Ultrathin hydrophobic films based on the metal organic framework UiO-66-COOH(Zr)

• Miguel A. Andrés,
• Clemence Sicard,
• Christian Serre,
• Olivier Roubeau and
• Ignacio Gascón

Beilstein J. Nanotechnol. 2019, 10, 654–665, doi:10.3762/bjnano.10.65

• containing 0.5 mg·mL−1 of pure MOF were used and a proper amount of ODP was added to prepare the mixture containing the MOF and 10 wt % of ODP. SEM images were taken at 10 kV with a FEG column using a SEM Inspect F50 (FEI Company). All samples were coated with a layer of platinum (5–10 nm) prior to SEM

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

• Juan Casanova-Cháfer,
• Carla Bittencourt and
• Eduard Llobet

Beilstein J. Nanotechnol. 2019, 10, 565–577, doi:10.3762/bjnano.10.58

• were taken at 80 kV. Fabrication of the sensor substrate A 10 × 10 mm2 alumina substrate was employed. Interdigitated electrodes and a heating resistor were screen-printed on either side of the substrate employing a platinum ink (see Supporting Information File 1, Figure S6). The electrode area was

• coated with a mat of CNTs via airbrushing through a shadow mask. Once the sensors were sputtered with gold and functionalized with thiols, two-wire contacts were made on the samples using a conductive epoxy (Ag component metallization, Heraeus) and platinum wires. The samples were bonded to a 20 × 30 mm2

Widening of the electroactivity potential range by composite formation – capacitive properties of TiO₂/BiVO₄/PEDOT:PSS electrodes in contact with an aqueous electrolyte

• Konrad Trzciński,
• Mariusz Szkoda,
• Andrzej P. Nowak,
• Marcin Łapiński and
• Anna Lisowska-Oleksiak

Beilstein J. Nanotechnol. 2019, 10, 483–493, doi:10.3762/bjnano.10.49

• cell was used for cyclic voltammetry and galvanostatic charge–discharge cycles measurements. Platinum mesh acted as a counter electrode, and Ag/AgCl (0.1 M KCl) was used as the reference electrode. The geometric surface area of tested electrodes was equal to 0.5 cm2. Current densities used for charge

• %) electrolyte containing 0.27 M NH4F and 1 M H3PO4 described previously [31]. The anodization process was performed in a two-electrode cell using platinum mesh as the cathode. The distance between the electrodes was about 2 cm. The anodization voltage was kept at 40 V for 2 h. The as-prepared electrodes were

• . The hydrogenation process significantly affects TiO2 conductivity and specific capacitance [34]. After the hydrogenation process samples were named as Ti/TiO2:H/BiVO4:H. PEDOT:PSS Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) films were prepared by direct electropolymerization on a platinum

Temperature-dependent Raman spectroscopy and sensor applications of PtSe₂ nanosheets synthesized by wet chemistry

• Mahendra S. Pawar and
• Dattatray J. Late

Beilstein J. Nanotechnol. 2019, 10, 467–474, doi:10.3762/bjnano.10.46

• effect. Apart from this, these TMDCs, for example MoS2 and MoSe2, show an indirect to direct band gap transition [13][14][15][16][17]. A 2D platinum diselenide (PtSe2) material has recently joined the growing class of stable TMDCs due its promising applications. The 2D PtSe2 has not been explored much to

• electronic device applications [20][21][22]. Bulk PtSe2 was first prepared in 1909 by Minozzi from elements [23]. PtSe2 nanosheets have been recently prepared by heating thin foils of platinum in selenium vapors at 400 °C [19][24]. In this paper we have synthesized few-layer-thick PtSe2 nanosheets by a wet

Integration of LaMnO_3+δ films on platinized silicon substrates for resistive switching applications by PI-MOCVD

• Raquel Rodriguez-Lamas,
• Dolors Pla,
• Odette Chaix-Pluchery,
• Benjamin Meunier,
• Fabrice Wilhelm,
• Andrei Rogalev,
• Laetitia Rapenne,
• Xavier Mescot,
• Quentin Rafhay,
• Hervé Roussel,
• Michel Boudard,
• Carmen Jiménez and
• Mónica Burriel

