Stimuli-responsive polypeptide nanogels for trypsin inhibition

• Petr Šálek,
• Jana Dvořáková,
• Sviatoslav Hladysh,
• Diana Oleshchuk,
• Ewa Pavlova,
• Jan Kučka and
• Vladimír Proks

Beilstein J. Nanotechnol. 2022, 13, 538–548, doi:10.3762/bjnano.13.45

• confirmed by dynamic light scattering and zeta potential measurements. The loading capacity of PHEG-Tyr and Nα-Lys-NG nanogels and their release profiles were first optimized with bovine serum albumin. The nanogels were then used for loading and release of AAT. PHEG-Tyr and Nα-Lys-NG nanogels showed

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• , Romania RDI Laboratory of Applied Raman Spectroscopy, RDI Institute of Applied Natural Sciences (IRDI-ANS), Babeş-Bolyai University, Fântânele 42, 400293, Cluj-Napoca, Romania 10.3762/bjnano.13.40 Abstract Since the initial discovery of surface-enhanced Raman scattering (SERS) and surface-enhanced

• , enhanced Raman scattering for periodic ZnO-elevated Au dimer nanostructures [12] and enhanced fluorescence emission signals from Al-doped ZnO films [13] were obtained. The development of hybrid nanocomposites based on ZnO and noble metals for fluorescence and Raman signal enhancement has recently attracted

• great interest and will be the focus of this review. The electromagnetic (EM) enhancement in surface-enhanced Raman scattering (SERS) appears due to the enhanced local electric field that is generated when localized surface plasmon resonances (LSPRs) are excited by light incident on noble metal

Tunable superconducting neurons for networks based on radial basis functions

• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Igor I. Soloviev,
• Mikhail Yu. Kupriyanov,
• Maxim V. Tereshonok and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2022, 13, 444–454, doi:10.3762/bjnano.13.37

• components of the input vector x are fed. Every neuron of the hidden layer calculates the values of the 1D function hk(x). where xk is the k-th reference point and σk is the scattering parameter for the one-dimensional function . In this paper, we propose a modified tunable neuron circuit [44] for RBFNs (see

Alcohol-perturbed self-assembly of the tobacco mosaic virus coat protein

• Ismael Abu-Baker and
• Amy Szuchmacher Blum

Beilstein J. Nanotechnol. 2022, 13, 355–362, doi:10.3762/bjnano.13.30

• TMV A-protein to larger species, likely bilayer disks, as determined by analytical centrifugation and light scattering [32]. They attributed this behaviour to the salting-out effect of glycine and its derivatives. Only the transition from A-protein to disk was investigated, so it is unclear what

• TEM and dynamic light scattering (DLS). The TMV-cp samples in this work are polydisperse and non-spherical, which complicates the interpretation of DLS data. Because DLS is a light scattering technique, the signal intensity is proportional to the sixth power of the radius [39]. This means that the

Controllable two- and three-state magnetization switching in single-layer epitaxial Pd_1−xFe_x films and an epitaxial Pd_0.92Fe_0.08/Ag/Pd_0.96Fe_0.04 heterostructure

• Igor V. Yanilkin,
• Amir I. Gumarov,
• Gulnaz F. Gizzatullina,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2022, 13, 334–343, doi:10.3762/bjnano.13.28

• associated with the mutual orientations of the magnetic moment and the direction of the current, there is a resistance drop with an increase of the magnetic field strength, that is, the negative magnetoresistance. The latter effect is related to a decrease in electron-magnon scattering due to the suppression

• are the resistivities for the cases of the magnetic moment oriented along the X-, Y-, and Z-axes, respectively. The contribution from the electron–magnon scattering is subtracted for each of ρx, ρy, and ρz. Angles θM and φM are referenced relative to the [001] and [100] axes, respectively. For a

• slope with temperature. Lines are drawn using the model of Equation 1. (b) Dependence of the resistance on the orientation of the magnetic field at T = 5 K. The contribution from the electron–magnon scattering is subtracted. Lines are drawn using the model of Equation 2. Dependences of the resistivity

Coordination-assembled myricetin nanoarchitectonics for sustainably scavenging free radicals

• Xiaoyan Ma,
• Haoning Gong,
• Kenji Ogino,
• Xuehai Yan and
• Ruirui Xing

Beilstein J. Nanotechnol. 2022, 13, 284–291, doi:10.3762/bjnano.13.23

• dynamic light scattering were used to record absorption spectra and size change. Cytotoxicity experiment in vitro The cytotoxicity of the as-prepared MZG nanoparticles was assessed against 3T3 cells. 3T3 cells were cultivated with Dulbecco's Modified Eagle Medium (DMEM) containing 10% (v/v) fetal bovine

