Charged particle single nanometre manufacturing

• Philip D. Prewett,
• Cornelis W. Hagen,
• Claudia Lenk,
• Steve Lenk,
• Marcus Kaestner,
• Tzvetan Ivanov,
• Ahmad Ahmad,
• Ivo W. Rangelow,
• Xiaoqing Shi,
• Stuart A. Boden,
• Alex P. G. Robinson,
• Dongxu Yang,
• Sangeetha Hari,
• Marijke Scotuzzi and
• Ejaz Huq

Beilstein J. Nanotechnol. 2018, 9, 2855–2882, doi:10.3762/bjnano.9.266

• fabrication of isolated structures, for example by Koops et al. [79], and by Frabboni et al. [80] who attempted to overcome the resolution limit due to the presence of a bulk or thin substrate by growing suspended nanowires by EBID on the tip of a tilted pillar, achieving a lateral resolution of 5 nm. Sub-10

• common in electrical measurements. Another important application of EBIE demonstrated there was the modification of as-deposited EBID structures to alter their physical or chemical properties. Carbonaceous nanowires of about 24 nm width deposited by EBID were slimmed by repeatedly scanning the field of

• view containing the deposits in the presence of water. In this manner, nanowires with widths down to 13 nm were achieved, as shown in Figure 12. The specific case of EBIE of SiO2 using XeF2 was studied by Randolph et al. [95] who performed experiments to study the etch rate as a function of beam

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• components is equal, which accounts for the improved sensing performance to CO at room temperature. Wang et al. [52] mixed ZnO nanowires, prepared via carbothermal reduction, with GO under a protective gas atmosphere (Ar) at 300 °C to synthesize ZnO–rGO hybrids. Although the response to NH3 was not as well

Controlling surface morphology and sensitivity of granular and porous silver films for surface-enhanced Raman scattering, SERS

• Sherif Okeil and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2018, 9, 2813–2831, doi:10.3762/bjnano.9.263

• ][55][56], and nanotransfer printing, which was used to build stacks of gold nanorods or nanowires [4]. The production of nanoporous metal films or particles through a dealloying process also emerged as an effective tool for the facile formation of a large number of SERS-active hot spots [57][58][59

Oriented zinc oxide nanorods: A novel saturable absorber for lasers in the near-infrared

• Pavel Loiko,
• Tanujjal Bora,
• Josep Maria Serres,
• Haohai Yu,
• Magdalena Aguiló,
• Francesc Díaz,
• Uwe Griebner,
• Valentin Petrov,
• Xavier Mateos and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2018, 9, 2730–2740, doi:10.3762/bjnano.9.255

• , a lot of attention has been paid to the studies of ZnO nanostructures of various shapes, including oriented nanorods (NRs), nanowires, nanobelts, nanoparticles, etc. for versatile photonic applications [1][2]. ZnO NRs are especially attractive for short-wavelength nano-devices due to their high

Silencing the second harmonic generation from plasmonic nanodimers: A comprehensive discussion

• Jérémy Butet,
• Gabriel D. Bernasconi and
• Olivier J. F. Martin

Beilstein J. Nanotechnol. 2018, 9, 2674–2683, doi:10.3762/bjnano.9.250

• nanowires with various gap sizes. They observed that the SHG does not increase as the gap between the two nanowires decreases, despite an increase of the fundamental field enhancement. Their experimental observations were supported by numerical results demonstrating that the SHG from nanogaps is not

Impact of the anodization time on the photocatalytic activity of TiO₂ nanotubes

• Jesús A. Díaz-Real,
• Geyla C. Dubed-Bandomo,
• Juan Galindo-de-la-Rosa,
• Luis G. Arriaga,
• Janet Ledesma-García and
• Nicolas Alonso-Vante

Beilstein J. Nanotechnol. 2018, 9, 2628–2643, doi:10.3762/bjnano.9.244

• synthesis methods resulting in a wide range of morphologies, such as mesoporous structures [4], microtubes [5], microdendrites, nanoparticles [6][7][8], nanorods [9][10], nanotubes [11][12][13], nanowires [14], and nanosheets [15][16]. Standing out from the rest of the synthesis techniques, electrochemical

