Deposition of metal particles onto semiconductor nanorods using an ionic liquid

• Michael D. Ballentine,
• Elizabeth G. Embry,
• Marco A. Garcia and
• Lawrence J. Hill

Beilstein J. Nanotechnol. 2019, 10, 718–724, doi:10.3762/bjnano.10.71

• an ionic liquid, and the effect this has on catalytic performance. Platinum, gold, and silver nanoparticles were deposited onto CdSe@CdS (core@shell) nanorods from metal salts in an ionic liquid (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) without additional surfactants or reducing

• methylene blue. This hybrid approach using traditional organic ligands for the synthesis of well-defined nanorods followed by [bmim][Tf2N] for metal deposition was found to be applicable to other noble metals in addition to platinum. Gold and silver nanoparticles were also deposited onto CdSe@CdS nanorods

• those previously observed using organic solvents and ligands [39][40]. We were also able to deposit silver nanoparticles onto CdSe@CdS nanorods using only [bmim][Tf2N] and AgNO3 at 50 °C (Figure 3b). Due to the lower contrast in electron microscopy of Ag compared to Au, silver deposition was conducted

Gold nanoparticles embedded in a polymer as a 3D-printable dichroic nanocomposite material

• Lars Kool,
• Anton Bunschoten,
• Aldrik H. Velders and
• Vittorio Saggiomo

Beilstein J. Nanotechnol. 2019, 10, 442–447, doi:10.3762/bjnano.10.43

• due to gold nanoparticles (AuNPs) and silver nanoparticles (AgNPs) of different sizes and shapes [9][10]. However, only the Lycurgus cup, now stored in the British Museum, and six other broken pieces showing the same dichroic effect were found worldwide, hinting that the achievement of such an optical

Controlling surface morphology and sensitivity of granular and porous silver films for surface-enhanced Raman scattering, SERS

• Sherif Okeil and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2018, 9, 2813–2831, doi:10.3762/bjnano.9.263

• obtain porous silver nanostructures [12]. Other routes include the use of gold or silver nanoparticles of different shapes in solution and their assembly on a solid substrate [6][13][14][15][16][17], nanosphere lithography [18][19][20][21][22][23][24][25] as well as nanolithography and nanoimprinting [26

• from Abacus (Analytical Systems GmbH) consisting of silver nanoparticles on a paper substrate was used for comparison. Results and Discussion Processing and characterization of sputtered and plasma-treated silver films Radio frequency plasma is generated through exposing the feed gas to an external

• well-known for silver nanoparticles. In case of argon plasma treatment (Figure 9c) increasing plasma treatment time results in an increase of absorption of the silver film over the whole UV–vis spectrum indicating some sort of densification of the silver film [87]. The wetting behavior was analyzed by

Comparative biological effects of spherical noble metal nanoparticles (Rh, Pd, Ag, Pt, Au) with 4–8 nm diameter

• Alexander Rostek,
• Marina Breisch,
• Kevin Pappert,
• Kateryna Loza,
• Marc Heggen,
• Manfred Köller,
• Christina Sengstock and
• Matthias Epple

Beilstein J. Nanotechnol. 2018, 9, 2763–2774, doi:10.3762/bjnano.9.258

• biological effects of rhodium nanoparticles except that these nanoparticles can penetrate into human skin [32]. Silver nanoparticles are applied in various fields including healthcare and biomedicine due to their antimicrobial, antifungal and antiviral effect [33][34][35][36][37]. This is based on the

• ][52]. This previously prompted us to carry out a multicentre study where the same silver nanoparticles were investigated in different laboratories with different biological assays [44]. Following the same approach, we have synthesized and thoroughly characterized nanoparticles of the noble metals Rh

• reduction with sodium borohydride leads to small palladium nanoparticles (<10 nm) [65]. Silver nanoparticles can be synthesized in many different ways [66][67]. A bottom-up synthesis of silver nanoparticles can be performed either in organic solvents like ethylene glycol (EG), oleylamin (cis-1-amino-9

Enhancement of X-ray emission from nanocolloidal gold suspensions under double-pulse excitation

• Wei-Hung Hsu,
• Frances Camille P. Masim,
• Armandas Balčytis,
• Hsin-Hui Huang,
• Tetsu Yonezawa,
• Aleksandr A. Kuchmizhak,
• Saulius Juodkazis and
• Koji Hatanaka

