Micro- and nanotechnology in biomedical engineering for cartilage tissue regeneration in osteoarthritis

• Zahra Nabizadeh,
• Mahmoud Nasrollahzadeh,
• Hamed Daemi,
• Mohamadreza Baghaban Eslaminejad,
• Ali Akbar Shabani,
• Mehdi Dadashpour,
• Majid Mirmohammadkhani and
• Davood Nasrabadi

Beilstein J. Nanotechnol. 2022, 13, 363–389, doi:10.3762/bjnano.13.31

• films (nanofiber composites) coated with PLDLA nanofibers on the behavior of bovine chondrocytes [109]. The researchers observed that electrospun nanofibers supported the adhesion of cells and maintained the chondrocyte phenotype. Besides, the adhesivity and mechanics of the nanofiber-based scaffolds

• , and OH) and surface roughness to CNT, Antonioli et al. used oxygen plasma treatment and fabricated novel superhydrophilic VA–CTN films. This treatment could increase the wettability of the nanofilms to acquire appreciable cytocompatibility [134]. The chondrocytes expressed major chondrogenic markers

Selected properties of Al_xZn_yO thin films prepared by reactive pulsed magnetron sputtering using a two-element Zn/Al target

• Witold Posadowski,
• Artur Wiatrowski,
• Jarosław Domaradzki and
• Michał Mazur

Beilstein J. Nanotechnol. 2022, 13, 344–354, doi:10.3762/bjnano.13.29

• Witold Posadowski Artur Wiatrowski Jaroslaw Domaradzki Michal Mazur Wroclaw University of Science and Technology, Faculty of Electronics, Photonics and Microsystems, Janiszewskiego 11/17, 50-372 Wrocław, Poland 10.3762/bjnano.13.29 Abstract AlxZnyO thin films were obtained by reactive pulsed

• magnetron sputtering. A two-element Zn/Al planar target was used as source material prepared in the form of a Zn disc (100 mm diameter) with Al rings pressed into its surface. The sputtering processes were carried out in a mixture of argon and oxygen. The films were deposited with a discharge power of PE

• = 400 W, which corresponded to a power density on the target surface of approximately 5 W/cm2. The films were deposited on glass strip substrates, placed symmetrically over the target, making it possible to obtain films with different composition and thickness. The film sheet resistance was measured as

Controllable two- and three-state magnetization switching in single-layer epitaxial Pd_1−xFe_x films and an epitaxial Pd_0.92Fe_0.08/Ag/Pd_0.96Fe_0.04 heterostructure

• Igor V. Yanilkin,
• Amir I. Gumarov,
• Gulnaz F. Gizzatullina,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2022, 13, 334–343, doi:10.3762/bjnano.13.28

• , extending its functionality. Palladium–iron alloys Pd1−xFex with x < 0.10 are of strong practical interest for such MJJ and SSV structures [13][14][15][16][17] as a material for weak ferromagnetic links with tunable magnetic properties [18]. Epitaxial films of Pd1−xFex alloys with low iron content x are

• easy-plane ferromagnets with four-fold anisotropy in the film plane [18][19]. Our conjecture is a possibility to switch the magnetic moment of a Pd1−xFex alloy film between the steady directions (90° apart) as it had been done with epitaxial iron films [20][21][22]. To realize this idea, it is

• magnetic moment by 90° in epitaxial Pd1−xFex films has not been yet explored. In [18][19], based on magnetometry data, it was assumed that magnetization reversal occurs as a result of the coherent rotation of the magnetic moment by 180°; and in the study of the Pd0.96Fe0.04/VN/Pd0.92Fe0.08 structure [23

A broadband detector based on series YBCO grain boundary Josephson junctions

• Egor I. Glushkov,
• Alexander V. Chiginev,
• Leonid S. Kuzmin and
• Leonid S. Revin

Beilstein J. Nanotechnol. 2022, 13, 325–333, doi:10.3762/bjnano.13.27

• deposition of YBaCuO films on a bicrystal substrate [25]. This problem can be mitigated by using ion irradiation [4][18][26] or step-edge junction technology [19], which will significantly increase the receiving properties and efficiency of the JJ series at high frequencies. While the integral received power

