Enhancement of the piezoelectric coefficient in PVDF-TrFe/CoFe₂O₄ nanocomposites through DC magnetic poling

• Marco Fortunato,
• Alessio Tamburrano,
• Maria Paola Bracciale,
• Maria Laura Santarelli and
• Maria Sabrina Sarto

Beilstein J. Nanotechnol. 2021, 12, 1262–1270, doi:10.3762/bjnano.12.93

• were recorded at RT using a FTIR spectrometer (Vertex 70 by Bruker Optics GmbH) equipped with a single reflection diamond ATR cell. The analyses were performed in the typical mid-IR spectral range (4000–400 cm−1) at a resolution of 2 cm−1 and with 256 scans. The piezoelectric coefficients were measured

Fate and transformation of silver nanoparticles in different biological conditions

• Barbara Pem,
• Marija Ćurlin,
• Darija Domazet Jurašin,
• Valerije Vrček,
• Rinea Barbir,
• Vedran Micek,
• Raluca M. Fratila,
• Jesus M. de la Fuente and
• Ivana Vinković Vrček

Beilstein J. Nanotechnol. 2021, 12, 665–679, doi:10.3762/bjnano.12.53

• diamond knife (Ultra 45; Diatome, Biel, Switzerland), they were contrasted using uranyl acetate and lead citrate. The TEM images were made in a microscope (902A; Carl Zeiss Meditec AG, Jena, Germany) operating in bright-field mode with an acceleration voltage of 80 kV and a Canon PowerShot S50 camera was

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• increasing dose the ferroelectric domains were gradually destroyed [57]. Optical properties In early work concerned with tuning optical properties with the HIM, arrays of nitrogen-vacancy centers were fabricated in diamond [58][59]. Starting with a diamond sample that already contained substitutional

• properties of helium ion-irradiated silicon nanopillars have since been investigated as well, observing a softening behavior upon amorphization and swelling [89]. Helium ion irradiation of single-crystal diamond nanopillars has revealed an orientation dependence of the irradiation damage and associated

• square frame and annulus patterns, respectively, with increasing dose from the perimeter to the center (Figure 3e, bottom). This tumefaction technique has the potential to be used to fabricate molds for nanoimprint lithography. In a recent study, localized helium ion implantation into diamond

Properties of graphene deposited on GaN nanowires: influence of nanowire roughness, self-induced nanogating and defects

• Jakub Kierdaszuk,
• Piotr Kaźmierczak,
• Justyna Grzonka,
• Aleksandra Krajewska,
• Aleksandra Przewłoka,
• Wawrzyniec Kaszub,
• Zbigniew R. Zytkiewicz,
• Marta Sobanska,
• Maria Kamińska,
• Andrzej Wysmołek and
• Aneta Drabińska

Beilstein J. Nanotechnol. 2021, 12, 566–577, doi:10.3762/bjnano.12.47

• was partially supported by the Ministry of Science and Higher Education in 2015–2019 as a research grant “Diamond Grant” (n°. DI2014 015744). The GaN nanowires were grown within the Polish National Science Centre (grants n°. UMO-2016/21/N/ST3/03381 and 2016/23/B/ST7/03745). This work was supported by

The preparation temperature influences the physicochemical nature and activity of nanoceria

• Robert A. Yokel,
• Wendel Wohlleben,
• Johannes Georg Keller,
• Matthew L. Hancock,
• Jason M. Unrine,
• D. Allan Butterfield and
• Eric A. Grulke

Beilstein J. Nanotechnol. 2021, 12, 525–540, doi:10.3762/bjnano.12.43

• 900 °C at 10 °C/min. Fourier-transform infrared spectroscopy (FTIR) (Nicolet 6700 FTIR with a diamond ATR crystal) was used to detect organic functional groups on the ENM surface. Thirty-two scans were completed. Nanoceria calcination Two samples (6.5 and 6.7 mg) of solvothermally synthesized

The patterning toolbox FIB-o-mat: Exploiting the full potential of focused helium ions for nanofabrication

• Victor Deinhart,
• Lisa-Marie Kern,
• Jan N. Kirchhof,
• Sabrina Juergensen,
• Joris Sturm,
• Enno Krauss,
• Thorsten Feichtner,
• Sviatoslav Kovalchuk,
• Michael Schneider,
• Dieter Engel,
• Bastian Pfau,
• Bert Hecht,
• Kirill I. Bolotin,
• Stephanie Reich and
• Katja Höflich

