Alloyed Pt₃M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction

• Stéphane Louisia,
• Yohann R. J. Thomas,
• Pierre Lecante,
• Marie Heitzmann,
• M. Rosa Axet,
• Pierre-André Jacques and
• Philippe Serp

Beilstein J. Nanotechnol. 2019, 10, 1251–1269, doi:10.3762/bjnano.10.125

• issue for a PEMFC catalyst. A well-known phenomenon of catalyst degradation is due to the formation of hydrogen peroxide near the electrolyte membrane [78]. Moreover, it was shown that in aqueous KNO3 solutions, nitrogen-doped carbon structures were active for ORR with lower H2O2 selectivity than Pt/C

• [79]. During the CV measurements in O2-saturated electrolyte, the amount of hydrogen peroxide produced during the ORR was monitored to compare its production for each catalyst. Figure 5 presents the hydrogen peroxide yield during the ORR for all the catalysts shown before. First, between 1 and 0.7 V

Photoactive nanoarchitectures based on clays incorporating TiO₂ and ZnO nanoparticles

• Eduardo Ruiz-Hitzky,
• Pilar Aranda,
• Marwa Akkari,
• Nithima Khaorapapong and
• Makoto Ogawa

Beilstein J. Nanotechnol. 2019, 10, 1140–1156, doi:10.3762/bjnano.10.114

• , industrial and agricultural wastewater. They are based on the in situ generation of reactive species as hydroxyl radicals (OH•) with high oxidizing capability [24]. AOP include Fenton and photo-Fenton reactions based on the combination of chemical oxidants, e.g., hydrogen peroxide, and UV irradiation, and

Glucose-derived carbon materials with tailored properties as electrocatalysts for the oxygen reduction reaction

• Rafael Gomes Morais,
• Natalia Rey-Raap,
• José Luís Figueiredo and
• Manuel Fernando Ribeiro Pereira

Beilstein J. Nanotechnol. 2019, 10, 1089–1102, doi:10.3762/bjnano.10.109

• potentials (0.75–0.78 V and 0.30–0.33 V), indicating that the ORR mechanism proceeds via the two-electron pathway. These results are corroborated by the experiments performed with a rotating ring disk electrode, from which the production of hydrogen peroxide was evaluated. More than 18% of hydrogen peroxide

• positive onset potential of sample AGBM is due to its higher conductance. Moreover, samples AG and AGBM exhibit a second shoulder at more negative potentials, indicating that the ORR mechanism proceeds via the two-electron pathway producing hydrogen peroxide. This second reduction shoulder does not appear

• for ORR. The approximation to a four-electron pathway with the modification of the surface chemistry is important to reduce the amount of hydrogen peroxide produced. The production of H2O2 was only determined for activated samples, since they have a mechanism closer to four-electron, whereas

Scavenging of reactive oxygen species by phenolic compound-modified maghemite nanoparticles

• Małgorzata Świętek,
• Yi-Chin Lu,
• Rafał Konefał,
• Liliana P. Ferreira,
• M. Margarida Cruz,
• Yunn-Hwa Ma and
• Daniel Horák

Beilstein J. Nanotechnol. 2019, 10, 1073–1088, doi:10.3762/bjnano.10.108

• ROS levels and protect themselves from the deleterious impact of uncontrolled ROS activity. The enzymatic antioxidant defense involves catalase, superoxide dismutase, and glutathione peroxidase, which convert harmful oxidative products first to hydrogen peroxide and then to water. These processes are

• functional groups. In this study, magnetite (Fe3O4) nanoparticles were synthetized by coprecipitation of iron(II) chloride and iron(III) chloride with ammonia and subsequently oxidized with hydrogen peroxide under mild acidic conditions. The resulting maghemite (γ-Fe2O3) has the benefit of higher chemical

• levels after treatment with hydrogen peroxide. The density plot in the left panel shows the relationship between cellular volume and complexity. The R1 region in the density plot indicated cell population, whereas the left population outside the R1 region was related to the nanoparticles loosely bound on

Revisiting semicontinuous silver films as surface-enhanced Raman spectroscopy substrates

• Malwina Liszewska,
• Bogusław Budner,
• Małgorzata Norek,
• Bartłomiej J. Jankiewicz and
• Piotr Nyga

