Unipolar magnetic field pulses as an advantageous tool for ultrafast operations in superconducting Josephson “atoms”

• Daria V. Popolitova,
• Nikolay V. Klenov,
• Igor I. Soloviev,
• Sergey V. Bakurskiy and
• Olga V. Tikhonova

Beilstein J. Nanotechnol. 2019, 10, 1548–1558, doi:10.3762/bjnano.10.152

• transitions between the qubit states and to allow for Raman Λ-type transitions between them via the upper level. Using an existing analogy with spin states |↓⟩ and |↑⟩ the direction of should be chosen along the z-axis such that the interaction term μzHz is proportional to the matrix, which prevents the

• direct spin-flip transition. Finally we expand the non-stationary wave function of the system in terms of the considered eigenfunctions of the double-well potential φn with energies En, and obtain a set of coupled differential equations for the probability amplitudes Cn(t) of the corresponding states

• , which is dramatically faster than that obtained in the case of a carrier magnetic pulse resonant to the direct transition between spin states. Since in the experimental realization of such a scheme it is rather difficult to provide explicitly the required duration of the magnetic pulse, the required

Development of a new hybrid approach combining AFM and SEM for the nanoparticle dimensional metrology

• Loïc Crouzier,
• Alexandra Delvallée,
• Sébastien Ducourtieux,
• Laurent Devoille,
• Guillaume Noircler,
• Christian Ulysse,
• Olivier Taché,
• Elodie Barruet,
• Christophe Tromas and
• Nicolas Feltin

Beilstein J. Nanotechnol. 2019, 10, 1523–1536, doi:10.3762/bjnano.10.150

• silicon substrates through the spin-coating method detailed in [11]. This method yields well-dispersed nanoparticles on the substrate while maximizing the number of isolated NPs preventing agglomeration of the NPs. NP SEM images have been recorded using a Zeiss ULTRA-Plus field-emission (FE) microscope

• particularly suitable for a controlled deposition of NPs implementing the spin-coater detailed in [11]. The best coverage of isolated NPs has been found in an intermediary area between the substrate edges and the central area very close to rotation axis of the spin-coater. As a consequence, the patterns

Synthesis of P- and N-doped carbon catalysts for the oxygen reduction reaction via controlled phosphoric acid treatment of folic acid

• Rieko Kobayashi,
• Takafumi Ishii,
• Yasuo Imashiro and
• Jun-ichi Ozaki

Beilstein J. Nanotechnol. 2019, 10, 1497–1510, doi:10.3762/bjnano.10.148

• of P2 and P3 species, i.e., by the contents of P atoms directly bonded to one or two carbon atoms as shown in Figure 9. Previously, the enhanced ORR activity of PN-doped carbon materials was ascribed to an increase of asymmetric spin density [24][25][39], electron transfer from N or P to C [36

Superconducting switching due to a triplet component in the Pb/Cu/Ni/Cu/Co₂Cr_1−xFe_xAl_y spin-valve structure

• Andrey Andreevich Kamashev,
• Nadir Nurgayazovich Garif’yanov,
• Aidar Azatovich Validov,
• Joachim Schumann,
• Vladislav Kataev,
• Bernd Büchner,
• Yakov Victorovich Fominov and
• Ilgiz Abdulsamatovich Garifullin

Beilstein J. Nanotechnol. 2019, 10, 1458–1463, doi:10.3762/bjnano.10.144

• Technology, 141700 Dolgoprudny, Russia National Research University Higher School of Economics, 101000 Moscow, Russia 10.3762/bjnano.10.144 Abstract We report the superconducting properties of the Co2Cr1−xFexAly/Cu/Ni/Cu/Pb spin-valve structure the magnetic part of which comprises the Heusler alloy layer HA

• = Co2Cr1−xFexAly with a high degree of spin polarization (DSP) of the conduction band and a Ni layer of variable thickness. The separation between the superconducting transition curves measured for the parallel (α = 0°) and perpendicular (α = 90°) orientation of the magnetization of the HA and the Ni

• suggests that the observed minimum and the corresponding full switching effect of the spin valve is caused by the long-range triplet component of the superconducting condensate in the multilayer. Such a large effect can be attributed to a half-metallic nature of the HA layer, which in the orthogonal

Gas sensing properties of individual SnO₂ nanowires and SnO₂ sol–gel nanocomposites

• Alexey V. Shaposhnik,
• Dmitry A. Shaposhnik,
• Sergey Yu. Turishchev,
• Olga A. Chuvenkova,
• Stanislav V. Ryabtsev,
• Alexey A. Vasiliev,
• Xavier Vilanova,
• Francisco Hernandez-Ramirez and
• Joan R. Morante

