Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

• , persistence, ecological, and health risks associated with them. However, to detect these emerging contaminants, analytical techniques that are sensitive and selective enough must be developed due to their incredibly low concentrations [2][6][7][8][9]. Colourimetry, chromatography, enzyme-linked immunoassay

• . Therefore, it is anticipated that the concepts presented in this review will stimulate further investigation into MOF-based materials for opto-electrochemical detection of various other analytes (explosives, viruses, and various other emerging contaminants). Review Opto-electrochemical sensors: mechanisms

• hundred seconds), relaxation to the singlet S0 may take place with the emission of a photon, known as phosphorescence. Since the majority of these emerging contaminants (antibiotics and hormones) are non-fluorescent, several luminescent or fluorescent materials have been utilised to monitor their levels

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• applications, are addressed. Keywords: advanced oxidation processes; emerging contaminants; low-dimensional nanomaterials; pharmaceutical by-products; Schottky junction; Review Introduction Worldwide, water pollution is rising, endangering the economic potential and development objectives of severely

• precipitation, in particular, are believed to be ineffective [4][11]. As a result of the non-biodegradable and persistent nature of the majority of organic contaminants, some physicochemical treatment techniques, such as adsorption, are ineffective in removing them from water resources [11]. Because of their

• pair (e− and h+) on the surface of the photocatalyst. Three possibilities exist at this point: (a) The generated charge carriers recombine and generate heat, (b) the generated interfacial charge carriers simultaneously reduce and oxidise contaminants, or (c) the generated charge carrier and an electron

Atmospheric water harvesting using functionalized carbon nanocones

• Fernanda R. Leivas and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2023, 14, 1–10, doi:10.3762/bjnano.14.1

• super flow in nanostructures has been explored in processes of separating water from salt or from other contaminants. This high mobility of water under nanoconfinement requires huge pressure and, consequently, a lot of energy [27][28]. In order to help water entrance and decrease the amount of required

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• solar radiation as an energy source [11]. The photocatalysts are activated by radiation and produce highly reactive photo-induced charge carriers, which can react with the contaminants adsorbed on the surface of the catalyst. Understanding the properties of the photocatalyst material is critical to

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• energies. Many persistent organic contaminants can be degraded at room temperature through the oxidizing power of VB holes in bismuth oxyhalides [26]. BiOCl, BOI, BiOBr, and composites made from them have been widely reported due to their excellent photocatalytic properties [27][28][29]. However, the

• degradation, the most notable oxidizing species are •OH, photogenerated holes, and •O2−. These species are responsible for the photodegradation of organic and inorganic contaminants in wastewater [40]. To date, it is widely understood that the main limitation of photocatalysts is their low photocatalytic

• , environmental monitoring, disinfection, and sterilization are all areas where the photocatalytic breakdown of contaminants is used. Primary energy uses included photocatalytic hydrogen production from carbon dioxide, conversion of carbon dioxide to specific molecular organic matter, and nitrogen fixation [1

Influence of water contamination on the sputtering of silicon with low-energy argon ions investigated by molecular dynamics simulations

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2022, 13, 986–1003, doi:10.3762/bjnano.13.86

• ignored. Contaminants on the sample surface can also play a critical role during the milling process: water can be found on nearly every sample surface [21]. For example, in a vacuum chamber at a pressure of 10−8 mbar, there are still 106 to 109 molecules per cm3. This contaminant has a strong impact on

• . For the clean sample, the amorphization depth linearly evolves until the implanted argon atoms reach a saturation concentration due to the diffusion and desorption of excess atoms. In the contaminated sample, the observations are similar for argon and for the contaminants, and hydrogen is implanted

• normal. In the amorphous region, contaminants and argon atoms reach a saturation concentration. Once the argon saturation is reached, the thickness of the amorphous layer reaches a maximum, which is defined by the range of the argon atoms. At the same time, material is removed by sputtering from the

Solar-light-driven LaFe_xNi_1−xO₃ perovskite oxides for photocatalytic Fenton-like reaction to degrade organic pollutants