Beilstein J. Nanotechnol. 2019, 10, 1048–1055, doi:10.3762/bjnano.10.105

• sulfuric acid (97%; Fluka), hydrogen peroxide (30%; Chempur), ethanol (96%; Chempur) and deionized water. SERS analyte 4-aminothiophenol (97%) was purchased from Sigma-Aldrich. Fabrication of semicontinuous silver films SSFs were fabricated on BK7 glass substrates using the electron beam PVD technique. The

The systemic effect of PEG-nGO-induced oxidative stress in vivo in a rodent model

• Qura Tul Ain,
• Samina Hyder Haq,
• Abeer Alshammari,
• Moudhi Abdullah Al-Mutlaq and
• Muhammad Naeem Anjum

Beilstein J. Nanotechnol. 2019, 10, 901–911, doi:10.3762/bjnano.10.91

• scavenging enzyme that converts hydrogen peroxide (H2O2) into water and oxygen, thus preventing cell damage. A reduction of the acitivity of CAT after PEG-nGO administration was observed as shown in Table 2. One hour after PEG-nGO administration, the decrease in CAT enzyme activity was significant (P* < 0.05

• kinds of SOD exist in all organs of mammals. SOD1, SOD2, and SOD3 are present in the cytoplasm, mitochondria, and extracellular, respectively. SOD converts the superoxide (O2−) produced due to the xenobiotic into oxygen and hydrogen peroxide. The amount of SOD present in the brain, heart, liver, and

• graphite powder, potassium permanganate, phosphoric acid (85%), sulfuric acid (98%), and hydrogen peroxide (30%). Polyethylene glycol (PEG) was used for PEGylation. Thiobarbituric acid (TBA, 0.6%), and trichloroacetic acid (TCA, 20%) were used to estimate the malondialdehyde (MDA) level, sodium phosphate

Thermal control of the defunctionalization of supported Au₂₅(glutathione)₁₈ catalysts for benzyl alcohol oxidation

• Zahraa Shahin,
• Hyewon Ji,
• Rodica Chiriac,
• Nadine Essayem,
• Franck Rataboul and
• Aude Demessence

Beilstein J. Nanotechnol. 2019, 10, 228–237, doi:10.3762/bjnano.10.21

• ], direct synthesis of hydrogen peroxide by the hydrogenation of O2 [3], ozone decomposition [4], selective oxidation reactions [5][6][7][8] and so on. However, a debate regarding the particle size effect on the catalytic activity and the concerns related to the synthesis and stabilization of monodisperse

In situ characterization of nanoscale contaminations adsorbed in air using atomic force microscopy

• Jesús S. Lacasa,
• Lisa Almonte and
• Jaime Colchero

Beilstein J. Nanotechnol. 2018, 9, 2925–2935, doi:10.3762/bjnano.9.271

• , Standard Clean-1 is performed with a solution composed of 5:1:1 parts by volume of Milli-Q water, NH4OH (ammonium hydroxide, 29%) and H2O2 (hydrogen peroxide, 30%). When utilized as sample, the chips with the cantilevers are sonicated for about 1 min in this solution, which removes organic residues. When

• used as cantilevers, the cantilever chips are immersed in the corresponding solution. Before the next step the samples are rinsed with Milli-Q water. The second step (Standard Clean-2) is performed with a solution composed of 5:1:1 parts by volume of Milli-Q water, H2O2 (hydrogen peroxide, 30%), and

The role of adatoms in chloride-activated colloidal silver nanoparticles for surface-enhanced Raman scattering enhancement

• Nicolae Leopold,
• Andrei Stefancu,
• Krisztian Herman,
• István Sz. Tódor,
• Stefania D. Iancu,
• Vlad Moisoiu and
• Loredana F. Leopold

Beilstein J. Nanotechnol. 2018, 9, 2236–2247, doi:10.3762/bjnano.9.208

• in the solution. Also, at this time, gaseous reaction products were observed, probably due to the O2 released during the decomposition of hydrogen peroxide. No further color changes could be visually observed after 5 min of light exposure, but the reaction mixture was further exposed to light for a

• reaction does not proceed in the absence of an intense light source, regardless of the amount of hydrogen peroxide added in the reaction mixture. It should be mentioned that the formation of stable, SERS-active Cl-AgNP colloids can also be obtained in the absence of hydrogen peroxide, but in this case, the

