Superstructures with cyclodextrins: Chemistry and applications III
Cyclodextrins (CDs) are of increasing scientific and commercial interest because they are readily available, harmless and well-defined, forming sophisticated supramolecular structures in aqueous media. More than 2,300 publications and more than 1,200 patents appeared in 2015 in which CDs played a significant role. CD chemistry has developed into a very attractive field of research. This series follows "Superstructures with cyclodextrins: Chemistry and applications II" and "Superstructures with cyclodextrins: Chemistry and applications".
- Full Research Paper
- Published 02 Sep 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: Tritylates of α-CD examined in the present study and the reaction pathway. Letters A to F represent...
-
![]()
Figure 1: UFLC chromatogram of three regioismers of di-6-O-trityl-α-CD with 50% aqueous acetonitrile as an el...
-
![]()
Figure 2: UFLC chromatogram of four regioisomers of tri-6-O-trityl-α-CD with an eluent of acetonitrile/methan...
-
![]()
Figure 3: A part of 13C NMR spectra of di-6-O-trityl-α-CD in DMSO-d6 at 50 °C a) AD-isomer, b) AC-isomer, and...
-
![]()
Scheme 2: A pathway of the conversion of a regioisomer of tri-6-O-trityl-α-CD (ABE isomer) to the correspondi...
-
![]()
Figure 4: A part of 13C NMR spectra of tri-6-O-trityl-α-CD in DMSO-d6 at 50 °C. a) ABE-isomer, b) ABD-isomer,...
-
![]()
Figure 5: Time-course of the formation of mono- (left ordinate) and di-6-O-tritylates (right ordinate) of α-C...
-
![]()
Figure 6: Time-course of the formation of the regioisomers of di-6-O-trityl-α-CD in a reaction of α-CD(Tr)1 w...
-
![]()
Figure 7: Time-course of the formation of the regioisomers of tri-6-O-trityl-α-CD in a reaction of AD-isomer ...
-
![]()
Figure 8: Time-course of the formation of the regioisomers of tri-6-O-trityl-α-CD in a reaction of AC-isomer ...
-
![]()
Figure 9: Time-course of the formation of the regioisomers of tri-6-O-trityl-α-CD in a reaction of the AB-iso...
-
![]()
Figure 10: 1H NMR spectra of α-CD (a) and the A,D-isomer (b) in DMSO-d6 at 50 °C.
-
![]()
Figure 11: A part of 2D ROESY spectrum of the A,D-isomer in DMSO-d6 at 50 °C.
-
-
Supp. Info
- Full Research Paper
- Published 03 Nov 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Preparation scheme of Lac-β-CyD.
-
![]()
Figure 2: MALDI–TOF MS (A) and 1H NMR (B) spectra of Lac-β-CyD.
-
![]()
Figure 3: Cytotoxic activity of β-CyDs in U18666A-treated HepG2 cells after treatment for 24 h. U18666A-treat...
-
![]()
Figure 4: Cellular association of TRITC-Lac-β-CyD in U18666A-treated HepG2 cells after treatment for 24 h. Th...
-
![]()
Figure 5: Intracellular distribution of TRITC-Lac-β-CyD in U18666A-treated HepG2 cells. U18666A-treated HepG2...
-
![]()
Figure 6: Effect of concentration of Lac-β-CyD on intracellular level of free form of cholesterol in U18666A-...
-
- Full Research Paper
- Published 16 Nov 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Nanocomposite polyrotaxane network formed by covalent bonds between cyclic components of polyrotaxa...
-
![]()
Scheme 1: Synthesis of polyrotaxane with partially triethoxysilylated α-CDs (TES-PR) and crosslinking of the ...
-
![]()
Figure 2: 1H NMR spectra (400 MHz, DMSO-d6, 343 K) of polyrotaxane and its derivatives with modified cyclic c...
-
![]()
Figure 3: GPR traces of polyrotaxane and its derivatives; eluent: DMSO/LiBr (10 mM LiBr), detection: RI.
-
![]()
Figure 4: Photograph of silica nanocomposite polyrotaxane gel.
-
![]()
Figure 5: SAXS profiles of (a) silica nanocomposite polyrotaxane gels and (b) silica solutions with different...
-
![]()
Figure 6: (a) Relaxation Young’s modulus with 5% strain and (b) frequency-dependence of dynamic storage and l...
