Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• al. on using Ag@SnO2 NPs for removing NO, taking advantage of plasmonic-induced photocatalysis [72]. The Ag@SnO2 NPs were fabricated by a simple and green approach using hydrothermal growth and photoreduction deposition. The introduction of Ag induced a bending of the band structure of SnO2 NPs

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• luminescence properties of europium-doped titanium dioxide and tellurium oxide thin films enhanced by gold plasmonic nanostructures. We propose a new type of plasmon structure with an ultrathin dielectric film between plasmonic platform and luminescent material. Plasmonic platforms were manufactured through

• . Potential new materials can be found through the computation of luminescent thin films and plasmonic platforms. Such a hybrid structure can be formed by thin oxide layers doped with rare-earth ions deposited on metal nanostructures [1][2][3]. Plasmonic resonance can be observed in metallic nanostructures

• , so-called plasmonic platforms, and thin films. Among different plasmonic materials, gold nanostructures exhibit resonance in the visible range and have been extensively studied as a material for light absorption and emission improvement [4][5][6][7][8]. Titanium dioxide seems to be one of the most

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• plasmonic gold (Au) metasurface for sensing volatile organic compounds (VOCs) [49]. This modification enhanced the plasmonic field and local surface plasmonic resonance (LSPR). The influence of the gold nanodisk diameter and the average thickness of the TiO2 fractal on LSPR sensing of VOCs, specifically

• Plasmonic Metasurfaces for Selective and Sensitive Optical Sensing of Volatile Compounds”, Advanced Materials, with permission from John Wiley & Sons. Copyright © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This content is not subject to CC BY 4.0. TiO2 fractals on candle soot templates. SEM images of

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• quantum efficiencies, and luminance. De facto, plasmonic nanoparticles, such as Au and Ag have boosted the luminance of red, green, and blue emissions. When combined with carbon nanostructures they additionally offer new possibilities towards lightweight and flexible devices with better thermal management

• . This review surveys the diverse possibilities to combine various inorganic, organic, and carbon nanostructures along with plasmonic nanoparticles. Such combinations would allow an enhancement in the overall properties of LED. Keywords: carbon nanotubes (CNT); graphene; light-emitting diodes (LED

• ); plasmonic nanoparticles; quantum dots; Review Introduction Nanomaterials have engendered the miniaturization of devices, bringing about advances in a variety of fields, such as biomedicine, environmental technologies, optoelectronics, and photocatalysis [1][2]. In particular, light-emitting diodes (LED

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• ), Ghaziabad 201002, India 10.3762/bjnano.12.69 Abstract Plasmonic metal nanoparticles are widely used for many applications due to their unique optical and chemical properties. Over the past decade, anisotropic metal nanoparticles have been explored for imaging, sensing, and diagnostic applications. The

• utilizing safe nanomaterials for advanced biomedical and clinical applications. Keywords: anisotropic nanoparticles; carrageenan; cytotoxicity; eutectic solvents; surfactants; Review Introduction Plasmonic metals such as gold and silver, upon achieving nanoscale dimensions, exhibit unusual physicochemical

• characteristics, such as interesting plasmonic, optical and catalytic properties, and facile surface modification with tunable size and morphology [1]. Among these properties, the ability of surface plasmon resonance (SPR) at visible to near-infrared (NIR) wavelengths is the most striking characteristic feature

Modification of a SERS-active Ag surface to promote adsorption of charged analytes: effect of Cu²⁺ ions

• Bahdan V. Ranishenka,
• Andrei Yu. Panarin,
• Irina A. Chelnokova,
• Sergei N. Terekhov,
• Peter Mojzes and
• Vadim V. Shmanai

Beilstein J. Nanotechnol. 2021, 12, 902–912, doi:10.3762/bjnano.12.67

• the electrostatic interaction between analyte molecules and silver nanoparticles (Ag NPs) on the intensity of surface-enhanced Raman scattering (SERS). For this, we fabricated nanostructured plasmonic films by immobilization of Ag NPs on glass plates and functionalized them by a set of differently

• of metallic NP arrays with controllable parameters such as size, shape, interparticle distance, and ordering degree [5][6][7][8][9][10][11][12], with a focus on plasmonic structures with a high density of “hot spots”. Due to the progress in nanotechnology, a large number of highly sensitive SERS

• substrates has been synthesized [1][13]. The design of SERS substrates commonly aims at maximizing the plasmonic effect of Raman enhancement. There are two generally recognized mechanisms responsible for the SERS enhancement, namely electromagnetic enhancement (EM) and chemical enhancement (CE) [14][15]. The

