Nanoporous water oxidation electrodes with a low loading of laser-deposited Ru/C exhibit enhanced corrosion stability

• Sandra Haschke,
• Dmitrii Pankin,
• Vladimir Mikhailovskii,
• Maïssa K. S. Barr,
• Adriana Both-Engel,
• Alina Manshina and
• Julien Bachmann

Beilstein J. Nanotechnol. 2019, 10, 157–167, doi:10.3762/bjnano.10.15

• RF mode on the sample side of laser deposition (step (d) in Figure 5). Instrumental methods Scanning electron micrographs were obtained on a Zeiss Merlin field-emission SEM with a field-emission cathode and standard In-lens SE and SE2 detectors. All measurements were performed in the chamber with a

Apparent tunneling barrier height and local work function of atomic arrays

• Neda Noei,
• Alexander Weismann and
• Richard Berndt

Beilstein J. Nanotechnol. 2018, 9, 3048–3052, doi:10.3762/bjnano.9.283

• . This is reflected by the notion of a local work function Φ [7][8][9]. Adsorbates modify Φ in an intriguing manner [10][11][12][13]. In turn, variations of Φ produce, e.g., atomic-scale contrast in field-emission microscopy, photo-emission electron microscopy, and low-energy electron microscopy [14][15

Charged particle single nanometre manufacturing

• Philip D. Prewett,
• Cornelis W. Hagen,
• Claudia Lenk,
• Steve Lenk,
• Marcus Kaestner,
• Tzvetan Ivanov,
• Ahmad Ahmad,
• Ivo W. Rangelow,
• Xiaoqing Shi,
• Stuart A. Boden,
• Alex P. G. Robinson,
• Dongxu Yang,
• Sangeetha Hari,
• Marijke Scotuzzi and
• Ejaz Huq

Beilstein J. Nanotechnol. 2018, 9, 2855–2882, doi:10.3762/bjnano.9.266

• to 196 beams is under development based on a commercial SEM platform. Among its potential applications is the manufacture of templates for nanoimprint lithography, NIL. This is also a target application for the third and final charged particle technology, viz. field emission electron scanning probe

• ; electron; field emission; ion; nanolithography; Review 1 Introduction Methods for nanostructuring – the fabrication of structures with sizes on the nanoscale – are required for the fabrication of next-generation nanoelectronics, such as quantum-based devices, for nanophotonics, nanobiotechnology

• beams can be divided into two approaches: either the particle beam is generated far from the sample and scanned over it using electric or magnetic focusing and deflection optics or the beam is generated at a field-emission tip located in close proximity to the sample and the tip itself is scanned to

Nanostructure-induced performance degradation of WO₃·nH₂O for energy conversion and storage devices

• Zhenyin Hai,
• Mohammad Karbalaei Akbari,
• Zihan Wei,
• Danfeng Cui,
• Chenyang Xue,
• Hongyan Xu,
• Philippe M. Heynderickx,
• Francis Verpoort and
• Serge Zhuiykov

Beilstein J. Nanotechnol. 2018, 9, 2845–2854, doi:10.3762/bjnano.9.265

• samples were identified with a high-resolution X-ray diffractometer (HR-XRD, SmartLab, Rigaku). The morphology of samples was investigated by field-emission scanning electron microscopy (FE-SEM, JSM-7100F, Jeol) together with energy-dispersive spectroscopy (EDS). Information about chemical composition and

Biomimetic surface structures in steel fabricated with femtosecond laser pulses: influence of laser rescanning on morphology and wettability

• Camilo Florian Baron,
• Alexandros Mimidis,
• Daniel Puerto,
• Evangelos Skoulas,
• Emmanuel Stratakis,
• Javier Solis and
• Jan Siegel

Beilstein J. Nanotechnol. 2018, 9, 2802–2812, doi:10.3762/bjnano.9.262

• , the depth was positive (the laser ablated material producing a hole in the sample) whereas in some cases, negative depths where also measured (the irradiated sample protrudes out). In addition, the morphology of the surfaces was characterized with a field emission electron microscope (Hitachi S-4800

