2 article(s) from Krasavin, Mikhail
Examples of imidazole (1 and 2) and oxazole (3) syntheses from propargylamides previously reported ...
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Substrate scope for the three-component synthesis of 5.
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Plausible mechanism for the formation of 5.
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Beilstein J. Org. Chem. 2019, 15, 1061–1064, doi:10.3762/bjoc.15.103
The Castagnoli–Cushman reaction (CCR).
Assembly of hexahydropyrrolo[1,2-b]isoquinoline core via the CCR and its occurrence in natural and ...
Indolenine substrates 9a–t investigated in this work. aPrepared for the first time (the rest are kn...
Anti- and syn-diastereomers of 10 and 10'.
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Single-crystal X-ray structure of compound 10l.
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Formation of unwanted products 11 and 12 in lieu of the CCR with 9p–t.
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Typical J(H11-H11a)-values and corresponding dihedral angles for syn- and anti-diastereomers of com...
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The difference in the 13C NMR chemical shifts of the angular methyl group between syn- and anti-dia...
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Criteria for stereochemistry assignment of anti-10o.
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Syn/anti isomerization of compound 10e.
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Alternative mechanistic pathways for the CCR.
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Formation and fate of Mannich adduct 13e.
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Mechanistic rationale for the 13e→ syn/anti-10e conversion.
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Decarboxylation of anti/syn-10h.
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Beilstein J. Org. Chem. 2017, 13, 1413–1424, doi:10.3762/bjoc.13.138
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