Controlling surface morphology and sensitivity of granular and porous silver films for surface-enhanced Raman scattering, SERS

• Sherif Okeil and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2018, 9, 2813–2831, doi:10.3762/bjnano.9.263

• treatment; silver; sputtering; surface-enhanced Raman spectroscopy (SERS); surface roughening; Introduction The great enhancement of Raman signals obtained from molecules when they are in close vicinity to a rough noble-metal surface (e.g., gold, silver and copper) has attracted a great deal of interest in

• and depends on the local electromagnetic field at the metal surface while the chemical enhancement depends on the analyte itself and results from an effective charge transfer between the noble metal and the adsorbed probe molecule [5][6]. While the Raman effect is intrinsically weak and typically does

Comparative biological effects of spherical noble metal nanoparticles (Rh, Pd, Ag, Pt, Au) with 4–8 nm diameter

• Alexander Rostek,
• Marina Breisch,
• Kevin Pappert,
• Kateryna Loza,
• Marc Heggen,
• Manfred Köller,
• Christina Sengstock and
• Matthias Epple

Beilstein J. Nanotechnol. 2018, 9, 2763–2774, doi:10.3762/bjnano.9.258

• determine the effect of particle exposure on the viability of human mesenchymal stem cells (hMSCs). Except for silver, no adverse effect of any of the metal nanoparticles was observed for concentrations up to 50 ppm (50 mg L−1) incubated for 24 h, indicating that noble metal nanoparticles (rhodium

• , and nanomedicine [1][2][3]. Noble metal nanoparticles are of particular importance due to their diverse properties such as surface plasmon resonance, chemical inertness, and antibacterial action (silver) [4][5][6][7][8][9]. However, concerns have been raised with respect to their biological effect

• after unintended exposure [10][11][12][13][14]. Noble metal nanoparticles such as Au, Pt, Pd, and Rh have distinct catalytic properties in biology, and have been reported to show several enzyme-like activities in vitro, including reactive oxygen species scavenger activity [15][16][17][18][19][20][21][22

Size-selected Fe₃O₄–Au hybrid nanoparticles for improved magnetism-based theranostics

• Maria V. Efremova,
• Yulia A. Nalench,
• Eirini Myrovali,
• Anastasiia S. Garanina,
• Ivan S. Grebennikov,
• Polina K. Gifer,
• Maxim A. Abakumov,
• Marina Spasova,
• Makis Angelakeris,
• Alexander G. Savchenko,
• Michael Farle,
• Natalia L. Klyachko,
• Alexander G. Majouga and
• Ulf Wiedwald

Beilstein J. Nanotechnol. 2018, 9, 2684–2699, doi:10.3762/bjnano.9.251

• be adjusted by heterogeneous nucleation of NPs on noble metal seeds [21][22]. Additionally, such bifunctional Fe3O4–Au NPs are potentially applicable for targeted drug delivery, enhanced hyperthermia, multimodal imaging and theranostics [8][23][24][25][26][27]. In this work, we present the first size

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• limited ability to uniformly disperse NPs. A solution could be the encapsulation of NPs in polar proteins that could repel each other resulting in uniform dispersion over the entire surface area. Kim et al. [75][189][190][191] reported protein (apoferritin) encapsulated catalytic/noble metal NP

Self-assembled quasi-hexagonal arrays of gold nanoparticles with small gaps for surface-enhanced Raman spectroscopy

• Emre Gürdal,
• Simon Dickreuter,
• Fatima Noureddine,
• Pascal Bieschke,
• Dieter P. Kern and
• Monika Fleischer

Beilstein J. Nanotechnol. 2018, 9, 1977–1985, doi:10.3762/bjnano.9.188

• . A combination of micellar nanolithography and electroless deposition (ED) enables the tuning of the spacing and size of the noble metal nanoparticles. Long-range ordered quasi-hexagonal arrays of gold nanoparticles on silicon substrates with a variation of the particle sizes from about 20 nm to 120

• lithography; optical antenna; self-assembly; SERS; Introduction Over the last decades self-assembled layers of gold nanoparticles have taken an important role in emerging nanotechnologies. Noble metal nanoparticles show localized surface plasmon polariton resonances (LSPRs) in the visible and infrared

Optical near-field mapping of plasmonic nanostructures prepared by nanosphere lithography

