Reliable fabrication of transparent conducting films by cascade centrifugation and Langmuir–Blodgett deposition of electrochemically exfoliated graphene

• Teodora Vićentić,
• Stevan Andrić,
• Vladimir Rajić and
• Marko Spasenović

Beilstein J. Nanotechnol. 2022, 13, 666–674, doi:10.3762/bjnano.13.58

• threshold is 82.4%, matching the value found in an earlier work that showed particle size selection by control of liquid-phase exfoliation time [27], possibly indicating an upper limit for optical transparency achievable with Langmuir–Blodgett graphene films. The observed critical threshold transparency is

Antibacterial activity of a berberine nanoformulation

• Hue Thi Nguyen,
• Tuyet Nhung Pham,
• Anh-Tuan Le,
• Nguyen Thanh Thuy,
• Tran Quang Huy and
• Thuy Thi Thu Nguyen

Beilstein J. Nanotechnol. 2022, 13, 641–652, doi:10.3762/bjnano.13.56

• ], particle size reduction [25], and encapsulation in nanoscale delivery systems [11]. Nanoscale BBR crystals can be formed using top-down technologies (ball mills, high-pressure homogenizers, microfluidic technology, and spray drying) or bottom-up technologies (evaporative precipitation of nanosuspension

• (EPN) and antisolvent precipitation (ASP)). Although top-down technologies have a high yield, they are energy-consuming and the obtained crystal size is inhomogeneous [26][27]. The ASP technique can modify crystal formation and particle size distributions [5]. Sahibzada et al. [26] reported that BBR

• BBR NPs. The mean size of the particles measured by DLS was 156 nm for BBR NPs at a concentration of 2.0 mg/mL. The particle size measured by DLS was larger than the size obtained from TEM analysis because this dynamic measurement is affected by the concentration of the solution, surface properties of

A new method for obtaining the magnetic shape anisotropy directly from electron tomography images

• Cristian Radu,
• Ioana D. Vlaicu and
• Andrei C. Kuncser

Beilstein J. Nanotechnol. 2022, 13, 590–598, doi:10.3762/bjnano.13.51

• very brief review of such techniques is given in the following. The particle size and shape of particulate systems ranging from the nanometer (characteristic to catalysis, sensoristics, spintronics, and some medical therapies [1][2][3]) over the micrometer (pharmaceutical industry and powder metallurgy

• technique. The “translation” of the experimentally measured parameter to the parameter of interest (particle size in this case) is always accomplished by imperfect assumptions or extrapolations in the mathematical models. For example, in the case of X-ray diffraction, the mean crystal size is provided only

• , ImageJ, IMOD, tomo3d, or Genfire). The proposed program was designed to work directly with electron tomograms reconstructed using Genfire [22]. Although Magn3t is technically capable to provide correct information regarding particle size distribution (with particle separation capabilities) for any 3D

Detection and imaging of Hg(II) in vivo using glutathione-functionalized gold nanoparticles

• Gufeng Li,
• Shaoqing Li,
• Rui Wang,
• Min Yang,
• Lizhu Zhang,
• Yanli Zhang,
• Wenrong Yang and
• Hongbin Wang

Beilstein J. Nanotechnol. 2022, 13, 549–559, doi:10.3762/bjnano.13.46

• Fluorescence spectrophotometer (Hitachi, Japan). Mean particle size and the zeta potential were recorded using a Zetasizer Nano ZS90 (Malvern, UK). A Nicolet iS10 infrared spectrometer (Nicolet, USA) was used to gather FTIR spectra in a scanning range of 400–4000 cm−1. Fluorescence images of cells were

Stimuli-responsive polypeptide nanogels for trypsin inhibition

• Petr Šálek,
• Jana Dvořáková,
• Sviatoslav Hladysh,
• Diana Oleshchuk,
• Ewa Pavlova,
• Jan Kučka and
• Vladimír Proks

Beilstein J. Nanotechnol. 2022, 13, 538–548, doi:10.3762/bjnano.13.45

• presence of SPAN 80 [24]. TEM microscopy analysis has revealed a slight narrowing of the particle size distribution with Đ = 1.43. PHEG-Tyr nanogel is composed of two families of compact hydrogel spheres with Dn = 111 and 19 nm, and Dw = 159 and 24 nm, respectively. Biocompatible zwitterionic Nα-Lys-NG was

• to the measurement at 25 °C as a result of the contribution from hydrophobic interactions and hydrogen bonds. However, it is important to note that the measurement was also affected by the broad particle size distribution of Nα-Lys-NG nanogel documented by the error bars in Figure 3a. PDI values

