Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• varying concentrations. Specifically, our model system consist of a supercell composed of a zirconia (ZrO2) matrix containing two nickel dopants (2Ni), which substitute two Zr atoms at a finite separation. We found the 2Ni atoms to be most stable in a ferromagnetic configuration in the absence of oxygen

• hybridized with unoccupied Ni 3d states. The intensity of this pre-edge peak, however, reduces upon the introduction of a single vacancy in the 2Ni-doped zirconia matrix. The corresponding ground state remains ferromagnetic, while one of the nickel atoms adopts a trigonal bipyramidal geometry, and the other

• been achieved [3][4]). Also, in the last decade, considerable efforts have been devoted to determine the type of magnetic interaction (paramagnetic, ferromagnetic, or antiferromagnetic) and the microscopic mechanisms responsible for the magnetism in doped magnetic oxides (DMO) [5]. Several experimental

Efficiency of electron cooling in cold-electron bolometers with traps

• Dmitrii A. Pimanov,
• Vladimir A. Frost,
• Anton V. Blagodatkin,
• Anna V. Gordeeva,
• Andrey L. Pankratov and
• Leonid S. Kuzmin

Beilstein J. Nanotechnol. 2022, 13, 896–901, doi:10.3762/bjnano.13.80

• -electron bolometers with traps and hybrid superconducting/ferromagnetic absorbers have shown a temperature reduction of the electrons in the refrigerator junctions from 300 to 82 mK, from 200 to 33 mK, and from 100 to 25 mK in the idle regime without optical power load. The electron temperature was

Self-assembly of C₆₀ on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C₆₀ monolayer

• Guglielmo Albani,
• Michele Capra,
• Alessandro Lodesani,
• Alberto Calloni,
• Gianlorenzo Bussetti,
• Marco Finazzi,
• Franco Ciccacci,
• Alberto Brambilla,
• Lamberto Duò and
• Andrea Picone

Beilstein J. Nanotechnol. 2022, 13, 857–864, doi:10.3762/bjnano.13.76

• [15][16]. The ability to tailor the degree of electronic coupling between the molecules and the substrate is of utmost importance when it comes to embedding the interface in a specific application. For instance, if the molecules are interfaced with ferromagnetic electrodes in spin-valve architectures

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• ferromagnetic state causes a qualitative change of both the reflectivity and the magneto-optical Kerr effect transients. A nanoscale magnetic inhomogeneity of the ferromagnet/paramagnet type inherent in the palladium-rich Pd1−xFex alloys reveals itself through the occurrence of a relatively slow, 10–25 ps

• inhomogeneities. The low-temperature fraction of the residual paramagnetic phase can be deduced from the magnitude of the slow reflectivity relaxation component. It is estimated as ≈30% for x = 0.038 and ≈15% for x = 0.062 films. The minimal iron content ensuring the magnetic homogeneity of the ferromagnetic

• required, including logic gates [19][20][21][22][23], programmable logics [16], non-dissipative biasing [1], and random access and cache memories [17][24][25][26][27][28]. From the fabrication point of view, it is strongly desirable to utilize a universal tunable ferromagnetic material for every

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• effect at a ferromagnetic insulator–superconductor (FI–S) interface. The calculations are based on the boundary condition for diffusive quasiclassical Green’s functions, which accounts for arbitrarily strong spin-dependent effects and spin mixing angles. The resulting phase diagram shows a transition

• central for obtaining unprecedentedly high thermoelectric performance at low temperatures [19][20][21][22][23]. Ferromagnetic insulators such as EuO and EuS are interesting materials since they show ferromagnetism (they are almost ideal Heisenberg ferromagnets) but are electrically insulating at the same

• time [24][25][26]. Magnetic insulators have been used successfully, for example, in magnetic Josephson junctions [27], superconducting spin switches [13], and for studying the triplet proximity effect [28]. Ferromagnetic insulators are a good probe of the spin-dependent proximity effect in bilayer

Tunable superconducting neurons for networks based on radial basis functions

• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Igor I. Soloviev,
• Mikhail Yu. Kupriyanov,
• Maxim V. Tereshonok and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2022, 13, 444–454, doi:10.3762/bjnano.13.37