• Gitanjali Kolhatkar,
• Alexandre Merlen,
• Jiawei Zhang,
• Chahinez Dab,
• Gregory Q. Wallace,
• François Lagugné-Labarthet and
• Andreas Ruediger

Beilstein J. Nanotechnol. 2018, 9, 1536–1543, doi:10.3762/bjnano.9.144

• is focused onto a nano-antenna consisting of a noble metal tip, whose role is to enhance and to confine the near-field and to transform it into a measurable far-field signal. An electromagnetic near-field amplification is generated in the process. The main challenge is to fabricate highly efficient

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• range of TiO2 by modification with metal sulfides. The enhancement in photocatalytic reduction of Cr(VI) over noble-metal-modified TiO2 is depicted in section five whereas section six includes the use of dye-sensitized TiO2 for photoreduction of Cr(VI). Optical and electrochemical characteristics of

Understanding the performance and mechanism of Mg-containing oxides as support catalysts in the thermal dry reforming of methane

• Nor Fazila Khairudin,
• Mohd Farid Fahmi Sukri,
• Mehrnoush Khavarian and
• Abdul Rahman Mohamed

Beilstein J. Nanotechnol. 2018, 9, 1162–1183, doi:10.3762/bjnano.9.108

• support and active metal particles [16][17][18]. The loss of catalytic activity or selectivity over time of production affects the cost of catalyst replacement, process shutdown, and product quality and quantity. Numerous researchers have reported that noble metal-based catalysts, such as Pt, Rh, Pd, Ru

Noble metal-modified titania with visible-light activity for the decomposition of microorganisms

• Maya Endo,
• Zhishun Wei,
• Kunlei Wang,
• Baris Karabiyik,
• Kenta Yoshiiri,
• Paulina Rokicka,
• Bunsho Ohtani,
• Agata Markowska-Szczupak and
• Ewa Kowalska

Beilstein J. Nanotechnol. 2018, 9, 829–841, doi:10.3762/bjnano.9.77

• oxidized (shell) forms, whereas gold was mainly zero valent. The obtained noble metal-modified samples were examined with regard to antibacterial (Escherichia coli (E. coli)) and antifungal (Aspergillus niger (A. niger), Aspergillus melleus (A. melleus), Penicillium chrysogenum (P. chrysogenum), Candida

• ; antimicrobial properties; bactericidal effect; noble-metal nanoparticles; plasmonic photocatalysis; Introduction Environmental pollution and the lack of clean potable water are main issues facing human development. Although, various methods of efficient control and monitoring of waste management have been

• antimicrobial properties of noble metals with the high photocatalytic activity of modified titania should result in a high purification efficiency of noble metal-modified titania [6][46][47][48][49][50][51][52]. Indeed, in our recent study, noble metal-modified faceted anatase titania (octahedral anatase

Surface-plasmon-enhanced ultraviolet emission of Au-decorated ZnO structures for gas sensing and photocatalytic devices

• T. Anh Thu Do,
• Truong Giang Ho,
• Thu Hoai Bui,
• Quang Ngan Pham,
• Hong Thai Giang,
• Thi Thu Do,
• Duc Van Nguyen and
• Dai Lam Tran

Beilstein J. Nanotechnol. 2018, 9, 771–779, doi:10.3762/bjnano.9.70

• quantity of active electrons involved in the surface response plays a key role for the sensor performance. The incorporation of noble metal nanostructures such as gold (Au) into ZnO surfaces is considered as an effective way to enhance the gas sensing response and to reduce the operation temperature and

Mechanistic insights into plasmonic photocatalysts in utilizing visible light

• Kah Hon Leong,
• Azrina Abd Aziz,
• Lan Ching Sim,
• Pichiah Saravanan,
• Min Jang and
• Detlef Bahnemann

Beilstein J. Nanotechnol. 2018, 9, 628–648, doi:10.3762/bjnano.9.59

• sustainable photocatalysts that can collectively harvest visible light. However, the bottleneck in utilising the low energy photons has led to the discovery of plasmonic photocatalysts. The presence of noble metal on the plasmonic photocatalyst enables the harvesting of visible light through the unique

• characteristic features of the noble metal nanomaterials. Moreover, the formation of interfaces between noble metal particles and semiconductor materials further results in the formation of a Schottky junction. Thereby, the plasmonic characteristics have opened up a new direction in promoting an alternative path