• shows spherical MZG nanoparticles. Size and zeta potential value of the MZG nanoparticles were 44.6 ± 26.5 nm and −23.1 ± 3.4 mV, respectively, measured by dynamic light scattering (DLS) (Figure 2b) and consistent with the TEM results. Importantly, the co-assembly mechanism was further revealed through

Systematic studies into uniform synthetic protein nanoparticles

• Nahal Habibi,
• Ava Mauser,
• Jeffery E. Raymond and
• Joerg Lahann

Beilstein J. Nanotechnol. 2022, 13, 274–283, doi:10.3762/bjnano.13.22

• thorough shape analysis into the assessment of emerging platforms from the very onset of their expansion into the general nano-bio research. The solution-based corollary to dry-state imaging that can provide the above parameters is dynamic light scattering (DLS). DLS uses the deconvolution of a correlation

• function for the scattering intensity to deduce a size distribution spectrum based on signal intensity (or a calculated size distribution based on volume or number of particles). While SEM analysis can provide key insights into the “as manufactured” state, DLS provides insights into the in situ state of

• process. Dynamic light scattering DLS measurements were performed on particles in their hydrated state using a Zetasizer Nano ZS (Malvern Panalytical). The solution in which the particles were suspended was DPBS. DLS was employed to measure the particle size distribution after particle collection and

Photothermal ablation of murine melanomas by Fe₃O₄ nanoparticle clusters

• Xue Wang,
• Lili Xuan and
• Ying Pan

Beilstein J. Nanotechnol. 2022, 13, 255–264, doi:10.3762/bjnano.13.20

• 59.4 emu/g (Figure 1c) and stronger absorption intensities at the NIR wavelength of 808 nm than individual nanoparticles [17]. In addition, the dynamic light scattering (DLS) analysis of NPCs suspended in aqueous culture medium reflected good dispersion (Figure 1d). The colloidal stability of our

• morphology of the as-synthesized nanoparticle clusters was characterized with a JEOL JEM-2100 transmission electron microscopy (TEM). Dynamic light scattering (DLS) The synthesized Fe3O4 NPCs were diluted in RPMI 1640 medium to a final concentration of 0.25 mg/mL. The particle size distribution was

• determined by DLS on a Malvern Nanosizer Zen 3600 instrument (Worcestershire, United Kingdom) equipped with a 633 nm laser using backscatter technology. The temperature was maintained at 25 °C, and the scattering angle was 173° from the incident laser beam. The mean particle diameter was calculated from the

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• surface in phosphate buffer, even after immersion for 72 h. This is not the case for the NaCl solution (Figure 4d), where a significant scattering of friction values is observed, especially after a longer immersion. The general trend is still towards higher friction forces of the outer layer for the

Surfactant-free syntheses and pair distribution function analysis of osmium nanoparticles

• Mikkel Juelsholt,
• Jonathan Quinson,
• Emil T. S. Kjær,
• Baiyu Wang,
• Rebecca Pittkowski,
• Susan R. Cooper,
• Tiffany L. Kinnibrugh,
• Søren B. Simonsen,
• Luise Theil Kuhn,
• María Escudero-Escribano and
• Kirsten M. Ø. Jensen

Beilstein J. Nanotechnol. 2022, 13, 230–235, doi:10.3762/bjnano.13.17

• opposed to the case of Pt or Ir NPs. The robustness of the synthesis for a precursor concentration up to 100 mM allows for the performance of X-ray total scattering with pair distribution function (PDF) analysis, which shows that 1–2 nm hexagonal close packed (hcp) NPs are formed from chain-like [OsOxCly

• using small angle X-ray scattering (SAXS) analysis as presented in Figure S22 and Table S2, Supporting Information File 1. However, our experiment showed that either methanol or ethanol is needed for the reaction to proceed playing the role of reducing agents, as no product is formed when the synthesis

• turned to X-ray total scattering and pair distribution function (PDF) analyses to investigate the atomic structure of the Os NPs [33]. The pair distribution function is now widely used for nanomaterial characterization, as it allows to obtain atomic structure information from materials showing no long