Improved catalytic combustion of methane using CuO nanobelts with predominantly (001) surfaces

• Qingquan Kong,
• Yichun Yin,
• Bing Xue,
• Yonggang Jin,
• Wei Feng,
• Zhi-Gang Chen,
• Shi Su and
• Chenghua Sun

Beilstein J. Nanotechnol. 2018, 9, 2526–2532, doi:10.3762/bjnano.9.235

• with CuO nanobelts comprised of predominantly (001) surfaces has been performed and it is confirmed that the performance of such nanobelts is much higher than normal nanoparticles and nanowires. First principle calculations further clarified that two-coordinated oxygen plays a key role for methane

• shows high reactivity due to the high ratio of lowly coordinated oxygen – a feature that has been employed for gas sensing and Li-ion batteries [21]. Now we turn to the experimental validation, starting with the synthesis of CuO nanowires (NWs) and CuO nanobelts (NBs) comprised of predominantly (001

• are needed to improve the thermal stability of such nanostructures as they tend to aggregate after high temperature treatment. Experimental Synthesis of CuO nanowires and nanobelts For a typical sample, 1 g of Cu(NO3)2 was dissolved in 100 mL distilled water and 30 mL ammonia solution (NH3·H2O, 0.15

Thickness-dependent photoelectrochemical properties of a semitransparent Co₃O₄ photocathode

• Malkeshkumar Patel and
• Joondong Kim

Beilstein J. Nanotechnol. 2018, 9, 2432–2442, doi:10.3762/bjnano.9.228

• 4.5 mA·cm−2 with Ag nanowires [24]. Interestingly, a high photocurrent density of 29 mA·cm−2 can be achieved from Co3O4 under one-sun illumination (AM1.5G) suggesting a high (solar-to-hydrogen) efficiency of 35.8% [3]. Studies using Co3O4 as a catalyst have explored the oxygen evolution reaction (OER

Magnetism and magnetoresistance of single Ni–Cu alloy nanowires

• Andreea Costas,
• Camelia Florica,
• Elena Matei,
• Maria Eugenia Toimil-Molares,
• Ionel Stavarache,
• Andrei Kuncser,
• Victor Kuncser and
• Ionut Enculescu

Beilstein J. Nanotechnol. 2018, 9, 2345–2355, doi:10.3762/bjnano.9.219

• University of Bucharest, Faculty of Physics, PO Box MG-11, 077125, Magurele-Bucharest, Romania 10.3762/bjnano.9.219 Abstract Arrays of magnetic Ni–Cu alloy nanowires with different compositions were prepared by a template-replication technique using electrochemical deposition into polycarbonate nanoporous

• membranes. Photolithography was employed for obtaining interdigitated metallic electrode systems of Ti/Au onto SiO2/Si substrates and subsequent electron beam lithography was used for contacting single nanowires in order to investigate their galvano-magnetic properties. The results of the magnetoresistance

• measurements made on single Ni–Cu alloy nanowires of different compositions have been reported and discussed in detail. A direct methodology for transforming the magnetoresistance data into the corresponding magnetic hysteresis loops was proposed, opening new possibilities for an easy magnetic investigation of

Intrinsic ultrasmall nanoscale silicon turns n-/p-type with SiO₂/Si₃N₄-coating

• Dirk König,
• Daniel Hiller,
• Noël Wilck,
• Birger Berghoff,
• Merlin Müller,
• Sangeeta Thakur,
• Giovanni Di Santo,
• Luca Petaccia,
• Joachim Mayer,
• Sean Smith and
• Joachim Knoch

Beilstein J. Nanotechnol. 2018, 9, 2255–2264, doi:10.3762/bjnano.9.210

• of Si nanowires relevant to devices As we will show below, a Si-NWire with a combined SiO2-/Si3N4-coating can work as a highly scalable, high-performance and dopant-free metal-insulator-silicon (MIS) FET device. Using the same h-DFT methods as above, we computed the electronic properties of a Si233