• complete synthesis of the silver colloids takes several hours. The UV–vis absorption monitoring of the Cl-AgNP synthesis obtained in the absence of hydrogen peroxide is presented in Supporting Information File 1, Figure S2A, whereas the SERS activity of the Cl-AgNPs tested after different times of light

Metal-free catalysis based on nitrogen-doped carbon nanomaterials: a photoelectron spectroscopy point of view

• Mattia Scardamaglia and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2018, 9, 2015–2031, doi:10.3762/bjnano.9.191

• pathway that involves the formation of hydrogen peroxide ions as intermediate [19]. The nitrogen-doped (NCNTs) and the commercial Pt–C electrodes exhibit a one-step process for the ORR with a half-wave potential of −0.1 V associated to a more efficient four-electron pathway that directly produces water as

Heterostuctures of 4-(chloromethyl)phenyltrichlorosilane and 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine prepared on Si(111) using particle lithography: Nanoscale characterization of the main steps of nanopatterning

• Phillip C. Chambers and
• Jayne C. Garno

Beilstein J. Nanotechnol. 2018, 9, 1211–1219, doi:10.3762/bjnano.9.112

• ) were rinsed with water and cleaned in piranha solution (3:1 sulfuric acid to hydrogen peroxide) for 1.5 h to remove surface contaminants. Caution: this solution is highly corrosive and should be handled carefully. The substrates were then rinsed with ultrapure water and dried under nitrogen. After

Electrodeposition of reduced graphene oxide with chitosan based on the coordination deposition method

• Mingyang Liu,
• Yanjun Chen,
• Chaoran Qin,
• Zheng Zhang,
• Shuai Ma,
• Xiuru Cai,
• Xueqian Li and
• Yifeng Wang

Beilstein J. Nanotechnol. 2018, 9, 1200–1210, doi:10.3762/bjnano.9.111

• degree), concentrated sulfuric acid, hydrochloric acid, sodium nitrate, potassium permanganate, hydrogen peroxide, hydrazine hydrate, acetic acid, sodium hydrate, and 1-naphthol were purchased from Sinopharm Chemical Reagent Co., Ltd., China. 2-Hydroxypropyltrimethylammonium chloride chitosan was

A simple extension of the commonly used fitting equation for oscillatory structural forces in case of silica nanoparticle suspensions

• Sebastian Schön and
• Regine von Klitzing

Beilstein J. Nanotechnol. 2018, 9, 1095–1107, doi:10.3762/bjnano.9.101

• ± 2 nm [34]. Silicon wafers (Wacker Chemie) were used as substrates. Preparation The silicon wafers were cleaned prior to each experiment by etching in a 1:1:5 solution of hydrogen peroxide (30% Th. Geyer GmbH & Co KG), ammonium hydroxide (30–33% Carl Roth GmbH & Co KG) and water at 60 °C for 10 min

Noble metal-modified titania with visible-light activity for the decomposition of microorganisms

• Maya Endo,
• Zhishun Wei,
• Kunlei Wang,
• Baris Karabiyik,
• Kenta Yoshiiri,
• Paulina Rokicka,
• Bunsho Ohtani,
• Agata Markowska-Szczupak and
• Ewa Kowalska

Beilstein J. Nanotechnol. 2018, 9, 829–841, doi:10.3762/bjnano.9.77

• burn wounds (bandage and dressing), and protection against infection (braces and catheters). Photocatalysis is considered as one of the best methods for environmental purification since additional chemical compounds, such as strong oxidants (ozone, hydrogen peroxide or chlorine) [7][8][9][10][11][12

Mechanistic insights into plasmonic photocatalysts in utilizing visible light

• Kah Hon Leong,
• Azrina Abd Aziz,
• Lan Ching Sim,
• Pichiah Saravanan,
• Min Jang and
• Detlef Bahnemann

Beilstein J. Nanotechnol. 2018, 9, 628–648, doi:10.3762/bjnano.9.59

• ), superoxide anion radical (•O2−), singlet oxygen (1O2) and hydrogen peroxide (H2O2). Since the redox reaction takes place during the photocatalysis reaction, ROSs are produced sequentially both from O2 and H2O as illustrated in Figure 11 [113][114][115]. In general ROSs of •OH, H2O2, •O2− and 1O2 would be

