Advanced scanning probe lithography using anatase-to-rutile transition to create localized TiO₂ nanorods

• Julian Kalb,
• Vanessa Knittel and
• Lukas Schmidt-Mende

Beilstein J. Nanotechnol. 2019, 10, 412–418, doi:10.3762/bjnano.10.40

• contrast, local light scattering, high-resolution surface roughness gradients or microchannels. This set of extensions for rutile TiO2 nanorod applications is a valuable toolkit for lab-on-a-chip devices [33][34][35]. Recently, we investigated the influence of rutile seed layers on the growth and shape of

• directly on polycrystalline anatase TiO2 films. The resulting nanorod arrangements are compared with similar structures obtained with conventional electron-beam lithography, which is a more expensive and laborious procedure. The method is drafted in Figure 1. A silicon tip, as it is used in a conventional

• of the written line is covered with nanorods completely. The average size and shape of the nanorods is given by the parameters of the growth solution and growth process and does not depend on the writing process. Figure 4D shows that light scattering is enhanced by the TiO2 nanorod lines locally

Uniform Sb₂S₃ optical coatings by chemical spray method

• Jako S. Eensalu,
• Atanas Katerski,
• Erki Kärber,
• Ilona Oja Acik,
• Arvo Mere and
• Malle Krunks

Beilstein J. Nanotechnol. 2019, 10, 198–210, doi:10.3762/bjnano.10.18

• two-step process on ZnO nanorod/TiO2 substrates [7]. In this study, we applied this two-step process, i.e., depositing amorphous Sb2S3 layers on planar substrates, followed by post-deposition crystallization. The aim of this study was to produce crystalline, continuous, Sb2S3 optical coatings with

Surface plasmon resonance enhancement of photoluminescence intensity and bioimaging application of gold nanorod@CdSe/ZnS quantum dots

• Siyi Hu,
• Yu Ren,
• Yue Wang,
• Jinhua Li,
• Junle Qu,
• Liwei Liu,
• Hanbin Ma and
• Yuguo Tang

Beilstein J. Nanotechnol. 2019, 10, 22–31, doi:10.3762/bjnano.10.3

Controlling surface morphology and sensitivity of granular and porous silver films for surface-enhanced Raman scattering, SERS

• Sherif Okeil and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2018, 9, 2813–2831, doi:10.3762/bjnano.9.263

• ][27][28][29][30][31][32][33][34]. Additional methods appeared in which nanoparticles or metal films are deposited on structured substrates as carbon nanotubes [35][36][37][38][39], graphene foam [40], nanorod or nanopillar arrays [41][42], biological scaffolds [43][44], black silicon [45][46

• ], anisotropically etched single-crystal silicon [47], plasma-treated plastic [48] and anodic aluminum oxide films [49][50][51][52]. Some methods aim at the fabrication of three -dimensional silver or gold structures, such as oblique-angle vapor deposition used for the fabrication of silver nanorod arrays [53][54

Silencing the second harmonic generation from plasmonic nanodimers: A comprehensive discussion

• Jérémy Butet,
• Gabriel D. Bernasconi and
• Olivier J. F. Martin

Beilstein J. Nanotechnol. 2018, 9, 2674–2683, doi:10.3762/bjnano.9.250

• deformed to mimic the presence of defects on the nanorod surfaces. Finally, gold dimers made of rectangular arms are considered. Numerical Methods The linear optical response was calculated using a surface integral formulation [23][24]. All the nanostructures are embedded in a homogeneous medium with

• comparison, the scattering from a single nanorod is also shown as a dashed line. In all the scattering spectra, one can observe a peak corresponding to the excitation of a LSPR. This LSPR corresponds to the bonding dipolar mode, resulting from the in-phase coupling of the longitudinal dipolar modes supported

• by each nanorod. As expected, this mode redshifts as the gap between the nanorods decreases, i.e., as the coupling increases [2]. As a consequence of this coupling, the bonding dipolar mode for a dimer always arises at a longer wavelength than the longitudinal electric dipole mode of the

Polarization-dependent strong coupling between silver nanorods and photochromic molecules