Near-infrared light harvesting of upconverting NaYF₄:Yb³⁺/Er³⁺-based amorphous silicon solar cells investigated by an optical filter

• Daiming Liu,
• Qingkang Wang and
• Qing Wang

Beilstein J. Nanotechnol. 2018, 9, 2788–2793, doi:10.3762/bjnano.9.260

• optical filter. Photoelectric performances of a-Si:H solar cells with and without UC were compared under AM1.5 solar irradiation. Results and Discussion Field-emission scanning electron microscopy (FE-SEM) was used to investigate the sample morphologies over the course of the reaction. In Figure 1a, the

Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry

• Pierre Farger,
• Cédric Leuvrey,
• Mathieu Gallart,
• Pierre Gilliot,
• Guillaume Rogez,
• João Rocha,
• Duarte Ananias,
• Pierre Rabu and
• Emilie Delahaye

Beilstein J. Nanotechnol. 2018, 9, 2775–2787, doi:10.3762/bjnano.9.259

• a JEOL 6700F (scanning electron microscope (SEM) equipped with a field-emission gun (FEG), operating at 3 kV in the SEI mode instrument. FTIR spectra were collected on a Perkin Elmer Spectrum Two UATR-FTIR spectrometer. TGA-TDA experiments were performed using a TA instrument SDT Q600 (heating rates

Accurate control of the covalent functionalization of single-walled carbon nanotubes for the electro-enzymatically controlled oxidation of biomolecules

• Naoual Allali,
• Veronika Urbanova,
• Mathieu Etienne,
• Xavier Devaux,
• Martine Mallet,
• Brigitte Vigolo,
• Jean-Joseph Adjizian,
• Chris P. Ewels,
• Sven Oberg,
• Alexander V. Soldatov,
• Edward McRae,
• Yves Fort,
• Manuel Dossot and
• Victor Mamane

Beilstein J. Nanotechnol. 2018, 9, 2750–2762, doi:10.3762/bjnano.9.257

• microscopy (HRSTEM) were performed using a probe aberration-corrected JEOL ARM200 microscope equipped with a cold field emission gun, a JEOL JED2300T energy dispersive X-ray spectrometer (EDS) and a Gatan GIF Quantum energy filter for electron energy loss spectroscopy (EELS). The microscope was operated at

Oriented zinc oxide nanorods: A novel saturable absorber for lasers in the near-infrared

• Pavel Loiko,
• Tanujjal Bora,
• Josep Maria Serres,
• Haohai Yu,
• Magdalena Aguiló,
• Francesc Díaz,
• Uwe Griebner,
• Valentin Petrov,
• Xavier Mateos and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2018, 9, 2730–2740, doi:10.3762/bjnano.9.255

• studied by field emission scanning electron microscopy (FESEM) using a JEOL JSM-7600F microscope. The structure of the grown ZnO NRs was studied by X-ray diffraction (XRD) using a Rigaku MiniFlex600 diffractometer. The XRD patterns of the samples were obtained using Cu Kα radiation (1.5406 Å) with

• found elsewhere [31]. Field emission scanning electron microscope (FESEM) images of ZnO nanorods grown hydrothermally on glass substrates for (a,d) 5 h, (b,e) 10 h and (c,f) 15 h; (a,b,c) top- and (d,e,f) side-view. Images (b) and (e) are reproduced with permission from [28], copyright 2017, IEEE. (a) X

• demonstrate the suitability of hydrothermally grown, oriented ZnO NRs as SAs for lasers emitting at 1 and 2 µm, for the first time, to the best of our knowledge. The preliminary results of this work were presented in a conference paper [28]. Results and Discussion Structural study Figure 1 shows the field

Low cost tips for tip-enhanced Raman spectroscopy fabricated by two-step electrochemical etching of 125 µm diameter gold wires