• , ferromagnetic, and normal layers. Keywords: networks on radial basis functions; Josephson circuits; radial basis functions (RBFs); spintronics; superconducting electronics; superconducting neural network; Introduction For modern telecommunications, probabilistic identification of various sources in a

• proximity effect. The typical spin valve [55][56][57] is a hybrid structure containing at least a pair of ferromagnetic (FM) layers with different coercive forces. Variations in the relative orientation of their magnetizations change the spatial distribution of the superconducting order parameter. In the

• can be implemented as a multilayer structure FM1–s–FM2–s–FM1–s–FM2 with several ferromagnetic layers FM1 and FM2 of different thicknesses dFM1,2 (dFM1 = 0.15ξ, dFM2 = 0.1ξ, exchange energy H = 100 kBTC in calculations, separated by thin spacers of a superconductor or normal metal (N) (ds = 0.5ξ for

Controllable two- and three-state magnetization switching in single-layer epitaxial Pd_1−xFe_x films and an epitaxial Pd_0.92Fe_0.08/Ag/Pd_0.96Fe_0.04 heterostructure

• Igor V. Yanilkin,
• Amir I. Gumarov,
• Gulnaz F. Gizzatullina,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2022, 13, 334–343, doi:10.3762/bjnano.13.28

• the film. In a wide range of the appled field directions, the magnetization reversal proceeds in two steps via the intermediate easy axis. An epitaxial heterostructure of two magnetically separated ferromagnetic layers, Pd0.92Fe0.08/Ag/Pd0.96Fe0.04, was synthesized and studied with dc magnetometry

• alloy; thin epitaxial film; Introduction The generation of the long-range triplet component of the superconducting pairing at noncollinear orientations of magnetization in ferromagnetic layered systems is extensively studied in the framework of magnetic Josephson junctions (MJJs) ([1][2][3] for early

• , extending its functionality. Palladium–iron alloys Pd1−xFex with x < 0.10 are of strong practical interest for such MJJ and SSV structures [13][14][15][16][17] as a material for weak ferromagnetic links with tunable magnetic properties [18]. Epitaxial films of Pd1−xFex alloys with low iron content x are

Influence of magnetic domain walls on all-optical magnetic toggle switching in a ferrimagnetic GdFe film

• Rahil Hosseinifar,
• Evangelos Golias,
• Ivar Kumberg,
• Quentin Guillet,
• Karl Frischmuth,
• Sangeeta Thakur,
• Mario Fix,
• Manfred Albrecht,
• Florian Kronast and
• Wolfgang Kuch

Beilstein J. Nanotechnol. 2022, 13, 74–81, doi:10.3762/bjnano.13.5

• ][10][11][12][13][14][15]. AOS has been observed in a broad variety of ferri- and ferromagnetic materials, either as single-pulse or multiple-pulse switching. It can be both, depending on the helicity of the exciting laser pulse or independent of helicity. Particularly interesting is the switching of

Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• prepared, too. Magnetic properties were measured and the growth mechanism was discussed [10]. The formation of Cr/Ge nanoparticles during the epitaxial growth of Cr/Ge films and their magnetic properties were studied to understand the ferromagnetic semiconductor behavior [11]. In this work, we made an

Biocompatibility and cytotoxicity in vitro of surface-functionalized drug-loaded spinel ferrite nanoparticles

• Sadaf Mushtaq,
• Khuram Shahzad,
• Tariq Saeed,
• Anwar Ul-Hamid,
• Bilal Haider Abbasi,
• Nafees Ahmad,
• Waqas Khalid,
• Muhammad Atif,
• Zulqurnain Ali and
• Rashda Abbasi

Beilstein J. Nanotechnol. 2021, 12, 1339–1364, doi:10.3762/bjnano.12.99

• physical property measurement system (PPMS) was used to evaluate magnetic properties of MFe2O4 NPs. Hysteresis loops were measured at room temperature upon an applied field of 2.0 T. The samples clearly showed ferromagnetic behavior with different saturation magnetization Ms (emu/g) and coercivity Hc (Oe

Enhancement of the piezoelectric coefficient in PVDF-TrFe/CoFe₂O₄ nanocomposites through DC magnetic poling