• : localized surface plasmon resonance (LSPR); noble metal; plasmonic photocatalyst; reactive radicals; Schottky junctions; visible light; Review Introduction Photocatalysts have played and will continue to play a pivotal role in environmental and energy applications in order to fulfil the needs of the

Facile phase transfer of gold nanorods and nanospheres stabilized with block copolymers

• Yaroslav I. Derikov,
• Georgiy A. Shandryuk,
• Raisa V. Talroze,
• Alexander A. Ezhov and
• Yaroslav V. Kudryavtsev

Beilstein J. Nanotechnol. 2018, 9, 616–627, doi:10.3762/bjnano.9.58

• copolymers doped with noble metal nanoparticles are considered as promising hybrid materials that combine the plasmonic, catalytic or other functionality of nanoparticles, their periodic spatial arrangement in the microphase separated copolymer domains and the general processability of polymer matrices [3][4

BN/Ag hybrid nanomaterials with petal-like surfaces as catalysts and antibacterial agents

• Konstantin L. Firestein,
• Denis V. Leybo,
• Alexander E. Steinman,
• Andrey M. Kovalskii,
• Andrei T. Matveev,
• Anton M. Manakhov,
• Irina V. Sukhorukova,
• Pavel V. Slukin,
• Nadezda K. Fursova,
• Sergey G. Ignatov,
• Dmitri V. Golberg and
• Dmitry V. Shtansky

Beilstein J. Nanotechnol. 2018, 9, 250–261, doi:10.3762/bjnano.9.27

• utilized toward the development of cutting-edge hybrid nanostructures. For example, BN/noble metal (Pt, Au, Ag) hybrid nanomaterials are envisaged to be the promising components of highly active catalysts, drug delivery systems, molecular probe sensors, surface enhanced Raman spectroscopy techniques, and

Comparative study of post-growth annealing of Cu(hfac)₂, Co₂(CO)₈ and Me₂Au(acac) metal precursors deposited by FEBID

• Marcos V. Puydinger dos Santos,
• Aleksandra Szkudlarek,
• Artur Rydosz,
• Carlos Guerra-Nuñez,
• Fanny Béron,
• Kleber R. Pirota,
• Stanislav Moshkalev,
• José Alexandre Diniz and
• Ivo Utke

Beilstein J. Nanotechnol. 2018, 9, 91–101, doi:10.3762/bjnano.9.11

• removing the carbon matrix and drastically reducing the electrical resistance of the deposit. Keywords: copper; gold; cobalt; focused-electron-beam-induced deposition; noble metal; non-noble metals; post-growth annealing; Introduction Focused-electron-beam-induced deposition (FEBID) constitutes a well

• resolution [52][53]. Novel strategies have also been recently implemented to produce high-purity Cu nanodeposits using an aqueous solution precursor [54]. Moreover, the conventional post-growth annealing of FEBID deposits under vacuum has been reported as a promising protocol for tuning the non-noble metal

• percolated metallic film with much lower resistance. Conclusion We have used a vacuum-based post-growth annealing protocol for tuning the crystalline properties of FEBID materials produced under a low electron-beam density from non-noble metal, Co2(CO)8 and Cu(hfac)2, as well as noble metal, Me2Au(acac

Growth model and structure evolution of Ag layers deposited on Ge films

• Arkadiusz Ciesielski,
• Lukasz Skowronski,
• Ewa Górecka,
• Jakub Kierdaszuk and
• Tomasz Szoplik

Beilstein J. Nanotechnol. 2018, 9, 66–76, doi:10.3762/bjnano.9.9

• -assembly; silver; thin films; Introduction Silver is a noble metal with lowest loss in the visible to the near-infrared wavelengths; therefore, the surface plasmon polariton (SPP) wave propagation length crucial for plasmonic devices is greatest at Ag/dielectric interfaces [1][2][3]. A pure Ag layer of 35

Review on optofluidic microreactors for artificial photosynthesis

• Xiaowen Huang,
• Jianchun Wang,
• Tenghao Li,
• Jianmei Wang,
• Min Xu,
• Weixing Yu,
• Abdel El Abed and
• Xuming Zhang