-
![]()
Figure 7: Repeated stress-strain curves for a silica nanocomposite polyrotaxane gel with 20% silica content.
-
- Full Research Paper
- Published 23 Nov 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: Schematic description of self-assembly of γ-CDs with PMA-PPO-PEO-PPO-PMA and one-pot endcapping via...
-
![]()
Scheme 2: Synthetic pathway of PMA-PPO-PEO-PPO-PMA.
-
![]()
Figure 1: Photographs of the formation of a PEP100M15CD hydrogel.
-
![]()
Figure 2: WXRD patterns of γ-CD (A), PEP15CD (B), PEP100M (C), PEP100M10CD (D), PEP100M15CD (E), PEP100M30CD ...
-
![]()
Figure 3: 1H NMR spectra of PR30CD80P in DMF-d7/D2O (A) and DMSO-d6/D2O (B).
-
![]()
Figure 4: GPC curves of γ-CD (A), PR0CD30P (B), PR30CD30P (C), PR30CD50P (D) and PR30CD80P (E).
-
![]()
Figure 5: 13C CP/MAS NMR spectra of PEP100M15CD (A) and γ-CD (B).
-
![]()
Figure 6: 2D NOESY NMR spectrum of PR30CD80P in DMSO-d6/D2O.
-
![]()
Figure 7: FTIR spectra of PEP100M (A), PEP100M15CD (B), PR0CD30P (C), PR30CD80P (D) and γ-CD (E).
-
![]()
Figure 8: TGA curves of PEP100M (A), γ-CD (B), PEP15CD (C), PEP100M10CD (D), PEP100M15CD (E) and PEP100M30CD ...
-
![]()
Figure 9: BrPEPBr (A), PEP15CD (B), PEP100M (C), PEP100M15CD (D), PR0CD30P (E), PR30CD50P (F), PR30CD80P (G) ...
-
-
Supp. Info
- Full Research Paper
- Published 25 Nov 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Schematic views of a) β-CD and b) α-mangostin (α-MGS) geometries.
-
![]()
Figure 2: Solubility of α-mangostin as a function of ethanol concentration for different β-CD concentrations.
-
![]()
Figure 3: Solubility of α-mangostin as a function of β-CD for different ethanol concentrations.
-
![]()
Figure 4: RMSD plots of β-CD (grey) and α-MGS (black) for the five systems with different ethanol percentages....
-
![]()
Figure 5: Displacement of the A–C rings of α-MGS with respect to the β-CD center of gravity for five systems ...
-
![]()
Figure 6: Radial distribution functions (RDF) of (a–d) ethanol, and (e–h) water molecules around the oxygen a...
-
![]()
Figure 7: Snapshots of solvation around heteroatoms of α-MGS/β-CD for systems containing 5% and 60% v/v ethan...
-
-
Supp. Info
- Full Research Paper
- Published 30 Nov 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: (A) Chemical structure and (B) schematic illustration of DM-β-CD/PDI polymer.
-
![]()
Figure 2: 1H NMR spectra of (A) DM-β-CD/PDI polymer and (B) DM-β-CD in (CD3)2SO.
-
![]()
Figure 3: (A) Number-averaged particle size distributions of DM-β-CD/PDI nanogels measured by DLS at concentr...
-
![]()
Figure 4: (A,B) Digital photograhs of (1) the initial DM-β-CD/PDI nanogel (0.1 wt %) with (A) n-dodecane or (...
-
![]()
Figure 5: (A,B) Phase volume fractions and (C,D) droplet diameters of n-dodecane-(A) or toluene- (B) in-water...
-
![]()
Figure 6: (A) Optical and (B) fluorescence micrographs of the n-dodecane-in-water emulsion stabilized by the ...
-
![]()
Figure 7: Laser microscope images of the toluene-in-water droplets stabilized by the DM-β-CD/PDI nanogel afte...
-
![]()
Figure 8: SEM images of the toluene-in-water droplets stabilized by the DM-β-CD/PDI nanogel after evaporation...
-
-
Supp. Info
- Full Research Paper
- Published 01 Dec 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Microcalorimetric titrations of a) CD-PEI (CD concentration of 0.088 mM, cell) with Ad-TEG (1.1 mM,...
