The nanoscaled metal-organic framework ICR-2 as a carrier of porphyrins for photodynamic therapy

• Jan Hynek,
• Sebastian Jurík,
• Martina Koncošová,
• Jaroslav Zelenka,
• Ivana Křížová,
• Tomáš Ruml,
• Kaplan Kirakci,
• Ivo Jakubec,
• František Kovanda,
• Kamil Lang and
• Jan Demel

Beilstein J. Nanotechnol. 2018, 9, 2960–2967, doi:10.3762/bjnano.9.275

• identical conditions (e.g., irradiation wavelength, time, dose). We can compare the activity of nanoICR-2/TPPPi(Ph) with the activity of previously studied PCN-222 nanoparticles where both systems display comparable activity [22]. Conclusion In the context of photodynamic therapy, we present composite

Hybrid Au@alendronate nanoparticles as dual chemo-photothermal agent for combined cancer treatment

• Anouchka Plan Sangnier,
• Romain Aufaure,
• Laurence Motte,
• Claire Wilhelm,
• Erwann Guenin and
• Yoann Lalatonne

Beilstein J. Nanotechnol. 2018, 9, 2947–2952, doi:10.3762/bjnano.9.273

• under irradiation within the first biological window (650–900 nm). The Au@alendronate nanoplatform thus provided a combined antitumor activity through drug delivery and photothermal therapy. Au@alendronate NPs inhibited in vitro the proliferation of prostate cancer cells (PC3) in a dose-dependent manner

• , with an IC50 value of 100 µM. Under NIR irradiation a temperature increase was observed leading to a reduction of the IC50 value to 1 µM, with total tumor cell death at 100 µM. Keywords: alendronate; bisphosphonate; cancer treatment; gold nanoparticles; photothermia; Findings Bisphosphonates (BPs

• within the biological transparency windows of 650–950 nm or 1000–1350 nm, to minimize light absorption by surrounding biological tissues [27]. The principal limitation of PTT is that it requires direct light irradiation, which reduces its effect against disseminated metastatic tumors. A promising

Site-controlled formation of single Si nanocrystals in a buried SiO₂ matrix using ion beam mixing

• Xiaomo Xu,
• Thomas Prüfer,
• Daniel Wolf,
• Hans-Jürgen Engelmann,
• Lothar Bischoff,
• René Hübner,
• Karl-Heinz Heinig,
• Wolfhard Möller,
• Stefan Facsko,
• Johannes von Borany and
• Gregor Hlawacek

Beilstein J. Nanotechnol. 2018, 9, 2883–2892, doi:10.3762/bjnano.9.267

• single Si NCs. Line irradiation with a fluence of 3000 Ne+/nm2 and a line width of 4 nm leads to the formation of a chain of Si NCs, and a single NC with 2.2 nm diameter is subsequently isolated and visualized in a few nanometer thin lamella prepared by a focused ion beam (FIB). The Si NC is centered

• pyrolysis [13] and ion beam synthesis in an SiO2 matrix [14][15][16][17]. Compared to conventional ion beam synthesis using low-energy ion implantation, collisional mixing of Si into an SiO2 layer by ion irradiation at higher energies leads to a better control over the Si excess, and a self-aligned δ-layer

• precise irradiation. The recent advance in noble gas ion microscopy, in particular the availability of a highly focused Ne+ beam from a helium ion microscope (HIM), provides ultimate control over the irradiation geometry and fluence [23][24], which leads to a minimal mixed volume and the formation of a

Charged particle single nanometre manufacturing

• Philip D. Prewett,
• Cornelis W. Hagen,
• Claudia Lenk,
• Steve Lenk,
• Marcus Kaestner,
• Tzvetan Ivanov,
• Ahmad Ahmad,
• Ivo W. Rangelow,
• Xiaoqing Shi,
• Stuart A. Boden,
• Alex P. G. Robinson,
• Dongxu Yang,
• Sangeetha Hari,
• Marijke Scotuzzi and
• Ejaz Huq