Interfacial nanoarchitectonics for ZIF-8 membranes with enhanced gas separation

• Season S. Chen,
• Zhen-Jie Yang,
• Chia-Hao Chang,
• Hoong-Uei Koh,
• Sameerah I. Al-Saeedi,
• Kuo-Lun Tung and
• Kevin C.-W. Wu

Beilstein J. Nanotechnol. 2022, 13, 313–324, doi:10.3762/bjnano.13.26

• films were synthesized via an interfacial method, while an interfacial method and a counter-diffusion method were adopted to synthesize α-Al2O3-supported ZIF-8 membranes for CO2/N2 gas separation. Materials and Methods Chemicals Zinc nitrate hexahydrate, 2-methylimidazole (2-MIM), sodium formate of

• reagent grade, methanol and 1-octanol of analysis grade were purchased from Sigma-Aldrich. Deionized water produced with a Merck Millipore system was used. The α-Al2O3 disks (30 mm in diameter and 1 mm in thickness) were purchased from Fraunhofer IKTS. Synthesis of ZIF-8 free-standing films Zinc nitrate

• -ray diffraction were measured on a Rigaku Ultima IV with Cu Kα radiation (λ = 1.5418 Å) to check the crystallinity of the synthesized ZIF-8 thin films. The morphology of the supports, the free-standing thin films, and the supported membranes was observed by FE-SEM (NovaTM NanoSEM 230). The elemental

Investigation of a memory effect in a Au/(Ti–Cu)Ox-gradient thin film/TiAlV structure

• Damian Wojcieszak,
• Jarosław Domaradzki,
• Michał Mazur,
• Tomasz Kotwica and
• Danuta Kaczmarek

Beilstein J. Nanotechnol. 2022, 13, 265–273, doi:10.3762/bjnano.13.21

• analysis of resistive switching properties observed in a Au/(Ti–Cu)Ox/TiAlV structure with a gradient distribution of Cu and Ti along the (Ti–Cu)Ox thin film thickness. Thin films were prepared via multisource reactive magnetron co-sputtering. The programmed profile of the pulse width modulation

• resistive switching behavior. Results of optical, X-ray, and ultraviolet photoelectron spectroscopy measurements allowed us to elaborate the scheme of the bandgap alignment of the prepared thin films with respect to the Au and TiAlV electrical contacts. Detailed structure and elemental profile

• previous works [41][42] have shown that an interesting alternative to the well-known conventional structures, with a multilayer stack of thin films with different electrical conducting and nonconducting properties described above, could be a thin film the composition of which changes along its thickness

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• films form on most metal surfaces and act as a barrier to the corrosive environment, thus impeding further corrosion. The corrosion properties of MGs, for example, the ability to passivate and to remain in the passive state in corrosive aqueous solutions, have been addressed in many studies using

• electrochemical methods, often combined with surface analytical techniques [13][14][15]. Wang et al. [13] reported that the passive oxide films are grown as a double layer structure on MGs with a corrosion product layer underlying an inner barrier layer in NaCl and Na2SO4 solutions. Since most metals and alloys

• are susceptible to corrosion when exposed to environmental conditions, the role of surface chemistry for friction must be investigated. At the macroscale, the existence of metal oxide surface films on MGs enhanced the wear resistance in corrosive solutions and the fluid lubricating films formed by

Piezoelectric nanogenerator for bio-mechanical strain measurement

• Zafar Javed,
• Lybah Rafiq,
• Muhammad Anwaar Nazeer,
• Saqib Siddiqui,
• Muhammad Babar Ramzan,
• Muhammad Qamar Khan and
• Muhammad Salman Naeem

Beilstein J. Nanotechnol. 2022, 13, 192–200, doi:10.3762/bjnano.13.14

• usually non-polar as their structural packing is anti-parallel [21]. Usually, PVDF is non-reactive towards acids and bases. It was discovered in 1969 that PVDF can produce electrical signals. Thus, it can be used in various applications of energy harvesting, in various forms such as fibers, films