Beilstein J. Nanotechnol. 2018, 9, 2609–2617, doi:10.3762/bjnano.9.242

• with different sizes was applied for the efficient X-ray generation in an aqueous phase [17][18], and plasmonic silver nanoparticles were excited to accelerate electrons in vaccum [19]. In addition, there is another new theoretical approach on X-ray sources using plasmonic graphene [20]. Nanoparticles

SERS active Ag–SiO₂ nanoparticles obtained by laser ablation of silver in colloidal silica

• Cristina Gellini,
• Francesco Muniz-Miranda,
• Alfonso Pedone and
• Maurizio Muniz-Miranda

Beilstein J. Nanotechnol. 2018, 9, 2396–2404, doi:10.3762/bjnano.9.224

• of the present work is to apply laser ablation to the fabrication of new materials for surface enhanced Raman scattering (SERS) [15][16], focusing on silver and silica nanoparticles in aqueous suspension. This research was undertaken for three main reasons. The first is that silver nanoparticles that

• silica, exhibiting suitable SERS enhancements by means of the vicinal presence of silver nanoparticles. Finally, the third reason is the use of laser ablation to obtain silver nanoparticles free of reagents and/or reaction products that could interfere in both ligand adsorption and SERS detection (as

• laser ablation time, the growth of the plasmonic band of the silver nanoparticles in two silica suspensions, with 10 and 5 wt % SiO2 concentrations. The results appear quite similar, as shown in the Figure S2 of Supporting Information File 1. The TEM images (Figure 2) show silver nanoparticles (5–10 nm

Surface energy of nanoparticles – influence of particle size and structure

• Dieter Vollath,
• Franz Dieter Fischer and
• David Holec

Beilstein J. Nanotechnol. 2018, 9, 2265–2276, doi:10.3762/bjnano.9.211

• expectation of a reduced surface energy. Results for silver nanoparticles, shown by Alarifi et al. [46], demonstrate the existence of both an outer liquid layer and subsequent a quasi-liquid transition layer at the surface of nanoparticles. Even when both the quasi-liquid and the liquid layer are not

The role of adatoms in chloride-activated colloidal silver nanoparticles for surface-enhanced Raman scattering enhancement

• Nicolae Leopold,
• Andrei Stefancu,
• Krisztian Herman,
• István Sz. Tódor,
• Stefania D. Iancu,
• Vlad Moisoiu and
• Loredana F. Leopold

Beilstein J. Nanotechnol. 2018, 9, 2236–2247, doi:10.3762/bjnano.9.208

• Medicine, Manastur 3-5, 400372 Cluj-Napoca, Romania 10.3762/bjnano.9.208 Abstract Chloride-capped silver nanoparticles (Cl-AgNPs) allow for high-intensity surface-enhanced Raman scattering (SERS) spectra of cationic molecules to be obtained (even at nanomolar concentration) and may also play a key role in

• understanding some fundamental principles behind SERS. In this study, we describe a fast (<10 min) and simple protocol for obtaining highly SERS-active colloidal silver nanoparticles (AgNPs) with a mean diameter of 36 nm by photoconversion from AgCl precursor microparticles in the absence of any organic

• seems to prevail over the Raman enhancement due to nanoparticle aggregation. Keywords: chloride activation; electronic coupling; photoreduction; silver nanoparticles; SERS-active sites; SERS switch-on effect; Introduction The most common surface-enhanced Raman scattering (SERS) substrate is the silver

Fabrication of photothermally active poly(vinyl alcohol) films with gold nanostars for antibacterial applications

• Mykola Borzenkov,
• Maria Moros,
• Claudia Tortiglione,
• Serena Bertoldi,
• Nicola Contessi,
• Silvia Faré,
• Angelo Taglietti,
• Agnese D’Agostino,
• Piersandro Pallavicini,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2018, 9, 2040–2048, doi:10.3762/bjnano.9.193

• studies have reported the preparation and the antibacterial efficacy of PVA films containing plant extracts, silver nanoparticles or zinc oxide nanoparticles [17][18][19][20][21][22]. However, when bacteria start to form biofilms they become resistant and conventional antibiotics do not eradicate biofilms

• from the surfaces where they formed [8]. Silver nanoparticles prevent biofilm formation but with a controversial results – Ag nanoparticles are effective towards Gram-negative bacterial strains but much less so towards Gram-positive [8][23]. There is a strong need for novel lightweight antibacterial

Cathodoluminescence as a probe of the optical properties of resonant apertures in a metallic film

• Kalpana Singh,
• Evgeniy Panchenko,
• Babak Nasr,
• Amelia Liu,
• Lukas Wesemann,
• Timothy J. Davis and
• Ann Roberts