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• were so low, the change in optical properties was attributed to the local accumulation of defects (as opposed to collisional phase mixing). In a plasmonic application, resonant triangular nanostructures were created in a graphene sheet supported on SiO2/Si by selectively irradiating the graphene in the

High-yield synthesis of silver nanowires for transparent conducting PET films

• Gul Naz,
• Hafsa Asghar,
• Muhammad Ramzan,
• Muhammad Arshad,
• Rashid Ahmed,
• Muhammad Bilal Tahir,
• Bakhtiar Ul Haq,
• Nadeem Baig and
• Junaid Jalil

Beilstein J. Nanotechnol. 2021, 12, 624–632, doi:10.3762/bjnano.12.51

• have gained much attention in replacing ITO because of their low-cost solution-based fabrication, flexibility, and high optical transparency [14][15]. A large-scale uniform synthesis of AgNWs with high aspect ratio would be greatly preferred because of better plasmonic and optical properties [16]. An

• redshift of the peak positions. An overall hypsochromatic shift of the two plasmonic bands of AgNWs is accompanied by the enhancement of their aspect ratios. The SPR peak at 365 nm may be attributed to the plasmon response along the transverse axis of AgNWs, which is identical to that of bulk silver. The

A review on nanostructured silver as a basic ingredient in medicine: physicochemical parameters and characterization

• Gabriel M. Misirli,
• Kishore Sridharan and
• Shirley M. P. Abrantes

Beilstein J. Nanotechnol. 2021, 12, 440–461, doi:10.3762/bjnano.12.36

• induce the production of hot electrons from plasmonic metals, while larger size nanoparticles favor the scattering of the light. There is a strong electromagnetic field that is produced by fast and coherent oscillating electrons which extend into the metal and the surrounding environment [62][63]. The

Colloidal particle aggregation: mechanism of assembly studied via constructal theory modeling

• Scott C. Bukosky,
• Sukrith Dev,
• Monica S. Allen and
• Jeffery W. Allen

Beilstein J. Nanotechnol. 2021, 12, 413–423, doi:10.3762/bjnano.12.33

• variety of applications, including plasmonic/photonic devices, metamaterials, biomaterials and coatings, energetic materials, and high-strength ceramics [15][16][17][18][19][20][21][22][23][24][25]. Most applications, however, require precise manipulation of the particle placement, spacing, and

The impact of molecular tumor profiling on the design strategies for targeting myeloid leukemia and EGFR/CD44-positive solid tumors

• Nikola Geskovski,
• Nadica Matevska-Geshkovska,
• Simona Dimchevska Sazdovska,
• Marija Glavas Dodov,
• Kristina Mladenovska and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2021, 12, 375–401, doi:10.3762/bjnano.12.31

• activating the extracellular domain of membranous EGFR and influencing the EGFR signaling pathways through increased endocytosis (receptor internalization) and cytoplasmic accumulation of EGFR. In the study of Yokoyama et al. paramagnetic gold-coated plasmonic NPs (40–50 nm) with iron core and anti-EGFR

Structural and optical characteristics determined by the sputtering deposition conditions of oxide thin films

• Petronela Prepelita,
• Florin Garoi and
• Valentin Craciun

Beilstein J. Nanotechnol. 2021, 12, 354–365, doi:10.3762/bjnano.12.29

• properties. Transparent oxides are an attractive class of plasmonic materials which are under intense study for their integration into low-loss metamaterial structures and a series of applications in transformation optics, sensors, and imaging. Here we used oxide thin films and studied their optical

The patterning toolbox FIB-o-mat: Exploiting the full potential of focused helium ions for nanofabrication

• Victor Deinhart,
• Lisa-Marie Kern,
• Jan N. Kirchhof,
• Sabrina Juergensen,
• Joris Sturm,
• Enno Krauss,
• Thorsten Feichtner,
• Sviatoslav Kovalchuk,
• Michael Schneider,
• Dieter Engel,
• Bastian Pfau,
• Bert Hecht,
• Kirill I. Bolotin,
• Stephanie Reich and
• Katja Höflich

Beilstein J. Nanotechnol. 2021, 12, 304–318, doi:10.3762/bjnano.12.25

• -mat are presented. Keywords: automated patterning; focused He ion beam; graphene; magnetic multilayers; mechanical resonator; pattern generation; plasmonic antennas; two-dimensional materials; Introduction Future breakthroughs in nanotechnology will rely on the ability to fabricate materials and