• Chao-Wei Huang,
• Shu-Yu Hsu,
• Jun-Han Lin,
• Yun Jhou,
• Wei-Yu Chen,
• Kun-Yi Andrew Lin,
• Yu-Tang Lin and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 882–895, doi:10.3762/bjnano.13.79

• ]. LaFeO3 perovskite oxides are promising materials to conduct Fenton-like oxidation to decompose organic pollutants with light irradiation. Some literature exhibits the capability of LaFeO3 perovskite oxides as photocatalysts to degrade organic contaminants. Li et al. prepared intrinsic LaFeO3 or SmFeO3

Direct measurement of surface photovoltage by AC bias Kelvin probe force microscopy

• Masato Miyazaki,
• Yasuhiro Sugawara and
• Yan Jun Li

Beilstein J. Nanotechnol. 2022, 13, 712–720, doi:10.3762/bjnano.13.63

• . The tip was cleaned by Ar+ sputtering (0.8 keV, 5 × 10−7 Torr, 5 min) to remove the contaminants and the native oxide layer. We used a rutile TiO2(110) sample to demonstrate the AC-KPFM. TiO2 is one of the promising photocatalytic materials [38][39][40] and has been widely studied using AFM and KPFM

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

• , valleytronics, and nonlinear optics [2][3][4][5][6][7][8]. Many interesting phenomena can be observed, mainly due to the presence of structural irregularities such as point defects, edges, boundaries, and the formation of contaminants in the process of 2D-TMDC growth [9][10][11][12][13]. These structural

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• catalytic area, SnO2 is an emerging material for removing contaminants such as organic dyes, phenolic compounds, and volatile organic compounds (VOCs) due to strongly oxidizing properties thanks to flexible energy band structure, rich defects, good chemical, and high thermal stability, and easily controlled

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• presence of undesired contaminants, such as fragments of biological materials, which require complicated, expensive, and time-consuming purification procedures. Bio-assisted methods can be divided into three categories according to the system used: (i) microorganisms, (ii) biomolecules, and (iii) plant

The role of convolutional neural networks in scanning probe microscopy: a review

• Ido Azuri,
• Irit Rosenhek-Goldian,
• Neta Regev-Rudzki,
• Georg Fantner and
• Sidney R. Cohen

Beilstein J. Nanotechnol. 2021, 12, 878–901, doi:10.3762/bjnano.12.66

Impact of GaAs(100) surface preparation on EQE of AZO/Al₂O₃/p-GaAs photovoltaic structures

• Piotr Caban,
• Rafał Pietruszka,
• Jarosław Kaszewski,
• Monika Ożga,
• Bartłomiej S. Witkowski,
• Krzysztof Kopalko,
• Piotr Kuźmiuk,
• Katarzyna Gwóźdź,
• Ewa Płaczek-Popko,
• Krystyna Lawniczak-Jablonska and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 578–592, doi:10.3762/bjnano.12.48

• ][18][19]. Many protocols for etching solutions are known. Depending on the requirements (e.g., etched compound – oxide or semiconductor, etching profiles, etching rate, ability to remove contaminants – heavy metals, and crystallographic orientation of the substrate) one can use a suitable solution [20

The patterning toolbox FIB-o-mat: Exploiting the full potential of focused helium ions for nanofabrication

• Victor Deinhart,
• Lisa-Marie Kern,
• Jan N. Kirchhof,
• Sabrina Juergensen,
• Joris Sturm,
• Enno Krauss,
• Thorsten Feichtner,
• Sviatoslav Kovalchuk,
• Michael Schneider,
• Dieter Engel,
• Bastian Pfau,
• Bert Hecht,
• Kirill I. Bolotin,
• Stephanie Reich and
• Katja Höflich

Beilstein J. Nanotechnol. 2021, 12, 304–318, doi:10.3762/bjnano.12.25

• -step process without the need of potential contaminants, such as the resists used in lithographic approaches. For conventional gallium (Ga) ion beams the achievable minimum feature sizes are still limited to approx. 10 nm [2], and Ga implantation may cause unwanted modification of material properties

