Dry under water: air retaining properties of large-scale elastomer foils covered with mushroom-shaped surface microstructures

• Matthias Mail,
• Stefan Walheim,
• Thomas Schimmel,
• Wilhelm Barthlott,
• Stanislav N. Gorb and
• Lars Heepe

Beilstein J. Nanotechnol. 2022, 13, 1370–1379, doi:10.3762/bjnano.13.113

• Salvinia-like biomimetic surfaces are permanent over years, like in many air–water interfaces a neustonic microbial biofilm (“Bacterioneuston”), usually associated with fungi, becomes established under non-sterile and non-turbulent conditions rather fast. On the MSM already after one month the air–water

Straight roads into nowhere – obvious and not-so-obvious biological models for ferrophobic surfaces

• Wilfried Konrad,
• Christoph Neinhuis and
• Anita Roth-Nebelsick

Beilstein J. Nanotechnol. 2022, 13, 1345–1360, doi:10.3762/bjnano.13.111

• obvious biological models are no guarantee for success, and that it is difficult to arrive at a formalised biomimetic working scheme. Rather, a broad understanding of biological function and its complexity is beneficial. Keywords: air-retaining interfaces; bioinspiration; biomimetics; biomimicry; blast

• furnace; Collembola; gas/liquid interfaces; interfacial effects; persistant air layers; pits; Salvinia molesta; surfaces; tuyère failure; water transport in plants; xylem; Young–Laplace equation; Introduction and Motivation The basic concept of biomimetics is the derivation of technical applications from

• , persistence of the gas pockets within the structured surface should be energetically favourable over their displacement. The interfaces that separate the gas pockets from the liquid iron should form autonomously, that is, without the need for external manipulations. The typical dimensions of the structures

Design of a biomimetic, small-scale artificial leaf surface for the study of environmental interactions

• Miriam Anna Huth,
• Axel Huth,
• Lukas Schreiber and
• Kerstin Koch

Beilstein J. Nanotechnol. 2022, 13, 944–957, doi:10.3762/bjnano.13.83

• wetting properties of a natural leaf surface. Keywords: recrystallization; surface properties; wax composition; wetting; wheat; Introduction Cuticle One of the largest interfaces on earth is formed by thin layers that are a few nanometers to micrometers thin, namely the wax layers of the plant cuticle

Comparing the performance of single and multifrequency Kelvin probe force microscopy techniques in air and water

• Jason I. Kilpatrick,
• Emrullah Kargin and
• Brian J. Rodriguez

Beilstein J. Nanotechnol. 2022, 13, 922–943, doi:10.3762/bjnano.13.82

• of topography and surface properties of interfaces in a wide range of environments [1]. Kelvin probe force microscopy (KPFM) utilizes the application of a bias and a conductive probe to map the local electrical properties of an interface at the nanoscale [2], allowing for the determination of the

• of corrosion, sensing, solar cells, energy storage devices, and bioelectric interfaces [3][4][5][6][7][8]. Since its first application in 1991 [2], there have been significant developments in the field of KPFM [6][9][10] with significant advances in both temporal [11][12][13][14] and spatial

• ]. Whilst the application of DC bias is not required for OL operation it can still be utilized to allow CPD to be determined via bias sweeps [28][40] or to investigate gate-dependent potential profiles of interfaces [22][41][42]. There are a wide range of OL KPFM techniques beyond those examined in this

Bioselectivity of silk protein-based materials and their bio-inspired applications

• Hendrik Bargel,
• Vanessa T. Trossmann,
• Christoph Sommer and
• Thomas Scheibel

Beilstein J. Nanotechnol. 2022, 13, 902–921, doi:10.3762/bjnano.13.81

• , Germany Bavarian Polymer Institute (BPI), University of Bayreuth, Universitätsstr. 30, 95440 Bayreuth, Germany Bayreuth Center of Colloids and Interfaces (BZKG), University of Bayreuth, Universitätsstr. 30, 95440 Bayreuth, Germany Bayreuth Center for Molecular Biosciences (BZMB), University of Bayreuth

Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• –substrate interfaces, which promotes the wetting of the gallium melt [14][15]. Similarly, room-temperature-liquid eutectic Ga–In and eutectic Ga–In–Sn alloys have been reported to reactively wet thin indium and tin foils [16]. Also in [16], the authors demonstrated that the wetting of the same liquid alloys

• and calculate the corresponding work of adhesion Wad as suggested in [19] for solid interfaces. The authors measured the adhesion between atomically smooth quasicrystalline surfaces of TiN-coated AFM tips in ultrahigh vacuum by analyzing the pull-off force during atomic force spectroscopy measurements

• the surface energy of the tip material, the lower the interfacial energy between the tip and the Ga–In–Sn eutectic melt becomes. This result is so far expected as forming a tip–liquid interface rids areal parts of the tip–vapor and the Ga–In–Sn eutectic melt–vapor interfaces and, thus, decreases the

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• defined structures and flow characteristics. Thus, they are good experimental tools for the observation of crystallization process. The interfaces among the laminar fluids in microfluidic channels can be recognized as soft boundaries of crystallization zones. In the reaction–diffusion zone confined by

• liquid–liquid interfaces (soft boundary), crystallization of a 2D coordination polymer ([Cu(4,4′-bpy)](NO3)2, 4,4′-bpy = 4,4′-bipyridine) was investigated [102]. By changing the flow rate ratio between the focusing streams and the reagent fluids, the size and concentration gradient of the reaction

• into void-free structures [137]. The unavoidable interparticle voids limit interparticle interactions among the crystals, making the assemblies difficult to control. To solve this problem, assembling was tried in confined spaces, such as droplets, liquid–liquid interfaces, on the surface of substrates

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• -circuit model including the series resistances of electrolyte and FTO substrate (Rs) and the charge-transfer resistances on the CE/electrolyte and TiO2/dye/electrolyte interfaces (Rct1 and Rct2) associated with the corresponding constant phase elements (CPE1 and CPE2) as described in Figure 6 (Figure 6

Tunable superconducting neurons for networks based on radial basis functions

• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Igor I. Soloviev,
• Mikhail Yu. Kupriyanov,
• Maxim V. Tereshonok and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2022, 13, 444–454, doi:10.3762/bjnano.13.37

• the multilayer hybrid structures in the frame of Usadel equations [59]: with Kupriyanov–Lukichev boundary conditions [60], at the S/FM interfaces. Here G and F are normal and anomalous Green's functions, Δ is a pair potential (superconducting order parameter), ω = πkBT (2n + 1), where n is a natural

Micro- and nanotechnology in biomedical engineering for cartilage tissue regeneration in osteoarthritis

• Zahra Nabizadeh,
• Mahmoud Nasrollahzadeh,
• Hamed Daemi,
• Mohamadreza Baghaban Eslaminejad,
• Ali Akbar Shabani,
• Mehdi Dadashpour,
• Majid Mirmohammadkhani and
• Davood Nasrabadi

Beilstein J. Nanotechnol. 2022, 13, 363–389, doi:10.3762/bjnano.13.31

Investigation of a memory effect in a Au/(Ti–Cu)Ox-gradient thin film/TiAlV structure

• Damian Wojcieszak,
• Jarosław Domaradzki,
• Michał Mazur,
• Tomasz Kotwica and
• Danuta Kaczmarek

Beilstein J. Nanotechnol. 2022, 13, 265–273, doi:10.3762/bjnano.13.21

• and reaches 40% on average. Visible maxima and minima result from multiple interferences of the light reflected from interfaces between air and thin film and thin film and SiO2 substrate. From the optical spectra, an optical bandgap width of about 2.8 eV was determined for the allowed indirect