• Marco Fortunato,
• Alessio Tamburrano,
• Maria Paola Bracciale,
• Maria Laura Santarelli and
• Maria Sabrina Sarto

Beilstein J. Nanotechnol. 2021, 12, 1262–1270, doi:10.3762/bjnano.12.93

• place between PVDF-TrFe and CoFe2O4 nanoparticles, with the formation of a carbonyl group (C=O), as suggested by the FTIR spectra reported in Figure 1. When the DC magnetic field is applied, the ferromagnetic nanoparticles orient themselves along the direction of the applied field and then drag the

• piezoelectric coefficient by adding ferromagnetic CoFe2O4 nanoparticles to PVDF-TrFe and performing magnetic poling. The highest d33 value, up to 39 pm/V, was obtained after adding 5 wt % of CoFe2O4 nanoparticles and applying a DC magnetic field of 50 mT. Application of the magnetic field produced an alignment

• nanocomposite, including ferromagnetic CoFe2O4 nanoparticles, and the application of a DC magnetic poling provides an alternative route to obtain highly efficient piezoelectric materials with excellent d33 values, avoiding electrical poling or mechanical stretching. This process may be particularly attractive

In situ transport characterization of magnetic states in Nb/Co superconductor/ferromagnet heterostructures

• Olena M. Kapran,
• Roman Morari,
• Taras Golod,
• Evgenii A. Borodianskyi,
• Vladimir Boian,
• Andrei Prepelita,
• Nikolay Klenov,
• Anatoli S. Sidorenko and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 913–923, doi:10.3762/bjnano.12.68

• demonstrate how FORC can be used for detailed in situ characterization of magnetic states. It reveals that upon reduction of the external field, the magnetization in ferromagnetic layers first rotates in a coherent scissor-like manner, then switches abruptly into the antiparallel state and after that splits

• is caused by subtractive (in the AP state) and additive (in the P state) influences of ferromagnetic exchange fields from neighbor F-layers, which are detrimental to the spin-singlet order in S′ [1][2][3][4][5][6][7][8]. Simulations in Figure 1c demonstrate the tunability of superconductivity in such

• MLs. The key technique that we employ for this purpose is FORC, a powerful tool for the characterization of magnetic states in complex ferromagnetic structures [60][61][62]. FORC analysis starts at the same saturated state. Then the field is swept to a reversal field Hr and measurements are carried

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

Recent progress in actuation technologies of micro/nanorobots

• Ke Xu and
• Bing Liu

Beilstein J. Nanotechnol. 2021, 12, 756–765, doi:10.3762/bjnano.12.59

• content about MC-1 magnetotactic bacteria (MTB) in the treatment of cancer, especially as a supplementary means to advance in smaller capillaries. Therefore, Martel innovatively used MC-1 magnetotactic bacteria combined with ferromagnetic materials to push microbeads and therapeutic agents together for

Recent progress in magnetic applications for micro- and nanorobots

• Ke Xu,
• Shuang Xu and
• Fanan Wei

Beilstein J. Nanotechnol. 2021, 12, 744–755, doi:10.3762/bjnano.12.58

• this article, recent progress in magnetic applications in the field of micro- and nanorobots is reviewed. First, the achievements of manufacturing micro- and nanorobots by incorporating different magnetic nanoparticles, such as diamagnetic, paramagnetic, and ferromagnetic materials, are discussed in

• transportation of cargo [22][23], and transmit energy. Compared with other concepts, magnetic MNRs that combine diamagnetic, paramagnetic, and ferromagnetic materials [24] could have a greater driving force and exhibit characteristics such as biocompatibility [25]. Hence, magnetic nanoparticles (MNPs) are widely

• according to the alignment and response of magnetic dipoles, magnetic materials can be divided into diamagnetic, paramagnetic [31], ferromagnetic, ferrimagnetic, and antiferromagnetic. Diamagnetism of the material can be attributed to the orbital angular momentum, which is a phenomenon in which

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• junctions by the HIM method has again been demonstrated [48]. Ferromagnetic properties The first demonstration of defect engineering using the HIM was actually for a magnetic device by Franken and co-authors [49]. In this work, ferromagnetic microstrips comprising Pt(4 nm)/Co(0.6 nm)/Pt(2 nm) layers on an

