• Andrejs Ogurcovs

Beilstein J. Nanotechnol. 2022, 13, 424–436, doi:10.3762/bjnano.13.35

• obtained in the laboratory. CuO layer synthesis on copper wires A smooth film coating of copper oxide was obtained by annealing the copper wire in an oxygen atmosphere. Before annealing, the copper wire was washed several times with water and ethanol to clean the surface of possible contamination. The wire

• obtained by a one-step chemical hydrothermal oxidation. For this, copper wire was rinsed with water and ethanol in order to clean the surface of possible contamination. To prepare the working solution, 10 mL of a 10 M NaOH solution, 5 mL of a 1 M (NH4)2S2O8 solution and 26 mL of H2O were combined. The wire

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• was degassed over 12 h at 870 K and then cleaned by flashing to 1370 K for 10 s several times. The sample was observed at both room temperature (RT) and high temperatures. To reduce contamination effectively, we used a tip made of PtIr or Nb for the measurement at RT and a tip made of W for the

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

• limitations of the conventional membranes have been overcome by electrospun membranes due to their high porosity, interconnected pores, high surface area, narrow pore size distribution, and due to membrane modification possibilities. The solvent evaporation during spinning also prevents the contamination of

Bacterial safety study of the production process of hemoglobin-based oxygen carriers

• Axel Steffen,
• Yu Xiong,
• Radostina Georgieva,
• Ulrich Kalus and
• Hans Bäumler

Beilstein J. Nanotechnol. 2022, 13, 114–126, doi:10.3762/bjnano.13.8

• final particle suspensions. Therefore, we conclude that the HbMP fabrication procedure is safe in respect of bacterial contamination. Keywords: bacterial safety; EDTA; glutaraldehyde; hemoglobin; microparticles; Introduction Artificial oxygen carriers used as red blood cell (RBC) substitutes have

• animals are declared fit for human consumption after a post-mortem inspection. In the geographical area where the blood is collected, many critical viral pathogens do not occur [10]. Nevertheless, the blood is tested for viral contamination. In terms of bacterial safety, the blood and the hemoglobin

• hemoglobin is to sterile filter it after production and test it for endotoxin content and bioburden. This way, bacterial contamination is relatively unlikely. Nevertheless, it is conceivable that a minimal amount of bacteria will not be detected by the tests. In this case, it would be advantageous if any

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• solvent contamination [16]. However, the production rate is relatively low, and the cost of production is very high, mainly due to the massive waste produced during the synthesis [22]. A further drawback is the large consumption of energy to maintain the required pressure and temperature conditions used

• aggregation of NPs in the reaction mixture. Generally, the chemical methods are low-cost and allow one to produce large quantities of NPs; however, a couple of drawbacks can be highlighted and include contamination from precursor chemicals, use of solvents, and generation of sometimes hazardous by-products

Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• with the database PDF (00-004-0545) for cubic germanium (d111 = 0.3266 nm). The atomic elemental ratio [Cr]/[Ge] in the coating was in the range of 1:(6–7) (Supporting Information File 1, Figure S8). XP spectra showed the presence of Ge, Cr, and O. In order to reduce surface contamination and oxidized

Two dynamic modes to streamline challenging atomic force microscopy measurements

• Alexei G. Temiryazev,
• Andrey V. Krayev and
• Marina P. Temiryazeva

Beilstein J. Nanotechnol. 2021, 12, 1226–1236, doi:10.3762/bjnano.12.90

• step edge is also accompanied by an error in measuring the profile, and it often occurs also at zero amplitude, which means a pretty hard contact of the probe with the surface. This can lead to damage and contamination of the tip, as well as to the deformation of soft or poorly fixed objects on the

• and accordingly select Asp. Factors to consider are the risk of tip wear, sample deformation, and tip contamination. The most important parameter here is the tip–sample force at the turn-around point of the oscillation cycle. Note that this force Fp can be repulsive even in net-attractive regime. In

• tip and to visualize the contamination there. Such a sample is available in any AFM laboratory and allows one to demonstrate some of the features that make it difficult to work in standard modes. On the one hand, next to the scan area, there is a high console of the cantilever; on the other hand

