Polymorphic self-assembly of pyrazine-based tectons at the solution–solid interface

• Achintya Jana,
• Puneet Mishra and
• Neeladri Das

Beilstein J. Nanotechnol. 2019, 10, 494–499, doi:10.3762/bjnano.10.50

• highlighted the immense potential of molecules as a component of functional electronics [1][2], spintronics [3][4][5] and mechanical [6] devices. However, most of these studies employed extreme experimental conditions such as ultra-low temperatures, and ultra-high vacuum, which are far from any practically

Size limits of magnetic-domain engineering in continuous in-plane exchange-bias prototype films

• Alexander Gaul,
• Daniel Emmrich,
• Timo Ueltzhöffer,
• Henning Huckfeldt,
• Hatice Doğanay,
• Johanna Hackl,
• Muhammad Imtiaz Khan,
• Daniel M. Gottlob,
• Gregor Hartmann,
• André Beyer,
• Dennis Holzinger,
• Slavomír Nemšák,
• Claus M. Schneider,
• Armin Gölzhäuser,
• Günter Reiss and
• Arno Ehresmann

Beilstein J. Nanotechnol. 2018, 9, 2968–2979, doi:10.3762/bjnano.9.276

• sensor applications [3][4][5], for stray field design [6][7] and particle transport in lab-on-chip systems [8][9][10][11], or in spintronics and magnonics [12][13][14]. Currently available techniques for domain patterning are either based on focused ion beams (FIB) [15][16][17], ion implantation [18][19

Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry

• Pierre Farger,
• Cédric Leuvrey,
• Mathieu Gallart,
• Pierre Gilliot,
• Guillaume Rogez,
• João Rocha,
• Duarte Ananias,
• Pierre Rabu and
• Emilie Delahaye

Beilstein J. Nanotechnol. 2018, 9, 2775–2787, doi:10.3762/bjnano.9.259

• applications of lanthanide-based networks in information storage, quantum computing and spintronics [19][20][21][22][23]. Most of these lanthanide-based networks are obtained with neutral organic ligands such as benzene-1,4-dicarboxylate (1,4-bdc) [24], benzene-1,3,5-tricarboxylate (TMA) [25], pyridine-2,5

Silicene, germanene and other group IV 2D materials

• Patrick Vogt

Beilstein J. Nanotechnol. 2018, 9, 2665–2667, doi:10.3762/bjnano.9.248

• two-dimensional (2D) honeycomb materials with potentially similar exotic properties, as predicted by theoretical investigations. These properties may allow the application of these layered structures in novel electronic devices, including ultrafast electronics, spintronics, sensors, and novel device

Influence of the thickness of an antiferromagnetic IrMn layer on the static and dynamic magnetization of weakly coupled CoFeB/IrMn/CoFeB trilayers

• Deepika Jhajhria,
• Dinesh K. Pandya and
• Sujeet Chaudhary

Beilstein J. Nanotechnol. 2018, 9, 2198–2208, doi:10.3762/bjnano.9.206

• , AF-based spintronics is gaining momentum because of the unique properties such as zero net magnetization, no stray fields, low magnetic susceptibility, large spin–orbit coupling, ultrafast dynamics and large magneto-transport effects [2][3][4][5][6]. Several of the effects such as tunnel anisotropic

Free-radical gases on two-dimensional transition-metal disulfides (XS₂, X = Mo/W): robust half-metallicity for efficient nitrogen oxide sensors

• Chunmei Zhang,
• Yalong Jiao,
• Fengxian Ma,
• Sri Kasi Matta,
• Steven Bottle and
• Aijun Du

Beilstein J. Nanotechnol. 2018, 9, 1641–1646, doi:10.3762/bjnano.9.156

• could be uses in spintronics. But the lack of suitable materials limits the development of spintronic applications. Doping semiconductors may be applied to achieve spin-polarized currents, but this requires a complicated process. Although many materials have been predicted in theory for this purpose

Interaction-tailored organization of large-area colloidal assemblies

• Silvia Rizzato,
• Elisabetta Primiceri,
• Anna Grazia Monteduro,
• Adriano Colombelli,
• Angelo Leo,
• Maria Grazia Manera,
• Roberto Rella and
• Giuseppe Maruccio

Beilstein J. Nanotechnol. 2018, 9, 1582–1593, doi:10.3762/bjnano.9.150

• applications in many fields such as photonics/plasmonics [1], phononics [2][3], spintronics/magnonics [4][5], biosensors and energy harvesting [6][7][8]. For example, metal nanostructured systems, stimulated by incident light of a specific wavelength, can support localized surface plasmon resonant modes. The

Solid-state Stern–Gerlach spin splitter for magnetic field sensing, spintronics, and quantum computing

