Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• experiment and electron spin resonance (ESR) experiment suggest that the electron transfer path between Bi2O3 and MIL101(Fe) accords with the Z-type transfer mechanism. The possible photocatalytic degradation pathways were investigated via the analysis of the intermediate products in the degradation process

• (CHIQ660D, Chenhua Instrument, China). Electronic paramagnetic resonance signals were recorded with an electron paramagnetic resonance spectrometer (Brooke A300, Germany). Results and Discussion Characterization Figure 1 shows the XRD pattern of the synthesized MIL101(Fe), Bi2O3, and BOM-20 composite. The

Numerical study on all-optical modulation characteristics of quantum cascade lasers

• Biao Wei,
• Haijun Zhou,
• Guangxiang Li and
• Bin Tang

Beilstein J. Nanotechnol. 2022, 13, 1011–1019, doi:10.3762/bjnano.13.88

• standard 35-stage In0.52Al0.48As/In0.53Ga0.47As type-I four-level Fabry–Perot QCL based on a two-phonon-resonance design [27]. Current injection efficiency is defined as the ratio of current to total current injected into the upper subband of the QCL in the active region, which is close to 56%. The QCL

Effects of focused electron beam irradiation parameters on direct nanostructure formation on Ag surfaces

• Jānis Sniķeris,
• Vjačeslavs Gerbreders,
• Andrejs Bulanovs and
• Ēriks Sļedevskis

Beilstein J. Nanotechnol. 2022, 13, 1004–1010, doi:10.3762/bjnano.13.87

• micromechanical oscillators via EB irradiation which contradicts the model of EB-induced carbonization as a simple process of adding carbon mass to the irradiated area [32]. Doubly clamped beams made of Au85Pd15 were irradiated by EB and their resonance frequency increased with exposure time and beam current due

• to EB-induced carbonization. However, changing the position of the EB along the oscillator did not affect their resonance frequency, which should be the case if carbonization was happening locally. There is a potential for carbon and carbon-metal based nanostructured systems to be used in different

Comparing the performance of single and multifrequency Kelvin probe force microscopy techniques in air and water

• Jason I. Kilpatrick,
• Emrullah Kargin and
• Brian J. Rodriguez

Beilstein J. Nanotechnol. 2022, 13, 922–943, doi:10.3762/bjnano.13.82

• governing the performance of single and multifrequency Kelvin probe force microscopy (KPFM) techniques in both air and water. Metrics such as minimum detectable contact potential difference, minimum required AC bias, and signal-to-noise ratio are compared and contrasted both off resonance and utilizing the

• in the response of the lever proportional to the quality factor of that mode, Qn, where n is the mode number [36][55]. KPFM techniques can be applied off resonance (ω ≠ ωn), where ∝ 1/kn, where kn is the spring constant of the n-th eigenmode. More generally, KPFM techniques are applied at, or close

• significant SNR enhancements over off-resonance techniques, higher spatial resolution due to reduced influence of the cantilever to the electrostatic forces [17][60][63], and higher bandwidth than side-band techniques [10][58]. All modes of KPFM can in principle be applied in any of these scenarios. In

Numerical modeling of a multi-frequency receiving system based on an array of dipole antennas for LSPE-SWIPE

• Alexander V. Chiginev,
• Anton V. Blagodatkin,
• Dmitrii A. Pimanov,
• Ekaterina A. Matrozova,
• Anna V. Gordeeva,
• Andrey L. Pankratov and
• Leonid S. Kuzmin

Beilstein J. Nanotechnol. 2022, 13, 865–872, doi:10.3762/bjnano.13.77

• frequency channel at the level of 0.5 is 45 GHz. At 220 GHz there is a spurious resonance that can be suppressed with a low-pass filter. Auxiliary frequency channels of the LSPE-SWIPE The cells are located within a circle with a diameter of 4.5 mm; while one half of the circle is occupied by cells for 210

Self-assembly of C₆₀ on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C₆₀ monolayer

• Guglielmo Albani,
• Michele Capra,
• Alessandro Lodesani,
• Alberto Calloni,
• Gianlorenzo Bussetti,
• Marco Finazzi,
• Franco Ciccacci,
• Alberto Brambilla,
• Lamberto Duò and
• Andrea Picone