• local ion–solid interaction is a balance among several ion-induced, surface-related, and thermally triggered processes [24]. Physical sputtering is only one of the processes. Also, chemical reactions with adsorbed contaminants can occur and, under certain circumstances, may dominate over the atomic

• knock-out. Typically, ion beam machining is carried out under high-vacuum conditions, where the amount of contaminants in the chamber (mostly water, but also hydrocarbons) still can form a monolayer per second on average. Often, additional contaminants may be present on the sample surface, for example

Imaging of SARS-CoV-2 infected Vero E6 cells by helium ion microscopy

• Natalie Frese,
• Patrick Schmerer,
• Martin Wortmann,
• Matthias Schürmann,
• Matthias König,
• Michael Westphal,
• Friedemann Weber,
• Holger Sudhoff and
• Armin Gölzhäuser

Beilstein J. Nanotechnol. 2021, 12, 172–179, doi:10.3762/bjnano.12.13

• optimized for each magnification level. All HIM images were recorded with 1024 × 1024 pixels. Before imaging, each sample was stored in the vacuum chamber of the microscope at 3.3 × 10−7 mbar for at least 24 h to remove most volatile organic contaminants. Results and Discussion A comparison between a native

Thermophoretic tweezers for single nanoparticle manipulation

• Jošt Stergar and
• Natan Osterman

Beilstein J. Nanotechnol. 2020, 11, 1126–1133, doi:10.3762/bjnano.11.97

• slide) coated on the sample side with a 300 nm chromium layer by vertical deposition, a 5 μm thick experimental chamber is created (Figure 1a). All glass surfaces were thoroughly cleaned before use and treated with plasma to remove any unwanted surface contaminants. All surfaces were additionally coated

Adsorptive removal of bulky dye molecules from water with mesoporous polyaniline-derived carbon

• Hyung Jun An,
• Jong Min Park,
• Nazmul Abedin Khan and
• Sung Hwa Jhung

Beilstein J. Nanotechnol. 2020, 11, 597–605, doi:10.3762/bjnano.11.47

• removal of contaminants of emerging concern, hazardous organics and persistent organic pollutants. Carbonaceous materials have been particularly attractive in the purification of contaminated water via adsorption because of the easy preparation of carbon materials [26], especially from waste materials [28

Synthesis and enhanced photocatalytic performance of 0D/2D CuO/tourmaline composite photocatalysts

• Changqiang Yu,
• Min Wen,
• Zhen Tong,
• Shuhua Li,
• Yanhong Yin,
• Xianbin Liu,
• Yesheng Li,
• Tongxiang Liang,
• Ziping Wu and
• Dionysios D. Dionysiou

Beilstein J. Nanotechnol. 2020, 11, 407–416, doi:10.3762/bjnano.11.31

• of Chemical and Environmental Engineering, University of Cincinnati, Cincinnati, OH 45221, USA Chongyi Zhangyuan Tungsten Co., Ltd., Ganzhou 341000, China 10.3762/bjnano.11.31 Abstract Photocatalysis is considered to be a green and promising technology for transforming organic contaminants into

• tourmaline-based functional composite photocatalysts for the treatment of organic contaminants in water. Keywords: 0D/2D CuO; organic contaminants; photocatalytic activity; photoinduced charge separation; tourmaline; Introduction Developing a novel semiconductor with excellent photoreactive activity toward

• the treatment of organic contaminants in wastewater is in urgent need owing to the deterioration of the ecological environment [1]. Metal oxides, such as ZnO [2], TiO2 [3], Fe2O3 [4], and CuO [5], have been demonstrated to be promising photocatalysts. In particular, the band gap energy (Eg) of the p