Beilstein J. Nanotechnol. 2018, 9, 2855–2882, doi:10.3762/bjnano.9.266

• intense electron irradiation if the lithography takes place under ambient conditions. Unlike tSPL, FE-eSPL structuring is a cold process due to the low power density which has advantages when patterning over thin active device regions, which is common in R&D applications. In this respect, FE-eSPL avoids

Biomimetic surface structures in steel fabricated with femtosecond laser pulses: influence of laser rescanning on morphology and wettability

• Camilo Florian Baron,
• Alexandros Mimidis,
• Daniel Puerto,
• Evangelos Skoulas,
• Emmanuel Stratakis,
• Javier Solis and
• Jan Siegel

Beilstein J. Nanotechnol. 2018, 9, 2802–2812, doi:10.3762/bjnano.9.262

• allows fabrication of specific micro- and nanostructures over extended areas. In this work, we exploit this approach to fabricate complex biomimetic structures on the surface of steel 1.7131 formed upon irradiation with high repetition rate femtosecond laser pulses. In particular, the fabricated

• structures show similarities to the skin of certain reptiles and integument of insects. Different irradiation parameters are investigated to produce the desired structures, including laser repetition rate and laser fluence, paying special attention to the influence of the number of times the same area is

• angle measurements of water drops placed on the surface reveal that a wide range of angles can be accessed by selecting the appropriate irradiation parameters, highlighting also here the prominent role of the number of scans. Keywords: biomimetics; femtosecond laser irradiation; laser-induced periodic

Near-infrared light harvesting of upconverting NaYF₄:Yb³⁺/Er³⁺-based amorphous silicon solar cells investigated by an optical filter

• Daiming Liu,
• Qingkang Wang and
• Qing Wang

Beilstein J. Nanotechnol. 2018, 9, 2788–2793, doi:10.3762/bjnano.9.260

• rods were incorporated in a polymethylmethacrylate (PMMA) layer on the rear side of a-Si:H solar cell. Under AM1.5 solar irradiation, a facile optical filter was used to scrutinize the effect of upconversion on the cell performance. Compared with a bare cell, the NaYF4:Yb3+/Er3+-based a-Si:H cell

• UC effect; however, it does not imitate the actual solar irradiation in practical devices. In the present work, the upconverting NaYF4:Yb3+/Er3+ nanorods were synthesized thorugh a hydrothermal method and their UC effect on NIR light harvesting in a-Si:H solar cell was scrutinized by using a facile

• optical filter. Photoelectric performances of a-Si:H solar cells with and without UC were compared under AM1.5 solar irradiation. Results and Discussion Field-emission scanning electron microscopy (FE-SEM) was used to investigate the sample morphologies over the course of the reaction. In Figure 1a, the

Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry

• Pierre Farger,
• Cédric Leuvrey,
• Mathieu Gallart,
• Pierre Gilliot,
• Guillaume Rogez,
• João Rocha,
• Duarte Ananias,
• Pierre Rabu and
• Emilie Delahaye

Beilstein J. Nanotechnol. 2018, 9, 2775–2787, doi:10.3762/bjnano.9.259

• , Supporting Information File 1). The room-temperature emission spectra of [Tb0.90Eu0.10(L)(ox)(H2O)] under ambient pressure and after exposure to high vacuum (5 × 10−3 mbar, Figure S14, Supporting Information File 1) demonstrates the good stability of the emission of the sample against UV irradiation and

Accurate control of the covalent functionalization of single-walled carbon nanotubes for the electro-enzymatically controlled oxidation of biomolecules

• Naoual Allali,
• Veronika Urbanova,
• Mathieu Etienne,
• Xavier Devaux,
• Martine Mallet,
• Brigitte Vigolo,
• Jean-Joseph Adjizian,
• Chris P. Ewels,
• Sven Oberg,
• Alexander V. Soldatov,
• Edward McRae,
• Yves Fort,
• Manuel Dossot and
• Victor Mamane

