Aero-ZnS prepared by physical vapor transport on three-dimensional networks of sacrificial ZnO microtetrapods

• Veaceslav Ursaki,
• Tudor Braniste,
• Victor Zalamai,
• Emil Rusu,
• Vladimir Ciobanu,
• Vadim Morari,
• Daniel Podgornii,
• Pier Carlo Ricci,
• Rainer Adelung and
• Ion Tiginyanu

Beilstein J. Nanotechnol. 2024, 15, 490–499, doi:10.3762/bjnano.15.44

• . 05-0566 [29][30] and to a tetragonal rutile cassiterite SnO2 phase according to PDF 21-1250 and JCPDS card no. 41-1445 [31][32]. Whole powder pattern fitting (WPPF) weight fraction analysis revealed that the ZnS phase is 100% of zinc blende structure. The analysis of the XRD pattern in Figure 2b

Superconducting spin valve effect in Co/Pb/Co heterostructures with insulating interlayers

• Andrey A. Kamashev,
• Nadir N. Garif’yanov,
• Aidar A. Validov,
• Vladislav Kataev,
• Alexander S. Osin,
• Yakov V. Fominov and
• Ilgiz A. Garifullin

Beilstein J. Nanotechnol. 2024, 15, 457–464, doi:10.3762/bjnano.15.41

• order to check this, points in the thickness range between 40 and 60 nm would be required). The fitting parameters given in the caption to Figure 4 were obtained as follows. The coherence lengths in the S and F materials, ξS and ξF, respectively, were estimated from the residual resistivities of the

• to plot the theoretical curve for (dPb). The value of γ is consistent with the values of ξS and ξF. What is unexpected in the above fitting parameters is a rather small value of the interface resistance parameter, γb = 0.48. In the tunneling limit, one can estimate in terms of the effective

Potential of a deep eutectic solvent in silver nanoparticle fabrication for antibiotic residue detection

• Le Hong Tho,
• Bui Xuan Khuyen,
• Ngoc Xuan Dat Mai and
• Nhu Hoa Thi Tran

Beilstein J. Nanotechnol. 2024, 15, 426–434, doi:10.3762/bjnano.15.38

• Ag NPs-DES substrate is sensitive and can be used for quantitative analysis of NFT following the two linear fitting equations: For further investigations on the SERS performance of the Ag NPs-DES thin film, NFT was again selected to test the stability. In practice, a stable SERS substrate is not only

On the mechanism of piezoresistance in nanocrystalline graphite

• Sandeep Kumar,
• Simone Dehm and
• Ralph Krupke

Beilstein J. Nanotechnol. 2024, 15, 376–384, doi:10.3762/bjnano.15.34

• would mean that all the strain energy provided externally ends up at GBs leading to movements of dislocations at GBs or fractures at GBs. Fitting the tunneling + destruction model to our data, we find that the initial tunneling distance has a value of 3.6 nm, which is comparable to the nanographene

• long axis of non-spherical grains (a) at zero strain (marked as point A in the curve), (b) at point B in the curve, (c) in the plateau region marked as point C, and (d) at point D in the curve showing missing grains as rupture in the film. Value of extracted parameters by fitting from Figure 2c

Controllable physicochemical properties of WO_x thin films grown under glancing angle

• Rupam Mandal,
• Aparajita Mandal,
• Alapan Dutta,
• Rengasamy Sivakumar,
• Sanjeev Kumar Srivastava and
• Tapobrata Som

Beilstein J. Nanotechnol. 2024, 15, 350–359, doi:10.3762/bjnano.15.31

• curve fitting after Shirley background subtraction [38]. The two major symmetric peaks at 35.87 and 38.00 eV binding energies correspond to the 4f7/2 and 4f5/2 levels (spin–orbit splitting: 2.13 eV), respectively, indicating the presence of W6+ in the as-deposited WOx films [38][39]. The two minor peaks

Exploring the relationships between physiochemical properties of nanoparticles and cell damage to combat cancer growth using simple periodic table-based descriptors

• Joyita Roy and
• Kunal Roy

Beilstein J. Nanotechnol. 2024, 15, 297–309, doi:10.3762/bjnano.15.27

• . Importance of the zeta potential as a descriptor The developed QSPR model without zeta potential descriptor shows R2 = 0.47 and = 0.34, which is well below the desired acceptance criteria. The obtained results indicate that the fitting and robustness of the developed model without the presence of the zeta

Determining by Raman spectroscopy the average thickness and N-layer-specific surface coverages of MoS₂ thin films with domains much smaller than the laser spot size