• through three different PVDF solutions (12, 14, and 16 wt %). The secondary electron images, taken at 10,000× and 40,000×, magnifications of prepared PVDF electrospun films from a 12 wt % polymer solution are shown in Figure 2A. The images show that the nanofibers have a more bead-on-string-like structure

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• ; dissociative ionisation; focused electron beam-induced deposition; molybdenum hexacarbonyl; Introduction Studies on Mo-based semiconductor materials for the application as thin films with wafer-scale thickness homogeneity [1] and for solar hydrogen production [2] have attracted interest in the last years. For

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• cell of rutile SnO2, a Sn4+ ion is bonded to six oxygen ions, and every oxygen atom is coordinated by three Sn4+ ions, forming a (6, 3) coordination structure [44]. When SnO2 materials are prepared as thin films with two to eight layers the bandgap is larger than that of bulk SnO2 and decreases with

• thin film materials that can replace powder materials, (5) adhering the catalyst materials on commercial films such as polypropylene, polytetrafluorethylene, or PM2.5 films for real-life applications, such as air filters and NOx gas treatment membranes; and (6) applying the materials in biological

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• research papers for almost 20 years until 1996 when two research groups reported SoL experiments. Ye et al. studied the formation of silver films on the surface of silicon oil [10] while Wagener et al. prepared silver and aluminium NPs by deposition onto silicon oil using various experimental conditions

• SoL is presented including monometallic and alloy NPs, oxide NPs, thin films, and nanocomposites and their promising optical, luminescence, and catalytic properties. Review 1 Theoretical background 1.1 Techniques available for the synthesis of NPs The mass production of NPs with controlled

• gauge, the electric power supply, and the gas inlets. Sputtering processes have been studied and developed for a long time [7][8] and have been implemented in the coating industry to deposit nanometer-scale films onto various solid substrates. Such functional coatings must have tailored physicochemical

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• composite. The KPFM measurements were performed at room temperature and show diffusion coefficients in the range of 3 × 10−13 cm2·s−1, which is comparable to values measured for single-phase Gd-doped ceria thin films using the same method. Keywords: ceria; diffusion coefficient; Kelvin probe force

• films using the same experimental setup [24]. As the introduced gradient in the composite material was in most cases not circular as observed for the single-phase materials, one of the biggest sources of error for the calculation of the diffusion coefficients shown in Table 1 is the determination of the

• to literature values for single-phase Ce0.9Gd0.1O1.95 thin films from [24] obtained with the same method. The diffusion length L was determined from the average radius of the area affected by polarization, which could be measured in the KPFM map. The error of the chemical diffusion coefficient is in

Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• prepared, too. Magnetic properties were measured and the growth mechanism was discussed [10]. The formation of Cr/Ge nanoparticles during the epitaxial growth of Cr/Ge films and their magnetic properties were studied to understand the ferromagnetic semiconductor behavior [11]. In this work, we made an

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• luminescence properties of europium-doped titanium dioxide and tellurium oxide thin films enhanced by gold plasmonic nanostructures. We propose a new type of plasmon structure with an ultrathin dielectric film between plasmonic platform and luminescent material. Plasmonic platforms were manufactured through

• thermal annealing of the gold thin film. Thermal dewetting of gold film results in spherical gold nanostructures with average dimensions of 50 nm. Both, luminescent TiO2:Eu and TeO2:Eu films were deposited by RF magnetron sputtering from mosaic targets. The morphology of the gold nanostructures was

• . Potential new materials can be found through the computation of luminescent thin films and plasmonic platforms. Such a hybrid structure can be formed by thin oxide layers doped with rare-earth ions deposited on metal nanostructures [1][2][3]. Plasmonic resonance can be observed in metallic nanostructures

Enhancement of the piezoelectric coefficient in PVDF-TrFe/CoFe₂O₄ nanocomposites through DC magnetic poling

• Marco Fortunato,
• Alessio Tamburrano,
• Maria Paola Bracciale,
• Maria Laura Santarelli and
• Maria Sabrina Sarto