-
![]()
Figure 2: ITC titration of Fc-PEG (1.03 mM; cell) with native CD (10 mM; burette). H = host and G = guest. Ex...
-
![]()
Scheme 1: a) Schematic representation of the supramolecular nanoparticle (SNP) self-assembly and redox-trigge...
-
![]()
Figure 3: Size determination of SNPs prepared from CD-PEI and Fc8-PAMAM: SEM images (a–c) of the resulting SN...
-
![]()
Figure 4: DLS size determination of SNPs prepared from CD-PEI and Fc8-PAMAM by increasing the [Fc]/[CD] ratio...
-
![]()
Figure 5: Hydrodynamic diameter, d, of SNPs prepared from CD-PEI and Fc8-PAMAM or Ad8-PAMAM measured by DLS a...
-
![]()
Figure 6: DLS size determinations of SNPs prepared from CD-PEI, Fc8-PAMAM, in the absence or presence of a mo...
-
![]()
Figure 7: Size determinations of SNPs prepared from CD-PEI, Fc8-PAMAM and Ad-PEG: SEM images (a–c) of the res...
-
![]()
Figure 8: DLS size determination before (red) and after the addition of the oxidant agent Ce4+ (green) for as...
-
- Full Research Paper
- Published 07 Dec 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: Structure of an aCD functionalized with hydrophobic thioalkyl C2 (R = C2H5) or C6 (R = C6H13) chain...
-
![]()
Figure 1: The final optimized geometry of the aCD molecule in vacuo (panel a) and in explicit water (panel b)...
-
![]()
Figure 2: Some relevant PDF’s calculated along the runs for the isolated aCD. a) The PDF of the glycosidic ox...
-
![]()
Figure 3: The distance between the oxygen atoms of two water molecules and the c.o.m. of the aCD plotted as a...
-
![]()
Figure 4: The PDF of the oxygen and of the hydrogen atoms of the water molecules (in red and in blue, respect...
-
![]()
Figure 5: The pairwise initial arrangements of two amphiphilic molecules that face the two hydrophobic H grou...
-
![]()
Figure 6: Final optimized geometries at equilibrium after the 30 ns MD runs obtained both in vacuo and in wat...
-
![]()
Figure 7: The starting arrangements (a–c) of the four α-CD molecules (top row) and the final arrangement afte...
-
![]()
Figure 8: The optimized geometry achieved by four aCD molecules in water by four molecules after the MD run. ...
-
![]()
Figure 9: a) The initial random arrangement of eight molecules of the model aCD in a space-filling representa...
-
![]()
Figure 10: The two aggregates obtained in water, each comprising three molecules of the model aCD, cluster A (...
-
![]()
Figure 11: The PDF of the S atoms of the H groups at the primary rim (black symbols) and of the oxygen atoms o...
-
![]()
Figure 12: The time change of the potential energy and of the van der Waals energy due to the dispersion and c...
-
![]()
Figure 13: a) The PDF of the eight molecules of the model aCD in water as a function of their distance r from ...
-
-
Supp. Info
- Full Research Paper
- Published 16 Dec 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Chemical structures of 2-methoxyestradiol (top) and the derivatised CDs DIMEB and TRIMEB (bottom).
-
![]()
Figure 2: The mode of inclusion of 2ME in the DIMEB cavity (a), space-filling side view of the complex with t...
-
![]()
Figure 3: Stereoview of the asymmetric unit in the crystal of the inclusion complex TRIMEB•2ME, with the host...
-
![]()
Figure 4: Space-filling images of complex unit A (as representative of units A and B) (a) and complex unit C ...
-
![]()
Figure 5: Inclination of the mean plane of the included 2ME molecule relative to the O4-heptagon of the host ...
-
![]()
Figure 6: Overlay of the steroid nucleus of 2ME (blue) in its own crystal with the refined models (grey) of t...
-
![]()
Figure 7: The TRIMEB·2ME complex unit D with two distinct (guest)O19-H···O(host) hydrogen bonds highlighted. ...
-
![]()
Figure 8: Dissolution profiles in water at 37 °C for untreated 2ME and various β-CD-containing preparations o...
-
-
Supp. Info
- Full Research Paper
- Published 21 Dec 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: Synthetic route of 3·TM-βCD and 3·TM-γCD polyrotaxanes, and the non-rotaxane counterpart 3.