• Antonino Foti,
• Francesco Barreca,
• Enza Fazio,
• Cristiano D’Andrea,
• Paolo Matteini,
• Onofrio Maria Maragò and
• Pietro Giuseppe Gucciardi

Beilstein J. Nanotechnol. 2018, 9, 2718–2729, doi:10.3762/bjnano.9.254

• drops of HCl and rinsing in ethanol and water. This eliminates residual impurities from the surface. Scanning electron microscopy (SEM) inspection of the produced tips is carried out to characterize the tip apex using a Zeiss Merlin field emission electron microscope, equipped with a Gemini II column

Silencing the second harmonic generation from plasmonic nanodimers: A comprehensive discussion

• Jérémy Butet,
• Gabriel D. Bernasconi and
• Olivier J. F. Martin

Beilstein J. Nanotechnol. 2018, 9, 2674–2683, doi:10.3762/bjnano.9.250

• emission, meaning that these SH sources do not really contribute to the far-field emission and can even interfere destructively with other sources. Considering the SH sources in the nanogap only (coverage of 25%), the far-field SH intensity drops by a factor 7 for a gap g = 5 nm and by a factor 10 for a

Enhanced antineoplastic/therapeutic efficacy using 5-fluorouracil-loaded calcium phosphate nanoparticles

• Shanid Mohiyuddin,
• Saba Naqvi and
• Gopinath Packirisamy

Beilstein J. Nanotechnol. 2018, 9, 2499–2515, doi:10.3762/bjnano.9.233

• with an approximate diameter of 160–180 nm was confirmed by different methods. The physicochemical characterization of the synthesized CaP@5-FU NPs was done with transmission electron microscopy (TEM), dynamic light scattering (DLS), field emission scanning electron microscopy (FE-SEM), Fourier

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• microscope (XRD, Rigaku, SmartLab) (Cu Kα radiation, λ = 1.540598 Å, in grazing mode with a glancing angle of 0.5°, step size of 0.05°, and a 2θ range of 10–80°) as well as a field-emission transmission electron microscope (FETEM, JEOL, JEM-2100F) were used. Cross-sectional TEM samples were prepared using a

• films were characterized using a surface profiler (Vecco, Dektak XT-E). The planar and cross-sectional morphologies were analysed using a field-emission scanning electron microscope (FESEM, JEOL, JSM_7800F) with 5 kV of field voltage, using an SE2 secondary detector. Optical characterization was carried

Hydrothermal-derived carbon as a stabilizing matrix for improved cycling performance of silicon-based anodes for lithium-ion full cells

• Mirco Ruttert,
• Florian Holtstiege,
• Jessica Hüsker,
• Markus Börner,
• Martin Winter and
• Tobias Placke

Beilstein J. Nanotechnol. 2018, 9, 2381–2395, doi:10.3762/bjnano.9.223

• range between 25 °C and 800 °C on a TGA Q500 (TA Instruments) in an oxygen/nitrogen atmosphere (nitrogen flow: 10 mL min−1, oxygen flow: 25 mL min−1) in order to determine the Si content. A heating ramp of 20 °C min−1 was applied. Scanning electron microscopy (SEM) with a field emission gun (Schottky

Directional light beams by design from electrically driven elliptical slit antennas

• Shuiyan Cao,
• Eric Le Moal,
• Quanbo Jiang,
• Aurélien Drezet,
• Serge Huant,
• Jean-Paul Hugonin,
• Gérald Dujardin and
• Elizabeth Boer-Duchemin

Beilstein J. Nanotechnol. 2018, 9, 2361–2371, doi:10.3762/bjnano.9.221

• excitation of structure 8 (see Table 1) at the focus F(−c,0). Figure 5 shows the effect of the SPP source location on the far-field emission pattern. The emission of light from an elliptical slit (structure 8 in Table 1) is obtained using the STM nanosource at different positions along the major axis of the