Beilstein J. Nanotechnol. 2019, 10, 1380–1390, doi:10.3762/bjnano.10.136

• about chemical binding energy contributions in surface layers with complex phase compositions [43][44][45][46][47]. In the present study, we investigated core 1s states of oxygen atoms and core 3d states of tin atoms with high resolution provided by monochromatized synchrotron radiation. The spin–orbit

Highly ordered mesoporous silica film nanocomposites containing gold nanoparticles for the catalytic reduction of 4-nitrophenol

• Mohamad Azani Jalani,
• Leny Yuliati,
• Siew Ling Lee and
• Hendrik O. Lintang

Beilstein J. Nanotechnol. 2019, 10, 1368–1379, doi:10.3762/bjnano.10.135

• Mettler-Toledo TGA/SDTA851e device at a heating rate of 10 °C min−1. For the fabrication, the sol–gel solution was spin-coated on a quartz plate using a Laurell spin coater, model WS-400-6NPP-LITE. Calcination was carried out under atmospheric conditions using a Nabertherm model LE6/11 muffle furnace

• room temperature. For fabrication as thin films, 70 µL of the final sol–gel solution was spin-coated on a glass substrate to produce a colorless transparent thin film (around 0.5 mg of composite was successfully coated). It was followed by air-drying for a day at ambient temperature. Synthesis of

The effect of magneto-crystalline anisotropy on the properties of hard and soft magnetic ferrite nanoparticles

• Hajar Jalili,
• Bagher Aslibeiki,
• Ali Ghotbi Varzaneh and
• Volodymyr A. Chernenko

Beilstein J. Nanotechnol. 2019, 10, 1348–1359, doi:10.3762/bjnano.10.133

• the particles size. In fact, the high surface-to-volume ratio in the smaller nanoparticles leads to an increase of the surface effects such as spin disorder and dead layer on the surface, eventually resulting in a decrease of the magnetization. The thickness of the surface dead layer (t) equaling to t

Fabrication of phase masks from amorphous carbon thin films for electron-beam shaping

• Lukas Grünewald,
• Dagmar Gerthsen and
• Simon Hettler

Beilstein J. Nanotechnol. 2019, 10, 1290–1302, doi:10.3762/bjnano.10.128

• thickness profile showed considerable deviations from the ideal structure. Experimental For (positive) optical lithography we used a spin coater from POLOS to coat our wafers with a TI35ES resist (Microchemicals GmbH). Lithography masks for a mask aligner (MA6 by SÜSS MicroTec, light source with λ = 356 nm

Alloyed Pt₃M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction

• Stéphane Louisia,
• Yohann R. J. Thomas,
• Pierre Lecante,
• Marie Heitzmann,
• M. Rosa Axet,
• Pierre-André Jacques and
• Philippe Serp

Beilstein J. Nanotechnol. 2019, 10, 1251–1269, doi:10.3762/bjnano.10.125

• correspond to the oxidation of the sulfur species introduced during the doping during the purification step in H2SO4. As the S 2p peaks are typically presented in spin–orbit doublets of S 2p3/2 and S 2p1/2 (splitting magnitude ≈1.18 eV), four S 2p3/2 peaks representing sulfur bonding of FeS2 (≈162.5 eV), H–S

Molecular attachment to a microscope tip: inelastic tunneling, Kondo screening, and thermopower

• Rouzhaji Tuerhong,
• Mauro Boero and
• Jean-Pierre Bucher

Beilstein J. Nanotechnol. 2019, 10, 1243–1250, doi:10.3762/bjnano.10.124

• surfaces [13][14][15][16][17][18][19][20][21]. Low-temperature STM/STS is an ideal tool to study the Kondo effect, which manifests itself by a sharp zero-bias resonance in the conductance spectrum of a localized moment on a conducting substrate, due to the coherent spin-flip scattering between the

• localized spin and the conduction electrons of the substrate. Manganese phthalocyanine (MnPc) molecules adsorbed on noble-metal surfaces have been studied quite extensively by STM and Kondo behavior of MnPc is well documented [19][20][21]. However the electron transport through a single MnPc molecule

• on the Au(111) surface. The feature at zero bias in the spectrum of the flat-lying MnPc molecule of Figure 2b can be attributed to the Kondo resonance arising from the exchange interaction between the MnPc molecular spin and the itinerant conduction electrons of the Au(111) substrate [21]. The red

Angle-dependent structural colors in a nanoscale-grating photonic crystal fabricated by reverse nanoimprint technology