• demonstrated [51]. Furthermore, tuning of the metamagnetic transition temperature of an FeRh thin film (from antiferromagnetic to ferromagnetic behavior) has been achieved by varying the helium ion dose from 1 × 1014 to 5 × 1015 ions/cm2, with the patterning of features down to 25 nm in size [52]. In a study

• the collision cascade to create individual ferromagnetic domains in a previously non-ferromagnetic material [55]. In the cited work, Röder et al. used this phenomenon of disorder-induced ferromagnetism, together with the small probe size of the neon ion beam, to directly write nanomagnets into a

Spontaneous shape transition of Mn_xGe_1−x islands to long nanowires

• S. Javad Rezvani,
• Luc Favre,
• Gabriele Giuli,
• Yiming Wubulikasimu,
• Isabelle Berbezier,
• Augusto Marcelli,
• Luca Boarino and
• Nicola Pinto

Beilstein J. Nanotechnol. 2021, 12, 366–374, doi:10.3762/bjnano.12.30

• literature for other heteroepitaxial systems. Our study gives experimental evidence for the spontaneous formation of spatially uniform and compositionally homogeneous Mn-rich GeMn nanowires on Ge(111). The reliable and simple synthesis approach allows one to exploit the room-temperature ferromagnetic

• ]. The growth of MnxGe1−x alloys on Ge wafers, and in particular of Mn5Ge3, has been studied extensively in recent years [18][19][20][21][22][23][24]. The high Curie temperature of Mn5Ge3 (≈296 K), in particular, can make it suitable to exploit ferromagnetic properties in everyday applications [25][26

• ≃1.5 μm in length. Considering that several Mn-rich Ge–Mn phases are usually ferromagnetic at room temperature, our results offer an alternative route to a simple and fast fabrication process of novel nanodevices, capable to exploit ferromagnetic properties. SEM images of the morphological evolution of

Nickel nanoparticle-decorated reduced graphene oxide/WO₃ nanocomposite – a promising candidate for gas sensing

• Ilka Simon,
• Alexandr Savitsky,
• Rolf Mülhaupt,
• Vladimir Pankov and
• Christoph Janiak

Beilstein J. Nanotechnol. 2021, 12, 343–353, doi:10.3762/bjnano.12.28

• with a noncollinear spin configuration, which causes the formation of a surface spin canting due to thermal fluctuation of magnetic moments. Figure 7 shows the temperature dependence of the magnetization obtained in the course of the last measurement cycle at which, for nickel particles, ferromagnetic

Exploring the fabrication and transfer mechanism of metallic nanostructures on carbon nanomembranes via focused electron beam induced processing

• Christian Preischl,
• Linh Hoang Le,
• Elif Bilgilisoy,
• Armin Gölzhäuser and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2021, 12, 319–329, doi:10.3762/bjnano.12.26

• irradiation (100 eV, 120 mC/cm2) the whole surface of the cross-linked SAM is afterwards covered with clean iron nanocrystals (Figure S6d,e in Supporting Information File 1). The insulating ultrathin CNM is covered with a thin layer of conductive ferromagnetic iron crystals. By this process laterally

The patterning toolbox FIB-o-mat: Exploiting the full potential of focused helium ions for nanofabrication

• Victor Deinhart,
• Lisa-Marie Kern,
• Jan N. Kirchhof,
• Sabrina Juergensen,
• Joris Sturm,
• Enno Krauss,
• Thorsten Feichtner,
• Sviatoslav Kovalchuk,
• Michael Schneider,
• Dieter Engel,
• Bastian Pfau,
• Bert Hecht,
• Kirill I. Bolotin,
• Stephanie Reich and
• Katja Höflich

Beilstein J. Nanotechnol. 2021, 12, 304–318, doi:10.3762/bjnano.12.25

• , atomic composition, and crystallographic phase [33][34]. Here, the impact of He irradiation on the ferromagnetic multilayer [Co0.6/Pt0.8]15 is studied [35][36]. This multilayer shows perpendicular magnetic anisotropy arising from the Co/Pt interfaces and forms nanometer-scale, labyrinth-like domains with