• Felipe Wasem Klein,
• Jean-Roch Huntzinger,
• Vincent Astié,
• Damien Voiry,
• Romain Parret,
• Houssine Makhlouf,
• Sandrine Juillaguet,
• Jean-Manuel Decams,
• Sylvie Contreras,
• Périne Landois,
• Ahmed-Azmi Zahab,
• Jean-Louis Sauvajol and
• Matthieu Paillet

Beilstein J. Nanotechnol. 2024, 15, 279–296, doi:10.3762/bjnano.15.26

Ultrasensitive and ultrastretchable metal crack strain sensor based on helical polydimethylsiloxane

• Shangbi Chen,
• Dewen Liu,
• Weiwei Chen,
• Huajiang Chen,
• Jiawei Li and
• Jinfang Wang

Beilstein J. Nanotechnol. 2024, 15, 270–278, doi:10.3762/bjnano.15.25

• wires as electrodes on both sides of the helical polydimethylsiloxane. Fabrication of the metal crack strain sensor The helical structure of PDMS was achieved by utilizing a screw as a mold, as depicted in Figure 5. To ensure the absence of bubbles within the grooves of the screw, a precisely fitting

Design, fabrication, and characterization of kinetic-inductive force sensors for scanning probe applications

• August K. Roos,
• Ermes Scarano,
• Elisabet K. Arvidsson,
• Erik Holmgren and
• David B. Haviland

Beilstein J. Nanotechnol. 2024, 15, 242–255, doi:10.3762/bjnano.15.23

• 60 chips from one wafer, detecting the thermal fluctuations at room temperature under ambient conditions and fitting them to a Lorentzian lineshape. We found that ωm decreases with the increasing radial distance D from the center of the wafer, as shown in Figure 7, probably because of non-uniform

• overcoupled, making it difficult to extract a reliable value for Qint using the standard fitting methods. Nevertheless, we can reliably determine the resonant frequency for all measured samples and calculate the kinetic inductance using the simulated capacitance and nominal number of squares in the meander

In situ optical sub-wavelength thickness control of porous anodic aluminum oxide

• Aleksandrs Dutovs,
• Raimonds Popļausks,
• Oskars Putāns,
• Vladislavs Perkanuks,
• Aušrinė Jurkevičiūtė,
• Tomas Tamulevičius,
• Uldis Malinovskis,
• Iryna Olyshevets,
• Donats Erts and
• Juris Prikulis

Beilstein J. Nanotechnol. 2024, 15, 126–133, doi:10.3762/bjnano.15.12

• consistently manufacturing PAAO with the targeted thickness. An electrochemical cell with an optical window was designed for reflectance spectroscopy of PAAO during anodization. Real-time fitting of spectra to a transfer-matrix model enabled continuous monitoring of the thickness growth of the PAAO layer

• ) setup, the PAAO structure was analyzed using the fast Fourier transform (FFT) method [21]. However, the optimal PAAO thickness for FFT analysis was ≈2.5–5.0 μm, where multiple interference fringes can be observed in the reflectance spectra. Here, the PAAO thickness was calculated in real time by fitting

• stage of anodization, the alumina layer may not be correctly represented by a single-layer effective RI. This typically resulted in fitting errors during the first 1–2 min of anodization (hPAAO < 200 nm) as shown in Figure 3a. Moreover, the LM algorithm is sensitive to the initial guess value of the fit

Berberine-loaded polylactic acid nanofiber scaffold as a drug delivery system: The relationship between chemical characteristics, drug-release behavior, and antibacterial efficiency

• Le Thi Le,
• Hue Thi Nguyen,
• Liem Thanh Nguyen,
• Huy Quang Tran and
• Thuy Thi Thu Nguyen

Beilstein J. Nanotechnol. 2024, 15, 71–82, doi:10.3762/bjnano.15.7

• equations and parameters determined by fitting the BBR release data to the aforementioned mathematical models are shown in Supporting Information File 1 and Table 2. The correlation coefficient (R2) of BBR release from the BBR/PLA nanofiber scaffold was the largest when fitted to the Ritger–Peppas model

• of (a) control MA-104 cells and (b) MA-104 cells treated with BBR NPs/PLA nanofiber scaffold after 120 h of incubation. Average diameter and water contact angle of electrospun PLA, BBR/PLA, and BBR NPs/PLA nanofiber scaffolds. Parameters determined by fitting BBR release data to four different

Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• conductive carbon black concentrations in hydrogel composite samples (c). Analysis of electrical properties of hydrogel-based samples with catalyst (M CO) and conductive (cCB) particles (experimental data (dot line) and Randles model results (solid line)): a) Bode modulus and b) phase angle with fitting

Determination of the radii of coated and uncoated silicon AFM sharp tips using a height calibration standard grating and a nonlinear regression function