• Xu Zheng,
• Qing Wang,
• Jinjin Luan,
• Yao Li,
• Ning Wang and
• Rui Zhang

Beilstein J. Nanotechnol. 2019, 10, 1211–1216, doi:10.3762/bjnano.10.120

• solution was firstly poured onto the PC mould after degassing; (2) the PDMS film was fabricated through spin-coating at a speed of 500 rpm; (3) the photonic crystal was fabricated by reverse imprinting with the parameters of 0.5 MPa and 80 °C for 4 h to complete filling and cross-linking; (4) the photonic

Electroluminescence and current–voltage measurements of single-(In,Ga)N/GaN-nanowire light-emitting diodes in a nanowire ensemble

• David van Treeck,
• Johannes Ledig,
• Gregor Scholz,
• Jonas Lähnemann,
• Mattia Musolino,
• Abbes Tahraoui,
• Oliver Brandt,
• Andreas Waag,
• Henning Riechert and
• Lutz Geelhaar

Beilstein J. Nanotechnol. 2019, 10, 1177–1187, doi:10.3762/bjnano.10.117

• around 100 nm. Figure 1a shows a micrograph of the as-grown NW ensemble acquired in a Hitachi S-4800 field-emission SEM. The NW-ensemble LED we use as a reference for the EL and I–V characterizations in this study was processed from the same sample. The NW ensemble was planarized by spin coating using a

Tailoring the magnetic properties of cobalt ferrite nanoparticles using the polyol process

• Malek Bibani,
• Romain Breitwieser,
• Alex Aubert,
• Vincent Loyau,
• Silvana Mercone,
• Souad Ammar and
• Fayna Mammeri

Beilstein J. Nanotechnol. 2019, 10, 1166–1176, doi:10.3762/bjnano.10.116

• loss of ca. 30% of the magnetostrictive response. Such a result is quite reasonable since the magnetostriction of cobalt ferrites is induced by Co2+ ions in octahedral sites and the spin–orbit–lattice interaction with the distorted cubic crystal field. The other striking conclusion is that the larger

Influence of dielectric layer thickness and roughness on topographic effects in magnetic force microscopy

• Alexander Krivcov,
• Jasmin Ehrler,
• Marc Fuhrmann,
• Tanja Junkers and
• Hildegard Möbius

Beilstein J. Nanotechnol. 2019, 10, 1056–1064, doi:10.3762/bjnano.10.106

• a weak capacitive coupling between tip and dielectric layer. Figure 9 shows magnetic nanoparticles on a silicon substrate with a spin-coated dielectric layer of 380 nm thickness. The repulsive force of capacitive coupling is reduced significantly. However, an increase of the phase shift can still be

• paper to remove offset and slope of the measured data. The SPIONs with 10 ± 2 nm diameter with oleic acid as stabilizing ligand were used as received (Merck). A single-crystal silicon substrate with <100> orientation (Siegert Wafer) was cut in 2 cm2 squares. The dielectric layers were spin-coated on

• silicon substrates at 3000 rpm using a closed-system spin-coater with rotating lid (BLE). Bisphenol A-epichlorohydrin resin was used as dielectric layer. The resin is the hard component of AR-P 5910 resist (Allresist) with a dielectric constant of 3.1 [21]. The thickness was varied by different dilutions

Electronic and magnetic properties of doped black phosphorene with concentration dependence

• Ke Wang,
• Hai Wang,
• Min Zhang,
• Yan Liu and
• Wei Zhao

Beilstein J. Nanotechnol. 2019, 10, 993–1001, doi:10.3762/bjnano.10.100

• structures of Si- and S-doped phosphorene without spin polarization always show metallic states suggesting the bandgap is insensitive to the in-plane size of the supercell and the dopant content. However, the results are fairly different once the spin polarization is taken into account. The band structures

• for the Si-doped phosphorene with 2 × 2 × 1 supercell and a dopant content of 6.25%. The magnetic moment induced by 3p orbit–spin splitting increases with the in-plane size of the supercell, and the largest magnetic moment can be found in 4 × 4 × 1 and 5 × 5 × 1 supercells. These findings offer an

• supercell size due to decreasing deformation and dopant content. In the following, we discuss the magnetic and electronic properties of the stable doped phosphorenes induced by the deformation and impurity concentration. Band structure without spin polarization Before investigating the magnetic properties

Structural and optical properties of penicillamine-protected gold nanocluster fractions separated by sequential size-selective fractionation

• Xiupei Yang,
• Zhengli Yang,
• Fenglin Tang,
• Jing Xu,
• Maoxue Zhang and
• Martin M. F. Choi