Beilstein J. Nanotechnol. 2018, 9, 2750–2762, doi:10.3762/bjnano.9.257

• . The SWCNTs were oxidized in acidic media using microwave irradiation to control the number of oxidized groups created on the CNT sidewalls [9][11]. Several microwave irradiation times were investigated but an optimum was found at around 20 min. Two different acidic media were tested: a quite

• CNTs in the aim of making an electrochemical biosensor, we performed the oxidation step using microwave irradiation. Microwaves indeed promote oxidation through a fast thermal activation, which enables performing the oxidation step in only a few minutes and allows one to roughly control the number of

• defects introduced by tuning the irradiation time. A few milligrams of the corresponding oxidized SWCNTs were analyzed in each case before proceeding to step 2. At this stage, the samples were protected under argon gas to avoid any moisture contamination and directly analyzed by HRTEM, XPS and TGA-MS

Disorder in H⁺-irradiated HOPG: effect of impinging energy and dose on Raman D-band splitting and surface topography

• Lisandro Venosta,
• Noelia Bajales,
• Sergio Suárez and
• Paula G. Bercoff

Beilstein J. Nanotechnol. 2018, 9, 2708–2717, doi:10.3762/bjnano.9.253

• . 8400 San Carlos de Bariloche, Argentina 10.3762/bjnano.9.253 Abstract Disorder was induced in pristine highly oriented pyrolytic graphite (HOPG) by irradiation with H+ ions with energies of 0.4 MeV and 1 MeV, and doses of 1014 ions/cm2 and 1016 ions/cm2. Raman spectroscopy was used as the main

• characterization showed a distribution of surface defects, which were ascribed to the burst of hydrogen blisters formed as a consequence of the irradiation process. The results presented in this work contribute to the current trend in nanotechnology in areas devoted to the control of properties by defect

• clear explanation of the dependence of the D-band components on the irradiation parameters together with the type of defect is still a challenge. Hydrogen-irradiated carbon allotropes have received special attention as promising materials to develop hydrogen storage devices [16][17][18][19][20][21], as

Polarization-dependent strong coupling between silver nanorods and photochromic molecules

• Gwénaëlle Lamri,
• Alessandro Veltri,
• Jean Aubard,
• Pierre-Michel Adam,
• Nordin Felidj and
• Anne-Laure Baudrion

Beilstein J. Nanotechnol. 2018, 9, 2657–2664, doi:10.3762/bjnano.9.247

• evolution of the peaks after UV irradiation. The dashed horizontal red lines represent the position of the MC absorption band. Either for the transverse, or for the longitudinal plasmonic resonances, one can observe a clear splitting of the plasmonic mode, centered at the intersection of the MC absorption

Impact of the anodization time on the photocatalytic activity of TiO₂ nanotubes

• Jesús A. Díaz-Real,
• Geyla C. Dubed-Bandomo,
• Juan Galindo-de-la-Rosa,
• Luis G. Arriaga,
• Janet Ledesma-García and
• Nicolas Alonso-Vante

Beilstein J. Nanotechnol. 2018, 9, 2628–2643, doi:10.3762/bjnano.9.244

• generates charge carriers (electron–hole pairs) only under UV irradiation limiting the overall performance. This fact motivated the research on this material in order to increase the surface area and/or shift its light absorption toward the visible spectral region. Many reports are devoted to novel

• known as current-doubling in which a secondary electron is obtained from the oxidation of an (organic) molecule via surface holes when a semiconductor is excited with suitable photonic irradiation. However, the experimental results do not necessarily correspond to a two-fold increase in jph, especially

• , photocurrent transients were performed to discriminate the appearance of the Eonset. The transients were performed by interrupting the irradiation for a period of 5 s with a programmable shutter coupled to the illumination during the LSV and the curves are contrasted in Figure 6d. For the electrode with ta

