Ultrathin water layers on mannosylated gold nanoparticles

• Maiara A. Iriarte Alonso,
• Jorge H. Melillo,
• Silvina Cerveny,
• Yujin Tong and
• Alexander M. Bittner

Beilstein J. Nanotechnol. 2025, 16, 2183–2198, doi:10.3762/bjnano.16.151

• functionalization was performed as reported in [24]. Silicon wafers were washed first in methanol, then in a 1:1 v/v mixture of methanol and chloroform, and finally in chloroform under 5 min sonication at every step. Afterwards, the surfaces were immersed in a 7:2:1 (v/v) mixture of decalin (cis and trans)/toluene

• /chloroform, and 0.1% OTS was added. The procedure was done at ambient temperature inside a nitrogen glove box. After 12 h of incubation, the surfaces were rinsed with chloroform, then with a 1:1 (v/v) mixture of chloroform and methanol, and finally with methanol. The process was finished by drying the

Rapid synthesis of highly monodisperse AgSbS₂ nanocrystals: unveiling multifaceted activities in cancer therapy, antibacterial strategies, and antioxidant defense

• Funda Ulusu,
• Adem Sarilmaz,
• Yakup Ulusu,
• Faruk Ozel and
• Mahmut Kus

Beilstein J. Nanotechnol. 2025, 16, 2105–2115, doi:10.3762/bjnano.16.145

• using GraphPad prism version 8 (GraphPad Software, San Diego, CA, USA). Antioxidant activity of AgSbS2 NCs DPPH radical scavenging activity assay 100 μL of 0.2 mM methanolic DPPH solution was combined with 50 μL of nanocrystal solution dissolved in methanol at varying concentrations (12.5–400 µg/mL

Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• atmosphere. The solvents were dried according to the standard literature and stored under argon. All starting materials used for the synthesis were purchased from commercial sources (Merck or TCI). SIL: In a snap lid vial, dissolve 2.0 mL tetramethoxysilane (2.04 g, 13.4 mmol, 1 equiv) in 1.5 mL methanol

• (p.a.). With vigorous stirring, a solution of 1.0 mL NH3 (55.6 mmol H2O, 4 equiv) in 1.5 mL methanol (p.a.) is quickly added and stirred for 1 min. As soon as the gel is completely formed, it is left to age at room temperature. After ageing, the gel is layered with acetone (p.a.), and the acetone is

Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• formation of iron oxide nanowires was reported only in case of ablation with a 248 nm laser of iron powder suspended in methanol, while other solvents (including water, ethanol, isopropanol, and glycol) resulted in only spherical NPs. Moreover, ablation using a 532 nm laser produced spherical NPs in all the

• solvents including methanol. The authors explained the influence of the methanol environment on the nanomaterial shape by attributing it to chemical reactions between iron and methanol molecules, which resulted in the formation of goethite (FeO(OH)) and subsequently led to nanowire growth: Since iron oxide

• . However, the additional 248 nm laser irradiation of the spherical NPs in methanol could transform NPs into nanowires. This underlines the importance of controlling chemical reactions during all stages of laser ablation and laser modification processes. Chemical interactions can become key parameters if

Multifunctional anionic nanoemulsion with linseed oil and lecithin: a preliminary approach for dry eye disease

• Niédja Fittipaldi Vasconcelos,
• Almerinda Agrelli,
• Rayane Cristine Santos da Silva,
• Carina Lucena Mendes-Marques,
• Isabel Renata de Souza Arruda,
• Priscilla Stela Santana de Oliveira,
• Mércia Liane de Oliveira and
• Giovanna Machado

Beilstein J. Nanotechnol. 2025, 16, 1711–1733, doi:10.3762/bjnano.16.120

• LTDA (Brazil). Potassium hydroxide (KOH, code HP09874RA), trypan blue (code AT06398SO), and methanol (CH3OH, code AM07445RA) were purchased from Êxodo Científica® LTDA (Brazil). Monosodium phosphate (NaH2PO4, code 01414), phenolphthalein (C20H14O4, code 317415), and citric acid (C6H8O7·H2O, code 19228

