A carrier velocity model for electrical detection of gas molecules

• Ali Hosseingholi Pourasl,
• Sharifah Hafizah Syed Ariffin,
• Mohammad Taghi Ahmadi,
• Razali Ismail and
• Niayesh Gharaei

Beilstein J. Nanotechnol. 2019, 10, 644–653, doi:10.3762/bjnano.10.64

• other hand, the charge transfer between GNRs and the adsorbed target molecule can change the concentration of the carriers and modulate the conductivity of the GNR. In addition, because of the atomic forces and charge transfer, molecular adsorption can lead to modification of the energy band diagram and

• sensors are used to develop a new gas sensor model based on the carrier velocity and I–V characteristics. In addition, a first principle simulation study is employed for the band structure analysis, to calculate the charge transfer, and to evaluate the proposed models. For the sensor structure, an

• exposed to each of these gas molecules and its band structure and I–V characteristic variations before and after gas adsorption are studied; also, the adsorption energy and charge transfer between gas molecules and the AGNR surface are calculated and discussed. In the adsorption process of CO, different

Review of time-resolved non-contact electrostatic force microscopy techniques with applications to ionic transport measurements

• Aaron Mascaro,
• Yoichi Miyahara,
• Tyler Enright,
• Omur E. Dagdeviren and
• Peter Grütter

Beilstein J. Nanotechnol. 2019, 10, 617–633, doi:10.3762/bjnano.10.62

• understanding transport properties of real-world, often heterogeneous materials relevant for energy generation and storage. A number of AFM techniques have been developed to study relevant materials including time-resolved EFM to measure photoexcited charge accumulation and charge transfer [6][9][10][11], time

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

• Juan Casanova-Cháfer,
• Carla Bittencourt and
• Eduard Llobet

Beilstein J. Nanotechnol. 2019, 10, 565–577, doi:10.3762/bjnano.10.58

• more responsive to nitrogen dioxide than Au, Pt or Pd-decorated CNTs when operated at room temperature [10][18][40]. This was attributed to a stronger interaction and charge transfer between nitrogen dioxide and oxygenated defects in CNTs than with metal clusters. Possibly the surface of metal clusters

Quantification and coupling of the electromagnetic and chemical contributions in surface-enhanced Raman scattering

• Yarong Su,
• Yuanzhen Shi,
• Ping Wang,
• Jinglei Du,
• Markus B. Raschke and
• Lin Pang

Beilstein J. Nanotechnol. 2019, 10, 549–556, doi:10.3762/bjnano.10.56

• ]. This suggests that across a charge-transfer or molecular resonance, the enhancement of the asymmetric vs symmetric mode varies. Yet, in the absence of charge-transfer contributions, all modes are equally enhanced, irrespective of excitation frequency [29]. In our work, the mode ω3 is related with the

• charge-transfer contribution, and its CE value depends on the excitation wavelength. With regards to coupling between physical and chemical enhancement [20][22], a coupling factor can be introduced to quantify how the induced polarization modifies the charge redistribution and vice versa. However, we

• polarizability derivative, which in turn is due to a change in the ground-state electronic structure when the molecule adsorbs onto a metal surface. In addition, dynamic processes contribute, which are associated with the formation of hybrid states or charge transfer excitations between the molecule and the

Mo-doped boron nitride monolayer as a promising single-atom electrocatalyst for CO₂ conversion

• Qianyi Cui,
• Gangqiang Qin,
• Weihua Wang,
• Lixiang Sun,
• Aijun Du and
• Qiao Sun

Beilstein J. Nanotechnol. 2019, 10, 540–548, doi:10.3762/bjnano.10.55

• ) is the Mo atom and the three N atoms that the Mo atom linked with, and BN monolayer (moiety 3), as shown in Figure 5a. The variation of the charge distribution is illustrated in Figure 5b. The step 0 is the charge transfer to the adsorbed CO2. The CO2 molecule and the MoN3 gain 0.482 and 0.018

