Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• Province, Vietnam 10.3762/bjnano.13.127 Abstract TiO2 nanotube arrays (TNAs) have been studied for photoelectrochemical (PEC) water splitting. However, there are two major barriers of TNAs, including a low photo-response and the fast charge carrier recombination in TNAs, leading to poor photocatalytic

• . The stability of the MoS2/TNAs heterojunction is higher than that of g-C3N4/TNAs. Keywords: band structure; g-C3N4/TiO2; MoS2/TiO2; photoelectrochemical; water splitting; Introduction Hydrogen energy has become a target pursued in the energy development strategies of many countries and regions

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• -603103, Tamil Nadu, India 10.3762/bjnano.13.125 Abstract A TiO2@MWCNTs (multi-wall carbon nanotubes) nanocomposite photoanode is prepared for photoelectrochemical water splitting in this study. The physical and photoelectrochemical properties of the photoanode are characterized using field emission

• cyclic voltammograms show that incorporating TiO2 with the MWCNTs leads to a decrease in the electrical double layer, thereby facilitating the electron transfer rate in the TiO2@MWCNTs electrode. Moreover, the current density of the photoelectrochemical electrode formed by TiO2@MWCNTs under solar

• . The average STH conversion efficiency of the TiO2@MWCNTs electrode under solar exposure from 6 AM to 5 PM is 11.1%, 8.88 times higher than that of a TiO2 electrode. The findings suggested TiO2@MWCNTs is a feasible nanomaterial to fabricate the photoanode using photoelectrochemical water splitting

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• utilizing an EMX micro A200-9.5/12/S/W, Bruker Biospin, Germany. Photoelectrochemical study The photoelectrochemical properties of the studied materials were evaluated through a CHI 650 electrochemical workstation comprising a three-electrode system with Pt and Ag/AgCl as counter and reference electrodes

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• (λ > 420 nm), photoelectrochemical studies demonstrated that the RhB photodegradation effectiveness and photocurrent density of the BiIO4/Bi2MoO6 hybrid composite is much higher than that of the pure components. Because of the successful construction of the BiIO4/Bi2MoO6 hybrid, the photocatalytic

Hierarchical Bi₂WO₆/TiO₂-nanotube composites derived from natural cellulose for visible-light photocatalytic treatment of pollutants

• Zehao Lin,
• Zhan Yang and
• Jianguo Huang

Beilstein J. Nanotechnol. 2022, 13, 745–762, doi:10.3762/bjnano.13.66

• , respectively. Therefore, the EVB and ECB values of the TiO2 semiconductor are calculated to be 2.87 and −0.25 eV, and those of the Bi2WO6 semiconductor are 2.91 and 0.51 eV, respectively. Based on the results of the above photoelectrochemical characterizations and the scavenger experiments of the active

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• MoS2-based CEs was studied regarding the I3−/I− redox couple (prepared with 10 mM I2, 20 mM KI, and 0.1 M LiClO4 in acetonitrile) and compared to that of a FTO/Pt CE by CV. DSSC characterizations Photoelectrochemical measurements were performed using an Oriel Sol1A class ABB solar simulator (Oriel

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• combined with metal nanoparticles, resulting in enhanced photoactivity of Au-decorated ZnO nanocrystals for photoelectrochemical water splitting [9], improved photodetection performance of ZnO nanofibers decorated with Au NPs [10], or enhanced photocatalytic activity of ZnO doped with Au NPs [11]. Moreover

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• nanostructures such as nanotubes and nanowires have been utilized in photoelectrochemical sensing for the rapid and precise identification of biological analytes at low concentrations, useful for clinical diagnosis. These nanostructures have been employed for sensing humidity, oxygen, and hydrogen, inclusive of

• shell for the selective and rapid capture of peptides from human serum and urine samples [17]. Many studies have been published on using TiO2 nanotubes as photoelectrochemical glucose sensors for health purposes [18][19][20]. The present review focuses on contemporary research of TiO2 nanoparticles and

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core–shell nanostructures for photocatalytic activity

• Bridget K. Mutuma,
• Xiluva Mathebula,
• Isaac Nongwe,
• Bonakele P. Mtolo,
• Boitumelo J. Matsoso,
• Rudolph Erasmus,
• Zikhona Tetana and
• Neil J. Coville