Anchoring Fe₃O₄ nanoparticles in a reduced graphene oxide aerogel matrix via polydopamine coating

• Błażej Scheibe,
• Radosław Mrówczyński,
• Natalia Michalak,
• Karol Załęski,
• Michał Matczak,
• Mateusz Kempiński,
• Zuzanna Pietralik,
• Mikołaj Lewandowski,
• Stefan Jurga and
• Feliks Stobiecki

Beilstein J. Nanotechnol. 2018, 9, 591–601, doi:10.3762/bjnano.9.55

• ≥99.5%, dopamine hydrochloride and ethylenediamine were obtained from Sigma-Aldrich. Hydrochloric acid 35–38%, sulfuric acid 95%, ethanol 99.8%, ethanol 96% and hydrogen peroxide solution 30% were purchased from POCH. Ammonia solution 25% and potassium permanganate were obtained from Chempur and J.T

Ultralight super-hydrophobic carbon aerogels based on cellulose nanofibers/poly(vinyl alcohol)/graphene oxide (CNFs/PVA/GO) for highly effective oil–water separation

• Zhaoyang Xu,
• Huan Zhou,
• Sicong Tan,
• Xiangdong Jiang,
• Weibing Wu,
• Jiangtao Shi and
• Peng Chen

Beilstein J. Nanotechnol. 2018, 9, 508–519, doi:10.3762/bjnano.9.49

• Zhejiang Lishui, China. Graphite powder (40 μm), used as the source for GO, was obtained from Qingdao Henglide Graphite Co., Ltd. Poly(vinyl alcohol) (PVA, Mw ≈ 95,000 g/mol), glutaraldehyde (GA, crosslinker, 25 wt % in H2O), potassium hydroxide (KOH), Sudan III, acetic acid (CH3COOH), hydrogen peroxide

Blister formation during graphite surface oxidation by Hummers’ method

• Olga V. Sinitsyna,
• Georgy B. Meshkov,
• Anastasija V. Grigorieva,
• Alexander A. Antonov,
• Inna G. Grigorieva and
• Igor V. Yaminsky

Beilstein J. Nanotechnol. 2018, 9, 407–414, doi:10.3762/bjnano.9.40

• and hydrogen peroxide solution, the surface became gray and matte, which indicated a significant change in the surface roughness. Raman spectroscopy of the HAPG surface before and after the treatment Raman spectra, recorded from the ordered regions on the HAPG surface before and after the treatment

• the mixture was applied to the basal-plane surface of the HAPG. After 30 minutes, the samples were washed in a stream of milli-Q water (total volume of about 1 mL), in 3% hydrogen peroxide until the discoloration of the surface, and again in water. The samples were dried in air within a day. An

Photocatalytic and adsorption properties of TiO₂-pillared montmorillonite obtained by hydrothermally activated intercalation of titanium polyhydroxo complexes

• Mikhail F. Butman,
• Nikolay L. Ovchinnikov,
• Nikita S. Karasev,
• Nataliya E. Kochkina,
• Alexander V. Agafonov and
• Alexandr V. Vinogradov

Beilstein J. Nanotechnol. 2018, 9, 364–378, doi:10.3762/bjnano.9.36

• temperature of 60 °C. The intercalated samples are designated as Ti-MM. The effectiveness of intercalation was monitored photometrically (spectrophotometer UV-VisU-2001, Hitachi, Japan), with photometric technique based on the formation of a complex titanium(IV) compound with hydrogen peroxide, yellow in

CdSe nanorod/TiO₂ nanoparticle heterojunctions with enhanced solar- and visible-light photocatalytic activity

• Fakher Laatar,
• Hatem Moussa,
• Halima Alem,
• Lavinia Balan,
• Emilien Girot,
• Ghouti Medjahdi,
• Hatem Ezzaouia and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2017, 8, 2741–2752, doi:10.3762/bjnano.8.273

• accumulated in TiO2 can be trapped by dissolved oxygen molecules and generate superoxide O2•− radicals which are strong oxidants able to decompose organic substances. These O2•− radicals may also react with an electron and protons to form hydrogen peroxide which is further decomposed into hydroxyl •OH

Strategy to discover full-length amyloid-beta peptide ligands using high-efficiency microarray technology