• Gwénaëlle Lamri,
• Alessandro Veltri,
• Jean Aubard,
• Pierre-Michel Adam,
• Nordin Felidj and
• Anne-Laure Baudrion

Beilstein J. Nanotechnol. 2018, 9, 2657–2664, doi:10.3762/bjnano.9.247

• lithography to fabricate large arrays of silver nanorods on a glass substrate. The pitch of the arrays has been varied to keep the filling factor approximately equal to 10% and to avoid any lattice mode contribution in the optical spectra. For three different nanorod widths (70, 90 and 110 nm), the nanorod

• length was varied from the width value to the double width value. The height of the nanorods was fixed at 50 nm. Figure 1a shows a scanning electron microscope (SEM) image of a nanorod array recorded after the fabrication process. We used standard extinction spectroscopy to record the LSPR on each array

• . A halogen lamp is used to illuminate the sample from the glass side and the transmitted light is recorded through a 20× bright-field objective. The signal is then sent to a spectrometer to record extinction spectra. The Figure 1b shows typical extinction spectra recorded on five different nanorod

Enhancement of X-ray emission from nanocolloidal gold suspensions under double-pulse excitation

• Wei-Hung Hsu,
• Frances Camille P. Masim,
• Armandas Balčytis,
• Hsin-Hui Huang,
• Tetsu Yonezawa,
• Aleksandr A. Kuchmizhak,
• Saulius Juodkazis and
• Koji Hatanaka

Beilstein J. Nanotechnol. 2018, 9, 2609–2617, doi:10.3762/bjnano.9.242

• that the appropriate size for the highest X-ray intensity is 40–50 nm. For ultrasound generation under fs-laser excitation [34][49], gold nanorod particles with more efficient surface plasmon resonance effects [50] were also used. Further enhancements of X-ray intensities are expected under double

ZnO-nanostructure-based electrochemical sensor: Effect of nanostructure morphology on the sensing of heavy metal ions

• Marina Krasovska,
• Vjaceslavs Gerbreders,
• Irena Mihailova,
• Andrejs Ogurcovs,
• Eriks Sledevskis,
• Andrejs Gerbreders and
• Pavels Sarajevs

Beilstein J. Nanotechnol. 2018, 9, 2421–2431, doi:10.3762/bjnano.9.227

• components fall out as sediments. Furthermore, maintaining the temperature below the boiling point prevents any intense evaporation of the working solution, thereby allowing the experiment to be carried out without the use of an autoclave. In order to grow uniform and vertically aligned ZnO nanorod arrays

• times and dried. More detailed information can be found in [15][16]. The ZnO nanoneedles were synthesized by increasing the solution’s pH level to form nanorod arrays with reduced diameters and higher aspect ratios. In order to maintain the chemical purity of the samples, the same chemical components

• nanorod and nanotube arrays. Inset: EDS spectrum of the as-synthesized samples. CV curves of aqueous Pb(NO3)2 solution on ZnO electrodes with different morphologies: (a) nanorods, (b) nanotubes, (c) nanoneedles, and (d) CV reduction peak dependence on Pb(NO3)2 concentration for all morphologies. CV curves

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• reduced to a trivalent state [186]. Gao et al. fabricated MFe2O4 (M = Ni2+, Zn2+, Co2+ and Sr2+) modified TiO2 nanorod arrays (NRAs) to compare their photoelectrochemical and photocatalytic activity with that of bare TiO2 NRAs towards reduction of Cr(VI) [97]. All the modified TiO2 NRAs exhibited strong

Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations

• Jaison Jeevanandam,
• Ahmed Barhoum,
• Yen S. Chan,
• Alain Dufresne and
• Michael K. Danquah

Beilstein J. Nanotechnol. 2018, 9, 1050–1074, doi:10.3762/bjnano.9.98

• -object with three external nanoscale dimensions. The terms nanorod or nanoplate are employed, instead of nanoparticle (NP) when the longest and the shortest axes lengths of a nano-object are different. Nanofiber: When two similar exterior nanoscale dimensions and a third larger dimension are present in a