Beilstein J. Nanotechnol. 2022, 13, 857–864, doi:10.3762/bjnano.13.76

• range (filled electronic states) a strong resonance centered at about −2.60 eV is present, which we attribute to HOMO states, in excellent agreement with UPS measurements (−2.56 eV). In the positive energy range (empty states) of the STS spectrum the LUMO peak is visible at 1.15 eV, resulting in an

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• ferromagnetic resonance techniques (the latter two, because of the large scale, yield volume-averaged signals). Resonant magnetic small-angle X-ray scattering applied to Pd1−xFex alloy films with x = 0.03–0.07 revealed static magnetic fluctuations on the lateral scale of about 100 nm attributed to the magnetic

Optimizing PMMA solutions to suppress contamination in the transfer of CVD graphene for batch production

• Chun-Da Liao,
• Andrea Capasso,
• Tiago Queirós,
• Telma Domingues,
• Fatima Cerqueira,
• Nicoleta Nicoara,
• Jérôme Borme,
• Paulo Freitas and
• Pedro Alpuim

Beilstein J. Nanotechnol. 2022, 13, 796–806, doi:10.3762/bjnano.13.70

• analyzer had a pass energy of 20 eV. Atomic force microscopy The surface topographies of graphene were investigated by a Bruker Dimension Icon atomic force microscope (AFM), using PPP-NCH (NanosensorsTM) cantilevers with a tip radius smaller than 20 nm, a force constant of 42 N/m, and 250 kHz resonance

Gelatin nanoparticles with tunable mechanical properties: effect of crosslinking time and loading

• Agnes-Valencia Weiss,
• Daniel Schorr,
• Julia K. Metz,
• Metin Yildirim,
• Saeed Ahmad Khan and
• Marc Schneider

Beilstein J. Nanotechnol. 2022, 13, 778–787, doi:10.3762/bjnano.13.68

• same day. AFM measurements were carried out with a JPK NanoWizard® 3 AFM (JPK Instruments, Berlin, Germany) using the MLCT cantilever tip D (Bruker France Nano Surfaces, Wissembourg, France) with a nominal resonance frequency of 15 kHz and a spring constant of 0.03 N/m. Before each measurement, the

Direct measurement of surface photovoltage by AC bias Kelvin probe force microscopy

• Masato Miyazaki,
• Yasuhiro Sugawara and
• Yan Jun Li

Beilstein J. Nanotechnol. 2022, 13, 712–720, doi:10.3762/bjnano.13.63

• force This signal is measured with a lock-in amplifier and compensated by VAC control, yielding the SPV value. To improve the sensitivity, ωm is usually tuned to the second (first) resonance frequency of the cantilever, while the first (second) resonance frequency is assigned to the AFM measurement [29

• ]. Since these resonance frequencies are commonly in the kilohertz to megahertz range, the time scale of the measured SPV is from microseconds to milliseconds, which is much faster than that measured by classical KPFM, which measures the slow SPV response of the order of seconds to hours because of the

Tunable high-quality-factor absorption in a graphene monolayer based on quasi-bound states in the continuum

• Jun Wu,
• Yasong Sun,
• Feng Wu,
• Biyuan Wu and
• Xiaohu Wu

Beilstein J. Nanotechnol. 2022, 13, 675–681, doi:10.3762/bjnano.13.59

• energy conversion, while narrow-band absorbers [9][10][11][12] have great potential in sensing and monochromatic light detecting. An example is the application of narrow-band absorbers in refractive index sensing [13]. When the absorbers are surrounded by gas or liquid, the resonance wavelength will

• proposed to enhance the absorption in graphene monolayers, such as coherent perfect absorption effect [46], critical coupling effect [47], guided mode resonance effect [48], metal Tamm plasmon polaritons effect [49], and graphene Tamm surface plasmons effect [50]. In addition, the quasi-BICs mentioned

• structures without graphene monolayer for angles of 0°, 0.1°, 0.5°, 1.0°, 1.5°, and 2.0° in Figure 4a. Clearly, with the successively reduction of the incident angle from 2.0° to 0°, the bandwidth of the Fano resonance peak decreases rapidly. At θ = 0°, the bandwidth has completely vanished, indicating an