Beilstein J. Nanotechnol. 2021, 12, 304–318, doi:10.3762/bjnano.12.25

• standard use cases and lacks the flexibility to realize ultimate fidelity and robust large-area machining. So far, several patterning tools were developed, some of them only for specific photonic components, such as solid immersion lenses from diamond [8] or hole arrays and groove waveguides [9]. Others

Determination of elastic moduli of elastic–plastic microspherical materials using nanoindentation simulation without mechanical polishing

• Hongzhou Li and
• Jialian Chen

Beilstein J. Nanotechnol. 2021, 12, 213–221, doi:10.3762/bjnano.12.17

• –displacement data alone. This avoids the need to measure the area of indentation by imaging and facilitates the measurement of properties at the sub-micrometer scale. During nanoindentation, a diamond indenter with a geometry known to high precision is pressed into the surface of the specimen with increasing

Mapping the local dielectric constant of a biological nanostructured system

• Wescley Walison Valeriano,
• Rodrigo Ribeiro Andrade,
• Juan Pablo Vasco,
• Angelo Malachias,
• Bernardo Ruegger Almeida Neves,
• Paulo Sergio Soares Guimarães and
• Wagner Nunes Rodrigues

Beilstein J. Nanotechnol. 2021, 12, 139–150, doi:10.3762/bjnano.12.11

• , resulting in an orientation of the wing fragment perpendicular to the cutting plane. Sections 40 nm thick of the apex wedge were cut using a diamond knife and placed on 10 mm × 10 mm Au/Cr (60 nm/20 nm)-coated silicon wafer pieces. A conductive substrate surface is necessary for the proposed εr

Mapping of integrated PIN diodes with a 3D architecture by scanning microwave impedance microscopy and dynamic spectroscopy

• Rosine Coq Germanicus,
• Peter De Wolf,
• Florent Lallemand,
• Catherine Bunel,
• Serge Bardy,
• Hugues Murray and
• Ulrike Lüders

Beilstein J. Nanotechnol. 2020, 11, 1764–1775, doi:10.3762/bjnano.11.159

• , a body-centred tetragonal configuration (β-Sn, also called Si-II) must be formed from the initial cubic diamond silicon (Si-I) in the highly stressed region just below the tip [12]. Furthermore, in air and under ambient conditions, due to the interaction between the tip and the surface, the probe

• was hand-polished down to a roughness of a few nanometres with diamond-based lapping films with decreasing granularity. In the following section, the local electrical properties of all layers in the cross section of the PIN diode are analysed. In order to evaluate the impact of the applied VDC bias

Fabrication of nano/microstructures for SERS substrates using an electrochemical method

• Jingran Zhang,
• Tianqi Jia,
• Xiaoping Li,
• Junjie Yang,
• Zhengkai Li,
• Guangfeng Shi,
• Xinming Zhang and
• Zuobin Wang

Beilstein J. Nanotechnol. 2020, 11, 1568–1576, doi:10.3762/bjnano.11.139

•  3e. Structurally similar nanopores can be machined by using mechanical machining methods. For instance, micro/nanostructures can be fabricated using diamond turning, such as single point diamond turning or diamond fly cutting. For example, sinusoidal grid surfaces can be formed with the aid of fast

• tool servos. Nanopores with depths of 6.33 µm can be generated by using diamond turning [44]. Raman intensity of R6G molecules on the arrayed nanopores The PEO treatment time and the thickness of the Au film can have a significant impact on the performance of the SERS substrate. The performance was

Electrokinetic characterization of synthetic protein nanoparticles

• Daniel F. Quevedo,
• Cody J. Lentz,
• Adriana Coll de Peña,
• Yazmin Hernandez,
• Nahal Habibi,
• Rikako Miki,
• Joerg Lahann and
• Blanca H. Lapizco-Encinas

Beilstein J. Nanotechnol. 2020, 11, 1556–1567, doi:10.3762/bjnano.11.138

• positive and negative DEPs [28][45][46][47]. Other studies have employed triangular insulating posts with nanoscale gaps [48], cylindrical insulating structures to enrich BSA particles [49], or diamond-shaped posts to separate PEGylated ribonuclease A from non-PEGylated molecules [50]. The potential