• Kristofer Björnson and
• Annica M. Black-Schaffer

Beilstein J. Nanotechnol. 2018, 9, 1558–1563, doi:10.3762/bjnano.9.147

• magnetic flux and as a spintronics switch. With normal metallic leads a switchable spintronics NOT-gate can be implemented. Furthermore, we show that a sequence of such devices can be used to construct a single-qubit SU(2)-gate, one of the two gates required for a universal quantum computer. The field

• sensitivity, or switching field, b, is related to the characteristic size of the device, r, through b = h/(2πqr2), with q being the unit of electric charge. Keywords: Aharanov–Bohm; quantum computing; spintronics; Stern–Gerlach; SU(2); topological insulator; Introduction Two famous examples of the

• ferromagnetic leads, the device can be used for sensitive measurements of magnetic field strengths. The same setup can also be used to implement a spintronic switch. Instead using normal metallic leads, we show that a switchable spintronics NOT-gate can be constructed. Finally, we also demonstrate how a

Predicting the strain-mediated topological phase transition in 3D cubic ThTaN₃

• Chunmei Zhang and
• Aijun Du

Beilstein J. Nanotechnol. 2018, 9, 1399–1404, doi:10.3762/bjnano.9.132

• the d-orbital of the heavy element Ta and the p-orbital of N. Our results highlight a new 3D topological insulator with strain-mediated topological transition for potential applications in future spintronics. Keywords: Dirac cone; strain; ThTaN3; topological insulator; Introduction The ThTaN3

• large gap (≈0.25 eV) opened in the presence of SOC. Further analysis of orbital contribution indicates p–d band inversion in 3D ThTaN3. Our results highlight a new, interesting, 3D, topological insulator material with great potential for future application in spintronics. (a) Top view of ThTaN3 with

Valley-selective directional emission from a transition-metal dichalcogenide monolayer mediated by a plasmonic nanoantenna

• Haitao Chen,
• Mingkai Liu,
• Lei Xu and
• Dragomir N. Neshev

Beilstein J. Nanotechnol. 2018, 9, 780–788, doi:10.3762/bjnano.9.71

• that have a hexagonal lattice structure valleys of degenerate energy locate at the corners of the hexagonal Brillouin zone: the K and K′ points [4][5]. In analogy to spintronics, the valley pseudospin could also be used as non-volatile information storage and processing, which is known as valleytronics

Electron interactions with the heteronuclear carbonyl precursor H₂FeRu₃(CO)₁₃ and comparison with HFeCo₃(CO)₁₂: from fundamental gas phase and surface science studies to focused electron beam induced deposition

• Ragesh Kumar T P,
• Paul Weirich,
• Lukas Hrachowina,
• Marc Hanefeld,
• Ragnar Bjornsson,
• Helgi Rafn Hrodmarsson,
• Sven Barth,
• D. Howard Fairbrother,
• Michael Huth and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2018, 9, 555–579, doi:10.3762/bjnano.9.53

• such as magnetism at the nanoscale. Magnetic nanostructures are fundamental building blocks for applications in data storage and processing as well as the potential successor technologies based on magnonics [67] and spintronics [68] combined with high integration density relying on 3D nanostructure

Beyond Moore’s technologies: operation principles of a superconductor alternative

• Igor I. Soloviev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Mikhail Yu. Kupriyanov,
• Alexander L. Gudkov and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2017, 8, 2689–2710, doi:10.3762/bjnano.8.269

• quantum computers. QFPs are utilized as qubits and couplers in adiabatic quantum optimization systems of D-Wave Systems [60][61]. Another reason for the current rise of interest to ASL is the Japanese JST-ALCA project “Superconductor electronics system combined with optics and spintronics” [62]. The idea

Adsorption of iron tetraphenylporphyrin on (111) surfaces of coinage metals: a density functional theory study

• Hao Tang,
• Nathalie Tarrat,
• Véronique Langlais and
• Yongfeng Wang

Beilstein J. Nanotechnol. 2017, 8, 2484–2491, doi:10.3762/bjnano.8.248

• these complexes, iron tetraphenylporphyrin (FeTPP) is particularly attractive for molecular spintronics due to its magnetic bistability. Indeed, the Fe2+ centre (4s03d6) can have three magnetic states, i.e., low-spin state (LS, S = 0), intermediate state (IS, S = 1) and high-spin state (HS, S = 2

Towards molecular spintronics

• Georgeta Salvan and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2017, 8, 2464–2466, doi:10.3762/bjnano.8.245

• molecules; (magneto-)optical spectroscopy; molecular spintronics; photoelectron spectroscopy; surface science; thin films; The discovery of tunneling and giant magnetoresistance in inorganic spin valves has led to a revolution in the field of magnetic memory and the significant increase in the storage

• capacity of modern hard drives. Simultaneously, given their inexpensive production, flexibility and diverse applications, molecular-based organic materials have become extremely important in electronic devices and circuitry. A combination of spintronics and organic electronics is expected to lead to a new