Enhancement of X-ray emission from nanocolloidal gold suspensions under double-pulse excitation

• Wei-Hung Hsu,
• Frances Camille P. Masim,
• Armandas Balčytis,
• Hsin-Hui Huang,
• Tetsu Yonezawa,
• Aleksandr A. Kuchmizhak,
• Saulius Juodkazis and
• Koji Hatanaka

Beilstein J. Nanotechnol. 2018, 9, 2609–2617, doi:10.3762/bjnano.9.242

• and spatial overlaps between the pre-pulse and the main pulse were optimized for the highest X-ray emission. The maximum X-ray intensity was obtained at a 1–7 ns delay of the main pulse irradiation after the pre-pulse irradiation with the micro-jet position shifted along the laser beam propagation. It

• -absorption efficiency and an enhanced generation of high-energy electrons from a highly ionized plasma with high electron temperature [10][11] under intense laser irradiation. For an efficient augmentation in X-ray intensity, femtosecond (fs)-laser excitation of metal nanoparticles and nanoclusters is of

• enhancement in X-ray intensity from a water film was observed under double-pulse excitation with a pre-pulse ahead of the main pulse [26][27]. The pre-pulse irradiation with relatively low intensity induces a time-dependent laser-induced plasma (in the range of picoseconds) and ablation (in the range of

Au–Si plasmonic platforms: synthesis, structure and FDTD simulations

• Anna Gapska,
• Marcin Łapiński,
• Paweł Syty,
• Wojciech Sadowski,
• Józef E. Sienkiewicz and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2018, 9, 2599–2608, doi:10.3762/bjnano.9.241

• concluded that the proposed method of manufacturing nanostructures yields good results. Of course, there are also other methods for the production of nanostructures or metal nanoparticles, for example laser irradiation of thin metallic films deposited on various substrates [29][30][31][32][33]. This method

• also gives the possibility, by scanning the surface of the sample with a laser or by changing the energy of the pulse or its duration, to create patterns of various sizes of nanostructures. Laser irradiation, however, does not provide the possibility of accurate temperature control, which is extremely

Pattern generation for direct-write three-dimensional nanoscale structures via focused electron beam induced deposition

• Lukas Keller and
• Michael Huth

Beilstein J. Nanotechnol. 2018, 9, 2581–2598, doi:10.3762/bjnano.9.240

Exploring the photoleakage current and photoinduced negative bias instability in amorphous InGaZnO thin-film transistors with various active layer thicknesses

• Dapeng Wang and
• Mamoru Furuta

Beilstein J. Nanotechnol. 2018, 9, 2573–2580, doi:10.3762/bjnano.9.239

• visible light irradiation exceeded ≈2.7 eV. Furthermore, the influence of the TIGZO on NBIS-induced instability in a-IGZO TFTs was explored by the combination of current–voltage measurements in double-sweeping VGS mode and capacitance–voltage measurements. The NBIS-induced hysteresis was quantitatively

• because of its excellent electrical and optical properties [5][6][7][8]. Although the band gap of IGZO (≈3.1 eV) is higher than the photon energy of visible light, photoinduced leakage current under visible-light irradiation can be detected in the oxide-based TFTs [9][10]. This is due to the fact that the

• . The photoleakage current increased in all TFTs when the wavelength of visible-light irradiation was shorter than 460 nm. Moreover, the photoleakage current increased with an increase in the TIGZO. Furthermore, the impact of the active layer thickness on the NBIS-induced instability in a-IGZO TFTs was

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

• ]. Although cellulose alone exhibits limited photocatalytic activity under UV or visible light irradiation, many semiconductor materials have been added to enhance the photocatalytic activity. Several research groups have demonstrated photocatalytic wastewater treatment using cellulose-based metal oxide