Beilstein J. Nanotechnol. 2018, 9, 1491–1500, doi:10.3762/bjnano.9.140

• of inorganic compounds such as ceramics, minerals and semiconductors [41][42][43]. CL has also been shown to be an invaluable tool in the investigation of optical modes of nanostructures [44]. These include characterising the plasmonic modes of silver nanoparticles [45] and resonant modes of single

Colorimetric detection of Cu²⁺ based on the formation of peptide–copper complexes on silver nanoparticle surfaces

• Gajanan Sampatrao Ghodake,
• Surendra Krishna Shinde,
• Rijuta Ganesh Saratale,
• Avinash Ashok Kadam,
• Ganesh Dattatraya Saratale,
• Asad Syed,
• Fuad Ameen and
• Dae-Young Kim

Beilstein J. Nanotechnol. 2018, 9, 1414–1422, doi:10.3762/bjnano.9.134

• + is based on coordination reactions of Cu2+ with casein peptide-functionalized silver nanoparticles (AgNPs), leading to a distinct color change of the solution from yellow to red. The developed method has a good detection limit of about 0.16 µM Cu2+ using 0.05 mL of AgNPs stock solution and a

• samples [13][14]. However, the use of gold and/or platinum limits the affordability of sensing probe. As exemplified in this work, cost-effective silver nanoparticles (AgNPs) having specifically modified ligands for detecting lower concentrations of Cu2+ offer a more portable and practical approach. In a

• recorded after 20 min at 520 nm. A plot of the concentration versus absorbance intensity was prepared, and used as the standard graph for the determination of Cu2+ concentrations present in the water samples. (a) UV–vis spectrum and color of silver nanoparticles before and after centrifugation. A

Electrodeposition of reduced graphene oxide with chitosan based on the coordination deposition method

• Mingyang Liu,
• Yanjun Chen,
• Chaoran Qin,
• Zheng Zhang,
• Shuai Ma,
• Xiuru Cai,
• Xueqian Li and
• Yifeng Wang

Beilstein J. Nanotechnol. 2018, 9, 1200–1210, doi:10.3762/bjnano.9.111

• promising for uses in surface coatings, sensors and metallic biomaterials, however, to date little attention has been paid to this coordination electrodeposition method. A feature of the chitosan electrodeposition method is that it enables a controllable means to assemble nanoparticles (e.g., silver

• nanoparticles, carbon nanotubes, manganese oxides nanoparticles, and carbon dots) on electrodes through codeposition with chitosan, which offers attractive applications in antimicrobial coatings, biosensors, microbial fuel cells, and energy storage materials [14][15][16][17][18]. Among the studies on the

Facile chemical routes to mesoporous silver substrates for SERS analysis

• Elina A. Tastekova,
• Alexander Y. Polyakov,
• Anastasia E. Goldt,
• Alexander V. Sidorov,
• Alexandra A. Oshmyanskaya,
• Irina V. Sukhorukova,
• Dmitry V. Shtansky,
• Wolgang Grünert and
• Anastasia V. Grigorieva

Beilstein J. Nanotechnol. 2018, 9, 880–889, doi:10.3762/bjnano.9.82

• , Ruhr-University at Bochum, Universitätsstraße 150, Bochum, 44801, Germany 10.3762/bjnano.9.82 Abstract Mesoporous silver nanoparticles were easily synthesized through the bulk reduction of crystalline silver(I) oxide and used for the preparation of highly porous surface-enhanced Raman scattering (SERS

Noble metal-modified titania with visible-light activity for the decomposition of microorganisms

• Maya Endo,
• Zhishun Wei,
• Kunlei Wang,
• Baris Karabiyik,
• Kenta Yoshiiri,
• Paulina Rokicka,
• Bunsho Ohtani,
• Agata Markowska-Szczupak and
• Ewa Kowalska

Beilstein J. Nanotechnol. 2018, 9, 829–841, doi:10.3762/bjnano.9.77

• activity under visible-light irradiation, whereas the size and shape of silver nanoparticles (NPs) and the aspect ratio of titania affect the antifungal activity [29]. In the present study, antimicrobial properties of commercial titania samples modified with noble metals have been investigated in order to

Colloidal solution of silver nanoparticles for label-free colorimetric sensing of ammonia in aqueous solutions

• Alessandro Buccolieri,
• Antonio Serra,
• Gabriele Giancane and
• Daniela Manno