• generation of spin-based devices. These devices are expected to bring a wide range of exciting, new fields of application and products for organic/molecular spintronics. The work of the Research Unit “Towards Molecular Spintronics” funded by the German Science Foundation (Deutsche Forschungsgemeinschaft, DFG

The interplay between spin densities and magnetic superexchange interactions: case studies of mono- and trinuclear bis(oxamato)-type complexes

• Azar Aliabadi,
• Bernd Büchner,
• Vladislav Kataev and
• Tobias Rüffer

Beilstein J. Nanotechnol. 2017, 8, 2245–2256, doi:10.3762/bjnano.8.224

• , molecular electronics and spintronics was impressively brought into bloom by O. Kahn himself and his school later on [5][8][16][17][18]. Type-III complexes are of interest because, for example, the determination of their magnetic properties, in particular their magnetic superexchange couplings, is an

• Spintronics”. We express our gratitude to numerous co-workers and partners, whose contribution is acknowledged in the author list of the original works reviewed in this article.

Ester formation at the liquid–solid interface

• Nguyen T. N. Ha,
• Thiruvancheril G. Gopakumar,
• Nguyen D. C. Yen,
• Carola Mende,
• Lars Smykalla,
• Maik Schlesinger,
• Roy Buschbeck,
• Tobias Rüffer,
• Heinrich Lang,
• Michael Mehring and
• Michael Hietschold

Beilstein J. Nanotechnol. 2017, 8, 2139–2150, doi:10.3762/bjnano.8.213

• undecanol-1, and the time-dependent evolution of LP and ester pattern. Acknowledgements The authors thank for the financial support from the DFG Research Unit 1154 "Towards Molecular Spintronics".

Electronic structure, transport, and collective effects in molecular layered systems

• Torsten Hahn,
• Tim Ludwig,
• Carsten Timm and
• Jens Kortus

Beilstein J. Nanotechnol. 2017, 8, 2094–2105, doi:10.3762/bjnano.8.209

• ; Introduction Implementing molecular spintronics requires the understanding and the ability to modify and control charge-transport characteristics of organic molecules. Thus a solid understanding of the basic effects that govern the transport characteristics in the desired material is required for the

• discussions and the ZIH Dresden for providing computational resources. Financial support by the Deutsche Forschungsgemeinschaft, through Research Unit FOR 1154, Towards Molecular Spintronics, and HA5070/3, is gratefully acknowledged.

Coexistence of strongly buckled germanene phases on Al(111)

• Weimin Wang and
• Roger I. G. Uhrberg

Beilstein J. Nanotechnol. 2017, 8, 1946–1951, doi:10.3762/bjnano.8.195

• spin-splitting, quantum spin Hall effect, amongst others. Based on the wealth of physical phenomena exhibited by various 2D materials, they are considered as important future materials of high potential for applications in nano-scale electronics and spintronics. A sub-group of 2D materials is graphene

Spin-dependent transport and functional design in organic ferromagnetic devices

• Guichao Hu,
• Shijie Xie,
• Chuankui Wang and
• Carsten Timm

Beilstein J. Nanotechnol. 2017, 8, 1919–1931, doi:10.3762/bjnano.8.192

• .8.192 Abstract Organic ferromagnets are intriguing materials in that they combine ferromagnetic and organic properties. Although challenges in their synthesis still remain, the development of organic spintronics has triggered strong interest in high-performance organic ferromagnetic devices. This review

• filtering; transport; Introduction In recent years, organic spintronics has attracted more and more interest [1][2][3] in order to develop cheap and flexible devices employing the electronic spin degree of freedom. Organic spintronics has several merits compared with inorganic materials. The spin–orbit and

• research on OFs has focused on the synthesis, measurement, and characterization of the magnetic properties of the isolated molecules. Recently, the progress in organic and molecular spintronics has motivated us to explore the spin-dependent transport properties of OFs and the possibility to design organic

(Metallo)porphyrins for potential materials science applications

• Lars Smykalla,
• Carola Mende,
• Michael Fronk,
• Pablo F. Siles,
• Michael Hietschold,
• Georgeta Salvan,
• Dietrich R. T. Zahn,
• Oliver G. Schmidt,
• Tobias Rüffer and
• Heinrich Lang

Beilstein J. Nanotechnol. 2017, 8, 1786–1800, doi:10.3762/bjnano.8.180

• (metallo)porphyrins under review here. Acknowledgements This work was supported by the Deutsche Forschungsgemeinschaft through the Focused Research Unit FOR 1154 “Towards Molecular Spintronics”. We express our gratitude to numerous co-workers and partners, whose contribution is acknowledged in the author

Charge transfer from and to manganese phthalocyanine: bulk materials and interfaces