Revealing the formation mechanism and band gap tuning of Sb₂S₃ nanoparticles

• Maximilian Joschko,
• Franck Yvan Fotue Wafo,
• Christina Malsi,
• Danilo Kisić,
• Ivana Validžić and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 1021–1033, doi:10.3762/bjnano.12.76

• aluminum holder, explaining the detection of these elements. Oxygen may have been detected due to contamination of the sample, the grid, or the holder. Measurement results of the white product obtained by the direct injection of the Sb precursor into oleylamine at 150 °C without the addition of sulfur: (a

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

High-yield synthesis of silver nanowires for transparent conducting PET films

• Gul Naz,
• Hafsa Asghar,
• Muhammad Ramzan,
• Muhammad Arshad,
• Rashid Ahmed,
• Muhammad Bilal Tahir,
• Bakhtiar Ul Haq,
• Nadeem Baig and
• Junaid Jalil

Beilstein J. Nanotechnol. 2021, 12, 624–632, doi:10.3762/bjnano.12.51

• second peak at 373 nm is attributed to the longitudinal plasmon resonance of AgNWs. It is also noted that no other peak was observed, which shows that the final product was free from contamination of any other nanostructures, such as silver nanoparticles or nanocubes. The SEM results also confirm the

Influence of electrospray deposition on C₆₀ molecular assemblies

• Antoine Hinaut,
• Sebastian Scherb,
• Sara Freund,
• Zhao Liu,
• Thilo Glatzel and
• Ernst Meyer

Beilstein J. Nanotechnol. 2021, 12, 552–558, doi:10.3762/bjnano.12.45

• the sample. Nevertheless, the contamination from solvent introduction can be reduced down to conditions compatible with high-resolution scanning probe microscopy (SPM) techniques [10][12]. Buckminsterfullerene C60, scheme in Figure 1b, is among the most extensively studied molecules in surface science

The preparation temperature influences the physicochemical nature and activity of nanoceria

• Robert A. Yokel,
• Wendel Wohlleben,
• Johannes Georg Keller,
• Matthew L. Hancock,
• Jason M. Unrine,
• D. Allan Butterfield and
• Eric A. Grulke

Beilstein J. Nanotechnol. 2021, 12, 525–540, doi:10.3762/bjnano.12.43

• energies suggested the contamination could be an ester with a long alkyl chain. The contamination was a very thin, homogeneous layer [7]. TGA conducted in the present study showed an average weight loss of 1.3% (Figure 3) which can be attributed to a small amount of surface contamination. The comparison

Reconstruction of a 2D layer of KBr on Ir(111) and electromechanical alteration by graphene

• Zhao Liu,
• Antoine Hinaut,
• Stefan Peeters,
• Sebastian Scherb,
• Ernst Meyer,
• Maria Clelia Righi and
• Thilo Glatzel

Beilstein J. Nanotechnol. 2021, 12, 432–439, doi:10.3762/bjnano.12.35

• contamination and averaging effects in KPFM [51]. Conclusion In conclusion, a novel corrugated reconstruction of KBr was observed on Ir(111) by nc-AFM and confirmed by DFT simulations. It is attributed to the lattice symmetry of KBr with respect to the iridium substrate in one direction and a self-adjustment in

Spontaneous shape transition of Mn_xGe_1−x islands to long nanowires

• S. Javad Rezvani,
• Luc Favre,
• Gabriele Giuli,
• Yiming Wubulikasimu,
• Isabelle Berbezier,
• Augusto Marcelli,
• Luca Boarino and
• Nicola Pinto

Beilstein J. Nanotechnol. 2021, 12, 366–374, doi:10.3762/bjnano.12.30

• using these techniques, NWs are grown away from the substrate, usually in a tilted direction, and size distribution and geometry strongly depend on the growth dynamics [32][33]. Furthermore, it is known that the catalyst introduces uncontrolled and unwanted contamination inside the crystal lattice of

Structural and optical characteristics determined by the sputtering deposition conditions of oxide thin films