Ambient pressure XPS at MAX IV

• Mattia Scardamaglia,
• Ulrike Küst,
• Alexander Klyushin,
• Rosemary Jones,
• Jan Knudsen,
• Robert Temperton,
• Andrey Shavorskiy and
• Esko Kokkonen

Beilstein J. Nanotechnol. 2025, 16, 1677–1694, doi:10.3762/bjnano.16.118

• case studies from MAX IV’s APXPS beamlines. We will not concentrate on the typical reactions (e.g., CO oxidation, ethylene epoxidation, and methanol oxidation) already deeply reviewed elsewhere [5][12][13]. We will instead discuss a few catalysis niche cases dealing with complex catalytic reactions and

Prospects of nanotechnology and natural products for cancer and immunotherapy

• Jan Filipe Andrade Santos,
• Marcela Bernardes Brasileiro,
• Pamela Danielle Cavalcante Barreto,
• Ligiane Aranha Rocha and
• José Adão Carvalho Nascimento Júnior

Beilstein J. Nanotechnol. 2025, 16, 1644–1667, doi:10.3762/bjnano.16.116

• aptamer, sorafenib, and ursolic acid as an API at 4 mg·mL−1 in methanol. Physicochemical tests showed that the nanoparticles have a spherical shape, confirmed by atomic force microscopy (AFM), and are stable in ultrapure water and Dulbecco’s modified eagle medium (DMEM) with 10% FBS. Procedures to

• and drug carriers, and methanol, ethanol, and acetone as solvents. Both nanoparticle systems exhibited high biocompatibility and low cytotoxicity to normal cells. Additionally, the results demonstrated the technology had a tumor inhibition greater than 70% in mice with a synergistic antitumor effect

Photocatalytic degradation of ofloxacin in water assisted by TiO₂ nanowires on carbon cloth: contributions of H₂O₂ addition and substrate absorbability

• Iram Hussain,
• Lisha Zhang,
• Zhizhen Ye and
• Jin-Ming Wu

Beilstein J. Nanotechnol. 2025, 16, 1567–1579, doi:10.3762/bjnano.16.111

• -first-order kinetic model, as determined by Equation 3: The concentration of OFL was assessed using high-performance liquid chromatography with a C18 column maintained at 30 °C. The UV–vis detector was calibrated to a wavelength of 292 nm. The mobile phase consisted of a 15:85 ratio of methanol to 0.8

Dendrimer-modified carbon nanotubes for the removal and recovery of heavy metal ions from water

• Thao Quynh Ngan Tran,
• Huu Trung Nguyen,
• Subodh Kumar and
• Xuan Thang Cao

Beilstein J. Nanotechnol. 2025, 16, 1522–1532, doi:10.3762/bjnano.16.107

• 0.45 µm PTFE membrane, then thoroughly washed several times with deionized water followed by ethanol to remove any unreacted MA and residual DES. The washed material was subsequently dried in an oven at 45 °C overnight. The CNTs-MA (100 mg) was dispersed in 10 mL of methanol under a nitrogen atmosphere

• thoroughly with methanol and deionized water, and dried at 45 °C to obtain the first-generation dendrimer-functionalized CNTs, and labelled as CNTs-G0. This material served as the base for subsequent dendrimer growth through alternating reactions with MA and EDA. To initiate dendrimer growth, CNTs-G0 (100 mg

• ) and MA (0.3 g) were dispersed in 3.0 mL of methanol at room temperature and stirred overnight to allow carboxylation. The product was collected by vacuum filtration, washed thoroughly with ethanol, and dried at 45 °C to obtain the second-generation dendrimer-functionalized sample, denoted as CNTs-G1

Cross-reactivities in conjugation reactions involving iron oxide nanoparticles

• Shoronia N. Cross,
• Katalin V. Korpany,
• Hanine Zakaria and
• Amy Szuchmacher Blum

Beilstein J. Nanotechnol. 2025, 16, 1504–1521, doi:10.3762/bjnano.16.106

• ). Methanol (MeOH) (≥99.8%) were purchased from ACP Chemicals (Montreal, QC). Anhydrous ethanol (EtOH) was obtained from Commercial Alcohols (Brampton, ON). Benzene (99.00%) was purchased from Caledon Laboratories (Georgetown, ON). Sulfo-Cy3-maleimide (hereafter, referred to simply as Cy3-maleimide) (≥95