Beilstein J. Nanotechnol. 2018, 9, 499–507, doi:10.3762/bjnano.9.48

• Alessandro Buccolieri Antonio Serra Gabriele Giancane Daniela Manno GFA-Gruppo di Fisica Applicata, Dipartimento di Matematica e Fisica “E. De Giorgi”, Università del Salento Lecce, Italy 10.3762/bjnano.9.48 Abstract Silver nanoparticles were synthesized in the presence of saccharides and ammonia

• been identified: very low ammonia concentrations from 0.01 to 0.2 ppm, high ammonia concentrations from 20 to 350 ppm and, most importantly, the intermediate or physiological range of ammonia from 0.5 to 10 ppm. Keywords: electron diffraction; electron microscopy; NH3 sensors; silver nanoparticles; UV

• particular silver nanoparticles (AgNPs), are often considered for analytical application because of their peculiar optical and electrical properties [13]. The surface plasmon resonance (SPR) properties of metal nanoparticles are considered very useful for the use of colloidal solutions in the field of

Gas-assisted silver deposition with a focused electron beam

• Luisa Berger,
• Katarzyna Madajska,
• Iwona B. Szymanska,
• Katja Höflich,
• Mikhail N. Polyakov,
• Jakub Jurczyk,
• Carlos Guerra-Nuñez and
• Ivo Utke

Beilstein J. Nanotechnol. 2018, 9, 224–232, doi:10.3762/bjnano.9.24

• Figure 6b recorded on the background particles indicate that they are silver nanoparticles. The pattern corresponds to the Ag fcc pattern (green rings). Additionally, the EDX line scan spectrum in Figure 6c over two particles (indicated by red line in inset) confirms this assumption by clearly showing a

• high silver content in those particles. The particle sizes are significantly smaller than those in the FEBID structures and can range from 4 to 10 nm, as shown in the histogram in Figure 6d. We attribute this background deposition of silver nanoparticles either to competing thermal decomposition of the

Facile synthesis of silver/silver thiocyanate (Ag@AgSCN) plasmonic nanostructures with enhanced photocatalytic performance

• Xinfu Zhao,
• Dairong Chen,
• Abdul Qayum,
• Bo Chen and
• Xiuling Jiao

Beilstein J. Nanotechnol. 2017, 8, 2781–2789, doi:10.3762/bjnano.8.277

• nm. The absorption peak of silver nanoparticles becomes gradually stronger as the content of Ag increases, indicating that the sunlight utilization efficiency increases steadily. During UV irradiation, many defects are formed in AgSCN, including different interstitial sites and vacancies [29]. The

The role of ligands in coinage-metal nanoparticles for electronics

• Ioannis Kanelidis and
• Tobias Kraus

Beilstein J. Nanotechnol. 2017, 8, 2625–2639, doi:10.3762/bjnano.8.263

• of particle layers. For example, inks based on PVP-coated silver nanoparticles of different geometries were used to prepare conductive layers. Inks that contained only spheres (64 nm in diameter) formed layers with a conductivity of 769.2 S/cm at 70% metal mass fraction. Mixtures of spheres and

• -printed from inks based on silver–copper nanoparticles in 2-butoxyethanol acetate or electrocircuits from silver nanoparticles in water were inkjet-printed on paper substrates [50][91]. Alkanethiol-functionalized gold and silver nanoparticles in water exhibited increased dispersion stability with

• between the cores in deposited layers [96][97]. Silver nanoparticles stabilized by oleylamine ligands were immersed in 99.9% acetic acid in order to partially remove oleylamine, substitute it with acetic acid (Figure 2), and reduce the overall density of the ligand shell on the metal surface. The decrease

Fabrication of gold-coated PDMS surfaces with arrayed triangular micro/nanopyramids for use as SERS substrates

• Jingran Zhang,
• Yongda Yan,
• Peng Miao and
• Jianxiong Cai

Beilstein J. Nanotechnol. 2017, 8, 2271–2282, doi:10.3762/bjnano.8.227

• nanoparticles on a poly(methyl methacrylate) (PMMA) template, and malachite green on fish skin [27] was successfully detected. A flexible and transparent substrate consisting of silver nanoparticles on polyethylene terephthalate (PET) sheets was fabricated for in situ detection of R6G and thiram residues with a

Synthesis and characterization of noble metal–titania core–shell nanostructures with tunable shell thickness

• Bartosz Bartosewicz,
• Marta Michalska-Domańska,
• Malwina Liszewska,
• Dariusz Zasada and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2017, 8, 2083–2093, doi:10.3762/bjnano.8.208

• silver nanoparticles, respectively. The stirring was kept up for 12 h. After this time, the synthesized CSNs were centrifuged and washed several times with ethanol. Tunable resistive pulse sensing (TRPS) measurements Analogous to the description in [64], TRPS size distribution measurements were carried