Beilstein J. Nanotechnol. 2018, 9, 30–41, doi:10.3762/bjnano.9.5

• catalytic materials, modification of the existed catalytic materials (e.g., noble-gas doping, co-catalyst impregnation, noble-metal loading, plasmonic sensitization and Z-scheme systems), and optofluidics (or microfluidics) based APS. It should be noted that many efforts have been made to develop bio

Facile synthesis of silver/silver thiocyanate (Ag@AgSCN) plasmonic nanostructures with enhanced photocatalytic performance

• Xinfu Zhao,
• Dairong Chen,
• Abdul Qayum,
• Bo Chen and
• Xiuling Jiao

Beilstein J. Nanotechnol. 2017, 8, 2781–2789, doi:10.3762/bjnano.8.277

• -based semiconductors are well known due to their excellent visible-light catalytic properties, but their easy inactivation limits their utilization in practice. Aimed at this problem, a series of methods, such as doping, surface sensitization, heterojunctions and noble-metal plasma, have been adopted to

The rational design of a Au(I) precursor for focused electron beam induced deposition

• Ali Marashdeh,
• Thiadrik Tiesma,
• Niels J. C. van Velzen,
• Sjoerd Harder,
• Remco W. A. Havenith,
• Jeff T. M. De Hosson and
• Willem F. van Dorp

Beilstein J. Nanotechnol. 2017, 8, 2753–2765, doi:10.3762/bjnano.8.274

• decrease down the periodic table: The calculated CO dissociation energies for complexes of the heavier noble metals Pd and Pt are low. Consequently, Pd(CO)4 and Pt(CO)4 are unstable and only exist in an inert gas matrix at lower temperatures [58]. Similarly, CO complexes of Au(I), a noble metal of high

CdSe nanorod/TiO₂ nanoparticle heterojunctions with enhanced solar- and visible-light photocatalytic activity

• Fakher Laatar,
• Hatem Moussa,
• Halima Alem,
• Lavinia Balan,
• Emilien Girot,
• Ghouti Medjahdi,
• Hatem Ezzaouia and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2017, 8, 2741–2752, doi:10.3762/bjnano.8.273

• noble metal particles, or constructing heterojunctions between TiO2 and graphene-based materials or carbon nitride (C3N4), acting as electron-transport materials [3][4][5]. All of these strategies have the common goal of decreasing the charge carrier recombination rate by increasing the spatial charge

Laser-assisted fabrication of gold nanoparticle-composed structures embedded in borosilicate glass

• Nikolay Nedyalkov,
• Mihaela Koleva,
• Nadya Stankova,
• Rosen Nikov,
• Mitsuhiro Terakawa,
• Yasutaka Nakajima,
• Lyubomir Aleksandrov and
• Reni Iordanova

Beilstein J. Nanotechnol. 2017, 8, 2454–2463, doi:10.3762/bjnano.8.244

• glass; laser nanostructuring; optical properties of composite materials; Introduction The unique optical properties of noble-metal nanoparticles continue to attract the attention of researchers, especially in view of the potential industrial applications. The basic characteristics of the interaction of

• noble metal nanoparticles into dielectric oxide and polymer matrices results in a large increase of the third-order nonlinear optical susceptibility, an enhancement of the photoluminescence signal from the matrix, a metamaterial-like behavior, and the possibility of modifying the conductivity of the

• ] based on the interaction of laser radiation with noble-metal-doped simple oxides, glasses and polymers, that is capable of forming and manipulating nanoparticles with a high spatial selectivity. Thereby, ion-doped (gold, silver, copper) materials that are transparent in the visible wavelength range (e.g

Fabrication of CeO₂–MO_x (M = Cu, Co, Ni) composite yolk–shell nanospheres with enhanced catalytic properties for CO oxidation

• Ling Liu,
• Jingjing Shi,
• Hongxia Cao,
• Ruiyu Wang and
• Ziwu Liu

Beilstein J. Nanotechnol. 2017, 8, 2425–2437, doi:10.3762/bjnano.8.241

• noble metal-based catalysts in some catalytic reactions [11][12]. So far, a remarkable process has been developed for the synthesis of CeO2-based composite oxides, including CeO2–CuOx [13], CeO2–ZnCo2O4 [14], CeO2–CoOx [15], CeO2–MnOx [16], CeO2–ZnO [17], CeO2–Fe2O3 [18], and CeO2–ZrO2 systems [19