-
![]()
Figure 1: 1H NMR spectrum of the polyrotaxane 3·TM-βCD copolymer in CDCl3.
-
![]()
Figure 2: DSC traces on second heating scan of 3, 3·TM-βCD and 3·TM-γCD compounds.
-
![]()
Figure 3: Optical properties of 3·TM-γCD (dotted line), 3·TM-βCD (dashed line) and 3 (solid line) polymers: a...
-
![]()
Figure 4: CV of 3 (a), 3·TM-βCD (b) and 3·TM-γCD (c) in 0.1 M tetrabutylammonium perchlorate (TBAClO4)/ACN so...
-
![]()
Figure 5: Representative AFM images obtained over 3 × 3 µm2 areas of the non-rotaxane 3 (a), 3·TM-βCD (b) and ...
-
-
Supp. Info
- Full Research Paper
- Published 29 Dec 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Structures of (A) hesperetin, (B) naringenin and (C) the two cyclodextrins: β-CD and DM-β-CD with t...
-
![]()
Figure 2: Phase solubility study of hesperetin (upper panel) and naringenin (lower panel) with β-CD or RAMEB ...
-
![]()
Figure 3: DSC thermograms of hesperetin (left) and naringenin (right) (A) β-CD, (B) RAMEB, (C) Free flavanone...
-
![]()
Figure 4: The dissolution diagram at 37 °C in water of the free flavanones and their complexes. (A) hespereti...
-
![]()
Figure 5: The influence of flavanones and their complexes on IL-6 secretion from LPS-stimulated macrophages.
-
![]()
Figure 6: Cytotoxicity of free flavanones and their inclusion complexes on different cancer cell lines.
-
![]()
Figure 7: The docked orientations of hesperetin in the hydrophobic cavity of (A) β-CD and (B) DM-β-CD and top...
-
-
Supp. Info
- Full Research Paper
- Published 30 Dec 2015
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: Schematic representation of molecular imprinting technique. i) Polymerization process with toluene-...
-
![]()
Figure 1: FTIR spectra of (A): native CRYSMEB, (B): D3 (toluene/CD 3:1), (C): D2 (toluene/CD 4:1), and (D): D...
-
![]()
Figure 2: Top: XRPD pattern for CRYSMEB. Bottom: XRPD pattern for D1 polymer. The diffraction peaks denoted w...
-
![]()
Figure 3: 13C {1H} CP-MAS spectra of polymers D1, D2 and D3. Peak assignment is given in the upper trace.
-
![]()
Figure 4: 13C {1H} CP-MAS spectra of native CRYSMEB and polymer D3. Peak assignment is given on CRYSMEB spect...
-
![]()
Figure 5: 1D 13C CP/MAS spectra of polymer D3 as a function of the contact time varying from 35 μs to 4 ms.
-
![]()
Figure 6: Cross-polymerization (CP) build-up curve of the 13C resonances with variable contact times for the ...
-
![]()
Figure 7: Cross-polymerization (CP) build-up curve of the 13C resonances with variable contact time for polym...
-
![]()
Figure 8: CP build-up curves of the 13C resonances with cross-polymerization in the range 0–100 μs for polyme...
-
- Full Research Paper
- Published 08 Jan 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Chemical structures, logP values and molecular volumes (V) of carvacrol (1) and thymol (2). ahttp:/...
-
![]()
Figure 2: Phase solubility profiles of (a) CD/carvacrol (1) and (b) CD/thymol (2) inclusion complexes. Inset:...
-
![]()
Figure 3: 2D DOSY NMR spectra of (a) β-CD, carvacrol (1) and β-CD/carvacrol (1) inclusion complex and (b) β-C...
-
![]()
Figure 4: Representation of chemical shifts variations (Δδ) of a) carvacrol (1) and c) thymol (2) protons and...
-
![]()
Figure 5: 2D ROESY plots of β-CD/carvacrol (1) complex in D2O showing the NOEs between the H-3 and H-5 proton...
-
![]()
Figure 6: 2D ROESY plots of β-CD/thymol (2) complex in D2O showing the NOEs between the H-3 and H-5 protons o...
-
![]()
Figure 7: Representation of the most stable CD/guest inclusion complex conformers.
-
![]()
Figure 8: Effects of β-CD and HP-β-CD on the TEAC (μmol Trolox/ g of guest) of carvacrol (1) and thymol (2) b...