Luminescent supramolecular hydrogels from a tripeptide and nitrogen-doped carbon nanodots

• Maria C. Cringoli,
• Slavko Kralj,
• Marina Kurbasic,
• Massimo Urban and
• Silvia Marchesan

Beilstein J. Nanotechnol. 2017, 8, 1553–1562, doi:10.3762/bjnano.8.157

• allows several molecular precursors to be employed, such as amino acids in aqueous solution [3]. As an example, L-tyrosine was used to form hydrophobic CNDs able to sense ions and silver nanoparticles [4]. Arginine or cysteine have also been efficiently employed as starting materials through a

Surface-enhanced Raman spectroscopy of cell lysates mixed with silver nanoparticles for tumor classification

• Mohamed Hassoun,
• Iwan W.Schie,
• Tatiana Tolstik,
• Sarmiza E. Stanca,
• Christoph Krafft and
• Juergen Popp

Beilstein J. Nanotechnol. 2017, 8, 1183–1190, doi:10.3762/bjnano.8.120

• immuno-functionalized nanoparticles turned out to be challenging for cell identification because they require complex preparation procedures. Here, a new SERS strategy is presented for cell classification using non-functionalized silver nanoparticles and potassium chloride to induce aggregation. To

• silver nanoparticles. Keywords: cell lysate; silver nanoparticles; surface-enhanced Raman spectroscopy (SERS); tumor-cell differentiation; Introduction Cytopathology is the histopathologic inspection of cells. Dyes, such as hematoxylin for cell nuclei or eosin for cytoplasm, are commonly used to stain

• developed to disrupt the cell walls by sonication and to allow for the interaction of silver nanoparticles with the released cellular biomolecules. The measured SERS spectra from six different batches were subjected to a support vector machine (SVM) to train classification models. The sensitivities

Needs and challenges for assessing the environmental impacts of engineered nanomaterials (ENMs)

• Michelle Romero-Franco,
• Hilary A. Godwin,
• Muhammad Bilal and
• Yoram Cohen

Beilstein J. Nanotechnol. 2017, 8, 989–1014, doi:10.3762/bjnano.8.101

α-((4-Cyanobenzoyl)oxy)-ω-methyl poly(ethylene glycol): a new stabilizer for silver nanoparticles

• Jana Lutze,
• Miguel A. Bañares,
• Marcos Pita,
• Andrea Haase,
• Andreas Luch and
• Andreas Taubert

Beilstein J. Nanotechnol. 2017, 8, 627–635, doi:10.3762/bjnano.8.67

• function of the pH value both for the free stabilizer and for the polymers bound to the surface of the silver nanoparticles using 1H NMR spectroscopy and zeta potential measurements. The polymer shows a high stability between pH 3 and 9. At pH 12 and higher the polymer coating is degraded over time

• anchors. Keywords: cyano anchor group; poly(ethylene glycol); polymer coating; silver nanoparticles; Introduction Nanoparticles (NPs), especially metal NPs such as gold and silver NPs (SNPs), are currently among the most popular research subjects and many particles have been suggested for applications

• are currently of high interest [4][5]. Arguably, the most common stabilizer for gold and silver nanoparticles is PEG and the most common anchor group is the thiol/thiolate group. As stated in the introduction, there may however be situations where the thiol group may be unwanted. The new stabilizer

Microfluidic setup for on-line SERS monitoring using laser induced nanoparticle spots as SERS active substrate

• Oana-M. Buja,
• Ovidiu D. Gordan,
• Nicolae Leopold,
• Andreas Morschhauser,
• Jörg Nestler and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2017, 8, 237–243, doi:10.3762/bjnano.8.26

• substrate. Keywords: gold nanoparticles; malachite green; microfluidic setup; SERS; silver nanoparticles; Introduction Over the past decade special attention has been given to the investigation of hazardous environmental chemicals with impact on human health [1][2][3][4]. Surface-enhanced Raman scattering

• attached to a rough metallic surface of silver, gold, or copper [10]. While metallic substrates are available in different shapes and sizes [9], colloidal citrate-reduced silver nanoparticles, synthesized following the method by Lee and Meisel [11] under boiling conditions, are amongst the most common

• ][14][15][16][17][18][19][20], so far, for a successful experiment the procedures require the synthesis of the colloids and previous mixing of the analyte and the silver nanoparticles. This study focuses on the on-line SERS monitoring of malachite green (MG) as a model analyte. However, the detection