Transient coating of γ-Fe₂O₃ nanoparticles with glutamate for its delivery to and removal from brain nerve terminals

• Konstantin Paliienko,
• Artem Pastukhov,
• Michal Babič,
• Daniel Horák,
• Olga Vasylchenko and
• Tatiana Borisova

Beilstein J. Nanotechnol. 2020, 11, 1381–1393, doi:10.3762/bjnano.11.122

• software for graphic-mathematical modeling, that is, a demonstration version of Diamond 4.5.3 (Crystal Impact GbR©) for the simulation of nanoparticle polycrystals, a demonstration version of LeadIT 2.3.2 (BioSolveIT GmbH©) to find the most probable binding sites between protein and nanoparticles, a free

Impact of fluorination on interface energetics and growth of pentacene on Ag(111)

• Qi Wang,
• Meng-Ting Chen,
• Antoni Franco-Cañellas,
• Bin Shen,
• Thomas Geiger,
• Holger F. Bettinger,
• Frank Schreiber,
• Ingo Salzmann,
• Alexander Gerlach and
• Steffen Duhm

Beilstein J. Nanotechnol. 2020, 11, 1361–1370, doi:10.3762/bjnano.11.120

• close to monolayer coverage. The high-resolution XPS (HR-XPS) and normal-incidence XSW (NIXSW) experiments were performed at beamline I09 at Diamond Light Source (DLS, UK) using both the soft (110–1100 eV) and hard (2.1–18 keV) X-ray beams [104][105]. Sample preparation and measurements were performed

• , C 1s and F 1s core levels, full UPS survey spectra, XRD measurement and analysis of PFP on Ag(111) and a set of XSW measurements. Supporting Information File 158: Additional experimental data. Acknowledgements The authors thank the Diamond Light Source for access to beamline I09, and the staff, in

An atomic force microscope integrated with a helium ion microscope for correlative nanoscale characterization

• Santiago H. Andany,
• Gregor Hlawacek,
• Stefan Hummel,
• Charlène Brillard,
• Mustafa Kangül and
• Georg E. Fantner

Beilstein J. Nanotechnol. 2020, 11, 1272–1279, doi:10.3762/bjnano.11.111

• probes with boron-doped 1 kΩ sensing elements, connected in a Wheatstone bridge configuration with aluminum tracks [20][21] and with single crystal diamond (SCD) tips that are commercially available (SCL-SensorTech Fabrication GMBH, Vienna, Austria). The SCD tips (tip radius below 15 nm, height 12–16 µm

Gas sorption porosimetry for the evaluation of hard carbons as anodes for Li- and Na-ion batteries

• Yuko Matsukawa,
• Fabian Linsenmann,
• Maximilian A. Plass,
• George Hasegawa,
• Katsuro Hayashi and
• Tim-Patrick Fellinger

Beilstein J. Nanotechnol. 2020, 11, 1217–1229, doi:10.3762/bjnano.11.106

• isotherms (a, d), calculated pore size distributions (b, e), and cumulative pore volumes (c, f) for CO2 (a–c) and for H2O (d–f) adsorption (STP-standard pressure). Capacities (reversible: red circle, irreversible: blue diamond, Y-axis) and Coulombic efficiencies (gray asterisk, R-axis) against SSA obtained

• from Kr (a, c) and CO2 (b,d) adsorption isotherms of lithium (a, b) and sodium (c, d). Capacities (reversible: red circle, irreversible: blue diamond, Y-axis) and Coulombic efficiencies (gray asterisk, R-axis) against cumulative pore volumes (obtained from CO2 adsorption by Monte Carlo method (a, c

Revealing the local crystallinity of single silicon core–shell nanowires using tip-enhanced Raman spectroscopy

• Marius van den Berg,
• Ardeshir Moeinian,
• Arne Kobald,
• Yu-Ting Chen,
• Anke Horneber,
• Steffen Strehle,
• Alfred J. Meixner and
• Dai Zhang