-
- Review
- Published 12 Jan 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Structures of α-, β- and γ-CD. Individual carbon atom numbering is shown for one D-glucopyranose su...
-
![]()
Figure 2: Associations of hydrophobic substituents (circled) (a) and their disruption through host–guest comp...
-
![]()
Figure 3: Decrease of aqueous solution viscosity at a shear rate of 50 s−1 due to α-CD (circles), β-CD (recta...
-
![]()
Figure 4: The effect of (a) α-CD, (b) β-CD and (c) γ-CD on the hydrophobic interactions between n-C18H37 subs...
-
![]()
Figure 5: The effect of SDS addition on viscosity shear rate dependence for 2 wt % aqueous PAAodn solutions c...
-
![]()
Figure 6: Host–guest complexation between polymers with cyclodextrin and hydrophobic substituents.
-
![]()
Figure 7: Variation of viscosity with mole ratio of CD substituents to hydrophobic substituents on poly(acryl...
-
![]()
Figure 8: Illustration of the competitive intermolecular host–guest complexation of either the adamantyl subs...
-
![]()
Figure 9: Competitive host–guest complexations in which either the adamantyl substituent (red) or the n-hexyl...
-
![]()
Figure 10: (a) Substituted chitosan in which acyl- and adamantyl-substitution is 5% and 12 %, respectively. (b...
-
![]()
Figure 11: The formation of a AD-PEG micelle followed by the formation of a AD-PEG/α-CD supramolecular hydroge...
-
![]()
Figure 12: Interaction of PEG-b-PAA block copolymer with cis-diamminedichloroplatinum(II), cisplatin, to form ...
-
![]()
Figure 13: Solution to hydrogel transitions (a)–(d) for a PAAddn segment in the presence of competitive photo-...
-
![]()
Figure 14: Structures of the poly(acrylate)-based polymers PAAAzo (trans), PAAAzo (cis), PAA3α-CD and PAA6α-CD...
-
![]()
Figure 15: Variation of viscosity of a PAA6α-CD/PAAAzo solution (circles) and a PAA3α-CD/PAAAzo solution (tria...
-
![]()
Figure 16: The structures proposed for the poly(ethylene glycol)-b-poly(ethylamine)-g-dextran·γ-CD, PEG-PEI-de...
-
![]()
Figure 17: Structure of poly(ethylene glycol) polyrotaxane with adamantyl end substituents, and its temperatur...
-
![]()
Figure 18: Copolymers of either (a) N,N-dimethylacrylamide (DMAA) or (b) N-isopropylacrylamine (NIPAAM) with 1...
-
![]()
Figure 19: The copolymer of isopropylacrylamine and methacrylated β-CD (a) and its complexation of the anions ...
-
![]()
Figure 20: Solution to hydrogel transitions for two segments of PAAddn in the presence of β-CD and change in t...
-
![]()
Figure 21: Preparation of a β-CD and adamantyl substituted acrylamide polymer hydrogel involving host–guest co...
-
![]()
Figure 22: Aqueous solutions of the polymers poly-β-CD and poly-α-BrNP form the poly-β-CD/poly-α-BrNP hydrogel ...
-
![]()
Figure 23: (a) Randomly β-CD substituted poly(acrylate), PAA-6β-CD. (b) Randomly ferrocenyl substituted poly(a...
-
![]()
Figure 24: (a) The β-CD, adamantyl and ferrocenyl substituted pAAm and pNiPAAM polymers. (b) The β-CD, adamant...
-
- Full Research Paper
- Published 14 Jan 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: (a) Typical structure of aCD bearing hydrophobic chains (R) at the primary side and hydrophilic cha...
-
![]()
Figure 1: The aggregate of eight molecules of the aCD of Scheme 1 with n = 0, obtained from the first trial random ar...
-
![]()
Figure 2: The aggregate of eight molecules of the aCD of Scheme 1 with n = 0, obtained from the second trial random a...
-
![]()
Figure 3: The first trial starting arrangement of sixty-four molecules within the large cell of 123.0 Å, symm...
-
![]()
Figure 4: The second trial starting arrangement of sixty-four molecules within the large cell of 123.0 Å, sym...
-
![]()
Figure 5: The first final arrangement of sixty-four molecules within the large periodic cell of 123.0 Å after...