• (3.34 eV) for TiO2 were determined for a reference (about 100 nm thick) amorphous TiO2 layer, prepared in the magnetron sputtering process using the same deposition system with the coefficient pwmTi = 100% during the entire sputtering process. The analysis allowed us to conclude that both interfaces

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• friction with increasing immersion time reveals the interrelation of relevant physicochemical processes, namely the production of metal cations by surface dissolution at the interfaces of two layers, the diffusion of ions to the interface of outer layer and solution, the formation of hydrates at the

• vs Ag/AgCl are shown for comparison. (d) Schematic illustration of physicochemical processes at the interfaces of the surface oxide film related to the surface dissolution during corrosion. M+ represents dissolved metal cations, M(OH) denotes hydrates formed by reactions of metal cations with the

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• addressability, which is often a matter of appropriate interfaces and device design. Here, we compare two promising designs to build solid-state electronic devices utilizing the same functional unit. Optically addressable Ru-terpyridine complexes were incorporated in supramolecular wires or employed as ligands

Bacterial safety study of the production process of hemoglobin-based oxygen carriers

• Axel Steffen,
• Yu Xiong,
• Radostina Georgieva,
• Ulrich Kalus and
• Hans Bäumler

Beilstein J. Nanotechnol. 2022, 13, 114–126, doi:10.3762/bjnano.13.8

• Berlin, Berlin, Germany) for their support in the work with microorganisms and Dr. Dimitriya Borisova (Max-Planck Institute of Colloids and Interfaces, Golm, Germany) for SEM imaging. Funding We acknowledge the financial support from the European Community (EFRE-ProFIT 10139827, 10169193).

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• new insights into the underlying mechanism of heterojunction photocatalysts, especially those with Z-shaped interfaces [76]. Polyaniline (PANI) is a conducting polymer and compared to g-C3N4, PANI is inexpensive and easy to synthesize. Bui et al. [35] presented a SnO2/PANI nanocomposite for

Design aspects of Bi₂Sr₂CaCu₂O_8+δ THz sources: optimization of thermal and radiative properties

• Mikhail M. Krasnov,
• Natalia D. Novikova,
• Roger Cattaneo,
• Alexey A. Kalenyuk and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 1392–1403, doi:10.3762/bjnano.12.103

• from the brighter overall tone of the pattern in the middle panel. The EMW propagation is particularly well seen in the bottom hemisphere due to formation of a standing wave pattern in the substrate. It is induced by reflections at the substrate/vacuum interfaces caused by a significant difference in

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• environment are the strong decrease in oxygen ion mobility below 600 °C, mechanical stability and chemical stability against the used reactive gases, and local chemical reactions at the triple-phase boundaries (ceria|electron conductor|gas) as well as at the interfaces between the different components (ceria

• interfaces between CSO and FC2O have been shown to be mainly clean with only a slight segregation of Sm. Additionally, in some areas residues of a rock salt phase have been found. This phase is prone to develop during the synthesis process of CSO-FC2O depending on the sintering parameters. The formation can

• representing CSO, green: Co and thus representing FC2O). The arrow in (b) indicates a SmFeO3 grain. Interfaces between CSO and FC2O. (a) HAADF image of a CSO-FC2O interface, with CSO oriented along the [001] direction and FC2O randomly oriented. (b) EDX chemical mapping from the square-defined-region in (a

Enhancement of the piezoelectric coefficient in PVDF-TrFe/CoFe₂O₄ nanocomposites through DC magnetic poling

• Marco Fortunato,
• Alessio Tamburrano,
• Maria Paola Bracciale,
• Maria Laura Santarelli and
• Maria Sabrina Sarto

Beilstein J. Nanotechnol. 2021, 12, 1262–1270, doi:10.3762/bjnano.12.93

• with zinc oxide nanostructures [1][3][5][6]. Recently, it was shown that the β phase content of PVDF can be improved introducing CoFe2O4 nanoparticles into the polymer and applying a DC magnetic field [25]. This effect has been ascribed to the strong tensile stress at the CoFe2O4/PVDF interfaces