Facile synthesis of a ZnO–BiOI p–n nano-heterojunction with excellent visible-light photocatalytic activity

• Mengyuan Zhang,
• Jiaqian Qin,
• Pengfei Yu,
• Bing Zhang,
• Mingzhen Ma,
• Xinyu Zhang and
• Riping Liu

Beilstein J. Nanotechnol. 2018, 9, 789–800, doi:10.3762/bjnano.9.72

• . described the synthesis of p–n heterostructures where p-type BiOI nanoplates decorated on n-type ZnO nanorod arrays which were synthesized through a solvothermal route. The high-contact areas provided by the fast charge transfer channel of BiOI and ZnO create the efficient photocatalyst [35]. Tong et al

Surface-plasmon-enhanced ultraviolet emission of Au-decorated ZnO structures for gas sensing and photocatalytic devices

• T. Anh Thu Do,
• Truong Giang Ho,
• Thu Hoai Bui,
• Quang Ngan Pham,
• Hong Thai Giang,
• Thi Thu Do,
• Duc Van Nguyen and
• Dai Lam Tran

Beilstein J. Nanotechnol. 2018, 9, 771–779, doi:10.3762/bjnano.9.70

• are expected to serve as a potential photocatalysts with highly effective performance. For instance, plasmonic Au NP/vertically aligned ZnO nanorod structures were proposed for water splitting, solar cells, and environmental remediation [17][18][19]. Ag/ZnO nanohybrid structures were synthesized and

• agglomeration, but also bind to the crystal seed surface. These are believed to play an important role in the weakening of grain growth and the assembly of nanorods. Owing to the stronger bonding between the active component of the deposition solution and substrate surface, the self-assembly of the nanorod

Facile phase transfer of gold nanorods and nanospheres stabilized with block copolymers

• Yaroslav I. Derikov,
• Georgiy A. Shandryuk,
• Raisa V. Talroze,
• Alexander A. Ezhov and
• Yaroslav V. Kudryavtsev

Beilstein J. Nanotechnol. 2018, 9, 616–627, doi:10.3762/bjnano.9.58

• various organic solvents. The same copolymer can be further subjected to microphase separation so that no third component compatibilizer in the hybrid composite material is needed. Results and Discussion Au nanorod synthesis and phase transfer We synthesized Au nanorods by the seeded growth method [14][15

• dispersible in tetrahydrofuran, chloroform, methylene chloride, toluene and benzene. The phase transfer procedure is fully described in the Experimental section. The morphology and optical characteristics of the initial Au nanorod hydrosol and of the polymer-coated Au sol dried from benzene are shown in

• Figure 1. The results of the statistical analysis of the nanorod geometry from a series of transmission electron microscopy (TEM) images are listed in Table 1. The small values of the Pearson coefficients in Table 1 and the shapes of the scatter plots in Figure 1 indicate the absence of correlations

Sugarcane juice derived carbon dot–graphitic carbon nitride composites for bisphenol A degradation under sunlight irradiation

• Lan Ching Sim,
• Jing Lin Wong,
• Chen Hong Hak,
• Jun Yan Tai,
• Kah Hon Leong and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2018, 9, 353–363, doi:10.3762/bjnano.9.35

• [26][27], and degradation of pollutants [28][29][30]. However, the photocatalytic performance of bulk g-C3N4 remains unsatisfactory because of the fast recombination rate of electron pairs and narrower light absorption range over the entire solar spectrum. Turning g-C3N4 into a mesoporous nanorod

Review on optofluidic microreactors for artificial photosynthesis

• Xiaowen Huang,
• Jianchun Wang,
• Tenghao Li,
• Jianmei Wang,
• Min Xu,
• Weixing Yu,
• Abdel El Abed and
• Xuming Zhang

Beilstein J. Nanotechnol. 2018, 9, 30–41, doi:10.3762/bjnano.9.5

• membrane-based reactors were reported as well, for instance, mesoporous CdS/TiO2/SBA-15@carbon paper composite membranes [77] and copper-decorated TiO2 nanorod thin films [78]. In addition to the PDMS/PMMA-based microchannel reactors, bacterium has been shown to be a good microreactor as well. Yang et al