• based on a modified version of the methodology established in [42]. Briefly, 3,4-DHBA (40.7 mg, 0.26 mmol) was dissolved in 1 mL of methanol and added to 5 mg of IONP-OA in 14 mL of chloroform. The reaction mixture was sonicated for 0.5 h at rt. The resulting nanoparticles, which were no longer stable

• in chloroform, were collected by centrifugation and washed once with methanol. This same protocol is used to produce IONP-3,5-DHBA. Coupling of amine linkers to NHS-activated nanoparticles (IONP-PPA, IONP-CySH, and IONP-CySS) Here, we describe the procedure for preparing IONP-PPA, however, the same

Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications

• Akshana Parameswaran Sreekala,
• Pooja Raveendran Nair,
• Jithin Kundalam Kadavath,
• Bindu Krishnan,
• David Avellaneda Avellaneda,
• M. R. Anantharaman and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104

Acrocomia aculeata oil-loaded nanoemulsion: development, anti-inflammatory properties, and cytotoxicity evaluation

• Verónica Bautista-Robles,
• Hady Keita,
• Edgar Julián Paredes Gamero,
• Layna Tayná Brito Leite,
• Jessica de Araújo Isaías Muller,
• Mônica Cristina Toffoli Kadri,
• Ariadna Lafourcade Prada and
• Jesús Rafael Rodríguez Amado

Beilstein J. Nanotechnol. 2025, 16, 1277–1288, doi:10.3762/bjnano.16.93

• tube, and dried under a stream of nitrogen for 24 h. Then, 3 mL of a 2% methanolic NaOH solution was added to the tube. The tube was hermetically sealed and heated at 85 °C for 3 min. After cooling to room temperature, 2 mL of a BF3/methanol solution was added. The tube was resealed and heated for 25

Functional bio-packaging enhanced with nanocellulose from rice straw and cinnamon essential oil Pickering emulsion for fruit preservation

• Tuyen B. Ly,
• Duong D. T. Nguyen,
• Hieu D. Nguyen,
• Yen T. H. Nguyen,
• Bup T. A. Bui,
• Kien A. Le and
• Phung K. Le

Beilstein J. Nanotechnol. 2025, 16, 1234–1245, doi:10.3762/bjnano.16.91

• samples was assessed using the 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging assay. Exactly 1.00 g of biopackaging samples were added into 1.8 mL of 80% methanol. Afterwards, 3.2 mL of 0.1 mM DPPH solution was added to ensure that the absorbance of the control was above 0.6, and the samples were

Single-layer graphene oxide film grown on α-Al₂O₃(0001) for use as an adsorbent

• Shiro Entani,
• Mitsunori Honda,
• Masaru Takizawa and
• Makoto Kohda

Beilstein J. Nanotechnol. 2025, 16, 1082–1087, doi:10.3762/bjnano.16.79

• was annealed at 900 °C in open air in order to obtain an atomically flat surface. Then, the substrate was introduced into a vacuum furnace. The base pressure of the furnace was 6 × 10−6 Pa. After evacuating, the substrate was annealed up to 1000 °C for 1 h. For the graphene growth, a methanol vapor

• was used as a precursor. The SLG was grown by introducing 200 Pa methanol vapor for 30 min [18]. The single layer of graphene was inspected by the intensity analysis of XPS and the profiles of NIXSW for graphene/α-Al2O3(0001). After the SLG growth, the SLG in the sample was oxidized based on the

A calix[4]arene-based supramolecular nanoassembly targeting cancer cells and triggering the release of nitric oxide with green light

• Cristina Parisi,
• Loredana Ferreri,
• Tassia J. Martins,
• Francesca Laneri,
• Samantha Sollima,
• Antonina Azzolina,
• Antonella Cusimano,
• Nicola D’Antona,
• Grazia M. L. Consoli and
• Salvatore Sortino