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• high-energy electrons, leaving a pure metal deposit on the surface, while the dissociated, volatile ligands are pumped away [3][4][5][6][7]. However, when high-energy electrons impinge on a substrate surface, these are subject to elastic and inelastic scattering and a significant number of secondary

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• experimental challenge toward elucidating the dynamic processes in oxidation. For example, the formation processes of iron oxide nanoparticles have been studied in detail using state-of-the-art X-ray scattering methods [4]. As a complementary method, variable-temperature scanning tunneling microscopy (VT-STM

A photonic crystal material for the online detection of nonpolar hydrocarbon vapors

• Evgenii S. Bolshakov,
• Aleksander V. Ivanov,
• Andrei A. Kozlov,
• Anton S. Aksenov,
• Elena V. Isanbaeva,
• Sergei E. Kushnir,
• Aleksei D. Yapryntsev,
• Aleksander E. Baranchikov and
• Yury A. Zolotov

Beilstein J. Nanotechnol. 2022, 13, 127–136, doi:10.3762/bjnano.13.9

• . Black lines show the linear correspondence of the experimental data. (a) Photo of the sensor and (b) electron microscopy image of a CCA of polystyrene particles without a PDMS layer on a glass substrate (effective particle size = 201 nm). The data obtained with dynamic light scattering slightly

• overestimates the diameter in comparison with the data obtained from microphotographs. This may be related to the specificity of the dynamic light scattering (DLS) method (hydrodynamic diameter measurement). A mechanism of detecting hydrocarbons with a sensor based on a 3D PhC: (a, b) swelling of colloidal

Bacterial safety study of the production process of hemoglobin-based oxygen carriers

• Axel Steffen,
• Yu Xiong,
• Radostina Georgieva,
• Ulrich Kalus and
• Hans Bäumler

Beilstein J. Nanotechnol. 2022, 13, 114–126, doi:10.3762/bjnano.13.8

• CCD method produces nearly uniform, peanut-shaped particles. The size distribution determined by dynamic light scattering (DLS) was 759 ± 25 nm. Confocal laser scanning microscopy (CLSM) images confirmed this size range (Figure 1C). Scanning electron microscopy (SEM) images of particles produced with

Theranostic potential of self-luminescent branched polyethyleneimine-coated superparamagnetic iron oxide nanoparticles

• Rouhollah Khodadust,
• Ozlem Unal and
• Havva Yagci Acar

Beilstein J. Nanotechnol. 2022, 13, 82–95, doi:10.3762/bjnano.13.6

• particles used for pGFP transfection. Supporting Information Supporting Information File 72: Supporting Information contains dynamic light scattering (DLS), photoluminescence spectra, and zeta potential analysis of SPION@bPEI, SPION@bPEI/pDNA, SPION@bPEI-Erb, SPION @bPEI-Erb/pDNA, and SPION@bPEI-Erb/pDNA

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• as gas-phase scattering is minimized. The film deposition rate, lying typically in the range of several nanometers per minute, is therefore higher compared to non-magnetized sputtering discharges. Here a remark should be made: While the film growth rate is usually expressed in units of thickness per

• scattering efficiency for the various sputtered atoms transported in the gas phase and different sputter yields, ultimately leading to the abovementioned composition discrepancies between the source and the deposited material. The interested reader might refer to articles that exemplify this discussion such

Biocompatibility and cytotoxicity in vitro of surface-functionalized drug-loaded spinel ferrite nanoparticles

• Sadaf Mushtaq,
• Khuram Shahzad,
• Tariq Saeed,
• Anwar Ul-Hamid,
• Bilal Haider Abbasi,
• Nafees Ahmad,
• Waqas Khalid,
• Muhammad Atif,
• Zulqurnain Ali and
• Rashda Abbasi

Beilstein J. Nanotechnol. 2021, 12, 1339–1364, doi:10.3762/bjnano.12.99

• electrophoresis. All samples moved towards the positive potential due to the negatively charged PMA coating (Figure 2d). The colloidal stability (i.e., hydrodynamic size, surface charge, and polydispersity index, PDI) of NPs was assessed using dynamic light scattering (DLS). All NPs (PMA-coated, and drug-attached

Impact of electron–phonon coupling on electron transport through T-shaped arrangements of quantum dots in the Kondo regime

• Patryk Florków and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2021, 12, 1209–1225, doi:10.3762/bjnano.12.89