Beilstein J. Nanotechnol. 2020, 11, 1147–1156, doi:10.3762/bjnano.11.99

• of Si at about 520 cm−1 with the equation: In c-Si with cubic diamond structure, ΔΘ has a value of 0°, whereas in a-Si films ΔΘ was experimentally determined to be in the range of 7.7° ≤ ΔΘ ≤ 10.5°. In our experiments we calculated ΔΘavg,n-f = 9.2° and ΔΘavg,conf = 8.3° based on the near-field and

Light–matter interactions in two-dimensional layered WSe₂ for gauging evolution of phonon dynamics

• Avra S. Bandyopadhyay,
• Chandan Biswas and
• Anupama B. Kaul

Beilstein J. Nanotechnol. 2020, 11, 782–797, doi:10.3762/bjnano.11.63

• which was originally formulated for diamond [55], and is also applicable here, as given by Equation 7 below, where ω0 is the frequency of vibration of the and A1g modes at T = 0 K and χT is the first-order Raman temperature coefficient calculated for both the and A1g modes (just as in the computation

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• , quantum computation, and quantum sensing. Their integration in photonic structures such as photonic crystals, microdisks, microring resonators, and nanopillars is essential for their deployment in quantum technologies. While there are currently only two material platforms (diamond and silicon carbide

• spin–photon interfaces for remote spin–photon entanglement with available nuclear spins as ancilla qubits for quantum memory [11][12]. These include the nitrogen-vacancy (NV) center in diamond [13], the silicon-vacancy center in diamond [14][15][16], the germanium-vacancy center in diamond [17], the

• in diamond is currently the preferred platform for implementing quantum sensing and quantum computing approaches, the recent emergence of other interesting color centers in diamond itself [16][30][31] and in other materials indicates that indeed NV is not optimal for many applications, neither it is

Quantitative determination of the interaction potential between two surfaces using frequency-modulated atomic force microscopy

• Nicholas Chan,
• Carrie Lin,
• Tevis Jacobs,
• Robert W. Carpick and
• Philip Egberts

Beilstein J. Nanotechnol. 2020, 11, 729–739, doi:10.3762/bjnano.11.60

• then compared to experimental results. The method is demonstrated here using a silicon AFM probe with its native oxide and a diamond sample. Assuming the 6-12 Lennard-Jones potential form, best-fit values for the work of adhesion (Wadh) and range of adhesion (z0) parameters were determined to be 80

• separation distances. This methodology represents the first experimental technique in which material interaction potential parameters were verified over a range of tip–sample separation distances for a tip apex of arbitrary geometry. Keywords: adhesion; atomic force microscopy; diamond; frequency-modulated

• geometries. In this manuscript, frequency modulation (FM) AFM was used to determine the interaction forces between two irregularly shaped solids: the apex of a silicon AFM probe with its native oxide and a slightly roughened, nominally flat single-crystal diamond surface. This substrate was chosen due to its

Stochastic excitation for high-resolution atomic force acoustic microscopy imaging: a system theory approach

• Edgar Cruz Valeriano,
• José Juan Gervacio Arciniega,
• Christian Iván Enriquez Flores,
• Susana Meraz Dávila,
• Joel Moreno Palmerin,
• Martín Adelaido Hernández Landaverde,
• Yuri Lizbeth Chipatecua Godoy,
• Aime Margarita Gutiérrez Peralta,
• Rafael Ramírez Bon and
• José Martín Yañez Limón

Beilstein J. Nanotechnol. 2020, 11, 703–716, doi:10.3762/bjnano.11.58

• carried out using a NI PXIe-1073 device, which includes a NI 7961R FPGA, a NI 5762 digitizer at 200MS/s/ch and a PXI 6363DAQ from National Instruments. The white-noise signal is generated by a function waveform generator HP/Agilent 33120A. BudgetSensors diamond-coated silicon probes, 450 µm long with a

• compared with the fitted experimental cantilever used in this experiment. The comparison can be seen in Table 2. A commercial BudgetSensors diamond-coated silicon cantilever with 450 µm length and a spring constant of 0.2 N/m was considered. The first value was obtained from the manufacturer data, while

• observed dynamic behavior for a free AFM cantilever. Modeled values of klever. A BudgetSensors diamond-coated silicon cantilever with 450 μm length and a spring constant of 0.2 N/m was used in this experiment. Funding The work was supported by the Projects LIDTRA LN-295261 and LIDTRA LN2015-254119 of