-
![]()
Figure 6: The second final arrangement of sixty-four molecules within the large periodic cell of 123.0 Å afte...
-
![]()
Figure 7: RH distribution by CONTIN (and Mie scattering normalization) analysis of SC2OH dispersion (2 mg mL−1...
-
- Full Research Paper
- Published 19 Jan 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Example of elucidation of 2D NMR spectra of 2-O-Cin-α-CD.
-
![]()
Figure 2: 2D ROESY spectrum of 2-O-Cin-α-CD in D2O at 25 °C at 24 mM concentration.
-
![]()
Figure 3: Expansion of the 2D ROESY spectrum of 2-O-Cin-α-CD indicating the geometric arrangement.
-
![]()
Figure 4: 1H NMR spectra of 2-O-Cin-α-CD in D2O at 25 °C at different concentrations.
-
![]()
Figure 5: 1H NMR spectra of 3-O-Cin-α-CD in D2O at 25 °C recorded at various concentrations.
-
![]()
Figure 6: Diffusion coefficients of 2-O-Cin-α-CD (black) and, 3-O-Cin-α-CD (red) in D2O at various concentrat...
-
![]()
Figure 7: Effect of solvent on the size distribution of aggregates formed by 2-O-Cin-α-CD at 25 °C (the appli...
-
![]()
Figure 8: Effect of a solvent on the size distribution of aggregates formed by 3-O-Cin-α-CD at 25 °C (the app...
-
![]()
Figure 9: Aggregate sizes (diameter) of 2-O-Cin-α-CD (black) and 3-O-Cin-α-CD (red) in water at various tempe...
-
![]()
Figure 10: Schematic representation of the DLS experiment proving the host–guest nature of the aggregate forma...
-
![]()
Figure 11: The effect of competitive additives on the size distribution of aggregates formed by 3-O-Cin-α-CD a...
-
![]()
Figure 12: Expansion of the 2D ROESY spectrum of 2-O-Cin-α-CD in the presence of CioOK as competitive guest mo...
-
![]()
Figure 13: 1H NMR spectrum of 2-O-Cin-α-CD before (up) and after (down) the addition of CioOK in 5-fold molar ...
-
![]()
Figure 14: The influence of 5 mM 2-O-Cin-α-CD in BGE (right column) on the decrease of the effective electroph...
-
-
Supp. Info
- Full Research Paper
- Published 02 Feb 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Superimposed thermograms for β-CD (solid line) and (a) β-CD/ASO_1:1_a&b (duplicate) or (b) β-CD/ASO...
-
![]()
Figure 2: Superimposed DSC data for β-CD (solid line) and (a) β-CD/ASO_3:1_a&b (duplicate) or (b) β-CD/ASO_3:...
-
![]()
Figure 3: The equation of the KF chemical reaction.
-
![]()
Figure 4: Superimposed volume versus time linear correlations (all three specific intervals) from the KFT ana...
-
![]()
Figure 5: Superimposed volume versus time linear correlations (all three specific intervals) from the KFT ana...
-
-
Supp. Info
- Review
- Published 05 Feb 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Structure of NOPs.
-
![]()
Figure 2: Examples of structures of NOPs.
-
![]()
Figure 3: Structures of pesticides studied in the literature as guest to form an inclusion complex with CDs.
-
![]()
Figure 4: Structures of pesticides sensitive to the presence of CDs.
-
![]()
Scheme 1: The hydrolysis mechanism of substrate (S) in presence of a cyclodextrin (CD).
-
![]()
Figure 5: Structures of the different stereoisomers of G agents.
-
![]()
Scheme 2: Reaction mechanism of CD accelerated decomposition of organophosphorus compound (PX).
-
![]()
Scheme 3: Proposed degradation mechanism of cyclosarin by β-CD [72].
-
![]()
Figure 6: Schematic representations of β-CD and TRIMEB.
-
![]()
Scheme 4: Synthetic pathways to 6-monosubstituted CD derivatives.
-
![]()
Scheme 5: Synthetic pathways to 2-monosubstituted CD by an iodosobenzoate group.
-
![]()
Scheme 6: Synthetic pathways to 2-monosubstituted CDs with N–OH derivatives.
-
![]()
Scheme 7: Synthetic pathways to 3-monosubstituted CDs.