• nanostructures in the form of thin film, membrane, fibre and hybrid materials under UV and visible light irradiation. Nanocellulose–metal oxide (TiO2, ZnO, graphene oxide, and Fe2O3) composites have been used as photocatalysts to improve the degradation rate of organic pollutants as compared to individual

• derived from microbial cellulose to act as a highly efficient photocatalyst [109]. The composite catalyst demonstrated a high photocatalytic degradation efficiency of about 82% after 90 min of irradiation and exhibited high recyclability of up to five catalytic cycles. In addition, the potential of

SERS active Ag–SiO₂ nanoparticles obtained by laser ablation of silver in colloidal silica

• Cristina Gellini,
• Francesco Muniz-Miranda,
• Alfonso Pedone and
• Maurizio Muniz-Miranda

Beilstein J. Nanotechnol. 2018, 9, 2396–2404, doi:10.3762/bjnano.9.224

• irradiation time of the silver target was about 10 min. TEM samples were obtained by dropping a small amount of colloid onto carbon-coated copper grids and allowing it to evaporate. The images were recorded with a Philips CM12 at 120 kV. UV–visible absorption spectra of the colloidal suspensions were obtained

Magnetism and magnetoresistance of single Ni–Cu alloy nanowires

• Andreea Costas,
• Camelia Florica,
• Elena Matei,
• Maria Eugenia Toimil-Molares,
• Ionel Stavarache,
• Andrei Kuncser,
• Victor Kuncser and
• Ionut Enculescu

Beilstein J. Nanotechnol. 2018, 9, 2345–2355, doi:10.3762/bjnano.9.219

• with a poly(methyl methacrylate) film deposited by spin coating; (d) irradiation of the polymer layer for contacting the ends of the nanowire with the interdigitated metallic electrode; (e) SEM images of a single Ni–Cu alloy nanowire contacted using EBL. Supporting Information Supporting Information

Block copolymers for designing nanostructured porous coatings

• Roberto Nisticò

Beilstein J. Nanotechnol. 2018, 9, 2332–2344, doi:10.3762/bjnano.9.218

• case, the selective etching of activated oxygen molecules generated by the VUV radiation towards the two blocks (PS and PMMA) allowed for the preferential decomposition of PMMA and the consequent formation of a PS nanoporous network. The modulation of the irradiation time and pressure caused chemical

• and physical modifications of the PS nanostructures, since the complete removal of PMMA phase produces a hydrophobic PS surface whereas an irradiation at a pressure of 103 Pa caused the partial decomposition of the PS matrix with the modification of the material pore size and structure. By focusing on

• orientation of the ethylene oxide cylindrical domains in PS-b-PEO copolymers. UV light irradiation was used to crosslink the PS matrix and photodegrade the PEO domains. Afterwards, several washing techniques were tested to selectively remove the resorcinol together with the PEO moieties (selective cleavage

Hierarchical heterostructures of Bi₂MoO₆ microflowers decorated with Ag₂CO₃ nanoparticles for efficient visible-light-driven photocatalytic removal of toxic pollutants

• Shijie Li,
• Wei Jiang,
• Shiwei Hu,
• Yu Liu,
• Yanping Liu,
• Kaibing Xu and
• Jianshe Liu

Beilstein J. Nanotechnol. 2018, 9, 2297–2305, doi:10.3762/bjnano.9.214

• heterostructures exhibited substantially improved performance in the removal of industrial dyes (rhodamine B (RhB), methyl orange (MO), and methyl blue (MB)), and the antibiotic tetracycline hydrochloride (TC), compared with bare Bi2MoO6 and Ag2CO3 under visible-light irradiation. The enhancement of activity was

• . Photocatalytic test The photo-degradation of RhB, MO, TC and MB was carried out in a reactor containing 40 mg of sample, and 100 mL of RhB (10 mg·L−1), MO (10 mg·L−1), TC (20 mg·L−1) or MB (10 mg·L−1) under visible-light irradiation. A 300 W xenon lamp equipped with a UV-cutoff filter (λ > 400 nm) served as the