Quantitative dynamic force microscopy with inclined tip oscillation

• Philipp Rahe,
• Daniel Heile,
• Reinhard Olbrich and
• Michael Reichling

Beilstein J. Nanotechnol. 2022, 13, 610–619, doi:10.3762/bjnano.13.53

• -dependent shift in frequency, Δf(zp), of the sensor excitation frequency fexc that results when phase resonance for the sensor oscillation is maintained throughout the measurement [19]. The resulting curve Δf(zp) is a convolution of the covered part of the force curve and a kernel depending on the

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

• the interaction with local dipoles in plasma-treated MoS2 [22]. Additionally, the electronic band structure of MoS2 can be significantly modified after oxygen incorporation into MoS2. The charge transfer from the valence band of partially oxidized MoS2 to the LUMO of R6G can be tuned in resonance with

• (called Q-band) from 500 to 800 nm. The absorption peaks situated at 627 and 696 nm are due to the second and the first π–π* transition of the phthalocyanine macrocycle, respectively [30]. Therefore, the Raman measurements for CuPc/MoSe2 are conducted using a 636 nm laser, which shows good resonance with

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• ), respectively [63]. For pure spherical Zn NPs, on average 28 ± 5 nm in diameter, obtained by vacuum magnetron sputtering on molten quartz, the plasmonic resonance is located around 240 and 290 nm, while for ZnO NPs, the maximum is around 360 nm [64]. In addition, ZnO nanosubstrates serve as carriers of Ag or Au

• nanosubstrates. By combining Ag or Au with ZnO into core–shell NPs it is possible to tune the resonance excitation of the whole system to shorter wavelengths, due to the overlap of multiple plasmonic resonance peaks arising from different metals. Resonant excitation can be shifted to longer wavelengths by

• nanorods (NRs) and Au seeds alone. The results showed a stronger SERS signal in the case of Au–ZnO NRs compared to Au nanoscale seeds. The SERS signal enhancement is due to the increased charge transfer effect of ZnO, which is greatly improved by the localized surface plasmon resonance of Au seeds. For the

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• resonance. For the irradiation dose of 0.5 mC/cm2 with 1 keV primary electrons, an areal number density of (1.7 ± 0.7) × 1013 cm−2 was obtained for secondary electrons with kinetic energies within the window of the resonance (see detailed calculations in Supporting Information File 1). When considering the

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• for resonance detection of a GeSn alloy. Meija et al. [42] proposed the technique of using resonance aid to reduce the pull-in voltage of Ge0.91Sn0.09 NWs. By applying 610.8 kHz and 0.45 V AC voltage to a GeSn alloy nanowire, the pull-in voltage can be reduced from 13.8 to 5 V. This method can

Controllable two- and three-state magnetization switching in single-layer epitaxial Pd_1−xFe_x films and an epitaxial Pd_0.92Fe_0.08/Ag/Pd_0.96Fe_0.04 heterostructure

• Igor V. Yanilkin,
• Amir I. Gumarov,
• Gulnaz F. Gizzatullina,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2022, 13, 334–343, doi:10.3762/bjnano.13.28

• structural studies of similar films are described in [24], the magnetic properties measured by ferromagnetic resonance (FMR) and vibrating sample magnetometry (VSM) in magnetic fields along the easy and hard magnetic axes are presented in [18][19]. In this paper, the magnetization reversal in the

A broadband detector based on series YBCO grain boundary Josephson junctions

• Egor I. Glushkov,
• Alexander V. Chiginev,
• Leonid S. Kuzmin and
• Leonid S. Revin

Beilstein J. Nanotechnol. 2022, 13, 325–333, doi:10.3762/bjnano.13.27

• electrodynamics is taken into account through the amplitudes of the external signal Ai followed from the previous section. A complete model of the antenna interacting with the nonlinear resonance circuit (Josephson junction) through the Y-matrix is currently being developed. This model will allow one to

• (Z) = RL, dIm(Z)/dω = 2LL, and . For the serial resonance at 250 GHz, RL = 43 Ω, LL = 500 pH, and CL = 0.8 fF. Figure 5, right, shows the current–voltage characteristics (IVCs) of a single junction with the antenna under the influence of an external signal. A bias current regime with the optimum

Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• constants of the cantilever [47]. The resonance frequency of the cantilever at the first normal oscillation mode measured in the air was used to calculate the thickness of the cantilever [47]. The AFM tip sliding velocity was 8.0 μm·s−1 and the scan field was 1.0 × 0.125 μm2. Sixteen cycles of repetitive