Beilstein J. Nanotechnol. 2020, 11, 1834–1846, doi:10.3762/bjnano.11.165

• investigation of their photoelectrochemical properties has shown that they are semiconducting materials with a possible photoactivity within the visible region [39]. Thus, nickel-containing compounds such as NiPS possess a narrow bandgap with absorption in the visible region. The incorporation of TiO2 could

Materials nanoarchitectonics at two-dimensional liquid interfaces

• Katsuhiko Ariga,
• Michio Matsumoto,
• Taizo Mori and
• Lok Kumar Shrestha

Beilstein J. Nanotechnol. 2019, 10, 1559–1587, doi:10.3762/bjnano.10.153

• as an alternative to commercial photodetector devices with CdS and CdSe. Enhanced photoluminescence and photoelectrochemical properties of one-dimensional Lu2@C82 nanorods prepared through liquid–liquid interfacial precipitation between carbon disulfide and 2-propanol were demonstrated by Lu and co

BiOCl/TiO₂/diatomite composites with enhanced visible-light photocatalytic activity for the degradation of rhodamine B

• Minlin Ao,
• Kun Liu,
• Xuekun Tang,
• Zishun Li,
• Qian Peng and
• Jing Huang

Beilstein J. Nanotechnol. 2019, 10, 1412–1422, doi:10.3762/bjnano.10.139

• a Micromeritics ASAP 2020 surface area and porosity measurement system. A Unico UV-2600 spectrophotometer was used to analyze the concentration of RhB in the photocatalytic process. The photoelectrochemical properties were analyzed using electrochemical workstations (Gamry interface 1010 and Chenhua

Widening of the electroactivity potential range by composite formation – capacitive properties of TiO₂/BiVO₄/PEDOT:PSS electrodes in contact with an aqueous electrolyte

• Konrad Trzciński,
• Mariusz Szkoda,
• Andrzej P. Nowak,
• Marcin Łapiński and
• Anna Lisowska-Oleksiak

Beilstein J. Nanotechnol. 2019, 10, 483–493, doi:10.3762/bjnano.10.49

• vanadate obtained by pulsed laser deposition (PLD). It was recently reported that the TiO2/BiVO4 junction exhibits a synergistic effect towards photoelectrochemical water oxidation [26]. Further modification of the electrode material included hydrogenation. There are many ways to perform TiO2 hydrogenation

• hydrogenation. The phenomenon of hydrogenation of TiO2 and its influence on electrical, electrochemical and photoelectrochemical properties have been already reported [43][62]. Direct comparison of cv curves of Ti/TiO2 (Figure 4a) and Ti/TiO2:H (Figure 4b) showed that the hydrogenation process extremely extends

Electrolyte tuning in dye-sensitized solar cells with N-heterocyclic carbene (NHC) iron(II) sensitizers

• Mariia Karpacheva,
• Catherine E. Housecroft and
• Edwin C. Constable

Beilstein J. Nanotechnol. 2018, 9, 3069–3078, doi:10.3762/bjnano.9.285

• Scientific, Fluorochem, Alfa Aesar and Fluka, respectively. MeCN was HPLC grade. For DSCs with N719 dye, the electrolyte comprised electrolyte E1. EIS measurements A ModuLab® XM PhotoEchem photoelectrochemical measurement system from Solartron Analytical was used for the EIS measurements. The impedance was

Nanostructure-induced performance degradation of WO₃·nH₂O for energy conversion and storage devices

• Zhenyin Hai,
• Mohammad Karbalaei Akbari,
• Zihan Wei,
• Danfeng Cui,
• Chenyang Xue,
• Hongyan Xu,
• Philippe M. Heynderickx,
• Francis Verpoort and
• Serge Zhuiykov

Beilstein J. Nanotechnol. 2018, 9, 2845–2854, doi:10.3762/bjnano.9.265

• applications [24][33][34]. Oriented WO3·H2O sheets were hydrothermally grown in mixed acids at 80 °C for 17 h, followed by sintering at 500 °C in order to obtain crystalline WO3 for the photoelectrochemical water oxidation [35]. A 2D WO3 nanosheet sensor fabricated by high-temperature anodization of tungsten

Impact of the anodization time on the photocatalytic activity of TiO₂ nanotubes

• Jesús A. Díaz-Real,
• Geyla C. Dubed-Bandomo,
• Juan Galindo-de-la-Rosa,
• Luis G. Arriaga,
• Janet Ledesma-García and
• Nicolas Alonso-Vante

