A nonenzymatic reduced graphene oxide-based nanosensor for parathion

• Sarani Sen,
• Anurag Roy,
• Ambarish Sanyal and
• Parukuttyamma Sujatha Devi

Beilstein J. Nanotechnol. 2022, 13, 730–744, doi:10.3762/bjnano.13.65

• spectra of the samples were recorded in the 1000–3500 cm−1 region with a resolution of 1 cm−1 using a Renishaw via a Reflex micro-Raman spectrometer with an argon ion (514.6 nm) laser. The X-ray photoemission spectroscopy (XPS) data were obtained from a PHI 5000 Versa probe II scanning XPS microprobe

• phase of GO and RGO was characterized by X-ray diffraction (XRD) using a X’pertpro MPD XRD (PAN analytical B.V., the Netherlands) with Cu Kα radiation (λ = 1.5406 Å). Scanning electron microscopy (SEM) of the modified electrode was conducted on a JEOLEVO® 18 special edition (model: ZEISS EVO-MA 10) at

Design and selection of peptides to block the SARS-CoV-2 receptor binding domain by molecular docking

• Kendra Ramirez-Acosta,
• Ivan A. Rosales-Fuerte,
• J. Eduardo Perez-Sanchez,
• Alfredo Nuñez-Rivera,
• Josue Juarez and
• Ruben D. Cadena-Nava

Beilstein J. Nanotechnol. 2022, 13, 699–711, doi:10.3762/bjnano.13.62

• , hydrogen bonds, and interactions of the selected ligand and protein docked complexes were analyzed by PyMOL (version 2.4) and LigPlot+ (version 2.2) [33][34]. Protein and ligand preparation for AutoDock Vina AutoDock Vina (1.1.2) software was employed for all docking experiments [21]. The X-ray diffraction

Nanoarchitectonics of the cathode to improve the reversibility of Li–O₂ batteries

• Hien Thi Thu Pham,
• Jonghyeok Yun,
• So Yeun Kim,
• Sang A Han,
• Jung Ho Kim,
• Jong-Won Lee and
• Min-Sik Park

Beilstein J. Nanotechnol. 2022, 13, 689–698, doi:10.3762/bjnano.13.61

• , and Zn1Co4 particles grown on CNT frameworks, respectively. Field-emission scanning electron microscopy (FESEM) observations confirmed that abundant rhombic dodecahedral ZnxCoy particles with different Zn/Co ratios were successfully integrated into the CNTs. Corresponding energy-dispersive X-ray

• the carbonization process. After the carbonization and chemical etching processes, the sizes of the ZnxCoy particles were slightly decreased due to the thermal evaporation of organic linkers and metal ions, maintaining free spaces in the particles. According to the X-ray diffraction (XRD) patterns of

• /CNT composites was further investigated by using X-ray photoelectron spectroscopy (XPS), as shown in Figure 4. The XPS spectra were carefully deconvoluted, based on the excitation of C 1s at the binding energy of 284.5 eV. According to the Co 2p spectra collected from the ZnxCoy–C/CNT composites

Sodium doping in brookite TiO₂ enhances its photocatalytic activity

• Boxiang Zhuang,
• Honglong Shi,
• Honglei Zhang and
• Zeqian Zhang

Beilstein J. Nanotechnol. 2022, 13, 599–609, doi:10.3762/bjnano.13.52

• bandgap values of these four samples. Structural phase diagram, chemical composition, and morphology The crystal structure of samples calcinated at 300–900 °C was characterized by powder X-ray diffraction (XRD), as shown in Figure 3a. The sample calcinated at 300 °C is a mixture of brookite (B) and

• activity of these samples. Quantitative phase analysis of X-ray diffraction patterns provides the structure phase diagram, as shown in Figure 3b. It indicates that the weight fraction of the brookite phase can be up to 82% when samples were calcinated at 500 °C. Note that the sample at 600 °C precipitated

• little due to the finite content of sodium in the brookite phase. The X-ray diffraction experiment suggests the existence of sodium in the samples. Next, we verified in which structure sodium is present. Figure 4a shows four typical morphologies of products observed via SEM. Samples calcinated at 300–500