Magnetism and magnetoresistance of single Ni–Cu alloy nanowires

• Andreea Costas,
• Camelia Florica,
• Elena Matei,
• Maria Eugenia Toimil-Molares,
• Ionel Stavarache,
• Andrei Kuncser,
• Victor Kuncser and
• Ionut Enculescu

Beilstein J. Nanotechnol. 2018, 9, 2345–2355, doi:10.3762/bjnano.9.219

• 620 equipment situated into a cleanroom class 100 (ISO EN 14644) with RF magnetron sputtering and thermal vacuum evaporation (using TECTRA equipment). Thus, to contact single Ni–Cu alloy nanowires using a typical EBL process (Zeiss Merlin Compact field-emission scanning electron microscope combined

The role of adatoms in chloride-activated colloidal silver nanoparticles for surface-enhanced Raman scattering enhancement

• Nicolae Leopold,
• Andrei Stefancu,
• Krisztian Herman,
• István Sz. Tódor,
• Stefania D. Iancu,
• Vlad Moisoiu and
• Loredana F. Leopold

Beilstein J. Nanotechnol. 2018, 9, 2236–2247, doi:10.3762/bjnano.9.208

• transmission electron microscope (STEM), equipped with a cold field emission gun, working at an acceleration voltage of 200 kV. The absorption spectra were recorded with a Jasco V-630 UV–vis spectrometer at 1 nm spectral resolution. Raman and SERS spectra were obtained with a Renishaw InVia Raman microscope

Spin-coated planar Sb₂S₃ hybrid solar cells approaching 5% efficiency

• Pascal Kaienburg,
• Benjamin Klingebiel and
• Thomas Kirchartz

Beilstein J. Nanotechnol. 2018, 9, 2114–2124, doi:10.3762/bjnano.9.200

• MoOx forms a tunneling junction with the HTM is typical for organic solar cells in an n-i-p configuration. The cell area was 0.16 cm2. Layer and device characterization: The scanning electron microscope was a Zeiss (Leo) Gemini 1550 with Shottky field-emission cathode and an in-lens detector. The

The structural and chemical basis of temporary adhesion in the sea star Asterina gibbosa

• Birgit Lengerer,
• Marie Bonneel,
• Mathilde Lefevre,
• Elise Hennebert,
• Philippe Leclère,
• Emmanuel Gosselin,
• Peter Ladurner and
• Patrick Flammang

Beilstein J. Nanotechnol. 2018, 9, 2071–2086, doi:10.3762/bjnano.9.196

• dried by the critical-point method. They were mounted on aluminium stubs, coated with gold in a sputter-coater and observed with a JEOL JSM-7200F field emission scanning electron microscope. 3D confocal interference microscopy Footprints were collected on clean microscope glass slides, rinsed with

Electromigrated electrical optical antennas for transducing electrons and photons at the nanoscale

• Arindam Dasgupta,
• Mickaël Buret,
• Nicolas Cazier,
• Marie-Maxime Mennemanteuil,
• Reinaldo Chacon,
• Kamal Hammani,
• Jean-Claude Weeber,
• Juan Arocas,
• Laurent Markey,
• Gérard Colas des Francs,
• Alexander Uskov,
• Igor Smetanin and
• Alexandre Bouhelier

Beilstein J. Nanotechnol. 2018, 9, 1964–1976, doi:10.3762/bjnano.9.187

• work function of gold. The Fowler–Nordheim plot, as a function of 1/Vdc, is commonly used to distinguish the transition between direct tunneling at low Vdc and a high-bias regime where the energy barrier is drastically reduced and electrons are tunneling by field emission [44]. Thus, the

Synthesis of carbon nanowalls from a single-source metal-organic precursor

• André Giese,
• Sebastian Schipporeit,
• Volker Buck and
• Nicolas Wöhrl

Beilstein J. Nanotechnol. 2018, 9, 1895–1905, doi:10.3762/bjnano.9.181

• catalytically active and characterize their properties for this application. Although the nanorods have the smallest surface area of the synthesized morphologies in this work, they might be promising for electron field-emitter applications since they feature nanosized tips. The field-emission properties of