Beilstein J. Nanotechnol. 2018, 9, 2628–2643, doi:10.3762/bjnano.9.244

• Columbia, V6T 1Z4, Canada 10.3762/bjnano.9.244 Abstract Titanium oxide nanotubes (TNTs) were anodically grown in ethylene glycol electrolyte. The influence of the anodization time on their physicochemical and photoelectrochemical properties was evaluated. Concomitant with the anodization time, the NT

• photooxidation of methylene blue. Keywords: fluorine doping; nanotubes; photocatalytic activity; photoelectrochemistry; titanium(IV) oxide (TiO2); Introduction TiO2 started to attract great interest after Fujishima and Honda reported [1] on its photoelectrochemical (PEC) properties in 1972. Numerous features

• along the [004] direction [44], accompanied by a higher photocatalytic performance in the degradation of an organic pollutant [45]. Lee et al. also reported an enhanced photoelectrochemical behavior in photovoltaic devices ascribed to the preferred crystalline orientation due to faster electron

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• Co3O4 samples, which exhibit light-induced photocurrent in photoelectrochemical cells (PEC) containing the alkaline electrolyte. The thickness-dependent properties of Co3O4 related to its use as a working electrode in PEC cells are extensively studied and show potential for the application in water

• indicating the stoichiometric ratio of 1:2. We propose that a semitransparent Co3O4 photoactive electrode is a prospective candidate for use in PEC cells via heterojunctions for hydrogen generation. Keywords: cobalt(II,III) oxide (Co3O4); photocathode; photoelectrochemical cells; semitransparent; thickness

• -dependent properties; Introduction Hydrogen production using water splitting in photoelectrochemical (PEC) cells may help to overcome challenges in the conversion and storage of solar energy. Most of the metal oxides are earth-abundant, non-toxic, stable and easy to synthesise, and hence attractive

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• friendly manner [26][27][28][29]. This process involves: (i) generation of renewable energy such as H2 and O2 by photoelectrochemical water splitting [30][31][32], (ii) photocatalytic CO2 conversion [33][34][35][36][37], (iii) photocatalytic nitrogen (N2) fixation [38], (iv) selective organic

• (electrons (eCB−) and holes (hVB+)) must be effectively separated before they can carry out appropriate redox reactions at the semiconductor surface. Photoelectrochemical water splitting Hydrogen (H2) is considered as a sustainable, clean and renewable energy source to provide a solution to the global energy

• behind a small fraction of the excited carriers to be transferred to the surface of TiO2. This low electron transfer rate on the interface and fast recombination of photoinduced charge carriers causes its poor photocatalytic and photoelectrochemical efficiency [80][81][82][83]. (iii) The tendency of

Facile synthesis of ZnFe₂O₄ photocatalysts for decolourization of organic dyes under solar irradiation

• Arjun Behera,
• Debasmita Kandi,
• Sanjit Manohar Majhi,
• Satyabadi Martha and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 436–446, doi:10.3762/bjnano.9.42

• microstructure of the prepared catalysts were investigated by a TEM-JEOL-2010 200 kV instrument. The electrochemical analysis was carried out using an Ivium potentiostat. Photoelectrochemical (PEC) measurements were performed in a Pyrex electrochemical set up, which includes ZFO samples (deposited on FTO) as

Enhanced photoelectrochemical water splitting performance using morphology-controlled BiVO₄ with W doping

• Xin Zhao and
• Zhong Chen

Beilstein J. Nanotechnol. 2017, 8, 2640–2647, doi:10.3762/bjnano.8.264

• quantitative analysis showed an enhancement of about 50% of the photoelectrochemical performance for the porous structure compared to the planar structure. This enhancement is attributed to improved light absorption (13% increase), charge separation (14% increase), and interfacial charge injection (20

• % increase). Keywords: bismuth vanadate; charge separation; nanostructure; photoelectrochemical water splitting; Introduction Solar hydrogen generation is one of the most promising approaches to create clean energy and to overcome the environmental problems associated with use of conventional fossil fuels

• . Photoelectrochemical (PEC) water splitting generates hydrogen through chemical reactions assisted by photo-generated electrons and holes in semiconductor materials [1][2][3]. An ideal semiconductor for PEC water splitting requires a small bandgap to capture enough solar light, a high conversion efficiency, a good