• ubiquitous in ion beam machining with well-established applications in material characterization, for example, TEM lamella fabrication, cross sections or tomographies [19][20], or in the fabrication of prototype nanostructures, such as plasmonic antennas [2]. In contrast, appropriate fields of application

• , and the fabrication of coupled plasmonic nanoantennas from single-crystalline gold. The three latter examples are realized in this work by developing optimized patterning and automation routines [18]. Patterning and Beam Control Patterning with an ion beam is a digital process where the beam spot

Doxorubicin-loaded gold nanorods: a multifunctional chemo-photothermal nanoplatform for cancer management

• Uzma Azeem Awan,
• Abida Raza,
• Shaukat Ali,
• Rida Fatima Saeed and
• Nosheen Akhtar

Beilstein J. Nanotechnol. 2021, 12, 295–303, doi:10.3762/bjnano.12.24

• , nanorods, nanoshells, and nanocages) have great potential in photothermal cancer therapy due to plasmonic properties and the ease of biofunctionalization. Gold nanorods (GNRs) are more preferable than other gold nanomaterials because of their photothermal conversion efficiency. Better nanotherapeutics can

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

Fabrication of nano/microstructures for SERS substrates using an electrochemical method

• Jingran Zhang,
• Tianqi Jia,
• Xiaoping Li,
• Junjie Yang,
• Zhengkai Li,
• Guangfeng Shi,
• Xinming Zhang and
• Zuobin Wang

Beilstein J. Nanotechnol. 2020, 11, 1568–1576, doi:10.3762/bjnano.11.139

• /nanopore; nano/microstructures; SERS substrate; Introduction Surface-enhanced Raman spectroscopy (SERS) can be used to detect biomolecules [1][2][3], explosives [4][5][6], and pesticide residues [7][8][9]. Plasmonic metal nanostructures are often used as SERS substrates to increase the molecule-specific

Optically and electrically driven nanoantennas

• Monika Fleischer,
• Dai Zhang and
• Alfred J. Meixner

Beilstein J. Nanotechnol. 2020, 11, 1542–1545, doi:10.3762/bjnano.11.136

• configurations with increasing control over their optical performance [1][2][3][4]. The strong local near-field enhancement by plasmonic nanoantennas is being harnessed for high sensitivity, high-resolution optical nanospectroscopy techniques [5], such as surface-enhanced or tip-enhanced Raman spectroscopy (SERS

• top-down approaches such as thin film deposition and nanopatterning, as well as bottom-up approaches such as chemical synthesis and self-assembly [38]. Gap sizes may range from a few tens of nanometers down to sub-nanometer tunnel junctions, where the classical description of the plasmonic behavior

• deposition [41], or on dense silver island films created by pulsed laser deposition [42] or physical vapor deposition [43]. In [44], individual plasmonic nanotags are prepared by coating gold nanoparticle clusters with Raman reporters. This work explores the minimum number of tags required for obtaining a

Revealing the local crystallinity of single silicon core–shell nanowires using tip-enhanced Raman spectroscopy

• Marius van den Berg,
• Ardeshir Moeinian,
• Arne Kobald,
• Yu-Ting Chen,
• Anke Horneber,
• Steffen Strehle,
• Alfred J. Meixner and
• Dai Zhang

Beilstein J. Nanotechnol. 2020, 11, 1147–1156, doi:10.3762/bjnano.11.99

• can be obtained by rotating the prism while collecting optical spectra. The circle pattern is originating from the emission of the plasmonic oscillation along the tip shaft. This is in good agreement with the electric field distribution in the focus of a radially polarized laser beam, where the

• further increase the resolution a chemically etched gold tip, attached to a tuning fork, is brought into the focus [37][38][39][40][41]. A plasmonic oscillation is generated at the tip apex by the excitation with a radially polarized laser beam along the tip axis. Here, the local field intensity is

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

• Mykola Borzenkov,
• Piersandro Pallavicini,
• Angelo Taglietti,
• Laura D’Alfonso,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

• nanoparticles are due to the resonant oscillation of the surface electrons, called surface plasmons (e.g., plasmonic gold and silver nanoparticles) [38], or they are due to the energy of the band transitions (e.g., Cu2+ d–d transition in CuS nanoparticles) [39]. Under visible–NIR light irradiation, these

• nanomaterial used, for example, aqueous solutions, self-assembled monolayers or polymeric nanocomposites [33]. In the case of plasmonic nanoparticles, the plasmonic properties (i.e., the maximum position of the absorption band and the band shape) are strongly affected by the conditions under which the