• Perawat Boonpuek and
• Jonathan R. Felts

Beilstein J. Nanotechnol. 2023, 14, 1200–1207, doi:10.3762/bjnano.14.99

• . However, this method yields an accurate estimate of the tip radius with a low root mean squared error of the curve fitting results. Keywords: AFM tip calibration; nonlinear regression curve fitting; Introduction Atomic force microscopy (AFM) with a sharp tip is typically used to characterize

• AFM tip and the sample, which depends on the tip radius, defines how accurately the AFM tip determines those properties and the shape of fabricated micro- and nanostructures. The contact radius of the tip is a key variable for calculating the stiffness and Young’s modulus of the material by fitting

• at the top corner of a grating structure (a fabricated square column). Then, the tip radius was estimated by fitting a manually drawn circle to the curve profile of the AFM scan [10]. However, the tip curve profile can differ from the shape of a circle, leading to some deviation of the tip curve

A combined gas-phase dissociative ionization, dissociative electron attachment and deposition study on the potential FEBID precursor [Au(CH₃)₂Cl]₂

• Elif Bilgilisoy,
• Ali Kamali,
• Thomas Xaver Gentner,
• Gerd Ballmann,
• Sjoerd Harder,
• Hans-Peter Steinrück,
• Hubertus Marbach and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2023, 14, 1178–1199, doi:10.3762/bjnano.14.98

Dual-heterodyne Kelvin probe force microscopy

• Benjamin Grévin,
• Fatima Husainy,
• Dmitry Aldakov and
• Cyril Aumaître

Beilstein J. Nanotechnol. 2023, 14, 1068–1084, doi:10.3762/bjnano.14.88

• (SPV decay time constant) images can be mapped by appropriately fitting the amplitude spectrum. As with AM-heterodyne KPFM, there is a frequency mixing effect due to the capacitance term, and we restrict ourselves to the first harmonic to describe the time response of the capacitance gradient (K1

Low temperature atomic layer deposition of cobalt using dicobalt hexacarbonyl-1-heptyne as precursor

• Mathias Franz,
• Mahnaz Safian Jouzdani,
• Lysann Kaßner,
• Marcus Daniel,
• Frank Stahr and
• Stefan E. Schulz

Beilstein J. Nanotechnol. 2023, 14, 951–963, doi:10.3762/bjnano.14.78

• the carbonyl groups [33]. No evidence could be found of cobalt carbide formation, which would result in binding energies of approximately 284 eV or below [34][35]. The oxygen 1s peak has its maximum at 532.2 eV (Figure 5). However, assuming just one feature will result in a poor fitting result with an

• of oxidised cobalt CoO consist of a core level peak (Co2+) and a shake-up satellite (Co2+ (S)) [37]. The measured Co 2p3/2 peak consists of three features (Figure 5). This indicates the presence of metallic as well as oxidised cobalt (mainly Co2+). After fitting, the peak with a binding energy of

Upscaling the urea method synthesis of CoAl layered double hydroxides

• Camilo Jaramillo-Hernández,
• Víctor Oestreicher,
• Martín Mizrahi and
• Gonzalo Abellán

Beilstein J. Nanotechnol. 2023, 14, 927–938, doi:10.3762/bjnano.14.76

• all paths used in the fits were calculated using the FEFF9 code [78]. The k range was set from 2.3 to 12.1 Å−1. The passive reduction factor S02 values were restrained to 0.8. This value was obtained from fitting a standard foil of metallic Co and constraining the coordination numbers to the

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• ). Impedance parameters obtained from EIS fitting. Funding This research was funded by The Vietnamese Ministry of Education and Training under grant B2021-DQN-04.

The microstrain-accompanied structural phase transition from h-MoO₃ to α-MoO₃ investigated by in situ X-ray diffraction

• Zeqian Zhang,
• Honglong Shi,
• Boxiang Zhuang,
• Minting Luo and
• Zhenfei Hu

Beilstein J. Nanotechnol. 2023, 14, 692–700, doi:10.3762/bjnano.14.55

• raised to 380 °C, a tiny amount of α-MoO3 (ca. 2%) could be detected. When heated to 440 °C, the mass fraction of α-MoO3 quickly increased to 97.7%. According to the five-parameter logistic function fitting the mass fraction (the red curve in Figure 1b), the transition from h-MoO3 to α-MoO3 begins at a

Humidity-dependent electrical performance of CuO nanowire networks studied by electrochemical impedance spectroscopy

• Jelena Kosmaca,
• Juris Katkevics,
• Jana Andzane,
• Raitis Sondors,
• Liga Jasulaneca,
• Raimonds Meija,
• Kiryl Niherysh,
• Yelyzaveta Rublova and
• Donats Erts