• Clelia Galati,
• Natalia Spinella,
• Lucio Renna,
• Danilo Milardi,
• Francesco Attanasio,
• Michele Francesco Maria Sciacca and
• Corrado Bongiorno

Beilstein J. Nanotechnol. 2017, 8, 2446–2453, doi:10.3762/bjnano.8.243

• our laboratory. Experimental Chemicals Phosphate-buffered saline, hydrogen peroxide (29%), ammonium hydroxide (25%), hydrochloric acid (37%), methanol, dimethyl sulfoxide (DMSO), anhydrous toluene and 3-glycidyloxypropyltrimethoxysilane (GOPs) were acquired from Sigma-Aldrich. Bovine serum albumin

Increasing the stability of DNA nanostructure templates by atomic layer deposition of Al₂O₃ and its application in imprinting lithography

• Hyojeong Kim,
• Kristin Arbutina,
• Anqin Xu and
• Haitao Liu

Beilstein J. Nanotechnol. 2017, 8, 2363–2375, doi:10.3762/bjnano.8.236

• , USA). 2-Amino-2-(hydroxymethyl)-1,3-propanediol (Tris), ethylenediaminetetraacetic acid (EDTA), magnesium acetate tetrahydrate, sulfuric acid, hydrogen peroxide solution (30% H2O2), and poly(L-lactide) were purchased from Sigma-Aldrich (St. Louis, MO, USA). Acetic acid (glacial), dichloromethane, and

Photobleaching of YOYO-1 in super-resolution single DNA fluorescence imaging

• Joseph R. Pyle and
• Jixin Chen

Beilstein J. Nanotechnol. 2017, 8, 2296–2306, doi:10.3762/bjnano.8.229

• resistivity of 18 MΩ cm−1. Glass coverslips were first cleaned by sonication in 1% detergent (Liquinox) followed by rinsing with 18 MΩ water. Then the coverslips were immersed in 1:1:5 (v/v/v) of ammonium hydroxide/hydrogen peroxide/water for 15 min at 60 °C. Afterwards they were rinsed with water and dried

Enhanced catalytic activity without the use of an external light source using microwave-synthesized CuO nanopetals

• Govinda Lakhotiya,
• Sonal Bajaj,
• Arpan Kumar Nayak,
• Debabrata Pradhan,
• Pradip Tekade and
• Abhimanyu Rana

Beilstein J. Nanotechnol. 2017, 8, 1167–1173, doi:10.3762/bjnano.8.118

• found to be less effective as compared to other metal oxides [8][9][10][11][12]. Thus, in order to enhance its photocatalytic activity, CuO can be used with hydrogen peroxide (H2O2) [12][13][14][15][16][17][18][19][20][21]. However, the degradation time of dyes is an important problem when using CuO as

• /visible). A corresponding mechanism for the fast degradation observes was also proposed. Experimental Materials and instrumentation Commercial, high-grade copper sulphate (CuSO4·5H2O, 99.95%), sodium hydroxide (NaOH), ethanol (C2H5OH), acetone (C3H6O), methylene blue (MB), hydrogen peroxide (H2O2, 30

ZnO nanoparticles sensitized by CuInZn_xS_2+x quantum dots as highly efficient solar light driven photocatalysts

• Florian Donat,
• Serge Corbel,
• Halima Alem,
• Steve Pontvianne,
• Lavinia Balan,
• Ghouti Medjahdi and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2017, 8, 1080–1093, doi:10.3762/bjnano.8.110

• solution. A mechanism for the degradation pathways mediated by the ZnO/ZCIS catalyst is proposed. Interestingly, hydrogen peroxide, H2O2, and singlet molecular oxygen, 1O2, were found to play a key role in the oxidation of Orange II. Experimental Materials Indium acetate (In(OAc)3, 99.99%, Sigma), zinc

• singlet oxygen and hydrogen peroxide play a key role in the degradation of the dye. The improved solar light photocatalytic activity of the ZnO/ZCIS composite is achieved by the increased lifetime of charge carrier transfer and by the increased light absorption in the visible region due to the

• of the ZnO/ZCIS photocatalyst. Concentration of (a) hydroxyl and (b) superoxide radicals and (c) hydrogen peroxide produced by ZnO and ZnO/ZCIS particles under irradiation using a Hg–Xe lamp. Concentrations of hydroxyl and superoxide radicals and hydrogen peroxide were determined after 30 min, 1 h