Beilstein J. Nanotechnol. 2021, 12, 1262–1270, doi:10.3762/bjnano.12.93

• %. After curing, the spin coated nanocomposite thin films were exposed to a DC magnetic field for 1 h at 65 °C. In Figure 3 the d33 values are reported as function of the applied DC magnetic field strength. As can be seen, the piezoelectric coefficient increases when the magnetic field is increased and

• in the fabrication of energy harvesting devices or wearable sensors for flexible electronics applications. Experimental The PVDF-TrFe/CoFe2O4 nanocomposite thin films were produced through spin coating. The CoFe2O4 nanoparticles (Sigma-Aldrich, 99%) were dispersed in N,N-dimethylformamide (DMF, Sigma

• °C and a DC magnetic field was applied through a ferromagnetic core (Figure 8). The morphology of the PVDF-TrFe/CoFe2O4 nanocomposite thin films was investigated using a field-emission scanning electron microscope (FESEM, Auriga, Carl Zeiss) operated with an accelerating voltage of 5 kV. Chemical

Electrical, electrochemical and structural studies of a chlorine-derived ionic liquid-based polymer gel electrolyte

• Ashish Gupta,
• Amrita Jain,
• Manju Kumari and
• Santosh K. Tripathi

Beilstein J. Nanotechnol. 2021, 12, 1252–1261, doi:10.3762/bjnano.12.92

• fluoride-co-hexafluoropropylene) (PVdF-HFP) as a host polymer. The electrolyte films were synthesized by using the solution casting technique. The as-prepared films were free-standing and transparent with good dimensional stability. Optimized electrolyte films exhibit a maximum room-temperature ionic

• electrolyte film which contains 30 wt % of the ionic liquid. The optimized films have good potential to be used as electrolyte materials for energy storage applications. Keywords: ionic liquid; polymer gel electrolytes; solution casting technique; transference number; Introduction For the past two decades

• ionic liquid [BDiMIM][Cl], the host polymer PVdF-HFP, and the salt magnesium perchlorate (Mg(ClO4)2) were used to prepare polymer electrolyte films. The synthesized films were characterized by different microscopic and electrochemical techniques. Results and Discussion Structural characterization The

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• metal oxide (SMO) sensors are most popular due to their low cost, simplicity, easy fabrication, and wide range of gas detection capabilities [9]. Thin films and nanostructures exhibit better sensing characteristics. Various researchers have reported structures with morphologies such as nanowires (NWs

• geometry. Plugotarenko et al. employed sol–gel method to prepare SiO2·SnOx·CuOy nanofilms from a tetraethoxysilane (TEOS) alcohol solution modified by metal salts and applied the samples for NO2 sensing [50]. The SiO2·SnOx·CuOy films annealed at 500 °C exhibited a sample surface consisting of crater-like

• a lower value of fractal dimension is more effective in sensing NO2 gas and lowers the optimum operating temperature. Chen et al. used pulsed laser deposition for growing different SnO2 thin films by varying the substrate temperature. The obtained films exhibited fractal features [43]. In another

Irradiation-driven molecular dynamics simulation of the FEBID process for Pt(PF₃)₄

• Alexey Prosvetov,
• Alexey V. Verkhovtsev,
• Gennady Sushko and
• Andrey V. Solov’yov

Beilstein J. Nanotechnol. 2021, 12, 1151–1172, doi:10.3762/bjnano.12.86

• the whole simulated surface). The latter case is relevant for surface science experiments on irradiation of thin films of adsorbed precursor molecules. The yields of SE and BSE and the corresponding spatial distributions depend on the energy of the PE beam and the material of a substrate. These

First-principles study of the structural, optoelectronic and thermophysical properties of the π-SnSe for thermoelectric applications

• Muhammad Atif Sattar,
• Najwa Al Bouzieh,
• Maamar Benkraouda and
• Noureddine Amrane

Beilstein J. Nanotechnol. 2021, 12, 1101–1114, doi:10.3762/bjnano.12.82

• remarkably high value of ZT ≈ 2.6 at 773 K along the b axis has been reported, which is the world record so far [1][5]. Also, for the SnSe thin films and 2D sheets, the experimental ZT values were relatively low; the maximum value can only reach 0.28 at 675 K [67][68]. One recent study shows that the Gd