• Florian Rückerl,
• Daniel Waas,
• Bernd Büchner,
• Martin Knupfer,
• Dietrich R. T. Zahn,
• Francisc Haidu,
• Torsten Hahn and
• Jens Kortus

Beilstein J. Nanotechnol. 2017, 8, 1601–1615, doi:10.3762/bjnano.8.160

• phthalocyanines also show very interesting magnetic behavior [9]. They have even been discussed in terms of molecular magnets including their discussion in future applications in the field of molecular spintronics [10][11][12]. Among these transition-metal phthalocyanines, manganese phthalocyanine (MnPc) is one

• calculations the MnPc/F16CoPc dimer is characterized by a net spin of S = 2. Thus, the charge transfer is connected to a transfer/change of spin, which justifies to call the corresponding interface a spin-transfer interface with potential applications in the area of spintronics. Finally, we note that also a

Light-induced magnetoresistance in solution-processed planar hybrid devices measured under ambient conditions

• Sreetama Banerjee,
• Daniel Bülz,
• Danny Reuter,
• Karla Hiller,
• Dietrich R. T. Zahn and
• Georgeta Salvan

Beilstein J. Nanotechnol. 2017, 8, 1502–1507, doi:10.3762/bjnano.8.150

• -pentacene film. Keywords: HED-TIEs; hybrid electronic devices; organic field-effect transistors (OFETs); organic magnetoresistance; planar hybrid devices; TIPS-pentacene; Findings The field of molecular spintronics has received lot of research interest in the last years because of the possibility of

• process of the devices with trench isolated electrodes. This work was funded by the Deutsche Forschungsgemeinschaft within the Research Unit DFG FOR 1154 “Towards Molecular Spintronics”.

Formation of ferromagnetic molecular thin films from blends by annealing

• Peter Robaschik,
• Ye Ma,
• Salahud Din and
• Sandrine Heutz

Beilstein J. Nanotechnol. 2017, 8, 1469–1475, doi:10.3762/bjnano.8.146

• resulting films exhibit substantial coercivity (13 mT) at 2 K and a Curie temperature of 11.5 K. Keywords: co-deposition; molecular spintronics; organic thin films; phthalocyanines; tetracyanoquinodimethane (TCNQ); Introduction Controlling the structure of molecular thin films is of great interest for

• temperatures up to 10 K, and the Curie temperature as determined by susceptibility measurements is 11.5 K. The combination of new processing methodologies with attractive magnetic properties will have important implications for spintronics. Results and Discussion Sample preparation Blended films comprising

Spin-chemistry concepts for spintronics scientists

• Konstantin L. Ivanov,
• Alexander Wagenpfahl,
• Carsten Deibel and
• Jörg Matysik

Beilstein J. Nanotechnol. 2017, 8, 1427–1445, doi:10.3762/bjnano.8.143

• , Technische Universität Chemnitz, 09126 Chemnitz, Germany Universität Leipzig, Institut für Analytische Chemie, Linnéstr. 3, D-04103 Leipzig, Germany 10.3762/bjnano.8.143 Abstract Spin chemistry and spintronics developed independently and with different terminology. Until now, the interaction between the two

• fields has been very limited. In this review, we compile the two “languages” in an effort to enhance communication. We expect that knowledge of spin chemistry will accelerate progress in spintronics. Keywords: CIDEP; magnetic field effects; photo-CIDNP; radical pairs; triplet states; Review

• the field of spintronics as an introduction into the older field of spin chemistry. It seems to be economically reasonable to learn spin chemistry language and concepts to prevent reinvention of previous knowledge. We will first review the languages that developed mostly independently in both fields

Deposition of exchange-coupled dinickel complexes on gold substrates utilizing ambidentate mercapto-carboxylato ligands

• Martin Börner,
• Laura Blömer,
• Marcus Kischel,
• Peter Richter,
• Georgeta Salvan,
• Dietrich R. T. Zahn,
• Pablo F. Siles,
• Maria E. N. Fuentes,
• Carlos C. B. Bufon,
• Daniel Grimm,
• Oliver G. Schmidt,
• Daniel Breite,
• Bernd Abel and
• Berthold Kersting

Beilstein J. Nanotechnol. 2017, 8, 1375–1387, doi:10.3762/bjnano.8.139

• in various fields, including molecular spintronics. In this work, the synthesis of mixed-ligand complexes of the type [NiII2L(L’)](ClO4), where L represents a 24-membered macrocyclic hexaazadithiophenolate ligand and L’ is a ω-mercapto-carboxylato ligand (L’ = HS(CH2)5CO2− (6), HS(CH2)10CO2− (7), or

• molecular spintronics”) and the University of Leipzig for general support. We thank Prof. Dr. H. Krautscheid for providing facilities for X-ray crystallographic measurements and L. J. Endter for her assistance in the synthesis of the organic compounds.