• CeO2–CuOx-2 sample is comparable to the traditional noble-metal–CeO2 system, yielding complete CO conversion at a relatively low temperature of 145 °C. A greatly enhanced performance of the composites in CO oxidation can be attributed to the incorporation of highly-dispersed MOx onto the CeO2 surface

Evaluating the toxicity of TiO₂-based nanoparticles to Chinese hamster ovary cells and Escherichia coli: a complementary experimental and computational approach

• Alicja Mikolajczyk,
• Natalia Sizochenko,
• Ewa Mulkiewicz,
• Anna Malankowska,
• Michal Nischk,
• Przemyslaw Jurczak,
• Seishiro Hirano,
• Grzegorz Nowaczyk,
• Adriana Zaleska-Medynska,
• Jerzy Leszczynski,
• Agnieszka Gajewicz and
• Tomasz Puzyn

Beilstein J. Nanotechnol. 2017, 8, 2171–2180, doi:10.3762/bjnano.8.216

• inhibiting activity [5][6]. Reactivity of TiO2 under visible light (λ > 400 nm) can be achieved in several ways [7], including: (a) metal doping [8], (b) non-metal doping [9][10], (c) self-doping (reductive treatments) [11][12], (d) surface modification by noble-metal nanoparticles of silver (Ag), gold (Au

Synthesis and characterization of noble metal–titania core–shell nanostructures with tunable shell thickness

• Bartosz Bartosewicz,
• Marta Michalska-Domańska,
• Malwina Liszewska,
• Dariusz Zasada and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2017, 8, 2083–2093, doi:10.3762/bjnano.8.208

• , Kaliskiego 2 Str. 00-908 Warsaw, Poland 10.3762/bjnano.8.208 Abstract Core–shell nanostructures have found applications in many fields, including surface enhanced spectroscopy, catalysis and solar cells. Titania-coated noble metal nanoparticles, which combine the surface plasmon resonance properties of the

• [1][2]. This is because the combination of two or more different materials into one structure of controlled size, geometry and morphology can lead to either improved or new properties not observed in the individual constituent materials. CSNs with a silica core and noble metal shell exhibiting

• use in many fields. For example, TiO2 nanomaterials have been investigated for their use in photocatalysis [12][13][14], photocatalytic fuel generation [15], photovoltaics and sensors [16][17]. The CSNs with noble metal (Au, Ag) nanoparticles (NPs) as a core and TiO2 shell, Au@TiO2 and Ag@TiO2, have

Synthesis and functionalization of NaGdF₄:Yb,Er@NaGdF₄ core–shell nanoparticles for possible application as multimodal contrast agents

• Dovile Baziulyte-Paulaviciene,
• Vitalijus Karabanovas,
• Marius Stasys,
• Greta Jarockyte,
• Vilius Poderys,
• Simas Sakirzanovas and
• Ricardas Rotomskis

Beilstein J. Nanotechnol. 2017, 8, 1815–1824, doi:10.3762/bjnano.8.183

• . The similar localization of Tween 80-coated nanoparticles was observed in MCF-7 cells as well. The same results of endocytic NP accumulation in cells was demonstrated in different studies with UCNPs [31], quantum dots [32], magnetic nanomaterials [33] and noble metal nanoparticles [34]. Cell viability

Near-infrared-responsive, superparamagnetic Au@Co nanochains

• Varadee Vittur,
• Arati G. Kolhatkar,
• Shreya Shah,
• Irene Rusakova,
• Dmitri Litvinov and
• T. Randall Lee

Beilstein J. Nanotechnol. 2017, 8, 1680–1687, doi:10.3762/bjnano.8.168

• nanoparticles not only renders the nanoparticles biocompatible but also gives rise to distinct optical properties [18][19]. Noble metal nanoparticles, such as gold and silver, possess the unique property of surface plasmon resonance (SPR); the latter exhibit a strong extinction band in the visible region [19

• modulated depending on the noble metal selected [28]. Duan et al. synthesized Pt-coated Co nanochains in an aqueous medium by magnetic-field induced assembly and galvanic replacement reaction, and Lu et al. synthesized Au-coated Co nanochains in a similar fashion [29][30]. However, none of these studies