• for charge transfer between the BN monolayer and moiety 1. Conclusion In conclusion, we have systematically investigated TM atoms, including Sc to Zn, Mo, Ru, Rh, Pd and Ag, anchored on the boron-defective BN monolayer as an efficient SAC for CRR, as investigated by means of DFT calculations. The

• single transition metal (TM) doped BN monolayers. (b) The length of the C–O bond of CO2 that interacts with the TM atom doped onto the BN monolayers. (c) The angle of the captured CO2 molecule. (d) The charge transfer of CO2 adsorbed on various catalysts. The red dashed lines represent values

Choosing a substrate for the ion irradiation of two-dimensional materials

• Egor A. Kolesov

Beilstein J. Nanotechnol. 2019, 10, 531–539, doi:10.3762/bjnano.10.54

• to a peculiar doping effect, as it was shown for graphene in [1]. Besides, one cannot exclude participation of displaced recoil atoms [8] that reach the interface but remain within the substrate. Moreover, since there is a charge transfer between the substrate and the monolayer [9][10][11][12], the

• desorption in 2D material through charge transfer effects [9][10][11][12][16]. It is important to note that the electronically stimulated surface atom desorption is a mechanism that basically occurs in unsupported 2D materials under ion irradiation [13]. It principally relates to any non-central collision

A porous 3D-RGO@MWCNT hybrid material as Li–S battery cathode

• Yongguang Zhang,
• Jun Ren,
• Yan Zhao,
• Taizhe Tan,
• Fuxing Yin and
• Yichao Wang

Beilstein J. Nanotechnol. 2019, 10, 514–521, doi:10.3762/bjnano.10.52

• region the x-intercept is attributed to the contact resistance (R0), and the semicircle is attributed to the charge-transfer resistance (Rct) at the electrode/electrolyte interface. Finally, the inclined slope in the low-frequency region is associated with the Warburg impedance (W) [28], which correlates

• within a MWCNT lattice matrix, was successfully synthesized. The as-prepared S-3D-RGO@MWCNT cathode exhibited a very good electrochemical performance and cycle stability. This can be attributed to i) the conductive network inherently found in the RGO sheets and MWCNTs, which ensured efficient charge

• transfer within the cathode, ii) the 3D porous spherical RGO possessing a high surface area and pore volume to accommodate a high sulfur content; and iii) the interconnected pores in the spherical RGO and the lattice matrix formed by MWCNTs, which act as polysulfide reservoirs to alleviate the shuttle

Temperature-dependent Raman spectroscopy and sensor applications of PtSe₂ nanosheets synthesized by wet chemistry

• Mahendra S. Pawar and
• Dattatray J. Late

Beilstein J. Nanotechnol. 2019, 10, 467–474, doi:10.3762/bjnano.10.46

• resistance of the sensor device vs relative humidity plot. The resistance is significantly decreased from 3.75 GΩ to 0.83 MΩ. The humidity sensing mechanism for the PtSe2 sensor can be explained as follows. When the PtSe2 nanosheet sensor device was exposed to water molecules/vapors, a charge transfer

Reduced graphene oxide supported C₃N₄ nanoflakes and quantum dots as metal-free catalysts for visible light assisted CO₂ reduction

• Md Rakibuddin and
• Haekyoung Kim

Beilstein J. Nanotechnol. 2019, 10, 448–458, doi:10.3762/bjnano.10.44

• rGO [34]. The XPS peaks of g-C3N4 and rGO are shifted slightly to higher and lower binding energies in the GCN-5 hybrid, respectively, indicating possible charge transfer between g-C3N4 and rGO in the heterostructure. Hence, the XPS results confirm the successful preparation of the composite and the

Biocompatible organic–inorganic hybrid materials based on nucleobases and titanium developed by molecular layer deposition

