Carbometallation chemistry

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  1. Editor: Prof. Ilan Marek
    Technion – Israel Institute of Technology

Following the pioneering Ziegler addition of nucleophiles to nonactivated unsaturated carbon–carbon bonds, the controlled carbometallation reaction has emerged. Since then, reactions that result in the addition of a carbon–metal bond of an organometallic across a carbon–carbon unsaturated system, leading to a new organometallic in which the newly formed carbon–metal bond can be used for further synthetic transformations, are called carbometallation reactions. In the past few decades, the intra- as well as intermolecular additions of various organometallic species to a large variety of alkynes, alkenes and allenes have been successfully reported.

  • Editorial
  • Published 04 Feb 2013

Beilstein J. Org. Chem. 2013, 9, 234–235, doi:10.3762/bjoc.9.27

  • Letter
  • Published 18 Dec 2012

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  • Supp. Info

Beilstein J. Org. Chem. 2012, 8, 2202–2206, doi:10.3762/bjoc.8.248

  • Letter
  • Published 19 Dec 2012

Beilstein J. Org. Chem. 2012, 8, 2207–2213, doi:10.3762/bjoc.8.249

  • Full Research Paper
  • Published 21 Dec 2012

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  • Supp. Info

Beilstein J. Org. Chem. 2012, 8, 2214–2222, doi:10.3762/bjoc.8.250

Radical zinc-atom-transfer-based carbozincation of haloalkynes with dialkylzincs

  1. Fabrice Chemla,
  2. Florian Dulong,
  3. Franck Ferreira and
  4. Alejandro Pérez-Luna
  • Full Research Paper
  • Published 04 Feb 2013

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Beilstein J. Org. Chem. 2013, 9, 236–245, doi:10.3762/bjoc.9.28

  • Review
  • Published 11 Feb 2013

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Beilstein J. Org. Chem. 2013, 9, 278–302, doi:10.3762/bjoc.9.34

Inter- and intramolecular enantioselective carbolithiation reactions

  1. Asier Gómez-SanJuan,
  2. Nuria Sotomayor and
  3. Esther Lete
  • Review
  • Published 13 Feb 2013

Beilstein J. Org. Chem. 2013, 9, 313–322, doi:10.3762/bjoc.9.36

  • Full Research Paper
  • Published 13 Mar 2013

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  • Supp. Info

Beilstein J. Org. Chem. 2013, 9, 526–532, doi:10.3762/bjoc.9.57

  • Full Research Paper
  • Published 14 Mar 2013

Beilstein J. Org. Chem. 2013, 9, 537–543, doi:10.3762/bjoc.9.59

Carbolithiation of N-alkenyl ureas and N-alkenyl carbamates

  1. Julien Lefranc,
  2. Alberto Minassi and
  3. Jonathan Clayden
  • Full Research Paper
  • Published 28 Mar 2013

Beilstein J. Org. Chem. 2013, 9, 628–632, doi:10.3762/bjoc.9.70

Intramolecular carbonickelation of alkenes

  1. Rudy Lhermet,
  2. Muriel Durandetti and
  3. Jacques Maddaluno
  • Full Research Paper
  • Published 12 Apr 2013

Beilstein J. Org. Chem. 2013, 9, 710–716, doi:10.3762/bjoc.9.81

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