Beilstein J. Nanotechnol. 2023, 14, 683–691, doi:10.3762/bjnano.14.54

• equivalent circuit parameters obtained by fitting impedance spectra. The new investigation data can be useful to predict the behavior of nanostructured CuO in humid environments, which is favorable for advancing technology of nanowire-based systems suitable for sensor applications. Keywords: CuO

• applications, the measurements are performed in a RH range from 5% up to 97% and in a T range of 25–55 °C, which covers wider RH and T ranges than previous studies. Equivalent circuit models for the nanowire-based system are developed based on the EIS measurements. Fitting of the cell parameters shows

• reached the substrate. Fitting of the impedance spectra across the examined range of RH was performed using equivalent electric circuits R1(CR2), R1(QR2) and R1(Q[R2W]) as mentioned above (Figure 2b). The capacitor impedance is ZC,Q = 1/[Y0(iω)n], where the angular frequency ω, the imaginary unit i, Y0

Observation of multiple bulk bound states in the continuum modes in a photonic crystal cavity

• Rui Chen,
• Yi Zheng,
• Xingyu Huang,
• Qiaoling Lin,
• Chaochao Ye,
• Meng Xiong,
• Martijn Wubs,
• Yungui Ma,
• Minhao Pu and
• Sanshui Xiao

Beilstein J. Nanotechnol. 2023, 14, 544–551, doi:10.3762/bjnano.14.45

• elaborated below in the Discussion section. The positions of the illumination spots p1, p2, and p3 are schematically marked in Figure 4d. The full width at half maximum (FWHM) of each resonance peak is extracted by numerically fitting the spectrum to a Lorentzian function. The FWHM of the peak in Figure 4b

On the use of Raman spectroscopy to characterize mass-produced graphene nanoplatelets

• Keith R. Paton,
• Konstantinos Despotelis,
• Naresh Kumar,
• Piers Turner and
• Andrew J. Pollard

Beilstein J. Nanotechnol. 2023, 14, 509–521, doi:10.3762/bjnano.14.42

• recorded between 1000 cm−1 and 3000 cm−1 Raman shift, using 5% of the maximum power (ca. 0.8 mW incident on the sample), 10 s acquisition time, and a 100× (0.9 NA) objective lens. Spectra were processed to remove cosmic ray artefacts, and a baseline was subtracted using the “Intelligent Fitting” algorithm

• to either a graphite or GNP Raman spectrum. This fitting was carried out using the “Component Analysis” tool in Wire 5.4, using the average spectra from graphite and GNP samples respectively as the “pure” components. No additional baseline or normalization was applied during the analysis, and the

• spectra were fitted directly (rather than a derivative of the spectra). Similar fitting can be implemented in a range of other analysis packages. A higher value of the correlation value indicates a better match to that component. Plotting the median value of the graphite correlation value (Figure 4, black

Mixed oxides with corundum-type structure obtained from recycling can seals as paint pigments: color stability

• Dienifer F. L. Horsth,
• Julia de O. Primo,
• Nayara Balaba,
• Fauze J. Anaissi and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 467–477, doi:10.3762/bjnano.14.37

• [22][23], confirming what was observed in XRD. The Cr 2p spectrum (Figure 4c) shows peaks centered at 576.7 and 586.8 eV, which were assigned to Cr 2p3/2 and Cr 2p1/2, respectively. The fitting analysis of the Cr 2p3/2 peak suggests the presence of Cr6+ in CrO3 (component at 579.3 eV) and Cr3+ in

Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction

• Karolina Cysewska,
• Marcin Łapiński,
• Marcin Zając,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2023, 14, 420–433, doi:10.3762/bjnano.14.34

• Gaussian–Lorentzian (GL30) curve as a fitting algorithm and a Shirley background subtraction. Electrochemical studies The setup for the electrochemical studies was the same as for the fabrication of the catalysts (see section “Electrosynthesis and morphology of the deposits”) with some exceptions: The

Quercetin- and caffeic acid-functionalized chitosan-capped colloidal silver nanoparticles: one-pot synthesis, characterization, and anticancer and antibacterial activities

• Akif Hakan Kurt,
• Elif Berna Olutas,
• Fatma Avcioglu,
• Hamza Karakuş,
• Mehmet Ali Sungur,
• Cansu Kara Oztabag and
• Muhammet Yıldırım

Beilstein J. Nanotechnol. 2023, 14, 362–376, doi:10.3762/bjnano.14.31

• fitting. Figure 4c indicates the size distribution of both samples. The average particle size of the Ch/Q-Ag NPs was calculated as 11.2 ± 2.4 nm, whereas it was found to be 10.3 ± 2.4 nm for the Ch/CA-Ag NPs. To visualize the organic shell structure that covers the Ag NPs, which is difficult to display in