Gas-sensing behaviour of ZnO/diamond nanostructures

• Marina Davydova,
• Alexandr Laposa,
• Jiri Smarhak,
• Alexander Kromka,
• Neda Neykova,
• Josef Nahlik,
• Jiri Kroutil,
• Jan Drahokoupil and
• Jan Voves

Beilstein J. Nanotechnol. 2018, 9, 22–29, doi:10.3762/bjnano.9.4

• were exposed to pure hydrogen plasma for 10 min in order to create the p-type surface conductivity (Figure 1a) [29]. Vertically aligned 1-D ZnO nanorod arrays were synthesized either on a bare IDE glass substrate (Figure 1b) or on an IDE glass substrate covered with a diamond thin film (Figure 1c) by

• -oriented ZnO layer and an intrinsic diamond (i-diamond) passivated by hydrogen on the surface (Figure 4). The crystallographic orientation of the model ZnO surface was set to the real orientation of the nanorod sidewalls to better assess the influence of gas molecule interaction with the real hybrid ZnO

CdSe nanorod/TiO₂ nanoparticle heterojunctions with enhanced solar- and visible-light photocatalytic activity

• Fakher Laatar,
• Hatem Moussa,
• Halima Alem,
• Lavinia Balan,
• Emilien Girot,
• Ghouti Medjahdi,
• Hatem Ezzaouia and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2017, 8, 2741–2752, doi:10.3762/bjnano.8.273

The role of ligands in coinage-metal nanoparticles for electronics

• Ioannis Kanelidis and
• Tobias Kraus

Beilstein J. Nanotechnol. 2017, 8, 2625–2639, doi:10.3762/bjnano.8.263

• nanoparticles by the reduction of silver nitrate in the presence of PVP. The twin boundaries served as active sites for the addition of silver atoms as the strong interaction between PVP and the sides of the initially formed nanorod allowed preferential diffusion of the silver atoms to the ends of the nanorods

• spherical and rod-like gold nanoparticles dispersed in a formulation with PEDOT:PSS. Composite films with nanorod volume fractions between 10 and 70% were deposited onto quartz substrates; the film with the highest metal content reached a conductivity of 2000 S/cm without further processing, approximately

• (125 S/cm) [142]. Other researchers employed ligand exchange to attach PEDOT:PSS on the surface of gold nanorods that have lower percolation thresholds than spheres of equivalent volume. The original surface ligand used in nanorod synthesis (CTAB) forms insulating barriers in films. A thin PEDOT:PSS

In situ controlled rapid growth of novel high activity TiB₂/(TiB₂–TiN) hierarchical/heterostructured nanocomposites

• Jilin Wang,
• Hejie Liao,
• Yuchun Ji,
• Fei Long,
• Yunle Gu,
• Zhengguang Zou,
• Weimin Wang and
• Zhengyi Fu

Beilstein J. Nanotechnol. 2017, 8, 2116–2125, doi:10.3762/bjnano.8.211

• –500 nm, and every particle surface was covered by many multibranched, tapered nanorods with diameters in the range of 10–40 nm and lengths of 50–200 nm. In addition, the tapered nanorod presents a rough surface with abundant exposed atoms. The internal and external components of the nanorods were TiB2

• was performed, respectively. As shown in Figure 2d, the interlayer distances of the single tapered nanorod were measured as d1 = 0.319 nm and d2 = 0.241 nm, corresponding to the (001) plane of TiB2 and the (111) plane of TiN, respectively. The corresponding SAED pattern (Figure 2e) indicated that the

Systematic control of α-Fe₂O₃ crystal growth direction for improved electrochemical performance of lithium-ion battery anodes

• Nan Shen,
• Miriam Keppeler,
• Barbara Stiaszny,
• Holger Hain,
• Filippo Maglia and
• Madhavi Srinivasan