A new method for obtaining the magnetic shape anisotropy directly from electron tomography images

• Cristian Radu,
• Ioana D. Vlaicu and
• Andrei C. Kuncser

Beilstein J. Nanotechnol. 2022, 13, 590–598, doi:10.3762/bjnano.13.51

• , X-ray diffraction, magnetometry [4], transmission/scanning electron imaging [5][6], small-angle scattering techniques [7], dynamic light scattering, laser diffraction [8][9], resonant mass measurement, and spatial filter velocimetry. Each of these has certain features (i.e., ease of access, ease of

• technique. The “translation” of the experimentally measured parameter to the parameter of interest (particle size in this case) is always accomplished by imperfect assumptions or extrapolations in the mathematical models. For example, in the case of X-ray diffraction, the mean crystal size is provided only

• microscopy (STEM) operation mode, using the high-angle annular dark-field (HAADF) detectors and an appropriate camera length. The TEM specimen was prepared by a standard powder method, using a 300 Mesh, lacey Carbon, Cu grid. X-ray diffraction (XRD) has been performed on MNPs using a Bruker D8 Advance

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

• deposited on a MoS2 crystal surface. Using near-edge X-ray absorption (NEXAFS), it was observed a strong dichroism in FePc thin films thicker than 4.5 nm. The strongest intensity of the N 1s→π* orbital transition at grazing incidence implies that the molecules are predominantly flat-lying with respect to

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• , respectively. For comparison, DSSCs based on Pt/FTO CE (DSSCs-Pt) were also fabricated under the same conditions. Characterizations of MoS2 thin films X-ray diffraction (XRD) analysis was carried out using a D8 Advance (Bruker, Germany) with a copper anode (λKα = 1.54 Å). Raman spectroscopy measurements were

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• separation [36][37][38][39][40][41][42]. The interactions between aromatic SAMs and electrons have been studied by X-ray photoelectron spectroscopy (XPS), near-edge X-ray-absorption fine-structure (NEXAFS) technique [43][44][45][46][47][48][49], infrared spectroscopy [43][50][51][52], high-resolution

• K and the substrate was held at room temperature. The chamber pressure during the evaporation process was ≈10−8 mbar and the evaporation time was ≈30 min. X-ray photoelectron spectroscopy was employed to monitor the existence of thiolates as well as physisorbed thiols. To remove physisorbed

Tubular glassy carbon microneedles with fullerene-like tips for biomedical applications

• Sharali Malik and
• George E. Kostakis

Beilstein J. Nanotechnol. 2022, 13, 455–461, doi:10.3762/bjnano.13.38

• the nanoarchitectonics concept of bottom-up creation of functional materials, we use methane rather than a polymer to form glassy carbon. Here we show that tubular glassy carbon microneedles with fullerene-like tips form when methane undergoes pyrolysis on a curved alumina surface. X-ray diffraction

• Raman spectroscopy (WiTec CRM200, laser excitation at 632.8 nm), scanning electron microscopy (SEM Leo 1530, with a spatial resolution of 1 nm at 20 kV and 3 nm at 1 kV, equipped with an energy-dispersive X-ray analysis system EDX INCA 400 from Oxford Instruments), and X-ray diffraction (STOE STADI-P

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

• Ali Javed,
• Felix Steinke,
• Stephan Wöhlbrandt,
• Hana Bunzen,
• Norbert Stock and
• Michael Tiemann

Beilstein J. Nanotechnol. 2022, 13, 437–443, doi:10.3762/bjnano.13.36

• h in dry air. This process is supposed to remove surface-adsorbed water, such as residues from the synthesis process or from exposure to humid conditions. Powder X-ray diffraction confirmed that this process does not affect the crystallinity of the two materials, and no phase transformation was

• within 12 h. The compounds were collected via filtration, dried under ambient conditions, and identified by powder X-ray diffraction. [Mg(H2O)2(H3L)]·H2O was obtained as colorless needles (240 mg, 36%) and [Pb2(HL)]·H2O as small colorless crystals (152 mg, 38%). PXRD data at a relative humidity of 90