• Petronela Prepelita,
• Florin Garoi and
• Valentin Craciun

Beilstein J. Nanotechnol. 2021, 12, 354–365, doi:10.3762/bjnano.12.29

• XPS measurements of the analyzed samples were performed with photons that cause no major disturbances on the bombarded surface. To keep the contamination layer from the surface of the films, they were not sputtered using the ion gun. This is because sometimes the sputtering affects the stoichiometry

• good stoichiometry for this film. The general spectra of ZnO samples are shown in Figure 4, where peaks corresponding to C 1s, O 1s, and Zn 2p were identified for all investigated samples. The presence of photoelectron signals, ZnO electrons, and carbon contamination at the binding energy value of

• . This is a possible explanation for the decrease in carbon peaks as the thickness of the oxide films increases. It must be said that no metallic elements are identified; however, they are in oxide bonds just like in oxide compounds. This carbon contamination obviously decreases as the film thickness

Exploring the fabrication and transfer mechanism of metallic nanostructures on carbon nanomembranes via focused electron beam induced processing

• Christian Preischl,
• Linh Hoang Le,
• Elif Bilgilisoy,
• Armin Gölzhäuser and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2021, 12, 319–329, doi:10.3762/bjnano.12.26

• immersing the sample in a 1 M Fe(NO3)3 solution (ACROS Organics). The PMMA/CNM is then transferred into pure water in order to remove iron contamination. In the next step the PMMA/CNM is transferred onto a bulk SiO2 substrate. After drying the sample overnight, the PMMA layer is dissolved by soaking the

The patterning toolbox FIB-o-mat: Exploiting the full potential of focused helium ions for nanofabrication

• Victor Deinhart,
• Lisa-Marie Kern,
• Jan N. Kirchhof,
• Sabrina Juergensen,
• Joris Sturm,
• Enno Krauss,
• Thorsten Feichtner,
• Sviatoslav Kovalchuk,
• Michael Schneider,
• Dieter Engel,
• Bastian Pfau,
• Bert Hecht,
• Kirill I. Bolotin,
• Stephanie Reich and
• Katja Höflich

Beilstein J. Nanotechnol. 2021, 12, 304–318, doi:10.3762/bjnano.12.25

• , residues from wet-chemical processing. The locally introduced energy can mobilize these contaminants such that they diffuse towards the beam center where they are polymerized [24]. In the worst case, this results in material build-up instead of sputtering. Already minor surface contamination can lead to

Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition

• Cristiano Glessi,
• Aya Mahgoub,
• Cornelis W. Hagen and
• Mats Tilset

Beilstein J. Nanotechnol. 2021, 12, 257–269, doi:10.3762/bjnano.12.21

• yielded only traces of gold (2–3 atom % [19]). Within the series of gold acetonate complexes, the highest gold content has been achieved with Au(tfac)Me2 when water was co-injected as an oxidizing agent during the deposition (91 atom % gold) [26]. To circumvent carbon contamination, a series of inorganic

• experiments. The silicon substrates were cleaned by ultrasonication in acetone for 15 min, followed by ultrasonication in isopropanol for 15 min and blow drying with N2, and were kept in a dust free environment. For each precursor a different substrate was used to avoid cross contamination. The substrate was

• substrate, leaving a central circular area free for deposition. The precursor material was contained in a recessed hole in the bottom of the plate, connected by a small channel to the deposition area. For each precursor to be tested a new plate was taken to avoid cross contamination. Precursors were tested

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• contributions, the addition of nanomaterials to packaging materials and films in the food industry is reported to have curbed issues regarding food spoilage and contamination [16], pests, and disease management due to the usage of a nanomaterial-based formulation in agriculture [17]. The inclusion of

• contact with nanomaterial waste; (D) damage in the membrane and in the lumen of silkworm silk glands; (E) dead zebrafish embryos; (F) NM; (G) contamination of water bodies; (H) silkworm feeding on mulberry leaves containing chemical residues. An illustration of how nanomaterials are directly fed to the

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• smaller value, which indicated that the TENG-powered cathodic protection system has obvious anticorrosion properties. Marine fouling, caused by metal contamination and accumulation of biological organisms, is a major challenge for the oceanic ecosystem. With the growing threat to the environment caused by