• Leva Momtazi,
• Henrik H. Sønsteby and
• Ola Nilsen

Beilstein J. Nanotechnol. 2019, 10, 399–411, doi:10.3762/bjnano.10.39

• investigated the charge transfer shake-up satellite modes corresponding to the O 2peg → Ti 3deg transition [27]. No evidence of pure Ti–N bonding could be observed directly from the Ti peaks, indicating that titanium is not found only coordinated to nitrogen. We cannot, however, rule out the possibility of Ti

A Ni(OH)₂ nanopetals network for high-performance supercapacitors synthesized by immersing Ni nanofoam in water

• Donghui Zheng,
• Man Li,
• Yongyan Li,
• Chunling Qin,
• Yichao Wang and
• Zhifeng Wang

Beilstein J. Nanotechnol. 2019, 10, 281–293, doi:10.3762/bjnano.10.27

• peaks, which is related to the poor conductivity (larger ohmic resistance) of Ni(OH)2 nanopetals [21][43]. Larger ohmic resistance leads to slow kinetics of charge transport and interfacial charge transfer of the material. Thus, the electrode reaction rate slows down, resulting in a reduced

• reservoir” structure is badly damaged. This results in a decrease in the surface area of active materials and subsequently leads to the decline in the volumetric capacitance of the electrode. Impedance spectroscopy To better understand the kinetics of the charge transfer within the electrodes, EIS

• straight line at low frequencies. The semicircle represents the charge transfer impedance (Rct) for the redox reaction of Ni(OH)2/NiOOH at the electrode/electrolyte interface. The straight line at low frequencies indicates the diffusive resistance of the electrolyte ions (Warburg impedance) [49]. The

Wet chemistry route for the decoration of carbon nanotubes with iron oxide nanoparticles for gas sensing

• Hussam M. Elnabawy,
• Juan Casanova-Chafer,
• Badawi Anis,
• Mostafa Fedawy,
• Mattia Scardamaglia,
• Carla Bittencourt,
• Ahmed S. G. Khalil,
• Eduard Llobet and
• Xavier Vilanova

Beilstein J. Nanotechnol. 2019, 10, 105–118, doi:10.3762/bjnano.10.10

• into more reactive species that, in turn, interact with CNTs. In addition, such nanoparticles shift the Fermi level of CNTs, adsorb target molecules, and help in mediating the charge transfer between adsorbates and CNTs [6][10]. Several metal oxides have been reported as useful for decorating CNTs and

Amorphous Ni_xCo_yP-supported TiO₂ nanotube arrays as an efficient hydrogen evolution reaction electrocatalyst in acidic solution

• Yong Li,
• Peng Yang,
• Bin Wang and
• Zhongqing Liu

Beilstein J. Nanotechnol. 2019, 10, 62–70, doi:10.3762/bjnano.10.6

• −), suggesting a small electron density transfer from Ni and Co to P [37]. This charged structure is very beneficial for improving surface activity toward HER. A critical means to improve the charge transfer of HER is to enhance the conductivity of the electrocatalysts. Doping or hybridization to form a

• active site density, and thus the electrocatalytic activity. The Nyquist and Bode plots are displayed in Figure 8. In the Nyquist plot, the arc radius of the high-frequency section corresponds to the impedance of charge transfer between electrolyte and the catalyst surface, and the ones of the low

• -frequency area correspond to the impedance of charge transport inside the electrode [15][42][43][44]. In Figure 8a, the Nyquist curves are shown as two arcs with different radius in the high and low frequency, suggesting that the catalytic reaction was limited by the charge transfer step. The arc radii of

Electrolyte tuning in dye-sensitized solar cells with N-heterocyclic carbene (NHC) iron(II) sensitizers

• Mariia Karpacheva,
• Catherine E. Housecroft and
• Edwin C. Constable

Beilstein J. Nanotechnol. 2018, 9, 3069–3078, doi:10.3762/bjnano.9.285

• impedance spectroscopy (EIS) is an important technique for the investigation of interfaces in DSCs [49][50]. Fitting of the Nyquist and Bode plots, which are used to describe the EIS results, leads to parameters including the recombination resistance (Rrec), electron/hole transport resistance (Rtr), charge