Beilstein J. Nanotechnol. 2019, 10, 389–398, doi:10.3762/bjnano.10.38

• frequency of 2.5 Hz, and an opening time of the valve of 2 ms. These last two parameters allowed for a good evaporation of the precursors and a constant flux during deposition. Samples grown at 675 °C and ca. 1 h of deposition time (i.e., 10000 pulses) evidenced the thermal instability of the platinum

Site-specific growth of oriented ZnO nanocrystal arrays

• Rekha Bai,
• Dinesh K. Pandya,
• Sujeet Chaudhary,
• Veer Dhaka,
• Vladislav Khayrudinov,
• Jori Lemettinen,
• Christoffer Kauppinen and
• Harri Lipsanen

Beilstein J. Nanotechnol. 2019, 10, 274–280, doi:10.3762/bjnano.10.26

• , three electrode, glass cell. The bare/polymer-coated patterned ITO substrates were used as a working electrode (2 × 2 cm2) while a platinum sheet (2.5 × 2.5 cm2) and a saturated calomel electrode (SCE) were used as the counter and reference electrodes, respectively. The electrolyte (bath) temperature

Targeting strategies for improving the efficacy of nanomedicine in oncology

• Gonzalo Villaverde and
• Alejandro Baeza

Beilstein J. Nanotechnol. 2019, 10, 168–181, doi:10.3762/bjnano.10.16

• loaded with a platinum(IV) pro-drug that released active cisplatin(II) in the reductive environment of the intracellular space. Another targeting moiety that has been employed for delivering therapeutics to mitochondria is triphenylphosphine [44]. This positively charged group also binds to the

Wet chemistry route for the decoration of carbon nanotubes with iron oxide nanoparticles for gas sensing

• Hussam M. Elnabawy,
• Juan Casanova-Chafer,
• Badawi Anis,
• Mostafa Fedawy,
• Mattia Scardamaglia,
• Carla Bittencourt,
• Ahmed S. G. Khalil,
• Eduard Llobet and
• Xavier Vilanova

Beilstein J. Nanotechnol. 2019, 10, 105–118, doi:10.3762/bjnano.10.10

• layer were connected to a printed circuit board (PCB) using platinum wires. Those wires were attached to the heaters and CNT layers using silver paste that was cured in an oven at 120 °C for 30 minutes. To connect the Pt wires to the PCB we used tin wire and a soldering iron. Wire bonded sensors ready

• for testing can be seen in the Supporting Information File 2 (Figure S2). The silicon substrates onto which carbon nanotubes were deposited were glued to an alumina substrate that included a platinum heater employing a thermally conductive epoxy. A teflon chamber, which allowed allocating up to four

Amorphous Ni_xCo_yP-supported TiO₂ nanotube arrays as an efficient hydrogen evolution reaction electrocatalyst in acidic solution

• Yong Li,
• Peng Yang,
• Bin Wang and
• Zhongqing Liu

Beilstein J. Nanotechnol. 2019, 10, 62–70, doi:10.3762/bjnano.10.6

• electrochemical workstation (Chenhua, Shanghai) including linear sweep voltammetry (LSV), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and Tafel analysis at 25 °C. The three electrode system was constituted of the sample working electrode, a platinum counter electrode, a Ag/AgCl

Bidirectional biomimetic flow sensing with antiparallel and curved artificial hair sensors

• Claudio Abels,
• Antonio Qualtieri,
• Toni Lober,
• Alessandro Mariotti,
• Lily D. Chambers,
• Massimo De Vittorio,
• William M. Megill and
• Francesco Rizzi

Beilstein J. Nanotechnol. 2019, 10, 32–46, doi:10.3762/bjnano.10.4

• platinum or tungsten and its length varies between 50 and 200 μm. This approach based on their novel 3D assembly method makes it possible to form large arrays of sensors on a variety of substrate materials. The research group from the MESA+ Institute for Nanotechnology at the University of Twente developed