Beilstein J. Nanotechnol. 2019, 10, 955–966, doi:10.3762/bjnano.10.96

• F36%). This is qualitatively consistent with rotational spin relaxation (T2); that is, the larger 3.0 nm average core size AuNCs (Figure 5, spectrum 3) are significantly slower than the smallest 1.2 nm average core size (Figure 5, spectrum 6) [26]. Further expansion of the packing density gradient

• (2p1/2). Each doublet has a peak area ratio of 2:1 and a splitting of ≈1.2 eV that is consistent with the results determined theoretically by the spin–orbit splitting effect. The sulfur binding energy for S 2p3/2 at 162 eV suggests that all the sulfur atoms are bound to gold as a thiolate species [34

Co-doped MnFe₂O₄ nanoparticles: magnetic anisotropy and interparticle interactions

• Bagher Aslibeiki,
• Parviz Kameli,
• Hadi Salamati,
• Giorgio Concas,
• Maria Salvador Fernandez,
• Alessandro Talone,
• Giuseppe Muscas and
• Davide Peddis

Beilstein J. Nanotechnol. 2019, 10, 856–865, doi:10.3762/bjnano.10.86

• radius, magnetic nanoparticles (NPs) organize themselves as a single magnetic domain, where all magnetic moments align in the same direction forming a “super spin” with a magnitude of 103–104 Bohr magnetons [12]. Due to the similarity of such superspins with atomic magnetic moments, even if with

• temperature Tg. Both the Vogel–Fulcher and power-law model fit our data well. Hence, to confirm possible spin glass dynamics, the investigation has been extended to non-equilibrium dynamics, i.e., memory effects. As a reference curve, a conventional ZFC magnetization vs temperature curve has been measured

• general increment of the anisotropy. The Co2+ ions produced a marked magneto-crystalline contribution to the anisotropy in the spinel structure, more than Mn2+ and Mn3+ ions. Indeed, the crystal field does not entirely quench its orbital magnetic moment, allowing for a spin–orbital coupling responsible

Periodic Co/Nb pseudo spin valve for cryogenic memory

• Nikolay Klenov,
• Yury Khaydukov,
• Sergey Bakurskiy,
• Roman Morari,
• Igor Soloviev,
• Vladimir Boian,
• Thomas Keller,
• Mikhail Kupriyanov,
• Anatoli Sidorenko and
• Bernhard Keimer

Beilstein J. Nanotechnol. 2019, 10, 833–839, doi:10.3762/bjnano.10.83

• lead to a significant enhancement of the critical current through the junction. To control the magnetic alignment we propose to use a periodic system whose unit cell is a pseudo spin valve of structure F1/s/F2/s where F1 and F2 are two magnetic layers having different coercive fields. In order to check

• alignment can be controlled with a magnetic field of only several tens of Oersted. Keywords: cryogenic computing; neutron scattering; spin valve; superconducting spintronics; Findings Superconductor digital devices have attracted growing attention due to their unique energy efficiency and performance [1

• magnetic state can be switched between parallel and antiparallel directions of the magnetization vectors of the F layers [7]. The use of a thin superconducting layer (s) as a spacer instead of an N layer may lead to enhancement of the spin-valve effect due to the proximity of the thick superconductor banks

Electronic properties of several two dimensional halides from ab initio calculations

• Mohamed Barhoumi,
• Ali Abboud,
• Lamjed Debbichi,
• Moncef Said,
• Torbjörn Björkman,
• Dario Rocca and
• Sébastien Lebègue

Beilstein J. Nanotechnol. 2019, 10, 823–832, doi:10.3762/bjnano.10.82

• monolayers CrOF, GaOF, InOF and LaOF are shown in Figure 5. From the DOS, it can be seen that the CrOF monolayer has a finite spin polarisation, and its magnetic moments are ordered ferromagnetically. Also, it is seen that the fluorine atoms contribute to the valence bands for all fluorides monolayers, while

• , we have investigated their electronic structure, and demonstrated their dynamical stability by computing their phonon spectra (see Supporting Information File 1). We have found that their electronic bandgap energies range between 3.0 and 7.5 eV and that CrOF is found to have a spin polarisation

Trapping polysulfide on two-dimensional molybdenum disulfide for Li–S batteries through phase selection with optimized binding

• Sha Dong,
• Xiaoli Sun and
• Zhiguo Wang

Beilstein J. Nanotechnol. 2019, 10, 774–780, doi:10.3762/bjnano.10.77

• Li–S batteries. Simulation Details The same simulation method and models of [26] were used in the present work. All spin-polarized DFT calculations were performed with the Vienna ab initio simulation package (VASP) [42] plane-wave simulations. Electron–ion interaction and electron exchange