• -transfer resistance at the counter electrode (RPt) and the active layer surface chemical capacitance (Cµ). All experiments in the following discussion were performed at VOC conditions. The equivalent circuit model used in this study consisted of five elements (Figure S2, Supporting Information File 1). A

Hydrogen-induced plasticity in nanoporous palladium

• Markus Gößler,
• Eva-Maria Steyskal,
• Markus Stütz,
• Norbert Enzinger and
• Roland Würschum

Beilstein J. Nanotechnol. 2018, 9, 3013–3024, doi:10.3762/bjnano.9.280

• charge transfer during hydrogen loading, especially at strongly negative potentials, a calculation based on the recorded charge flow during hydrogenation might overestimate the hydrogen concentration in the samples. Therefore, the atomic ratio of hydrogen and palladium H/Pd (cf) was determined based on

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• concentrations of NO2, while the pure WO3 and graphene sensors did not respond to NO2 at room temperature. The authors claimed that the reason for room-temperature sensing of the composite sensor was the effective charge transfer between graphene and WO3 nanospheres by chemical bonds. The research group

Controlling surface morphology and sensitivity of granular and porous silver films for surface-enhanced Raman scattering, SERS

• Sherif Okeil and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2018, 9, 2813–2831, doi:10.3762/bjnano.9.263

• and depends on the local electromagnetic field at the metal surface while the chemical enhancement depends on the analyte itself and results from an effective charge transfer between the noble metal and the adsorbed probe molecule [5][6]. While the Raman effect is intrinsically weak and typically does

Variation of the photoluminescence spectrum of InAs/GaAs heterostructures grown by ion-beam deposition

• Alexander S. Pashchenko,
• Leonid S. Lunin,
• Eleonora M. Danilina and
• Sergei N. Chebotarev

Beilstein J. Nanotechnol. 2018, 9, 2794–2801, doi:10.3762/bjnano.9.261

• -GaAs layer thickness, on the one hand, limits the fluctuation of QD heights in vertically stacked arrays and stabilizes them and, on the other hand, improves the charge transfer due to the resonant tunneling between the vertical InAs QD layers. Photoluminescence properties of InAs/GaAsBi

Au–Si plasmonic platforms: synthesis, structure and FDTD simulations

• Anna Gapska,
• Marcin Łapiński,
• Paweł Syty,
• Wojciech Sadowski,
• Józef E. Sienkiewicz and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2018, 9, 2599–2608, doi:10.3762/bjnano.9.241

• same spectra measured for the as-prepared film and for bulk Au are added. The binding energy of the Au 4f core-level shifts, depending on cluster size, cluster–substrate interactions, cluster morphology and charge transfer between cluster and substrates [23][24]. Additionally, the peak ratio of the Au

High-temperature magnetism and microstructure of a semiconducting ferromagnetic (GaSb)_1−x(MnSb)_x alloy

• Leonid N. Oveshnikov,
• Elena I. Nekhaeva,
• Alexey V. Kochura,
• Alexander B. Davydov,
• Mikhail A. Shakhov,
• Sergey F. Marenkin,
• Oleg A. Novodvorskii,
• Alexander P. Kuzmenko,
• Alexander L. Vasiliev,
• Boris A. Aronzon and
• Erkki Lahderanta

Beilstein J. Nanotechnol. 2018, 9, 2457–2465, doi:10.3762/bjnano.9.230

• interaction is affected by the appearance of Schottky barriers at the MnSb/GaSb boundaries. Basically, these type of barriers appear on the semiconductor/metal interfaces providing a tunneling charge transfer across the boundary, if the barrier is high enough. In the present case, Schottky barriers may appear