• sensor array in parallel to two opposing, bent beams, air flow direction was determined by measuring the variation of platinum resistance between different cantilever beams with an external LCR meter (inductance L, capacitance C, and resistance R). The least resistance variation was caused by the upwind

• × 500 μm × 10 μm) which bent as air flow hit the plate. While the plate received the drag force of the air flow, the cantilevers measured the drag force using platinum strain gauges. One variable resistor (strain gauge) on each of the two cantilevers and two fixed resistances on the sensor substrate

Electrolyte tuning in dye-sensitized solar cells with N-heterocyclic carbene (NHC) iron(II) sensitizers

• Mariia Karpacheva,
• Catherine E. Housecroft and
• Edwin C. Constable

Beilstein J. Nanotechnol. 2018, 9, 3069–3078, doi:10.3762/bjnano.9.285

• series resistance (Rs), a resistance (RPt) and a constant phase element (CPE1) to model a platinum counter electrode, an extended distributed element (DX1) which represented the TiO2/electrolyte interface as a transmission line model, and a Warburg element (Ws) associated with diffusion of the

• used in the dye bath (in case of MeCN the electrodes were washed a second time with acetone) and dried with a heat gun. Commercial counter electrodes from Solaronix (Test Cell Platinum Electrodes Drilled) were rinsed with EtOH and dried on a heating plate at 500 °C for 30 min. The TiO2 electrodes and

A novel polyhedral oligomeric silsesquioxane-modified layered double hydroxide: preparation, characterization and properties

• Xianwei Zhang,
• Zhongzhu Ma,
• Hong Fan,
• Carla Bittencourt,
• Jintao Wan and
• Philippe Dubois

Beilstein J. Nanotechnol. 2018, 9, 3053–3068, doi:10.3762/bjnano.9.284

• dimensions of NLDH are roughly in accordance with the results obtained from TEM. However, as the thickness of the platinum coating layer is about 15 nm, close to the size of OLDH primary particles, the surface morphology of OLDH is not easily verified and seems to remind of stacked nuggets. Elemental

• hood before characterization. Scanning electron microscopy (SEM) images were recorded on an SU-70 or Utral 55 to study the surface morphologies. The samples were placed on a conducting carbon cement holder and were then coated with a thin layer of platinum using a sputter coater. Thermogravimetric

Hydrogen-induced plasticity in nanoporous palladium

• Markus Gößler,
• Eva-Maria Steyskal,
• Markus Stütz,
• Norbert Enzinger and
• Roland Würschum

Beilstein J. Nanotechnol. 2018, 9, 3013–3024, doi:10.3762/bjnano.9.280

• , reversible expansion. This distinguishes palladium from other metals in the same group of the periodic table, such as platinum or nickel, which are only capable of adsorbing hydrogen mainly on their surfaces. In the literature, a solubility of hydrogen in palladium up to concentrations of about 0.7 (H/Pd

In situ characterization of nanoscale contaminations adsorbed in air using atomic force microscopy

• Jesús S. Lacasa,
• Lisa Almonte and
• Jaime Colchero

Beilstein J. Nanotechnol. 2018, 9, 2925–2935, doi:10.3762/bjnano.9.271

• where the flat part of the cantilever chip has been analyzed in (true) nc-DAFM using Kelvin probe microscopy (KPM) to measure the contact potential. The three analyzed samples correspond to the surface of platinum-films evaporated onto silicon cantilevers, but with three different state of contamination

• platinum surface is covered by some contamination (round islands); that is, one would expect two kinds of materials on the surface: the platinum substrate and some other most probably organic material on top of the platinum. Surprisingly, the contact potential image (Figure 2Ae) is completely homogeneous

• , leading to the conclusion that either the islands are completely transparent to the measurement of contact potential or that the platinum surface is covered everywhere by the same material, that is, the contact-potential image detects the same material on the islands as well as on the flatter part between