Synthesis of hafnium nanoparticles and hafnium nanoparticle films by gas condensation and energetic deposition

• Irini Michelakaki,
• Nikos Boukos,
• Dimitrios A. Dragatogiannis,
• Spyros Stathopoulos,
• Costas A. Charitidis and
• Dimitris Tsoukalas

Beilstein J. Nanotechnol. 2018, 9, 1868–1880, doi:10.3762/bjnano.9.179

• of the NPs and NTFs were performed by field-emission scanning electron microscopy (FESEM FEI Nova Nano SEM 230) and atomic force microscopy (Veeco diInnova) in tapping mode. The nanomechanical properties of the NTFs were determined by nanoindentation. Nanoidentation testing was performed with a

Toward the use of CVD-grown MoS₂ nanosheets as field-emission source

• Geetanjali Deokar,
• Nitul S. Rajput,
• Junjie Li,
• Francis Leonard Deepak,
• Wei Ou-Yang,
• Nicolas Reckinger,
• Carla Bittencourt,
• Jean-Francois Colomer and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2018, 9, 1686–1694, doi:10.3762/bjnano.9.160

• transferred NSs sample showed excellent field-emission properties. A low turn-on field of 3.1 V/μm at a current density of 10 µA/cm2 was measured. The low turn-on field is attributed to the morphology of the NSs exhibiting vertically aligned sheets of MoS2 with sharp and exposed edges. Our findings show that

• the fabricated MoS2 NSs could have a great potential as robust high-performance electron-emitter material for various applications such as microelectronics and nanoelectronics, flat-panel displays and electron-microscopy emitter tips. Keywords: chemical vapor deposition (CVD); field emission

• ; molybdenum disulfide (MoS2); nanosheets; sulfurization; transmission electron microscopy (TEM); Introduction There is a great interest in the development of one- and two-dimensional (1D and 2D) materials for field-emission (FE) based cathodes using various nanostructured materials [1] for applications in

Sulfur-, nitrogen- and platinum-doped titania thin films with high catalytic efficiency under visible-light illumination

• Boštjan Žener,
• Lev Matoh,
• Giorgio Carraro,
• Bojan Miljević and
• Romana Cerc Korošec

Beilstein J. Nanotechnol. 2018, 9, 1629–1640, doi:10.3762/bjnano.9.155

• ). The BE shifts were corrected by assigning a value of 284.8 eV to the C 1s line of adventitious carbon [51]. UV–vis absorption spectra were collected using an Agilent Cary 60 UV–vis spectrophotometer in the wavelength range λ = 400–800 nm. The morphology of thin films was examined using a field

• emission scanning electron microscope (FEI Inspect™ F50 and Ultra Plus Zeiss). The band gap measurements were performed by measuring the reflectance of the samples using a UV–vis spectrophotometer (Evolution 600, Thermo Scientific), using the diffuse reflectance accessory (DRA-EV-600) integrating sphere

Correlative electrochemical strain and scanning electron microscopy for local characterization of the solid state electrolyte Li_1.3Al_0.3Ti_1.7(PO₄)₃

• Nino Schön,
• Deniz Cihan Gunduz,
• Shicheng Yu,
• Hermann Tempel,
• Roland Schierholz and
• Florian Hausen

Beilstein J. Nanotechnol. 2018, 9, 1564–1572, doi:10.3762/bjnano.9.148

• , Hillsboro, Oregon, USA) equipped with a field emission gun (FEG) and EDX (Octane 60 mm2, EDAX Inc., Mahwah, NJ, USA) was employed to visualize the grain structure of LATP samples. Chemical information from the various regions of interest was obtained by means of EDX. Atomic force microscopy and