A non-enzymatic electrochemical hydrogen peroxide sensor based on copper oxide nanostructures

• Irena Mihailova,
• Vjaceslavs Gerbreders,
• Marina Krasovska,
• Eriks Sledevskis,
• Valdis Mizers,
• Andrejs Bulanovs and
• Andrejs Ogurcovs

Beilstein J. Nanotechnol. 2022, 13, 424–436, doi:10.3762/bjnano.13.35

• spectroscopy and X-ray diffractometry. The resulting nanostructured samples were used for electrochemical determination of the H2O2 content in a 0.1 M NaOH buffer solution using cyclic voltammetry, differential pulse voltammetry, and i–t measurements. A good linear relationship between the peak current and the

• defined using an X-ray diffractometer (RIGAKU Smart Lab, Cu Kα [λ = 1.543 Å]) using parallel beam scanning geometry and an additional Ge(220) × 2 bounce monochromator. Electrochemical measurements The obtained wire samples were cut into 2 cm long pieces, and at one end were stripped to pure copper over 5

• amorphous background indicates a high degree of crystallinity of the obtained samples. The X-ray diffraction pattern shows a large number of crystallographic planes corresponding to the CuO (tenorite) lattice; however, the dominant orientation corresponds to the direction perpendicular to the (002) and (111

Selected properties of Al_xZn_yO thin films prepared by reactive pulsed magnetron sputtering using a two-element Zn/Al target

• Witold Posadowski,
• Artur Wiatrowski,
• Jarosław Domaradzki and
• Michał Mazur

Beilstein J. Nanotechnol. 2022, 13, 344–354, doi:10.3762/bjnano.13.29

• was performed using the WTheiss Hard- and Software Scout software, ver. 4.17. X-ray diffraction in the grazing incidence mode (GIXRD) was used to assess the structural properties of the deposited thin films. For this purpose, an Empyrean PANalytical X-ray diffractometer equipped with a PIXel3D

• detector and a Cu Kα X-ray source with a wavelength of 1.5406 Å was used. The diffraction patterns were collected with a step equal to 0.05°, a time per step of 5 s in the 2θ range of 30° to 80° and the incidence angle of the Cu Kα radiation was constant and equal to 3° relative to the sample surface. The

• morphology of the surface and cross section of the deposited thin films was investigated using a FEI Helios NanoLab 600i scanning electron microscope coupled with an energy-dispersive X-ray spectrometer (EDS) to determine the amount of Al and Zn in the deposited films (without taking the oxygen signal into

Interfacial nanoarchitectonics for ZIF-8 membranes with enhanced gas separation

• Season S. Chen,
• Zhen-Jie Yang,
• Chia-Hao Chang,
• Hoong-Uei Koh,
• Sameerah I. Al-Saeedi,
• Kuo-Lun Tung and
• Kevin C.-W. Wu

Beilstein J. Nanotechnol. 2022, 13, 313–324, doi:10.3762/bjnano.13.26

• membranes were synthesized according to the procedures described in the previous section with a reaction temperature of 80 °C and a reaction time of 12 h. Characterizations Pore size and porosity of α-Al2O3 disks were determined with a mercury porosimeter (AutoPore® IV 9520). Wide-angle patterns of powder X

• -ray diffraction were measured on a Rigaku Ultima IV with Cu Kα radiation (λ = 1.5418 Å) to check the crystallinity of the synthesized ZIF-8 thin films. The morphology of the supports, the free-standing thin films, and the supported membranes was observed by FE-SEM (NovaTM NanoSEM 230). The elemental

The effect of metal surface nanomorphology on the output performance of a TENG

• Yiru Wang,
• Xin Zhao,
• Yang Liu and
• Wenjun Zhou

Beilstein J. Nanotechnol. 2022, 13, 298–312, doi:10.3762/bjnano.13.25

• was measured using an oscilloscope DS1102E (produced by Rigol). The short-circuit current was tested using an electrochemical workstation (CH, model CHI660E). The crystal structure of the samples was analyzed using a Bruker D8 Advance X-ray diffractometer. A scanning electron microscope (Coxem, model