Charged particle single nanometre manufacturing

• Philip D. Prewett,
• Cornelis W. Hagen,
• Claudia Lenk,
• Steve Lenk,
• Marcus Kaestner,
• Tzvetan Ivanov,
• Ahmad Ahmad,
• Ivo W. Rangelow,
• Xiaoqing Shi,
• Stuart A. Boden,
• Alex P. G. Robinson,
• Dongxu Yang,
• Sangeetha Hari,
• Marijke Scotuzzi and
• Ejaz Huq

Beilstein J. Nanotechnol. 2018, 9, 2855–2882, doi:10.3762/bjnano.9.266

• van Oven et al. [65] using the organometallic precursor trimethyl(methylcyclopentadienyl)platinum(IV) (MeCpPtMe3). A combination of low beam current, low working distance and multiple pass patterning, synchronised with the 50 Hz disturbances, resulted in the successful fabrication of 3 nm Pt/C lines

• rates of the substrate materials to be made and hence the selectivity. A set of EBID masks with structures between 8 and 20 nm were fabricated using the platinum precursor MeCpPtMe3 on a silicon substrate with a 20 kV, 40 pA beam providing a dose of 4000 C·m−2 in ultrahigh-resolution (UHR) mode. The

Comparative biological effects of spherical noble metal nanoparticles (Rh, Pd, Ag, Pt, Au) with 4–8 nm diameter

• Alexander Rostek,
• Marina Breisch,
• Kevin Pappert,
• Kateryna Loza,
• Marc Heggen,
• Manfred Köller,
• Christina Sengstock and
• Matthias Epple

Beilstein J. Nanotechnol. 2018, 9, 2763–2774, doi:10.3762/bjnano.9.258

• , palladium, platinum, gold) that do not release ions are not cytotoxic under these conditions. Keywords: cytotoxicity; electron microscopy; metals; nanoparticles; nanotoxicity; Introduction Inorganic and metallic nanoparticles represent a well-established part of materials science, heterogeneous catalysis

• ]. Some authors have reported antimicrobial activity of gold, platinum, and palladium nanoparticles in the size range of 5 to 30 nm against gram-negative and gram-positive bacteria [23][24][25] and distinct adverse biological effects such as genotoxicity, induction of apoptosis and cell cycle arrest of

• = 40,000 g mol−1), sodium borohydride (Sigma-Aldrich, ≥96%, p.a.) trisodium citrate (Acros, anhydrous 98%), tannic acid (Fluka, p.a.), and D-glucose (Baker, p.a.) were all used as obtained. Aqueous solutions of H2PtCl6 or HAuCl4 (prepared by dissolution of platinum or gold in aqua regia), RhCl3, NaPdCl4

Accurate control of the covalent functionalization of single-walled carbon nanotubes for the electro-enzymatically controlled oxidation of biomolecules

• Naoual Allali,
• Veronika Urbanova,
• Mathieu Etienne,
• Xavier Devaux,
• Martine Mallet,
• Brigitte Vigolo,
• Jean-Joseph Adjizian,
• Chris P. Ewels,
• Sven Oberg,
• Alexander V. Soldatov,
• Edward McRae,
• Yves Fort,
• Manuel Dossot and
• Victor Mamane

Beilstein J. Nanotechnol. 2018, 9, 2750–2762, doi:10.3762/bjnano.9.257

• electrolyte), and a platinum wire auxiliary electrode. A working electrode (WE) incorporating the f-SWCNTs deposited on the GCE surface. a) HRTEM micrographs of the raw HIPCO material. The arrows point out residual iron nanoparticles. b) HRSTEM BF image showing carbonaceous impurities at the surface of SWCNTs

Low cost tips for tip-enhanced Raman spectroscopy fabricated by two-step electrochemical etching of 125 µm diameter gold wires

• Antonino Foti,
• Francesco Barreca,
• Enza Fazio,
• Cristiano D’Andrea,
• Paolo Matteini,
• Onofrio Maria Maragò and
• Pietro Giuseppe Gucciardi

Beilstein J. Nanotechnol. 2018, 9, 2718–2729, doi:10.3762/bjnano.9.254

• absolute ethanol (>99.5 wt %). All the reagents used are of analytical grade. The experimental setup is shown in Figure 1. The setup includes (Figure 1a) an adjustable DC voltage generator connected to (Figure 1b) the gold wire to be etched (the anode) and to a platinum wire (500 µm diameter, Advent PT5408