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• RHE, and the operation of the photocathode. The value of the onset potential (Von), which is the condition attributed to a minimum charge transfer of the cell, was found to be just below that of the OER potential. All of the Co3O4 samples exhibited a photoresponse, suggesting photoabsorption and the

• and PEC cells under this condition exhibit the minimum charge transfer. Additional details on the identification of band edges and VFB in the Co3O4 samples can be found elsewhere [20]. Figure S2 and Figure S3 (Supporting Information File 1) provide analysis of the MS characteristics including the

SERS active Ag–SiO₂ nanoparticles obtained by laser ablation of silver in colloidal silica

• Cristina Gellini,
• Francesco Muniz-Miranda,
• Alfonso Pedone and
• Maurizio Muniz-Miranda

Beilstein J. Nanotechnol. 2018, 9, 2396–2404, doi:10.3762/bjnano.9.224

• adsorbed on colloidal silver nanoparticles allow a SERS observation also for excitation in the near-IR spectral region [38][39][40]. This effect is attributable to the formation of charge-transfer complexes [41], which ensure SERS enhancement, even in the absence of an efficient resonance effect when the

• molecule → metal electronic charge-transfer and the long N–Ag bond distance, reported in Table 2. Moreover, the large difference between the complexation energies of the two proposed complexes indicates that the molecule by far prefers to bind to the positively charged silver atom than to a neutral one

• . The interaction of the molecule with Ag+ results in the formation of a complex characterized by a large charge transfer, more than half the electronic charge (Table 2). This model complex well reproduces the SERS frequencies, as well as those observed in the Raman spectrum of the Ag(I) coordination

Intrinsic ultrasmall nanoscale silicon turns n-/p-type with SiO₂/Si₃N₄-coating

• Dirk König,
• Daniel Hiller,
• Noël Wilck,
• Birger Berghoff,
• Merlin Müller,
• Sangeeta Thakur,
• Giovanni Di Santo,
• Luca Petaccia,
• Joachim Mayer,
• Sean Smith and
• Joachim Knoch

Beilstein J. Nanotechnol. 2018, 9, 2255–2264, doi:10.3762/bjnano.9.210

• embedded in Si3N4, presenting the entire system under investigation within one approximant. An interface charge transfer (ICT) of electrons from the usn-Si volume to the anions of the embedding dielectric – nitrogen (N) or oxygen (O) – is at the core of the energy shift [14]. We explain the shift of usn-Si

The role of adatoms in chloride-activated colloidal silver nanoparticles for surface-enhanced Raman scattering enhancement

• Nicolae Leopold,
• Andrei Stefancu,
• Krisztian Herman,
• István Sz. Tódor,
• Stefania D. Iancu,
• Vlad Moisoiu and
• Loredana F. Leopold

Beilstein J. Nanotechnol. 2018, 9, 2236–2247, doi:10.3762/bjnano.9.208

• cross-section of the adsorbed molecule. The charge-transfer electronic transition can be explained as follows [8][12][13][14]: The chemical mechanism of SERS involves the absorption of a photon and the excitation of an electron from the Fermi level of the metallic nanoparticle (M) to the LUMO orbital

Dumbbell gold nanoparticle dimer antennas with advanced optical properties

• Janning F. Herrmann and
• Christiane Höppener

Beilstein J. Nanotechnol. 2018, 9, 2188–2197, doi:10.3762/bjnano.9.205

• strength or the signal enhancement, and the achievable confinement of the light in plasmonic nanostructures [10][11][12][13][14]. Furthermore, this stimulated the discussion of the onset of non-classical phenomena, such as, screening effects, non-localities and charge transfer in coupled plasmonic systems

• characterized by a red-shift and a broadening of the BDP mode or even exhibit an additional peak (CTP-charge transfer plasmon mode) in the NIR region. The latter is indicative for the onset of charge transfer mechanisms. The origin for these deviations is not evident from the geometrical structure of the