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• a wider choice of emission wavelengths compared to conventional lighting systems. Inorganic LED consist of inorganic semiconductor materials in the active region, for example thin films of GaAs that emit in the red to near-infrared (>700 nm) region [4]. Ga-based LED belong to the III–V group of

• leverage over inorganic LED in display applications. Organic light-emitting diodes (OLED) consist of photoactive polymers, such as PPV and MEH-PPV that can be deposited as highly ordered crystalline thin films [15][16]. Despite several advantages, OLED have certain drawbacks, such as lower lifetime, high

• a large scale. For this purpose, transparent conducting oxides (TCO), such as thin films of In2O3, SnO2, ZnO, and their mixtures have been extensively studied [30][31][32][33][34]. The most widely studied TCO is indium tin oxide (ITO), which possesses good physical properties, such as high optical

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

Uniform arrays of gold nanoelectrodes with tuneable recess depth

• Elena O. Gordeeva,
• Ilya V. Roslyakov,
• Alexey P. Leontiev,
• Alexey A. Klimenko and
• Kirill S. Napolskii

Beilstein J. Nanotechnol. 2021, 12, 957–964, doi:10.3762/bjnano.12.72

• available porous AAO films with a highly irregular structure to prepare the Au nanowell electrodes with 600 nm depth by templated electrodeposition. It is worth noting that the percentage of nanoelectrodes in the array that are involved in electrochemical reactions has not been discussed in detail. At the

• Scientific and Educational School of Lomonosov MSU «The future of the planet and global environmental change» is acknowledged. Funding The work was supported by the Russian Science Foundation (Grant No. 19-73-10176) in part of preparation and characterization of the AAO porous films. Templated

Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• sufficient to truly electronically insulate molecular structures. For this, the usage of either thicker insulating films (mostly alkali halides) or bulk insulators is required. For studying molecules on bulk insulators, ionic crystals (e.g., KBr, NaCl, CaF2, and calcite) have mostly served as model systems

• . Due to lowered diffusion barrier and adsorption energy, the two-dimensional molecular layers can be affected by dewetting and may change into three-dimensional clusters [47]. In return, the reduced molecule–surface interaction on insulating films or bulk insulators can stabilize highly reactive

• quenched on bare Cu(111) and would require three molecular decoupling layers to be probed on Cu(111). In all three studies using hBN, ordered molecular films were observed. The decoupling even allowed for the formation of complex self-assemblies such as kagome lattices by tuning the number and position of

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• of CTAB-capped gold nanorods on estuarine model systems (consisting of sediments, plants, microbial films, fish, and snails) for observing ecological and environmental impact [71]. The results showed that the biofilms were the primary route through which gold nanorods enters the food chain. It is

In situ transport characterization of magnetic states in Nb/Co superconductor/ferromagnet heterostructures

• Olena M. Kapran,
• Roman Morari,
• Taras Golod,
• Evgenii A. Borodianskyi,
• Vladimir Boian,
• Andrei Prepelita,
• Nikolay Klenov,
• Anatoli S. Sidorenko and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 913–923, doi:10.3762/bjnano.12.68

• were used for the calibration of the etching rates of the films. MLs are patterned into micrometer-scale bridges with multiple contacts using photolithography and reactive ion etching. A scanning electron microscopy (SEM) image of one of the studied samples is shown in Figure 1a. Control of the

• by SQUID magnetometry in a field parallel to the film in the normal state at T > Tc. A significant hysteresis of M(H) reveals the in-plane anisotropy of Co films (albeit with a small coercive field, HC ≈ 30 Oe), consistent with earlier studies [44][45][46][47]. Figure 1c shows a numerical simulation

• the field. However, this effect is nonmonotonous with the field, as can be seen from the zoomed-in view in the inset. The rest of the transition is little affected in this field range (up to 500 Oe). This is caused by the large value of the upper critical field for thin Nb films in the parallel field