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

• nature in the form of water, its production from water using solar energy is therefore an area of immense interest for researchers because of its potential to fulfil the global energy demand and related environmental issues [5]. For the first time, photoelectrochemical (PEC) hydrogen production was

• attracted much attention in this field. In order to efficiently utilize the solar energy, many photoelectrochemical cells have been developed for hydrogen production [100][101]. Basically, in the process of photocatalytic water splitting, photons with energy greater than the band gap energy of the chosen

Sb₂S₃ grown by ultrasonic spray pyrolysis and its application in a hybrid solar cell

• Erki Kärber,
• Atanas Katerski,
• Ilona Oja Acik,
• Arvo Mere,
• Valdek Mikli and
• Malle Krunks

Beilstein J. Nanotechnol. 2016, 7, 1662–1673, doi:10.3762/bjnano.7.158

• sulfide [27] and tin sulfide [28][29] grown by pneumatic CSP. At the time of the present study, no publications were available on ultrasonically spray-grown Sb2S3, and on the application of any CSP-grown Sb2S3 in a solar cell, apart from a photoelectrochemical cell that showed an efficiency of 0.3% [30

Novel roles for well-known players: from tobacco mosaic virus pests to enzymatically active assemblies

• Claudia Koch,
• Fabian J. Eber,
• Carlos Azucena,
• Alexander Förste,
• Stefan Walheim,
• Thomas Schimmel,
• Alexander M. Bittner,
• Holger Jeske,
• Hartmut Gliemann,
• Sabine Eiben,
• Fania C. Geiger and
• Christina Wege

Beilstein J. Nanotechnol. 2016, 7, 613–629, doi:10.3762/bjnano.7.54

• , batteries, photoelectrochemical cells or environmental remediation [63][93][94][95][96][97][98][99][100][101][102][103][104][105][106][107][108][109][110][111][112][113], as scaffolds for the display of reporter dyes, nanoparticles or contrast agents such as gadolinium complexes, for light harvesting

Rigid multipodal platforms for metal surfaces

• Michal Valášek,
• Marcin Lindner and
• Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

• anchor to stabilize molecules on the surface by photoelectrochemical measurements, where the molecules comprising a tetraphenylmethane anchoring platform show a significantly higher photocurrent density than the same system with a monopodal anchoring group. This can be attributed to a stable arrangement

Surfactant-controlled composition and crystal structure of manganese(II) sulfide nanocrystals prepared by solvothermal synthesis

• Elena Capetti,
• Anna M. Ferretti,
• Vladimiro Dal Santo and
• Alessandro Ponti

Beilstein J. Nanotechnol. 2015, 6, 2319–2329, doi:10.3762/bjnano.6.238

• electrodes for photoelectrochemical water splitting), Regione Lombardia in the framework of the Second Agreement with CNR (RSPPTECH project), and the Italian MIUR under grant FIRB RBAP115AYN (Oxides at the nanoscale: multifunctionality and applications).

Influence of wide band gap oxide substrates on the photoelectrochemical properties and structural disorder of CdS nanoparticles grown by the successive ionic layer adsorption and reaction (SILAR) method

• Mikalai V. Malashchonak,
• Alexander V. Mazanik,
• Olga V. Korolik,
• Еugene А. Streltsov and
• Anatoly I. Kulak

Beilstein J. Nanotechnol. 2015, 6, 2252–2262, doi:10.3762/bjnano.6.231

• General and Inorganic Chemistry, National Academy of Sciences of Belarus, Surganov St. 9/1, 220072 Minsk, Belarus 10.3762/bjnano.6.231 Abstract The photoelectrochemical properties of nanoheterostructures based on the wide band gap oxide substrates (ZnO, TiO2, In2O3) and CdS nanoparticles deposited by the

• SILAR method to form CdS NPs on an oxide substrate, its influence on the quantum efficiency of photoelectrochemical processes and the structural disorder of CdS NPs with an increasing number of SILAR cycles (N) is still unclear. The aim of this study was to investigate the foregoing features to make the

• SILAR technique more flexible and predictable for QDSSC application. Along with the photoelectrochemical investigation, Raman spectroscopy was used to characterize CdS NPs. Raman spectroscopy in the simplest case can be applied as a type of phase analysis [16][17]. At the same time, in the general case