Small protein sequences can induce cellular uptake of complex nanohybrids

• Jan-Philip Merkl,
• Malak Safi,
• Christian Schmidtke,
• Fadi Aldeek,
• Johannes Ostermann,
• Tatiana Domitrovic,
• Sebastian Gärtner,
• John E. Johnson,
• Horst Weller and
• Hedi Mattoussi

Beilstein J. Nanotechnol. 2019, 10, 2477–2482, doi:10.3762/bjnano.10.238

• macrophages to these hybrid materials combined with an improvement in their in vivo tumour accumulation [6]. Weil and co-workers described the use of multimodal platforms, made of diamond dots combined with gold nanoparticles, as imaging probes of live cell cultures [7]. We have recently characterized a

pH-Controlled fluorescence switching in water-dispersed polymer brushes grafted to modified boron nitride nanotubes for cellular imaging

• Saban Kalay,
• Yurij Stetsyshyn,
• Volodymyr Donchak,
• Khrystyna Harhay,
• Ostap Lishchynskyi,
• Halyna Ohar,
• Yuriy Panchenko,
• Stanislav Voronov and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2019, 10, 2428–2439, doi:10.3762/bjnano.10.233

• heated from 30.00 to 600.00 °C at 10 °C/min. Fourier transform infrared spectroscopy (FTIR) FTIR spectra were recorded on a NICOLET iS50 FTIR spectrometer (Thermo Scientific, USA), equipped with a iS50 ATR multirange, diamond sampling station. The sample powders were either placed on diamond crystal or

Multiwalled carbon nanotube based aromatic volatile organic compound sensor: sensitivity enhancement through 1-hexadecanethiol functionalisation

• Nadra Bohli,
• Meryem Belkilani,
• Juan Casanova-Chafer,
• Eduard Llobet and
• Adnane Abdelghani

Beilstein J. Nanotechnol. 2019, 10, 2364–2373, doi:10.3762/bjnano.10.227

• 1011), operating at 100 kV. An Alpha FTIR spectrometer (Bruker, France) equipped with an ATR platinum crystal diamond module was used, in absorbance mode, to obtain the infrared spectra of the gold-decorated MWCNTs before and after the deposition of the SAM monolayer. This technique provides useful

Nitrogen-vacancy centers in diamond for nanoscale magnetic resonance imaging applications

• Alberto Boretti,
• Lorenzo Rosa,
• Jonathan Blackledge and
• Stefania Castelletto

Beilstein J. Nanotechnol. 2019, 10, 2128–2151, doi:10.3762/bjnano.10.207

• diamond with unique properties for use in ultra-sensitive, high-resolution magnetometry. One of the most interesting and challenging applications is nanoscale magnetic resonance imaging (nano-MRI). While many review papers have covered other NV centers in diamond applications, there is no survey targeting

• the specific development of nano-MRI devices based on NV centers in diamond. Several different nano-MRI methods based on NV centers have been proposed with the goal of improving the spatial and temporal resolution, but without any coordinated effort. After summarizing the main NV magnetic imaging

• ) centers in diamond as sensors. The NV centers in diamond are one example of a sensor for nano-MRI. Optical measurements with NV centers combined with electron paramagnetic resonance (EPR) were established at the end of the 1970s [6], although it was only in 1991 that EPR was also observed without

Magnetic properties of biofunctionalized iron oxide nanoparticles as magnetic resonance imaging contrast agents

• Natalia E. Gervits,
• Andrey A. Gippius,
• Alexey V. Tkachev,
• Evgeniy I. Demikhov,
• Sergey S. Starchikov,
• Igor S. Lyubutin,
• Alexander L. Vasiliev,
• Vladimir P. Chekhonin,
• Maxim A. Abakumov,
• Alevtina S. Semkina and
• Alexander G. Mazhuga

Beilstein J. Nanotechnol. 2019, 10, 1964–1972, doi:10.3762/bjnano.10.193

• ) indicates that the iron oxide nanoparticles adopted a diamond-type cubic crystal lattice structure (space group ) that is typical for magnetite (Fe3O4) [15] and/or disordered maghemite (γ-Fe2O3) [16]. The HRTEM images of several selected particles in both samples were analyzed by direct measurements of the