Optimization of the optical coupling in nanowire-based integrated photonic platforms by FDTD simulation

• Nan Guan,
• Andrey Babichev,
• Martin Foldyna,
• Dmitry Denisov,
• François H. Julien and
• Maria Tchernycheva

Beilstein J. Nanotechnol. 2018, 9, 2248–2254, doi:10.3762/bjnano.9.209

• design reported in the literature with a coupling efficiency of only 8.7%, we propose an optimized photonic platform with efficiency reaching 65.5%. Keywords: FDTD modeling; nanowire LED; nitride nanowires; photonic integrated circuit; photonic platform; SiN/InGaN co-integration; visible light

• tunable bandgap [14] and reduced dislocation density [15][16], nitride nanowires (NWs) have become important materials for optical components in the visible to ultraviolet (UV) spectral range [17][18]. Despite their small size, single NW light emitting diodes (LEDs) can produce bright electroluminescence

Lead-free hybrid perovskites for photovoltaics

• Oleksandr Stroyuk

Beilstein J. Nanotechnol. 2018, 9, 2209–2235, doi:10.3762/bjnano.9.207

• from exposure to air/moisture was suggested via the growth of HP nanowires in the pores of anodized alumina membranes [122]. The effective blockage of the diffusion of water and oxygen molecules to the alumina-incorporated MASnI3 nanowires resulted in a three order of magnitude slower degradation of

• min ripening at 220 °C (Figure 7c) [133]. The Cs2SnI6 nanorods gradually transform into nanowires (Figure 7d) with the aspect ratio increasing from 3 to 28 after a 10 min reaction. At longer reaction times (30 min) nanowires transform into nanobelts (Figure 7e) that assemble into nanoplatelets with a

Interaction-induced zero-energy pinning and quantum dot formation in Majorana nanowires

• Samuel D. Escribano,
• Alfredo Levy Yeyati and
• Elsa Prada

Beilstein J. Nanotechnol. 2018, 9, 2171–2180, doi:10.3762/bjnano.9.203

• , Universidad Autónoma de Madrid, E-28049 Madrid, Spain 10.3762/bjnano.9.203 Abstract Majorana modes emerge in non-trivial topological phases at the edges of specific materials such as proximitized semiconducting nanowires under an external magnetic field. Ideally, they are non-local states that are charge

• -neutral superpositions of electrons and holes. However, in nanowires of realistic length their wave functions overlap and acquire a finite charge that makes them susceptible to interactions, specifically with the image charges that arise in the electrostatic environment. Considering a realistic three

• features are observed in recent experiments on the detection of Majoranas and could thus help to properly characterize them. Keywords: hybrid superconductor–semiconductor nanowires; interactions; Majorana bound states; quantum dots; Introduction Semiconducting nanowires with strong spin–orbit interaction

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• , and larger surface-to-volume ratio [34]. The large surface-area-to-volume ratio of nanofibers (NFs), hollow nanofibers (HNFs), nanotubes (NTs) and nanowires (NWs) with micro/mesoporous surfaces results in improved adsorption and better reaction kinetics of gas-sensitive materials. Nanofibers can be

Localized photodeposition of catalysts using nanophotonic resonances in silicon photocathodes

• Evgenia Kontoleta,
• Sven H. C. Askes,
• Lai-Hung Lai and
• Erik C. Garnett

Beilstein J. Nanotechnol. 2018, 9, 2097–2105, doi:10.3762/bjnano.9.198

• spots”. These areas can be used for localized extraction of the photogenerated charges, which in turn could drive chemical reactions for synthesis of catalytic materials. In this work, we use these nanophotonic hot spots in vertical silicon nanowires to locally deposit platinum nanoparticles in a photo

• -electrochemical system. The tapering angle of the silicon nanowires as well as the excitation wavelength are used to control the location of the hot spots together with the deposition sites of the platinum catalyst. A combination of finite difference time domain (FDTD) simulations with scanning electron