Investigation of a memory effect in a Au/(Ti–Cu)Ox-gradient thin film/TiAlV structure

• Damian Wojcieszak,
• Jarosław Domaradzki,
• Michał Mazur,
• Tomasz Kotwica and
• Danuta Kaczmarek

Beilstein J. Nanotechnol. 2022, 13, 265–273, doi:10.3762/bjnano.13.21

• resistive switching behavior. Results of optical, X-ray, and ultraviolet photoelectron spectroscopy measurements allowed us to elaborate the scheme of the bandgap alignment of the prepared thin films with respect to the Au and TiAlV electrical contacts. Detailed structure and elemental profile

• of the current-to-voltage measurements. On the basis of the performed investigations, we suggest that the conducting filament switching is the most probable mechanism. This is supported by investigations of structure and surface properties using X-ray methods, UV photoelectron spectroscopy, and cross

• Lite). Additionally, circular 1 mm gold pads were evaporated on top of the prepared structure to allow for electrical characterization. The average material composition of the gradient thin film was determined using X-ray microanalysis employing an EDAX Genesis energy-dispersive spectrometer (EDS) as

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• -spinning technique and provided by the Physics Institute at the University of Basel (Switzerland). The X-ray diffraction of Cu Kα radiation (XRD) verified the amorphous nature of the ribbons. All friction experiments were conducted at room temperature in 0.2 M phosphate buffer (Na2HPO4 + NaH2PO4, pH ≈ 7

Surfactant-free syntheses and pair distribution function analysis of osmium nanoparticles

• Mikkel Juelsholt,
• Jonathan Quinson,
• Emil T. S. Kjær,
• Baiyu Wang,
• Rebecca Pittkowski,
• Susan R. Cooper,
• Tiffany L. Kinnibrugh,
• Søren B. Simonsen,
• Luise Theil Kuhn,
• María Escudero-Escribano and
• Kirsten M. Ø. Jensen

Beilstein J. Nanotechnol. 2022, 13, 230–235, doi:10.3762/bjnano.13.17

• X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, 9700 S Cass Ave, Lemont, IL 60439, USA Department of Energy Conversion and Storage, Technical University of Denmark, Fysikvej Bldg. 310, Lyngby, DK-2800 Kgs., Denmark 10.3762/bjnano.13.17 Abstract A surfactant

• opposed to the case of Pt or Ir NPs. The robustness of the synthesis for a precursor concentration up to 100 mM allows for the performance of X-ray total scattering with pair distribution function (PDF) analysis, which shows that 1–2 nm hexagonal close packed (hcp) NPs are formed from chain-like [OsOxCly

• using small angle X-ray scattering (SAXS) analysis as presented in Figure S22 and Table S2, Supporting Information File 1. However, our experiment showed that either methanol or ethanol is needed for the reaction to proceed playing the role of reducing agents, as no product is formed when the synthesis

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• . Instrumentation X-ray photoelectron spectroscopy (XPS) measurements were conducted with a PHI5000 VersaProbe II using monochromatic Al Kα radiation (1.486 keV). Survey scans (187.5 eV pass energy, 0.8 eV/step) and core level spectra (23.5 eV pass energy, 0.1 eV/step) of the elements C 1s, N 1s, O 1s, S 1s, Ru 3d

Piezoelectric nanogenerator for bio-mechanical strain measurement

• Zafar Javed,
• Lybah Rafiq,
• Muhammad Anwaar Nazeer,
• Saqib Siddiqui,
• Muhammad Babar Ramzan,
• Muhammad Qamar Khan and
• Muhammad Salman Naeem

Beilstein J. Nanotechnol. 2022, 13, 192–200, doi:10.3762/bjnano.13.14

• fluoride (PVDF) and other piezoelectric polymers are used in the form of fibers, filaments, and composites. In this research, PVDF nanofibers were developed and integrated onto a knitted fabric to fabricate a piezoelectric device for human body angle monitoring. Scanning electron microscopy and X-ray

• characterized through scanning electron microscopy (SEM) and X-ray diffraction (XRD) to determine morphology and crystalline structure, respectively. Sensor development, its embedding, and testing The prepared PVDF nanofibrous mesh was folded into a square shape (4 cm2) with 2 mm thickness for sensor