Implementation of data-cube pump–probe KPFM on organic solar cells

• Benjamin Grévin,
• Olivier Bardagot and
• Renaud Demadrille

Beilstein J. Nanotechnol. 2020, 11, 323–337, doi:10.3762/bjnano.11.24

• ) driven by a Matrix SPM control unit. Pt/Ir-coated silicon cantilevers (EFM, Nanosensors, resonance frequency in the 45–115 kHz range) were annealed in situ to remove atmospheric contaminants. Topographic imaging was realized in FM mode (FM-AFM) with negative frequency shifts of a few Hz and vibrational

Facile biogenic fabrication of hydroxyapatite nanorods using cuttlefish bone and their bactericidal and biocompatibility study

• Satheeshkumar Balu,
• Manisha Vidyavathy Sundaradoss,
• Swetha Andra and
• Jaison Jeevanandam

Beilstein J. Nanotechnol. 2020, 11, 285–295, doi:10.3762/bjnano.11.21

• washed with distilled water, followed by acetone and ethanol to remove surface contaminants. The washed bones were dried in a hot air oven (Indfurr model OR-3795) at 60 °C for 24 h and 20 g of cuttlefish bone pieces were taken for top down processing using high-energy ball milling (VB Ceramic Consultants

Kelvin probe force microscopy of the nanoscale electrical surface potential barrier of metal/semiconductor interfaces in ambient atmosphere

• Petr Knotek,
• Tomáš Plecháček,
• Jan Smolík,
• Petr Kutálek,
• Filip Dvořák,
• Milan Vlček,
• Jiří Navrátil and
• Čestmír Drašar

Beilstein J. Nanotechnol. 2019, 10, 1401–1411, doi:10.3762/bjnano.10.138

• beam source in order to remove surface contaminants. A monoatomic argon ion source was utilized with energy of 2 keV, ion current 10 µA, raster area 1 × 1 mm2 and sputtering time 30 s. Results and Discussion Separated metal nanoparticles on the substrate In TE materials the NIs applicable for an

Construction of a 0D/1D composite based on Au nanoparticles/CuBi₂O₄ microrods for efficient visible-light-driven photocatalytic activity

• Weilong Shi,
• Mingyang Li,
• Hongji Ren,
• Feng Guo,
• Xiliu Huang,
• Yu Shi and
• Yubin Tang

Beilstein J. Nanotechnol. 2019, 10, 1360–1367, doi:10.3762/bjnano.10.134

• degradation of organic contaminants in water [13][14]. However, bare CuBi2O4 shows poor photocatalytic performance under visible-light irradiation because of the rapid recombination rate of photo-induced charge carriers and the low chemical affinity to substrate ions. This results in only a small portion of

Nanoscale spatial mapping of mechanical properties through dynamic atomic force microscopy

• Zahra Abooalizadeh,
• Leszek Josef Sudak and
• Philip Egberts

Beilstein J. Nanotechnol. 2019, 10, 1332–1347, doi:10.3762/bjnano.10.132

• contaminants on the surface when measuring the mechanical properties of atomic-sized defects [15][16][17]. Furthermore, the high quality factor of the AFM cantilever that is achieved under UHV conditions can be very beneficial in dynamic AFM modes, as the Q-factor is inversely proportional to the force

• step edge resulting from the Schwoebel barrier [45][46] in the absence of contaminants with a rounded AFM tip as detected in the lateral forces acquired simultaneously [15]. More specifically, the elastic displacement of the step edge by the modulating normal force did not show any enhanced contrast in

Imaging the surface potential at the steps on the rutile TiO₂(110) surface by Kelvin probe force microscopy

• Masato Miyazaki,
• Huan Fei Wen,
• Quanzhen Zhang,
• Yuuki Adachi,
• Jan Brndiar,
• Ivan Štich,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2019, 10, 1228–1236, doi:10.3762/bjnano.10.122

• (1 keV, 6.7 × 10−7 mbar, 5 min) and annealing (600 K, less than 2.7 × 10−10 mbar, 20 min) to remove the native oxide layer and other contaminants. A clean rutile TiO2(110) crystal (provided by Furuuchi Chemical Corporation) was prepared by dozens of cycles of Ar+ sputtering (1 keV, 1.3 × 10−6 mbar