• nanoparticles are synthesized, resulting in nanoparticles with different dimensions and shape. On the other hand, the nanoparticle surface chemistry as well as the surrounding environment exert a weaker influence on the plasmonic properties. For the non-plasmonic nanoparticles, the photothermal properties are

Thermophoretic tweezers for single nanoparticle manipulation

• Jošt Stergar and
• Natan Osterman

Beilstein J. Nanotechnol. 2020, 11, 1126–1133, doi:10.3762/bjnano.11.97

• nanodots, so-called plasmonic tweezers [6][7][8] or a fluidic slit with appropriately tailored topography with resulting spatially modulated electrostatic potential [9] can be used to trap nanoparticles, but again a prefabricated nanostructured substrate is needed. A decade ago, the anti-Brownian

• microbeaker” to confine the motion of a single nano-object. For the creation of high thermal gradients, their approach requires prefabricated plasmonic structures, which results in a big drawback: the confinement of an object is possible just within the structure, i.e., the object can not be freely

• tweezers is that the former uses a plasmonic nanostructure to create large local temperature gradients of the order of 100 K/μm, while the temperature gradients in our experiments, using a uniform substrate, are approximately ten times lower. To understand the effect of the gradient ∇T, one can define the

Highly sensitive detection of estradiol by a SERS sensor based on TiO₂ covered with gold nanoparticles

• Andrea Brognara,
• Ili F. Mohamad Ali Nasri,
• Beatrice R. Bricchi,
• Andrea Li Bassi,
• Caroline Gauchotte-Lindsay,
• Matteo Ghidelli and
• Nathalie Lidgi-Guigui

Beilstein J. Nanotechnol. 2020, 11, 1026–1035, doi:10.3762/bjnano.11.87

• -enhanced Raman scattering (SERS) sensors for the detection of 17β-estradiol. Gold deposition on top of a TiO2 surface leads to the formation of nanoparticles the plasmonic properties of which fulfil the requirements of a SERS sensor. The morphological and optical properties of the surface were investigated

• use of composite systems of dielectrics (TiO2, ZnO) and metallic NPs has gathered increasing attention regarding SERS applications, because the plasmonic enhancement provided by metallic NPs can be combined with the optical properties of the semiconductor such as light trapping, scattering, and

• aggressive solvents, which can induce damage especially in delicate applications involving polymeric substrates. Also, the control over the size and shape of AuNPs and, thus, over their plasmonic behavior is often limited. Here, we propose the use of a nanostructured hierarchically organized TiO2 film as a

Electrochemical nanostructuring of (111) oriented GaAs crystals: from porous structures to nanowires

• Elena I. Monaico,
• Eduard V. Monaico,
• Veaceslav V. Ursaki,
• Shashank Honnali,
• Vitalie Postolache,
• Karin Leistner,
• Kornelius Nielsch and
• Ion M. Tiginyanu

Beilstein J. Nanotechnol. 2020, 11, 966–975, doi:10.3762/bjnano.11.81

• electrochemically filling the pores with metallic nanostructures such as nanowires or nanotubes, resulting in the production of 2D metallo-semiconductor interpenetrating networks, which are promising for various nanoelectronic, optoelectronic, plasmonic, and nanophotonic applications [4][5][6]. While the growth of

A set of empirical equations describing the observed colours of metal–anodic aluminium oxide–Al nanostructures

• Cristina V. Manzano,
• Jakob J. Schwiedrzik,
• Gerhard Bürki,
• Laszlo Pethö,
• Johann Michler and
• Laetitia Philippe

Beilstein J. Nanotechnol. 2020, 11, 798–806, doi:10.3762/bjnano.11.64

• (AAO) films; anodization; structural colours; reflectance; polar coordinates; plasmonic effects; Introduction Recently, the reproduction of the vivid colours found in nature has received increasing interest [1]. These colours appear when light interacts with periodic structures. With regard to this

• observed before [18][19]. In both cases, after the deposition of 8 nm of Cr and 10 nm of Au on top of the AAO–Al films (Figure 2b and Figure 2c, respectively), a blueshift and a decrease in the reflectance is observed due to plasmonic effects [4][11][13]. The wavelength of each sample and consequently the

• used in order to obtain different colours of the metal–AAO–Al nanostructures due the different plasmonic effects in both metals. In addition, three different metal thicknesses were studied (25, 17.5 and 10 nm of Au) to show the influence of metal thickness on the observed colour. It is important to