-
![]()
Scheme 8: Synthetic pathways to 3-homodisubstituted CDs.
-
![]()
Scheme 9: Synthetic pathways to 2,3-heterodisubstituted CDs.
-
- Review
- Published 15 Feb 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: (a) Multihorn-flow US reactor, (b) Cavitational turbine, (c) Pilot-scale BM, (d) High-pressure MW r...
-
![]()
Figure 2: Trends in CD papers and CD use in green chemical processes.
-
![]()
Figure 3: Distribution of energy efficient methods in CD publications.
-
![]()
Figure 4: Document type dealing with CD chemistry under non-conventional techniques (conference proceedings a...
-
![]()
Figure 5: Document type dealing with sustainable technologies in CD publications.
-
![]()
Scheme 1: Synthesis of 6I-(p-toluenesulfonyl)-β-CD.
-
![]()
Scheme 2: Example of CuAAC with 6I-azido-6I-deoxy-β-CD and phenylacetylene.
-
![]()
Scheme 3: Synthesis of 6I-benzylureido-6I-deoxy-per-O-acetyl-β-CD.
-
![]()
Scheme 4: Synthesis of 3I-azido-3I-deoxy-altro-α, β- and γ-CD.
-
![]()
Scheme 5: Synthesis of 2-2’ bridged bis(β-CDs). Reaction conditions: 1) TBDMSCl, imidazole, dry pyridine, sti...
-
![]()
Scheme 6: Insoluble reticulated CD polymer.
-
![]()
Scheme 7: CD-HDI cross linked polymers.
-
![]()
Scheme 8: Derivatization of 6I-(p-toluenesulfonyl)-β-CD by tosyl displacement.
-
![]()
Scheme 9: Synthetic scheme for the preparation of heptakis(6-amino-6-deoxy)-β-CD, heptakis(6-deoxy-6-ureido)-...
-
![]()
Scheme 10: Structure of CD derivatives obtained via MW-assisted CuAAC.
-
![]()
Scheme 11: Preparation of SWCN CD-DOTA carrier.
-
- Full Research Paper
- Published 24 Feb 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Scheme 1: Synthesis of oligoethylene glycol dithiols.
-
![]()
Scheme 2: Synthesis of β-cyclodextrinthiols and -disulfides.
-
-
Supp. Info
- Full Research Paper
- Published 17 Mar 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Structures of fluorescent xanthene dyes. Rhodamine B·HCl 1 and fluorescein disodium salt 2.
-
![]()
Figure 2: Reaction scheme for the synthesis of rhodamine-appended β-CD.
-
![]()
Figure 3: TLC plates at different development stages for monitoring the composition of Rho-β-CD crude (left p...
-
![]()
Figure 4: 1H NMR spectrum of Rho-β-CD with partial assignments (D2O, 500 MHz, 298 K).
-
![]()
Figure 5: Expansion of DEPT-ed-HSQC spectrum of Rho-β-CD with partial assignments (D2O, 500 MHz, 298 K).
-
![]()
Figure 6: Cartoon models for the possible intermolecular inclusion mode of Rho-β-CD in solution (3D perspecti...
-
![]()
Figure 7: 1H NMR spectrum of Flu-β-CD with partial assignments (D2O, 500 MHz, 298 K).
-
![]()
Figure 8: Cartoon models for the possible intermolecular inclusion mode of Flu-β-CD in solution (3D perspecti...
-
-
Supp. Info
- Full Research Paper
- Published 21 Mar 2016
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Molecular structure of S4TdR. H atoms are also labeled in the Figure.
-
![]()
Figure 2: Comparison between UV–vis absorption spectra (detailed view: 280–380 nm) obtained for 1 × 10−5 M aq...
-
![]()
Figure 3: Cyclic voltammetry of aqueous solutions containing S4TdR (black solid line) in presence of increasi...
-
![]()
Figure 4: (A) Plot of cathodic potential values and (B) of the corresponding current intensity, obtained for S...
-
![]()
Figure 5: Comparison between detailed views (frequency range: 4000–600 cm−1) of the FTIR–ATR spectra obtained...
-
![]()
Figure 6: Modified Benesi–Hildebrand plot of [H]/[G]/Δδ versus [H]/[G] in the presence of S4TdR at an initial...
-
-
Supp. Info