• min without pulsation, and 1 min pulsation (0.5 s pulse rate). All measurements were performed in pentaplicates, and data were expressed as mean and standard deviation. Morphology, size, and particle size distribution of the nanogels were studied using a Tecnai G2 Spirit Twin 12 transmission electron

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• , 25 μm), 18NR-T transparent titania paste (particle size of 20 nm), 18NR-AO active opaque titania paste (particle sizes of 20 and 450 nm), fluorine-doped tin oxide (FTO, TEC8 glass plates, 8 Ω·cm−2, 2.2 mm thickness), and N719 industry standard dye (N719) were purchased from Dyesol (Australia). All

Ethosomal (−)-epigallocatechin-3-gallate as a novel approach to enhance antioxidant, anti-collagenase and anti-elastase effects

• Çiğdem Yücel,
• Gökçe Şeker Karatoprak,
• Sena Yalçıntaş and
• Tuğba Eren Böncü

Beilstein J. Nanotechnol. 2022, 13, 491–502, doi:10.3762/bjnano.13.41

• ) (Figure 2). As seen in Table 1, increasing particle size and particle size distribution were determined depending on the increasing lipid ratio and ethanol ratio. It is possible to say that ethanol gives a net negative charge to the ethosomal system and provides it with some degree of steric stabilization

• ethosomal formulations containing a potent antioxidant, epigallocatechin-3-gallate (EGCG), and to evaluate their potential for use in cosmetics by determining their antioxidant and antiaging effects. Ethosomes (ETHs) were prepared via mechanical dispersion and characterized in vitro in terms of particle

• size (PS), zeta potential (ZP), polydispersity index (PDI), encapsulation efficiency percentage (EE%), and in vitro release. The best ETH formulation was used to prepare the ethosome-based gel (ETHG) by using Carbopol 980 as a gelling agent at a ratio of 1:1 (v/v). The gel formulation was evaluated

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• . With increasing the glycol chain length, the average particle size of ZnO is also increased [27]. Employing ethylene glycol as a polyol led to assembled hollow sphere structures, while diethylene glycol resulted in elliptical nanorod structures [29]. The simplicity and environmentally friendly

Micro- and nanotechnology in biomedical engineering for cartilage tissue regeneration in osteoarthritis

• Zahra Nabizadeh,
• Mahmoud Nasrollahzadeh,
• Hamed Daemi,
• Mohamadreza Baghaban Eslaminejad,
• Ali Akbar Shabani,
• Mehdi Dadashpour,
• Majid Mirmohammadkhani and
• Davood Nasrabadi

Beilstein J. Nanotechnol. 2022, 13, 363–389, doi:10.3762/bjnano.13.31

• monoiodoacetate-induced osteoarthritis in rats. The SM-loaded NPs showed suitable properties in terms of particle size (81.4 nm), zeta potential (−28.3 mV), and high encapsulation efficiency (97.5%). Histological criteria, knee bend score, and oxidative stress remarkably improved in rats treated with the SM

Alcohol-perturbed self-assembly of the tobacco mosaic virus coat protein

• Ismael Abu-Baker and
• Amy Szuchmacher Blum

Beilstein J. Nanotechnol. 2022, 13, 355–362, doi:10.3762/bjnano.13.30

• -spherical so the particle size from DLS is expected to be significantly lower than the size from TEM, especially for rods. With these issues in mind, DLS in this work should be considered an ensemble qualitative technique to detect the presence of large particles/aggregates. The effect of alcohol on TMV-cp

Interfacial nanoarchitectonics for ZIF-8 membranes with enhanced gas separation

• Season S. Chen,
• Zhen-Jie Yang,
• Chia-Hao Chang,
• Hoong-Uei Koh,
• Sameerah I. Al-Saeedi,
• Kuo-Lun Tung and
• Kevin C.-W. Wu

Beilstein J. Nanotechnol. 2022, 13, 313–324, doi:10.3762/bjnano.13.26

• ., strong acids or bases or organic solvents) compared to polymer substrates. The particle size of α-Al2O3 on dense top layers of these disks is around 200 nm (information from Fraunhofer IKTS, Germany). The porosity of the disks was measured as 41.58% by mercury porosimeter measurements. The XRD patterns

• synthesized at 80 and 120 °C (Figure 3b,c), which was in line with the higher crystallinity at higher synthesis temperatures indicated in Table 1. When the synthesis temperature increased to 120 °C, the particle size of ZIF-8 crystals was smaller than 500 nm (Figure 3c). Although a higher reaction temperature

The effect of metal surface nanomorphology on the output performance of a TENG

• Yiru Wang,
• Xin Zhao,
• Yang Liu and
• Wenjun Zhou

Beilstein J. Nanotechnol. 2022, 13, 298–312, doi:10.3762/bjnano.13.25

• ). After the size screening, the proportion of each particle size was calculated. The particle size distribution plays a vital role in improving the output performance. The nanocrystals can be divided into pyramids, spheroids and strips. The shape of the metal nanocrystals determines the distribution of