• Au(III) (reactions 1 and 2), yielding a yellow precipitate. At the same time, H+ ions are reduced at the platinum wire surface, leading to H2 gas formation (reaction 3). The H2, together with O2 and Cl2 present in the solution, can cause intense bubbling when the reaction is fast enough, as for

Pattern generation for direct-write three-dimensional nanoscale structures via focused electron beam induced deposition

• Lukas Keller and
• Michael Huth

Beilstein J. Nanotechnol. 2018, 9, 2581–2598, doi:10.3762/bjnano.9.240

• , the pattern files for B and D with the bpPAA. Besides the fact that both A and C do not comply as nicely to the target geometry as B and D, B and D are also taller due to more efficient use of precursor. All four structures were deposited in high-resolution mode on SiO2 employing the platinum

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• /galvanostat (PG-stat) (WonA Tech, ZIVE SP1). Co3O4/FTO/glass, Ag/AgCl (KCl, 3 M), and platinum gauze were connected to the working, reference, and counter electrodes of the PG-stat, respectively. All PEC cell measurements were carried out in 0.1 M NaOH aqueous electrolyte pH 12.5 at room temperature. A white

Magnetism and magnetoresistance of single Ni–Cu alloy nanowires

• Andreea Costas,
• Camelia Florica,
• Elena Matei,
• Maria Eugenia Toimil-Molares,
• Ionel Stavarache,
• Andrei Kuncser,
• Victor Kuncser and
• Ionut Enculescu

Beilstein J. Nanotechnol. 2018, 9, 2345–2355, doi:10.3762/bjnano.9.219

• electrode potential than Ni. Electrodeposition was performed using a potentiostat/galvanostat (PARSTAT 2276) controlled by a PC and employing a typical three-electrode configuration: a platinum foil of 1 cm2 (counter electrode), a thin film of Au covering one side of the polycarbonate membrane (working

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

Localized photodeposition of catalysts using nanophotonic resonances in silicon photocathodes

• Evgenia Kontoleta,
• Sven H. C. Askes,
• Lai-Hung Lai and
• Erik C. Garnett

Beilstein J. Nanotechnol. 2018, 9, 2097–2105, doi:10.3762/bjnano.9.198

• spots”. These areas can be used for localized extraction of the photogenerated charges, which in turn could drive chemical reactions for synthesis of catalytic materials. In this work, we use these nanophotonic hot spots in vertical silicon nanowires to locally deposit platinum nanoparticles in a photo

• -electrochemical system. The tapering angle of the silicon nanowires as well as the excitation wavelength are used to control the location of the hot spots together with the deposition sites of the platinum catalyst. A combination of finite difference time domain (FDTD) simulations with scanning electron

• microscopy image analysis showed a reasonable correlation between the simulated hot spots and the actual experimental localization and quantity of platinum atoms. This nanophotonic approach of driving chemical reactions at the nanoscale using the optical properties of the photo-electrode, can be very

High-throughput synthesis of modified Fresnel zone plate arrays via ion beam lithography

• Kahraman Keskinbora,
• Umut Tunca Sanli,
• Margarita Baluktsian,
• Corinne Grévent,
• Markus Weigand and
• Gisela Schütz

Beilstein J. Nanotechnol. 2018, 9, 2049–2056, doi:10.3762/bjnano.9.194

• the beam path), the current and the dwell time need to be precisely adjusted. Following the structuring of the zones, a ca. 3 µm thick beamstop was deposited in the central inactive region via focused ion beam induced deposition (FIBID) of Pt using trimethyl(cyclopentadienyl)platinum(IV), (CH3

• beamstop via FIBID. The parasitic deposition layer, where a Pt/C layer deposits unintentionally on the regions adjacent to the actual region of interest, covers the zones with a thin layer of platinum/gallium/carbon mixture (see Supporting Information File 1, Figure S3), which absorbs incident X-rays and