Beilstein J. Nanotechnol. 2025, 16, 1003–1013, doi:10.3762/bjnano.16.75

• methanol/water (1:1) and, for comparison, that of its non-nitrosated derivative 2b. Both compounds exhibit similar molar absorptivity, but the absorption maximum of 2 is by almost 100 nm blue-shifted due to the loss of the push−pull character of the nitroaniline chromophore. Irradiation of 2 with blue

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• methods [30][31][32]. Initial studies were performed by exposing the surface of interest to the chosen molecule at UHV-compatible pressures. The interaction between cerium oxide and, for example, CO [21][33], SO2 [34], methanol [32], ethanol [35], and water [36] have been considered. The higher energy

• on Pt NPs supported on ceria were compared with the ones observed on a Pt(111) surface [31]. The oxide-supported NPs were shown to have an enhanced reactivity and additional reaction pathways [31]. Regarding the same system, the efficient decomposition of methanol and the resistance to poisoning have

• rationalized the observed high activity of the material in direct methanol fuel cells [37]. Regarding the Ni-CeO2−x(111) system, a study of the methanol reaction revealed that the strong metal–support interactions between Ni and CeO2 determines the high selectivity for CO2 production, instead of the formation

Morphology and properties of pyrite nanoparticles obtained by pulsed laser ablation in liquid and thin films for photodetection

• Akshana Parameswaran Sreekala,
• Bindu Krishnan,
• Rene Fabian Cienfuegos Pelaes,
• David Avellaneda Avellaneda,
• Josué Amílcar Aguilar-Martínez and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 785–805, doi:10.3762/bjnano.16.60

• synthesize pyrite nanoparticles in various solvents, including isopropyl alcohol (IPA), dimethyl formamide (DMF), ethanol, methanol, and acetone, using a 532 nm wavelength output from a Nd:YAG laser. Pulsed laser ablation in liquid has been demonstrated as a reliable alternative to conventional chemical

• % pure, Beijing Goodwill Metals, China) was placed in a 250 mL beaker with 25 mL of solvent (IPA, DMF, ethanol, methanol, and acetone – all from Fermont, 99.9% pure, analytical grade). The FeS2 target surface was polished and washed each time using the respective solvent for ablation to get rid of any

• nanocolloids obtained in different solvents are shown in Supporting Information File 1, Figure S1. The NPs of FeS2 in IPA are referred to as FIPA, in DMF as FDMF, in ethanol as FET, in methanol as FMET, and in acetone as FAC. Morphology and composition of the nanoparticles obtained in all solvents are analyzed

Synthesis of a multicomponent cellulose-based adsorbent for tetracycline removal from aquaculture water

• Uyen Bao Tran,
• Ngoc Thanh Vo-Tran,
• Khai The Truong,
• Dat Anh Nguyen,
• Quang Nhat Tran,
• Huu-Quang Nguyen,
• Jaebeom Lee and
• Hai Son Truong-Lam

Beilstein J. Nanotechnol. 2025, 16, 728–739, doi:10.3762/bjnano.16.56

• ), were used as reference antibiotics in this study. Additional reagents included ciprofloxacin and enrofloxacin (both from Pharmaceutical Joint Stock Company of February 3rd, Vietnam), methanol (Merck, Germany), sodium carboxymethyl cellulose (Zhanyun, China), PVA (95.5–96.5% hydrolyzed, MW ≈ 85,000

Polyurethane/silk fibroin-based electrospun membranes for wound healing and skin substitute applications

• Iqra Zainab,
• Zohra Naseem,
• Syeda Rubab Batool,
• Muhammad Waqas,
• Ahsan Nazir and
• Muhammad Anwaar Nazeer

Beilstein J. Nanotechnol. 2025, 16, 591–612, doi:10.3762/bjnano.16.46

• crystalline), whereas random globules make up the amorphous region [80]. Silk I with α-helical structure can be turned into silk II with β-sheets through shearing, spinning, heating, or by using methanol or ethanol solvents; this transition is considered irreversible [81]. Triple helices of collagen and β

Fabrication and evaluation of BerNPs regarding the growth and development of Streptococcus mutans