• surface charge density, which, in turn, influences output current and voltage. Size and shape of the particles are related to the performance of TENG. The particle size distributions are given in Figure 7 and Figure 8. Narrower size distributions of copper nanoparticles lead to a higher output performance

• %, and the improvement is not obvious (Figure 9). This is because the particle size distributions are too large. This can be seen intuitively in the COMSOL displacement simulation below in Figure 11. However, the charge density at the sharps tips is higher than that at the spherical strips, which is very

Systematic studies into uniform synthetic protein nanoparticles

• Nahal Habibi,
• Ava Mauser,
• Jeffery E. Raymond and
• Joerg Lahann

Beilstein J. Nanotechnol. 2022, 13, 274–283, doi:10.3762/bjnano.13.22

• process. Dynamic light scattering DLS measurements were performed on particles in their hydrated state using a Zetasizer Nano ZS (Malvern Panalytical). The solution in which the particles were suspended was DPBS. DLS was employed to measure the particle size distribution after particle collection and

Photothermal ablation of murine melanomas by Fe₃O₄ nanoparticle clusters

• Xue Wang,
• Lili Xuan and
• Ying Pan

Beilstein J. Nanotechnol. 2022, 13, 255–264, doi:10.3762/bjnano.13.20

• dimension of 329.2 nm (Figure 1b). Moreover, SEM imaging at higher magnification showed that the clusters were composed of many regularly organized small nanoparticles, preventing the loss of superparamagnetism due to increased particle size. These NPCs possess high magnetization with a saturation value of

• morphology of the as-synthesized nanoparticle clusters was characterized with a JEOL JEM-2100 transmission electron microscopy (TEM). Dynamic light scattering (DLS) The synthesized Fe3O4 NPCs were diluted in RPMI 1640 medium to a final concentration of 0.25 mg/mL. The particle size distribution was

• quadratic fit of the correlation function. The particle size distribution was measured using the inbuilt DTS (nano) software. Samples were equilibrated for 1 min before measurement. All measurements were performed in triplicates. Hyperthermia effect of Fe3O4 nanoparticle clusters in solution The Fe3O4

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• stability, toxicity, and ultimately the fate of TiO2 nps [36]. Thus, there is a need to meticulously characterize the nanomaterial properties, emphasizing particle size, crystal structure, and specific surface area, for a reliable prediction of the toxicological behavior of TiO2 nanomaterials. A number of

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

• particulate matter. Ge et al. developed an electrospun nanocomposite with rare earth-fused polyurethane to adsorb volatile organic compounds, which are air pollutants [16]. Al-Attabi et al. fabricated a nanohybrid for the submicrometer aerosol particle size filtration by doping wrinkled silica into PAN via

A photonic crystal material for the online detection of nonpolar hydrocarbon vapors

• Evgenii S. Bolshakov,
• Aleksander V. Ivanov,
• Andrei A. Kozlov,
• Anton S. Aksenov,
• Elena V. Isanbaeva,
• Sergei E. Kushnir,
• Aleksei D. Yapryntsev,
• Aleksander E. Baranchikov and
• Yury A. Zolotov

Beilstein J. Nanotechnol. 2022, 13, 127–136, doi:10.3762/bjnano.13.9

• . Black lines show the linear correspondence of the experimental data. (a) Photo of the sensor and (b) electron microscopy image of a CCA of polystyrene particles without a PDMS layer on a glass substrate (effective particle size = 201 nm). The data obtained with dynamic light scattering slightly

Bacterial safety study of the production process of hemoglobin-based oxygen carriers

• Axel Steffen,
• Yu Xiong,
• Radostina Georgieva,
• Ulrich Kalus and
• Hans Bäumler

Beilstein J. Nanotechnol. 2022, 13, 114–126, doi:10.3762/bjnano.13.8

• analysis, one drop of the sample was applied to a glass slide, dried overnight, and sputtered with gold. A Gemini Leo 1550 (Carl Zeiss AG, Oberkochen, Germany) instrument was utilized for the measurements at an operation voltage of 10 kV. The particle size was measured by DLS applying a Zetasizer Nano ZS

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• a SnO2 thin film with a thickness of about 130 nm is 3.597 eV [42]. The reported bandgap of bulk SnO2 is 3.6 eV. Changing the morphology, particle size, or the formation of OVs or defects narrow the bandgap. In the study of Babu et al., a redshift of the absorption edge was observed when SnO2