Nanocasting synthesis of BiFeO₃ nanoparticles with enhanced visible-light photocatalytic activity

• Thomas Cadenbach,
• Maria J. Benitez,
• A. Lucia Morales,
• Cesar Costa Vera,
• Luis Lascano,
• Francisco Quiroz,
• Alexis Debut and
• Karla Vizuete

Beilstein J. Nanotechnol. 2020, 11, 1822–1833, doi:10.3762/bjnano.11.164

• visible-light region (2.1–2.8 eV), high chemical stability, and ferroelectric and ferromagnetic properties at room temperature [19][20][21][22][23][24][25][26][27]. Furthermore, slow electron–hole recombination as a result of efficient separation of the charge carriers has yielded an enhancement of its

Molecular dynamics modeling of the influence forming process parameters on the structure and morphology of a superconducting spin valve

• Alexander Vakhrushev,
• Aleksey Fedotov,
• Vladimir Boian,
• Roman Morari and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1776–1788, doi:10.3762/bjnano.11.160

• This work is a study of the formation processes and the effect of related process parameters of multilayer nanosystems and devices for spintronics. The model system is a superconducting spin valve, which is a multilayer structure consisting of ferromagnetic cobalt nanolayers separated by niobium

• atomic structures depending on the main parameters of the deposition process. Keywords: hybrid nanostructure; mathematical modeling; modified embedded-atom method; molecular dynamics; spintronics; spin valve; vacuum deposition; Introduction Multilayer superconductor/ferromagnetic (S/F) hybrid

• ferromagnetic layers causes a restructuring of the magnetic moment configuration under low-power magnetic fields and switches the spin valve from a high to a low resistance state. When a superconducting film is used as a magneto-resistive interlayer, a superconducting spin valve is obtained. Furthermore, these

Functional nanostructures for electronics, spintronics and sensors

• Anatolie S. Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1704–1706, doi:10.3762/bjnano.11.152

• functional nanostructures consisting of alternating layers of ferromagnetic and superconducting materials – has been observed. Due to the proximity effect of superconductor/ferromagnetic (S/F) layers and Andreev reflection of Cooper pairs at the S/F interface, a number of new phenomena were first

• in astrophysics and read-out tracts measuring signals generated by quantum circuits at a frequency of 6–9 GHz. Summarizing the above-mentioned milestones, one can see that the main focus of this thematic issue is the new area of research: superconductor/ferromagnetic hybrid nanostructures and their

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• , size and magnetic nature enables them to kill microorganisms through the application of an external magnetic field, resulting in an increase of the therapeutic antimicrobial properties, especially when compared to conventional antimicrobial compounds [136]. Ferromagnetic nanoparticles are probably the

• -volume ratio, increasing the surface of the atoms [19]. In addition, when a magnetic field is applied the magnetic moments of these ferromagnetic FeO NPs become aligned. The surface of the SPIONs can be modified to specifically improve their functionality as antimicrobial compounds by increasing their

Controlling the proximity effect in a Co/Nb multilayer: the properties of electronic transport

• Sergey Bakurskiy,
• Mikhail Kupriyanov,
• Nikolay V. Klenov,
• Igor Soloviev,
• Andrey Schegolev,
• Roman Morari,
• Yury Khaydukov and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1336–1345, doi:10.3762/bjnano.11.118

• We present both theoretical and experimental investigations of the proximity effect in a stack-like superconductor/ferromagnetic (S/F) superlattice, where ferromagnetic layers with different thicknesses and coercive fields are made of Co. Calculations based on the Usadel equations allow us to find

• superlattices can be used as tunable kinetic inductors designed for artificial neural networks representing the information in a “current domain”. Keywords: cryogenic computing; spin-valve; superconducting neural network; superconducting spintronics; Introduction Multilayer superconductor/ferromagnetic (S/F

• ferromagnetic (F) layers separated by thin superconducting layers, in which the superconducting order parameter is maintained due to the proximity to a thick superconducting bank (S-bank). Switching from the antiparallel (AP) to the parallel (P) alignment of neighboring F1 and F2 layers leads to a significant