Electrical, electrochemical and structural studies of a chlorine-derived ionic liquid-based polymer gel electrolyte

• Ashish Gupta,
• Amrita Jain,
• Manju Kumari and
• Santosh K. Tripathi

Beilstein J. Nanotechnol. 2021, 12, 1252–1261, doi:10.3762/bjnano.12.92

• space charge polarization). As the frequency decreases, more and more charge accumulation occurs at the electrode and electrolyte interfaces, which leads to a decrease in the number of mobile ions and eventually to a drop in the conductivity at low-frequency values. In the high-frequency region, the

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• starts drying, evaporation of the solvent causes voids and helps in generating clusters of the solute on the substrate. For smaller pockets of the fluid, which can be regarded as droplets, variation in surface tension or temperature at different interfaces predominantly causes either a surface tension

• concentrations of ethanol. The SnO2 with NDs showed enhanced ethanol sensing in comparison to SnO2 NWs without NDs, which was attributed to a higher surface-to-volume ratio, more grain boundaries, and the presence of junction barriers at the ND–NW interfaces. The estimated D for the SnO2 nanodendrites was 1.88

Open-loop amplitude-modulation Kelvin probe force microscopy operated in single-pass PeakForce tapping mode

• Gheorghe Stan and
• Pradeep Namboodiri

Beilstein J. Nanotechnol. 2021, 12, 1115–1126, doi:10.3762/bjnano.12.83

• calibration for the gain of the cantilever’s transfer function. DH-KPFM has found applications on sensitive materials and solid–liquid interfaces where conventional CL KPFM does not perform very well [43]. CPD measurements in an OL operation have also been demonstrated in more inclusive scanning probe modes

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

• [60]. Ultrasound is generally produced by the passage of electric current through a piezoelectric crystal [61]. The interaction of acoustic waves with the interfaces that exist between different tissues causes an alteration in the energy of the US. When these waves encounter tissues with different

• acoustic waves, reflection from inclusions, walls or other interfaces, and spatial variations in the propagation velocity [101]. The biomedical significance of the ARF effect was first demonstrated in 1971 by Pond, Woodward, and Dyson, who discovered that red blood cells in the blood vessels in vivo could

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• also lead to a nanofabrication outcome. For example, localized swelling by ion implantation can be used to pattern nanoscale surface topographies, ion-induced collisional mixing can restructure buried interfaces, and ion-induced chemical changes can be used for resist-based lithography. In the

• implantation phenomena (such as the formation of helium nanobubbles and blisters), as well as the opportunity to leverage these phenomena for practical applications. Using the HIM, individual grains/interfaces/regions of interest can be irradiated with a known dose of ions for systematic studies on the

• ], tungsten [83][84][85], an Fe–Zr alloy [86], a Y2O3/Fe bilayer [87], and nanocluster films of magnetite and core–shell iron–magnetite nanoparticles [88]. In these studies, various implantation effects have been investigated, including the tendency for grain boundaries and interfaces to act as sinks for

Nanoporous and nonporous conjugated donor–acceptor polymer semiconductors for photocatalytic hydrogen production

• Zhao-Qi Sheng,
• Yu-Qin Xing,
• Yan Chen,
• Guang Zhang,
• Shi-Yong Liu and
• Long Chen

Beilstein J. Nanotechnol. 2021, 12, 607–623, doi:10.3762/bjnano.12.50

• endowed a high AQT of 33.5% at 450 nm. Inspire by the architectures of organic solar cells, Cooper et al. selected a ITIC-based polymer as acceptor and a BT–carbazole-based one as donor to form polymer/polymer heterojunctions [95]. Due to the formation of abundant donor–acceptor interfaces, P78/P79