Surfactant-free syntheses and pair distribution function analysis of osmium nanoparticles

• Mikkel Juelsholt,
• Jonathan Quinson,
• Emil T. S. Kjær,
• Baiyu Wang,
• Rebecca Pittkowski,
• Susan R. Cooper,
• Tiffany L. Kinnibrugh,
• Søren B. Simonsen,
• Luise Theil Kuhn,
• María Escudero-Escribano and
• Kirsten M. Ø. Jensen

Beilstein J. Nanotechnol. 2022, 13, 230–235, doi:10.3762/bjnano.13.17

• reaction at 85 °C in nuclear magnetic resonance (NMR) tubes (volume approx. 0.2 mL). The size analysis suggests that the NPs are (a) 1.6 ± 0.4 nm and (b) 1.7 ± 0.3 nm. The size distribution is presented in (c) from the analysis of 103 and 106 NPs, respectively. PDFs obtained from three different syntheses

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• irradiation with light of wavelengths larger than 520 nm corresponding to the surface plasmon band (see Supporting Information File 1, Figure S13), while no current increase is recorded at the wavelength corresponding to the MLCT band. The local surface plasmon resonance of the Ru(MPTP)2–AuNP is found at 533

• to the AuNP surfaces is possible. Such a plasmon-induced resonance energy transfer is likely if a spectral overlap between the plasmon resonance and a molecular resonance, ideally of shorter wavelength, exists [41]. The transferred energy leads to the excitation of the redox center of the Ru(MPTP)2

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• are closer to 20:1 in the current study. This implies that [Mo(CO)5]− observed at 2.2 eV by Winters and Kiser, is from the high-energy tail of the threshold resonances or from the 1.65 eV resonance observed in the transmission spectra reported by Giordan and co-workers [18]. For the loss of two CO

• 3.29 eV resonances observed in the electron transmission experiments leaves the contribution of the 2.14 eV resonance unaccounted for in the ion yields. This may be due to the short lifetime of this resonance and/or the fact that [Mo(CO)4]− formed through this resonance is masked by the higher

• attributed to a distinct feature in the ETS and the low-intensity, high-energy [Mo(CO)2]− contribution is outside the energy range covered by the ETS. An alternative assignment of the observed DEA contributions to the resonances observed in the ETS would be that the 2.14 eV resonance appears through the 3.2

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• reports still proposed its photocatalytic behaviors partly based on •O2− species via the combination of experimental physicochemical analyses, such as electron spin resonance (ESR) spectroscopy, active species trapping experiments, valence band X-ray photoelectron spectroscopy (XPS), and diffuse

• density functional theory (DFT) calculations, trapping experiments, and electron spin resonance measurements (Figure 10). Thus, the impact of intrinsic OVs within SnO2 NPs and the resulting S-scheme heterojunction on the band structure, charge transfer, and photocatalytic activity was presented. The

Theranostic potential of self-luminescent branched polyethyleneimine-coated superparamagnetic iron oxide nanoparticles

• Rouhollah Khodadust,
• Ozlem Unal and
• Havva Yagci Acar

Beilstein J. Nanotechnol. 2022, 13, 82–95, doi:10.3762/bjnano.13.6

• theranostic nanomaterials, PAMAM and PEI were frequently coupled with superparamagnetic iron oxide nanoparticles (SPIONs) for drug/gene delivery combined with magnetic resonance imaging [31][32]. Usually, these systems were conjugated with other fluorescent tags for optical detection of nanoparticles in cells

• cancer [39][40]. Besides, SPIONs are already in the clinic as magnetic resonance imaging (MRI) agents and SPION@bPEI nanoparticles have a strong T2 signal (the signal that reflects the length of time it takes for the MR signal to decay in the transverse plane) [35]. In recent years, there has been a

• growing demand for a combination of different imaging modalities to improve the detection limit and to provide image-guided therapies [41][42]. Both MRI and optical imaging are noninvasive imaging modalities. Magnetic resonance imaging provides high spatial resolution but lacks sensitivity. Optical

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• nuclei of the final NPs [94][95]. Because silver clusters absorb light at different wavelengths than the surface plasmon resonance (SPR) band of Ag NPs (which is used for monitoring of NP growth kinetics by UV–vis spectroscopy) one can spot the induction period on the sigmoidal kinetic curves. Noteworthy