• Tuyen Huu Nguyen,
• Hong Thanh Pham,
• Kieu Kim Thanh Nguyen,
• Loan Hong Ngo,
• Anh Ngoc Tuan Mai,
• Thu Hoang Anh Lam,
• Ngan Thi Kim Phan,
• Dung Tien Pham,
• Duong Thuy Hoang,
• Thuc Dong Nguyen and
• Lien Thi Xuan Truong

Beilstein J. Nanotechnol. 2025, 16, 308–315, doi:10.3762/bjnano.16.23

• . Powder BerNPs were obtained by the freeze-drying for 48 h at −55 °C under vacuum. Physicochemical characterization of BerNPs The specific adsorption peak of BerNPs was determined by UV–vis absorption spectroscopy in a wavelength range from 200 to 600 nm after dilution in methanol. The berberine

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• insoluble in water, alkali, and most mineral acid systems. Additionally, chitosan is soluble in mixtures of water, methanol, ethanol, and acetone [52], making it feasible for the electrospinning process. Unbound amino groups make chitosan a positively charged polyelectrolyte in acidic media, resulting in

Mechanistic insights into endosomal escape by sodium oleate-modified liposomes

• Ebrahim Sadaqa,
• Satrialdi,
• Fransiska Kurniawan and
• Diky Mudhakir

Beilstein J. Nanotechnol. 2024, 15, 1667–1685, doi:10.3762/bjnano.15.131

• medium. This approach ensures the anchorage of the peptide to the liposome membrane surface. Synthesis of the liposomal formulations was conducted via a refined thin-film hydration technique, as inspired by existing protocols [34]. Initially, the lipids were dissolved in a chloroform and methanol

A biomimetic approach towards a universal slippery liquid infused surface coating

• Ryan A. Faase,
• Madeleine H. Hummel,
• AnneMarie V. Hasbrook,
• Andrew P. Carpenter and
• Joe E. Baio

Beilstein J. Nanotechnol. 2024, 15, 1376–1389, doi:10.3762/bjnano.15.111

• methanol for 20 min [30]. All substrates were then dried under a stream of nitrogen and sealed until use. The cleaned substrates were then immersed in dopamine hydrochloride (Sigma-Aldrich, St. Louis, MO) at a concentration of 2 mg/mL for 24 h in a 10 mM Trizma base (Sigma-Aldrich, St. Louis, MO) solution

Green synthesis of carbon dot structures from Rheum Ribes and Schottky diode fabrication

• Muhammed Taha Durmus and
• Ebru Bozkurt

Beilstein J. Nanotechnol. 2024, 15, 1369–1375, doi:10.3762/bjnano.15.110

• dried to synthesize CDs. Acetone, methanol, silicon, gold powder, and aluminum were purchased from Sigma-Aldrich, Merck, and Alfa Aesar. All studies were carried out at room temperature. Instruments Various devices were used for the structural, morphological, and optical characterization of the CDs. FEI

• substrate was cut to approximately 1 cm2 in size and cleaned by washing it in acetone, methanol, and pure water for 10 min each. An ohmic contact was made with aluminum on the cleaned sample at 1 × 10−7 Torr vacuum in a PVD thermal evaporation device. Approximately 30 μL of the CDs stock solution was taken

The role of a tantalum interlayer in enhancing the properties of Fe₃O₄ thin films

• Hai Dang Ngo,
• Vo Doan Thanh Truong,
• Van Qui Le,
• Hoai Phuong Pham and
• Thi Kim Hang Pham

Beilstein J. Nanotechnol. 2024, 15, 1253–1259, doi:10.3762/bjnano.15.101

• ) substrates were prepared by immersing them in a methanol bath at a temperature of 60 °C and drying them in N2 gas flow. Subsequently, the purified substrates were moved into an ultrahigh vacuum (UHV) chamber and underwent a pre-heating process at 600 °C for 30 min in order to eliminate any remaining

• impurities. The SiO2/Si(100) substrates were immersed in acetone and 2-propanol for a duration of 2 min in an ultrasonic bath. Subsequently, they were immersed in a solution of methanol at a temperature of 60 °C and then dried in N2 gas flow. A 5 nm thick layer of tantalum was deposited on a SiO2/Si(100