Palladium-catalyzed solid-state borylation of aryl halides using mechanochemistry

Scholarly Works

• Floyd, K. R.; Mella, L. S.; Kwok, R. W.; Gray, M.; Broker, E. J.; Marianski, M.; Friščić, T.; Batteas, J. D. Harnessing the copper surface for direct mechanocatalysis: a case study on mechanochemical sulfonylurea synthesis. Chemical science 2025, 16, 19830–19842. doi:10.1039/d5sc04099j
• Mkrtchyan, S.; Purohit, V. B.; Jakubczyk, M.; Prajapati, V. D.; Prajapati, R. V.; Garcia, M. G.; Karpun, E.; Yepishev, V.; Saini, M. K.; Sarfaraz, S.; Ayub, K.; Addová, G.; Filo, J.; Iaroshenko, V. O. Mechanochemical Sequential Deoxygenative Cross-Coupling Reactions of Phenols Under Ruthenium-Nickel Catalysis. Molecules (Basel, Switzerland) 2025, 30, 1835. doi:10.3390/molecules30081835
• Zhang, Z.; Stuparu, M. C. Intramolecular direct arylation through mechanochemistry: efficient synthesis of corannulene-based peri-annulated curved nanographenes. Science China Chemistry 2025, 68, 3586–3594. doi:10.1007/s11426-024-2520-y
• Spula, C.; Becker, V.; Talajić, G.; Grätz, S.; Užarević, K.; Borchardt, L. Metal-Free C-X Functionalization in Solid-State via Photochemistry in Ball Mills. ChemSusChem 2024, 18, e202401022. doi:10.1002/cssc.202401022
• Hum, G.; Muzammil, E. M.; Li, Y.; García, F.; Stuparu, M. C. Mechanochemical Synthesis of Corannulene Flanked N-heterocyclic Carbene (NHC) Precursors and Preparation of Their Metal Complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 30, e202402056. doi:10.1002/chem.202402056
• Qu, R.; Wan, S.; Zhang, X.; Wang, X.; Xue, L.; Wang, Q.; Cheng, G.-J.; Dai, L.; Lian, Z. Mechanical-Force-Induced Non-spontaneous Dehalogenative Deuteration of Aromatic Iodides Enabled by Using Piezoelectric Materials as a Redox Catalyst. Angewandte Chemie (International ed. in English) 2024, 63, e202400645. doi:10.1002/anie.202400645
• Qu, R.; Wan, S.; Zhang, X.; Wang, X.; Xue, L.; Wang, Q.; Cheng, G.; Dai, L.; Lian, Z. Mechanical‐Force‐Induced Non‐spontaneous Dehalogenative Deuteration of Aromatic Iodides Enabled by Using Piezoelectric Materials as a Redox Catalyst. Angewandte Chemie 2024, 136. doi:10.1002/ange.202400645
• Pajić, M.; Juribašić Kulcsár, M. Solid-State Synthesis of B←N Adducts by the Amine-Facilitated Trimerization of the Phenylboronic Acid. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 30, e202400190. doi:10.1002/chem.202400190
• Zong, L.; Sun, R.; Hu, X.; Zhang, J.; Luan, Y.; Xu, Z.; Xie, C.; Li, X.; Sun, F.; Liu, H.; Liu, Z.; Zhao, Z.; Zhang, L. Mechanochemical Synthesis of Arylsilanes via Barbier‐Type Reaction between Aryl Halides and Chlorosilanes with Magnesium. Advanced Synthesis & Catalysis 2024, 366, 1509–1516. doi:10.1002/adsc.202301244
• Báti, G.; Csókás, D.; Stuparu, M. C. Mechanochemical Scholl Reaction on Phenylated Cyclopentadiene Core: One-Step Synthesis of Fluoreno[5]helicenes. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 30, e202302971. doi:10.1002/chem.202302971
• Canale, V.; Kamiński, M.; Trybała, W.; Abram, M.; Marciniec, K.; Bantreil, X.; Lamaty, F.; Parkitna, J. R.; Zajdel, P. Multistep Mechanochemical Synthesis of PZ-1190, a Multitarget Antipsychotic Agent. ACS Sustainable Chemistry & Engineering 2023, 11, 16156–16164. doi:10.1021/acssuschemeng.3c04023
• Nishikawa, H.; Kuwayama, M.; Nihonyanagi, A.; Dhara, B.; Araoka, F. Rapid, solvent-minimized and sustainable access to various types of ferroelectric-fluid molecules by harnessing mechano-chemical technology. Journal of Materials Chemistry C 2023, 11, 12525–12542. doi:10.1039/d3tc02212a
• Choy, P. Y.; Tse, M. H.; Kwong, F. Y. Recent Expedition in Pd- and Rh-Catalyzed C(Ar) -B Bond Formations and Their Applications in Modern Organic Syntheses. Chemistry, an Asian journal 2023, 18, e202300649. doi:10.1002/asia.202300649
• Báti, G.; Laxmi, S.; Stuparu, M. C. Mechanochemical Synthesis of Corannulene: Scalable and Efficient Preparation of A Curved Polycyclic Aromatic Hydrocarbon under Ball Milling Conditions. ChemSusChem 2023, 16, e202301087. doi:10.1002/cssc.202301087
• Kubota, K. Exploring Novel Synthetic Concepts and Strategies Using Mechanochemistry. Bulletin of the Chemical Society of Japan 2023, 96, 913–930. doi:10.1246/bcsj.20230157
• Kondo, K.; Ishiyama, T.; Kubota, K.; Ito, H. An Improved Catalytic System for Solid-state Iridium(I)-catalyzed C–H Borylation Using Mechanochemistry. Chemistry Letters 2023, 52, 333–336. doi:10.1246/cl.230081
• Hou, Y.; Wang, H.; Xi, J.; Jiang, R.; Zhang, L.; Li, X.; Sun, F.; Liu, Q.; Zhao, Z.; Liu, H. Electromagnetic mill promoted mechanochemical palladium-catalyzed solid state cyanation of aryl bromides using non-toxic K4[Fe(CN)6]. Green Chemistry 2023, 25, 2279–2286. doi:10.1039/d2gc04506k
• Canale, V.; Trybała, W.; Chaumont-Dubel, S.; Koczurkiewicz-Adamczyk, P.; Satała, G.; Bento, O.; Blicharz-Futera, K.; Bantreil, X.; Pękala, E.; Bojarski, A. J.; Lamaty, F.; Marin, P.; Zajdel, P. 1-(Arylsulfonyl-isoindol-2-yl)piperazines as 5-HT6R Antagonists: Mechanochemical Synthesis, In Vitro Pharmacological Properties and Glioprotective Activity. Biomolecules 2022, 13, 12. doi:10.3390/biom13010012
• Borchardt, L.; Hernández, J. G. Dissecting Mechanochemistry III. Beilstein journal of organic chemistry 2022, 18, 1454–1456. doi:10.3762/bjoc.18.150

Explore citations to this article at