• appearance of localized “hot spots”. In particular, semiconducting nanostructures can sustain Mie-like leaky modes due to their high refractive index and the occurrence of multiple internal light reflections from the boundaries of the structure [9][13]. However, in vertical nanowires under normal-incidence

A scanning probe microscopy study of nanostructured TiO₂/poly(3-hexylthiophene) hybrid heterojunctions for photovoltaic applications

• Laurie Letertre,
• Roland Roche,
• Olivier Douhéret,
• Hailu G. Kassa,
• Denis Mariolle,
• Nicolas Chevalier,
• Łukasz Borowik,
• Philippe Dumas,
• Benjamin Grévin,
• Roberto Lazzaroni and
• Philippe Leclère

Beilstein J. Nanotechnol. 2018, 9, 2087–2096, doi:10.3762/bjnano.9.197

• can easily form nanostructures, such as nanoporous layers, nanowires or nanocolumns [5][11][12]. Because of its large band gap (3.2 eV [13]), light absorption is carried out by an organic or inorganic dye. The nanostructuration of the acceptor material is crucial for the cell performance [11], as it

High-throughput synthesis of modified Fresnel zone plate arrays via ion beam lithography

• Kahraman Keskinbora,
• Umut Tunca Sanli,
• Margarita Baluktsian,
• Corinne Grévent,
• Markus Weigand and
• Gisela Schütz

Beilstein J. Nanotechnol. 2018, 9, 2049–2056, doi:10.3762/bjnano.9.194

• . This can be attributed to the shifting plasmon resonances of the gold nanowires that make up the zones of the FZPs. A scanning transmission electron microscope (STEM) dark-field overview image of the completed array is shown in Figure 4b. The FZPs mostly exhibited high quality with zones free from

Recent highlights in nanoscale and mesoscale friction

• Andrea Vanossi,
• Dirk Dietzel,
• Andre Schirmeisen,
• Ernst Meyer,
• Rémy Pawlak,
• Thilo Glatzel,
• Marcin Kisiel,
• Shigeki Kawai and
• Nicola Manini

Beilstein J. Nanotechnol. 2018, 9, 1995–2014, doi:10.3762/bjnano.9.190

A differential Hall effect measurement method with sub-nanometre resolution for active dopant concentration profiling in ultrathin doped Si_1−xGe_x and Si layers

• Richard Daubriac,
• Emmanuel Scheid,
• Hiba Rizk,
• Richard Monflier,
• Sylvain Joblot,
• Rémi Beneyton,
• Pablo Acosta Alba,
• Sébastien Kerdilès and
• Filadelfo Cristiano

Beilstein J. Nanotechnol. 2018, 9, 1926–1939, doi:10.3762/bjnano.9.184

• this work will have a minimum thickness of about 6 nm, so that the quantum-confinement effect can be neglected. An additional low-dimension effect is the dielectric confinement, which has been investigated in silicon nanowires surrounded by a dielectric material (such as its native oxide) [37][38]. For

Nonlinear effect of carrier drift on the performance of an n-type ZnO nanowire nanogenerator by coupling piezoelectric effect and semiconduction

• Yuxing Liang,
• Shuaiqi Fan,
• Xuedong Chen and
• Yuantai Hu

Beilstein J. Nanotechnol. 2018, 9, 1917–1925, doi:10.3762/bjnano.9.183

• vertically aligned ZnO nanowires [18][19][20][21][22][23][24][25][26][27]. The principle of nanogenerators is that the piezoelectric potential produced by the piezoelectric effect can produce a current in an external circuit when the ZNW is deformed. Specifically, a transversely applied force makes the

• -workers [35]. In particular, Henneghien et al. have pointed out that circular and hexagonal nanowires exhibit the same behavior if the ZnO nanowire sections of each structure have the same area. Linear solutions were obtained for small fluctuations of carrier concentration in a bent n-type ZnO nanowire

Toward the use of CVD-grown MoS₂ nanosheets as field-emission source

• Geetanjali Deokar,
• Nitul S. Rajput,
• Junjie Li,
• Francis Leonard Deepak,
• Wei Ou-Yang,
• Nicolas Reckinger,
• Carla Bittencourt,
• Jean-Francois Colomer and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2018, 9, 1686–1694, doi:10.3762/bjnano.9.160