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• 1 µm) [133]. The gas sensing response is also improved without tuning the microstructure of nanofibers just by the introduction of UV irradiation [105][144][145]. The response of TiO2 nanofibers is enhanced from 1.8/25 ppm to 18/25 ppm of hydrogen, whereas the response/recovery time reduced from

Localized photodeposition of catalysts using nanophotonic resonances in silicon photocathodes

• Evgenia Kontoleta,
• Sven H. C. Askes,
• Lai-Hung Lai and
• Erik C. Garnett

Beilstein J. Nanotechnol. 2018, 9, 2097–2105, doi:10.3762/bjnano.9.198

• irradiation had caused the formation of nanoparticles. Energy-dispersive X-ray spectrometry (EDS) mapping clearly confirmed the presence of platinum, when an individual newly formed particle was analyzed (Figure 3d and Figure 3e). Furthermore, the oxidation state of platinum was investigated with X-ray photo

A scanning probe microscopy study of nanostructured TiO₂/poly(3-hexylthiophene) hybrid heterojunctions for photovoltaic applications

• Laurie Letertre,
• Roland Roche,
• Olivier Douhéret,
• Hailu G. Kassa,
• Denis Mariolle,
• Nicolas Chevalier,
• Łukasz Borowik,
• Philippe Dumas,
• Benjamin Grévin,
• Roberto Lazzaroni and
• Philippe Leclère

Beilstein J. Nanotechnol. 2018, 9, 2087–2096, doi:10.3762/bjnano.9.197

• 600 mV. The light source for sample irradiation was a green laser diode (wavelength = 500 nm, power density = 1.45 mW/mm2). Photo-assisted KPFM measurements were also performed in ambient conditions, with a Bruker multimode microscope controlled by a Nanoscope III unit coupled to a Nanonis control

Fabrication of photothermally active poly(vinyl alcohol) films with gold nanostars for antibacterial applications

• Mykola Borzenkov,
• Maria Moros,
• Claudia Tortiglione,
• Serena Bertoldi,
• Nicola Contessi,
• Silvia Faré,
• Angelo Taglietti,
• Agnese D’Agostino,
• Piersandro Pallavicini,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2018, 9, 2040–2048, doi:10.3762/bjnano.9.193

• , Piazza dell’AteneoNuovo, 20126, Milan, Italy 10.3762/bjnano.9.193 Abstract The unique photothermal properties of non-spherical gold nanoparticles under near-infrared (NIR) irradiation find broad application in nanotechnology and nanomedicine. The combination of their plasmonic features with widely used

• resulting films displayed good mechanical properties and a pronounced photothermal effect under NIR irradiation. The local photothermal effect triggered by NIR irradiation of the PVA-GNS films is highly efficient at killing bacteria, therefore providing an opportunity to develop new types of protective

• decoration) have received particular attention [6][7]. Previously, it was shown that these GNSs are highly photothermally active under NIR irradiation in aqueous solution in the form of monolayers grafted on dry glass surfaces and when inkjet-printed on flexible substrates, demonstrating the ability to reach

Metal-free catalysis based on nitrogen-doped carbon nanomaterials: a photoelectron spectroscopy point of view

• Mattia Scardamaglia and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2018, 9, 2015–2031, doi:10.3762/bjnano.9.191

• molecular dynamics combined with analytical potential and density functional theory methods, Lehtinen et al. reported on the influence of the ion kinetic energy and mass on the probability of defect formation during irradiation of suspended graphene sheets and single-walled CNTs [86]. Being proportional to

• . There are many other nonradiative relaxation channels in nanosystems that affect the excitation lifetimes. Reproduced with permission from [83], copyright 2010 American Institute of Physics. (d–i) Production of defects in graphene under ion irradiation as revealed by the analytical potential molecular