Beilstein J. Nanotechnol. 2017, 8, 2032–2044, doi:10.3762/bjnano.8.204

• Nanyang Drive, Singapore 637553, Singapore, BMW Group, Petuelring 130, 80788 Munich, Germany 10.3762/bjnano.8.204 Abstract α-Fe2O3 nanomaterials with an elongated nanorod morphology exhibiting superior electrochemical performance were obtained through hydrothermal synthesis assisted by diamine

• derivatives as shape-controlling agents (SCAs) for application as anodes in lithium-ion batteries (LIBs). The physicochemical characteristics were investigated via XRD and FESEM, revealing well-crystallized α-Fe2O3 with adjustable nanorod lengths between 240 and 400 nm and aspect ratios in the range from 2.6

• to 5.7. The electrochemical performance was evaluated by cyclic voltammetry and charge–discharge measurements. A SCA test series, including ethylenediamine, 1,2-diaminopropane, 2,3-diaminobutane, and N-methylethylenediamine, was implemented in terms of the impact on the nanorod aspect ratio. Varied

Freestanding graphene/MnO₂ cathodes for Li-ion batteries

• Şeyma Özcan,
• Aslıhan Güler,
• Tugrul Cetinkaya,
• Mehmet O. Guler and
• Hatem Akbulut

Beilstein J. Nanotechnol. 2017, 8, 1932–1938, doi:10.3762/bjnano.8.193

• nanostructure composed of uniform nanowires have 1–2 μm length and 40–60 nm average diameter. β-MnO2 (Figure 1b) shows that the as-prepared β-MnO2 sample has a nanorod structure with 0.5–1 μm length and 20–40 nm average diameter. The γ-MnO2 (Figure 1c) exhibits an urchin-like structure with 0.5–1 μm average

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

Structural properties and thermal stability of cobalt- and chromium-doped α-MnO₂ nanorods

• Romana Cerc Korošec,
• Polona Umek,
• Alexandre Gloter,
• Jana Padežnik Gomilšek and
• Peter Bukovec

Beilstein J. Nanotechnol. 2017, 8, 1032–1042, doi:10.3762/bjnano.8.104

• synthesized at 170 °C is significantly lower than in the undoped samples. Analysis of an individual cobalt-doped α-MnO2 nanorod with HAADF-STEM reveals that the distribution of cobalt through the cross-section of the nanorod is uniform. The course of thermal decomposition of the doped nanorods is similar to

• ). The sulfur detected in the samples is originating from the sulfuric acid that was a part of the reaction mixture [26]. The chemical composition of an individual nanorod (Co-90) was determined using electron energy loss spectroscopy (EELS) in combination with high-angle annular dark field scanning

• transmission electron microscopy (HAADF-STEM), both shown in Figure 7. The chemical profiles of manganese and oxygen show a correlation with the nanorod shape while the cobalt profile shows more fluctuations due to the rather lower cobalt content (1.3 atom %). Nevertheless, it is clear that cobalt is present

Recombinant DNA technology and click chemistry: a powerful combination for generating a hybrid elastin-like-statherin hydrogel to control calcium phosphate mineralization

• Mohamed Hamed Misbah,
• Mercedes Santos,
• Luis Quintanilla,
• Christina Günter,
• Matilde Alonso,
• Andreas Taubert and
• José Carlos Rodríguez-Cabello

Beilstein J. Nanotechnol. 2017, 8, 772–783, doi:10.3762/bjnano.8.80

• these CP structures, dicalcium phosphate dihydrate (DCPD), hydroxyapatite (HA) and β-tricalcium phosphate (β-TCP) have attracted attention because of their potential applications [2][3]. HA is a stable crystalline phase that forms the main inorganic component of bone and teeth [2][4]. HA has a nanorod

Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields

• Arpita Jana,
• Elke Scheer and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2017, 8, 688–714, doi:10.3762/bjnano.8.74

• life, high reversible specific capacity and excellent rate capability for LIB applications [187]. Self-assembled CoO nanorod clusters were synthesised on 3D graphene through a facile hydrothermal method followed by a heat treatment by Zhu et al. This hybrid exhibited good electromechanical performance