• displays, X-ray sources and cold-cathode electron sources [2]. 1D and 2D materials such as carbon nanotubes [3], ZnO nanorods [1], LaB6 nanowires [2], SnS2 nanosheets (NSs) [4], vertically aligned graphene [5], WS2 nanotubes [6], MoSe2 nanosheets [7], and MoS2 NSs [8][9][10] are potential field-emitter

• ][12], and comparable with the vertically aligned MoS2 NSs with ultrathin edges in [9] (Table 1). It has been shown previously that vertically grown 1D nanowires/nanotubes and 2D NSs with atomically thin edges may considerably improve the FE properties, so that vertically standing materials are

Josephson effect in junctions of conventional and topological superconductors

• Alex Zazunov,
• Albert Iks,
• Miguel Alvarado,
• Alfredo Levy Yeyati and
• Reinhold Egger

Beilstein J. Nanotechnol. 2018, 9, 1659–1676, doi:10.3762/bjnano.9.158

• ] have pointed out that the physics of the Kitaev chain could be realized in spin–orbit coupled nanowires with a magnetic Zeeman field and in the proximity to a nearby s-wave superconductor. The spinful nanowire model of references [2][3] indeed features p-wave pairing correlations for appropriately

• matrices σx,y,z and σ0 refer to spin. In the figures shown below, we choose the model parameters in Equation 34 as discussed in [43]. The lattice spacing is set to a = 10 nm, which results in a nearest-neighbor hopping t = 2/(2m*a2) = 20 meV and the spin–orbit coupling strength α = 4 meV for InAs nanowires

Sheet-on-belt branched TiO₂(B)/rGO powders with enhanced photocatalytic activity

• Huan Xing,
• Wei Wen and
• Jin-Ming Wu

Beilstein J. Nanotechnol. 2018, 9, 1550–1557, doi:10.3762/bjnano.9.146

• common but still draws much attention. Many types of TiO2(B) nanostructures have been synthesized, such as nanowires [9][10], nanotubes [11], nanobelts [12][13][14], nanofibers [15] and nanosheets [16]. TiO2(B) is mostly used in lithium-ion batteries due to its relatively open crystal structure, superior

Robust topological phase in proximitized core–shell nanowires coupled to multiple superconductors

• Tudor D. Stanescu,
• Anna Sitek and
• Andrei Manolescu

Beilstein J. Nanotechnol. 2018, 9, 1512–1526, doi:10.3762/bjnano.9.142

• Science and Engineering, Reykjavik University, Menntavegur 1, IS-101 Reykjavik, Iceland 10.3762/bjnano.9.142 Abstract We consider core–shell nanowires with prismatic geometry contacted with two or more superconductors in the presence of a magnetic field applied parallel to the wire. In this geometry, the

• the value of the critical field associated with the topological quantum phase transition. Keywords: core–shell nanowires; Majorana states; multiple 1D chains; prismatic geometry; topological superconducting phase; Introduction The intense ongoing search for Majorana zero modes (MZMs) in solid states

• . However, the experimental realization and detection of these modes involve 3D nanowires [26]. The most common materials are InSb and InAs due to their large g-factor and strong SOC. The wires are grown by bottom-up methods and have usually a prismatic shape with a hexagonal cross section, as determined by

Cathodoluminescence as a probe of the optical properties of resonant apertures in a metallic film

• Kalpana Singh,
• Evgeniy Panchenko,
• Babak Nasr,
• Amelia Liu,
• Lukas Wesemann,
• Timothy J. Davis and
• Ann Roberts

Beilstein J. Nanotechnol. 2018, 9, 1491–1500, doi:10.3762/bjnano.9.140

• GaAs nanowires [46], modes of single and pairs of AlGaAs disks [47], the optical properties of quantum discs of GaN/AlN in GaN nanowires [48] and various modes of gold nanodecahedra [49]. The potential of CL used in transmission to observe various colour centres in nanodiamonds has also been