The effect of translation on the binding energy for transition-metal porphyrines adsorbed on Ag(111) surface

• Luiza Buimaga-Iarinca and
• Cristian Morari

Beilstein J. Nanotechnol. 2019, 10, 706–717, doi:10.3762/bjnano.10.70

• tuning of spin states is possible by chemically substituting the central atom. Consequently, detailed investigations of the molecular interactions between TMPPs and metal surfaces has received extensive experimental [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23] and

• . Consequently, the spin-down states are occupied and the system has a non-zero magnetic moment. This effect is reversed for the deep orbital at −3.7 eV, which is localized (i.e., no coupling to energy bands of Ag) in the “i” states, while there is a clear interaction with the metallic substrate at the bridge

• d-orbitals (−0.5 eV for MnPP and −1.1 eV for VPP). The contributions to HOMO (and HOMO−1) are also relatively disperse and spin-dependent, as indicated in Supporting Information File 1, Table S4. The 3d orbitals of metal and the carbon atom orbitals play an important role here. For MnPP we found

Ultrathin hydrophobic films based on the metal organic framework UiO-66-COOH(Zr)

• Miguel A. Andrés,
• Clemence Sicard,
• Christian Serre,
• Olivier Roubeau and
• Ignacio Gascón

Beilstein J. Nanotechnol. 2019, 10, 654–665, doi:10.3762/bjnano.10.65

• homogeneity [11]. Therefore, several strategies have been used for the deposition of MOF films [12], including direct growth [13][14], electrochemical deposition [15], inkjet-printing [16], dip-coating [17], layer-by-layer [18][19][20], Langmuir–Blodgett [21][22], chemical vapor deposition [23], spin-coating

Coexisting spin and Rabi oscillations at intermediate time regimes in electron transport through a photon cavity

• Vidar Gudmundsson,
• Hallmann Gestsson,
• Nzar Rauf Abdullah,
• Chi-Shung Tang,
• Andrei Manolescu and
• Valeriu Moldoveanu

Beilstein J. Nanotechnol. 2019, 10, 606–616, doi:10.3762/bjnano.10.61

• the intermediate and transient regime coexist with slower non-equilibrium fluctuations in the occupation of states for opposite spin orientation. The interdot Rabi oscillation induces charge oscillations across the system and a phase difference between the transient source and drain currents. We point

• ]. The formation of very slow Rabi-like spin-flip transitions promoted by the interplay of tunneling and spin orbit interactions in a system of double quantum dots has been studied by Khomitsky et al. [14]. In earlier publications we have shown how a Rabi oscillation can be detected in the transport of

• oscillations of the transport current in time still reveal Rabi oscillations, but in a complex many-level system other oscillations can be present. In particular we find that for a weak Rabi splitting the even weaker Zeeman spin splitting caused by a small external magnetic field plays a role in the transport

Mo-doped boron nitride monolayer as a promising single-atom electrocatalyst for CO₂ conversion

• Qianyi Cui,
• Gangqiang Qin,
• Weihua Wang,
• Lixiang Sun,
• Aijun Du and
• Qiao Sun

Beilstein J. Nanotechnol. 2019, 10, 540–548, doi:10.3762/bjnano.10.55

• for experimental researchers in search of low cost and efficient SACs for CO2 reduction. Computational Methods All of the calculations were carried out by means of spin-polarized DFT with the DMol3 code [54][55]. The exchange and correlation potentials were calculated using the Perdew, Burke, and

Biocompatible organic–inorganic hybrid materials based on nucleobases and titanium developed by molecular layer deposition

• Leva Momtazi,
• Henrik H. Sønsteby and
• Ola Nilsen

Beilstein J. Nanotechnol. 2019, 10, 399–411, doi:10.3762/bjnano.10.39

• ]. The Ti 2p core level spectra are the same for all three sample types, here exemplified by thymine Ti 2p (Figure 12). The 457.8 eV binding energy of the Ti 2p3/2 peak point towards predominant Ti–O-type bonding. We confirmed this by the 5.8 eV split spin-orbit energy difference. In addition, we

• energies of O–Ti–N-type bonding [28]. Upon water exposure, titanium in the as-deposited films is observed only as TiO2. This is evident from the 458.5 eV binding energy for the 2p3/2 peak, in addition to the 5.7 eV spin-orbit splitting. Furthermore, the characteristic TiO2 XPS satellite peak is observed at