• introduced potential scattering correlated to dot occupancy . This perturbation stabilizes symmetry-broken CO state (d1 ≈ 1, d2 ≈ 0 or d2 ≈ 1, d1 ≈ 0). Hereafter this approach is called by us SB1 and is used by us only in n = 2 region. Now let us look at the conductance for q = 0, but starting from dot

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

pH-driven enhancement of anti-tubercular drug loading on iron oxide nanoparticles for drug delivery in macrophages

• Karishma Berta Cotta,
• Sarika Mehra and
• Rajdip Bandyopadhyaya

Beilstein J. Nanotechnol. 2021, 12, 1127–1139, doi:10.3762/bjnano.12.84

• Cell, USA). NOR@IONP synthesis, at each of the respective pH, were performed with 3 distinct replicates. Nanoparticle characterization The hydrodynamic diameter of nanoparticles was determined after re-dispersing in milli-Q water and loading the sample in a cuvette for dynamic light scattering (DLS

• nanoparticles. (a) Dynamic light scattering plot of number (%) v/s size (nm) of the nanoparticles in solution at the end of synthesis (n = 3). (b) Transmission electron microscopy image with a 50 nm scale bar. (c) X-ray diffraction plot indicating the Bragg’s 2θ diffraction angles identical to peaks observed

• for crystalline iron oxide. (d) FTIR spectrum of transmittance v/s wavenumber, depicting major functional groups of iron oxide and NOR. Characterization of NOR@IONPpH10 nanoparticles. (a) Dynamic light scattering plot of number (%) v/s size (nm) of the nanoparticles in solution at the completion of

Open-loop amplitude-modulation Kelvin probe force microscopy operated in single-pass PeakForce tapping mode

• Gheorghe Stan and
• Pradeep Namboodiri

Beilstein J. Nanotechnol. 2021, 12, 1115–1126, doi:10.3762/bjnano.12.83

• 0.229 V, which give an average value of 0.227 ± 0.037 V for the CPD at that location on Au. In general, the scattering of the CPD determined from the five parabolic fits of each bias train, either on Al or Au, was within 0.050 V; here and in the rest of the text, the uncertainties represent one standard

First-principles study of the structural, optoelectronic and thermophysical properties of the π-SnSe for thermoelectric applications

• Muhammad Atif Sattar,
• Najwa Al Bouzieh,
• Maamar Benkraouda and
• Noureddine Amrane

Beilstein J. Nanotechnol. 2021, 12, 1101–1114, doi:10.3762/bjnano.12.82

• large entropy impact which accelerates the phonon–phonon scattering process. The total thermal conductivity (κtot) for the π-SnSe alloy is also plotted and presented in Figure 9c. It can be noted that initially, by the increase in temperature, κtot decreases and reaches its minimum value of 1.089 W·m−1

• from the dielectric function by using the following expressions [72]: The real part ε1(ω) of the dielectric tensor describes the polarization and the induced scattering of the incident light photons, while ε2(ω) refers to the magnitude of absorption of the incident radiations. The real part ε1(ω) of

• [79]. No dispersion or scattering is observed in L(ω) as the curve is linear between 0 and 1.4 eV. The real optical conductivity σ(ω) is a valuable tool to evaluate the concentration of electrons that participate in optical transitions. The optical conductivity plot for the π-SnSe alloy is presented

Criteria ruling particle agglomeration

• Dieter Vollath

Beilstein J. Nanotechnol. 2021, 12, 1093–1100, doi:10.3762/bjnano.12.81

• double logarithmic scale using decimal logarithms. These data are replotted in Figure 5b, similar to Figure 2. One recognizes a perfect straight line; the parameter b determined from this plot is 0.6929. This value coincides, within the scattering ranges caused by fluctuations, exactly with the values in

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• from the device with AgNP increased by 30% compared to the device without AgNP. Choi et al. have used a scattering layer of AgNP in order to study the SPR effect, which increased the EQE by 24% in the flexible OLED [49]. Au and AgNP have also been embedded at the interface of the anode and the HTL in

Revealing the formation mechanism and band gap tuning of Sb₂S₃ nanoparticles

• Maximilian Joschko,
• Franck Yvan Fotue Wafo,
• Christina Malsi,
• Danilo Kisić,
• Ivana Validžić and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 1021–1033, doi:10.3762/bjnano.12.76

• scattering coefficient s, which, in turn, is correlated to the reflectance of an infinitely thick specimen R∞ [39]: In the literature, there are different opinions regarding the type of electron transition of Sb2S3. Some authors assumed a direct transition for the amorphous and the crystalline material [30