• , hydrothermal, and microwave synthesis [49][50][51]. The formation and concentration of OVs depend on particle size, synthesizing temperature, and morphology of SnO2. The OVs play the role of an electron donor and provide free electrons, making SnO2 an n-type semiconductor [52]. Guoliang Xu et al. indicated

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

Biocompatibility and cytotoxicity in vitro of surface-functionalized drug-loaded spinel ferrite nanoparticles

• Sadaf Mushtaq,
• Khuram Shahzad,
• Tariq Saeed,
• Anwar Ul-Hamid,
• Bilal Haider Abbasi,
• Nafees Ahmad,
• Waqas Khalid,
• Muhammad Atif,
• Zulqurnain Ali and
• Rashda Abbasi

Beilstein J. Nanotechnol. 2021, 12, 1339–1364, doi:10.3762/bjnano.12.99

• show a crystalline structure with edges of single grains of nanoparticles. The interplanar distance was meaured for each sample with marked lattice fringes of the respective planes. The average particle size was found to be 16–21 nm for FeO, 14–18 nm for CFO, and 12–16 nm for NFO with d spacing values

Identifying diverse metal oxide nanomaterials with lethal effects on embryonic zebrafish using machine learning

• Richard Liam Marchese Robinson,
• Haralambos Sarimveis,
• Philip Doganis,
• Xiaodong Jia,
• Marianna Kotzabasaki,
• Christiana Gousiadou,
• Stacey Lynn Harper and
• Terry Wilkins

Beilstein J. Nanotechnol. 2021, 12, 1297–1325, doi:10.3762/bjnano.12.97

• simple fashion [23][27]. Specifically, in addition to using other qualitative and quantitative physicochemical characteristics (such as average primary particle size), these studies only used the names of chemical components, that is, the core, surface functional groups (FGs) or the shell, as descriptors

• primary particle size. Nonetheless, the importance of the Pauling metal atom electronegativity descriptor is confirmed based upon consideration of a conditional variable importance estimate (Figure 11) obtained using a variation on the Random Forest modelling and variable importance protocol, which can be

• significantly related to excess lethality at 120 hpf, with limited influence of descriptors representing the primary particle size or surface characteristics is interesting. The finding that the Pauling metal atom electronegativity descriptor was of greatest significance is broadly in keeping with earlier

The effect of cobalt on morphology, structure, and ORR activity of electrospun carbon fibre mats in aqueous alkaline environments

• Markus Gehring,
• Tobias Kutsch,
• Osmane Camara,
• Alexandre Merlen,
• Hermann Tempel,
• Hans Kungl and
• Rüdiger-A. Eichel

Beilstein J. Nanotechnol. 2021, 12, 1173–1186, doi:10.3762/bjnano.12.87

• , which is likely a result of the increasing particle size found in the SEM images. The presence of metallic cobalt as the bulk phase for the particles is clear from this result, but considering the catalytic properties a closer look at the particle surfaces is helpful. Therefore, the Co 2p XPS range was

• to electrochemical redox activity and stability. Microscopic analysis of the resulting fibre mats showed that, with increasing carbonisation temperatures, the mean fibre diameter decreased, whereas the mean cobalt-species particle size increased. The (surface) composition and structure of the

pH-driven enhancement of anti-tubercular drug loading on iron oxide nanoparticles for drug delivery in macrophages

• Karishma Berta Cotta,
• Sarika Mehra and
• Rajdip Bandyopadhyaya

Beilstein J. Nanotechnol. 2021, 12, 1127–1139, doi:10.3762/bjnano.12.84

• individual particle size in comparison to the NOR@IONPs synthesized in our previous study. However, the hydrodynamic diameter in this work is observed to be smaller, with majority of the particles lying between 70–80 nm and 40–70 nm for NOR@IONPpH5 and NOR@IONPpH10, respectively. Additionally, the zeta

Criteria ruling particle agglomeration

• Dieter Vollath

Beilstein J. Nanotechnol. 2021, 12, 1093–1100, doi:10.3762/bjnano.12.81

• Dieter Vollath NanoConsulting, Primelweg 3, 76297 Stutensee, Germany 10.3762/bjnano.12.81 Abstract Most of the technically important properties of nanomaterials, such as superparamagnetism or luminescence, depend on the particle size. During synthesis and handling of nanoparticles, agglomeration

• teach that, in case of any energetic interaction of the particles, the influence of the entropy is minor or even negligible. Complementary to the simulations, the extremum of the entropy was determined using the Lagrange method. Both approaches yielded identical result for the particle size distribution

• ; Introduction Many properties of technical importance of nanomaterials depend on the particle size. Typical examples are superparamagnetism, luminescence, or energetic applications. In many cases, the particles show in an “as produced” state the requested size distributions. However, during handling or storage