• similar peaks with the exception of unique peaks that are used to identify the crystalline structure. X-ray diffractograms were used to analyze the crystalline structure [39] of prepared PVDF nanofibrous meshs obtained from different solutions to identify the beta phase in the fibers, which is primarily

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• ®. Energy-dispersive X-ray analyses was done with a ZEISS Crossbeam system with an integrated Oxford EDX detector. Deposits for EDX analysis were prepared on a 100 nm thick polycrystalline gold substrate on a 4 inch silicon wafer, purchased from Georg Albert PVD. The Au-based substrate was chosen because of

• scanning area of 1 μm2, resulting in a 230 nm thick pad. Energy-dispersive X-ray analysis was carried out at 5 keV beam energy. Mo(CO)6 was purchased from Merck, Darmstadt, Germany, with stated purity of 98% and used as delivered. Results and Discussion Dissociative electron attachment Figure 1 shows the

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• experimental challenge toward elucidating the dynamic processes in oxidation. For example, the formation processes of iron oxide nanoparticles have been studied in detail using state-of-the-art X-ray scattering methods [4]. As a complementary method, variable-temperature scanning tunneling microscopy (VT-STM

• the Si 2p and O 1s core levels in detail during thermal oxidation using high-resolution X-ray photoelectron spectroscopy with synchrotron radiation [7][8][9]. Using a state-of-the-art wet oxidation procedure, we also reduced the interface trap density (Dit) at the SiO2/Si interface on the Si(113

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• reports still proposed its photocatalytic behaviors partly based on •O2− species via the combination of experimental physicochemical analyses, such as electron spin resonance (ESR) spectroscopy, active species trapping experiments, valence band X-ray photoelectron spectroscopy (XPS), and diffuse

Theranostic potential of self-luminescent branched polyethyleneimine-coated superparamagnetic iron oxide nanoparticles

• Rouhollah Khodadust,
• Ozlem Unal and
• Havva Yagci Acar

Beilstein J. Nanotechnol. 2022, 13, 82–95, doi:10.3762/bjnano.13.6

• , holds great potential for effective gene/drug delivery coupled with dual-mode imaging. a) TEM image of SPION@bPEI. b) AFM micrograph image of SPION@bPEI (magnetic mode). c) X-ray diffraction pattern of SPION@bPEI prepared via the in situ coating method. Since the presence of the polymer prevented the

Influence of magnetic domain walls on all-optical magnetic toggle switching in a ferrimagnetic GdFe film

• Rahil Hosseinifar,
• Evangelos Golias,
• Ivar Kumberg,
• Quentin Guillet,
• Karl Frischmuth,
• Sangeeta Thakur,
• Mario Fix,
• Manfred Albrecht,
• Florian Kronast and
• Wolfgang Kuch

Beilstein J. Nanotechnol. 2022, 13, 74–81, doi:10.3762/bjnano.13.5

• film with out-of-plane easy axis of magnetization by X-ray magnetic circular dichroism photoelectron emission microscopy. Individual linearly polarized laser pulses of 800 nm wavelength and 100 fs duration above a certain threshold fluence reverse the sample magnetization, independent of the

• individual ultrashort focused laser pulses has been reported [21]. In this paper, we investigate nondeterministic all-optical toggle switching of a Gd26Fe74 film with out-of-plane easy axis of magnetization by magnetic imaging using photoemission electron microscopy (PEEM) with X-ray magnetic circular

• Information File 1 for temperature-dependent magnetization loops. Magnetic domains were resolved using the photoemission electron microscope (PEEM) at the UE49-PGM SPEEM beamline of BESSY II. The acceleration potential between the sample and the first objective lens of the PEEM was set to 15 keV. X-ray

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• energy-dispersive X-ray spectroscopy (S(T)EM-EDS). Typical examples of the formation of compositional gradients on coated surfaces can be found, for example, in [54][55]. Further control on film chemistry is obtained through reactive (magnetron) sputtering. In this case, the metallic target is sputtered