Organic free radical chemistry

  1. editorImage
  1. Editor: Corey R. J. Stephenson
    University of Michigan

Free radicals are highly reactive towards other substances and play an important role in many chemical or biological processes. This Thematic Series presents a broad spectrum of articles extending the current knowledge in the field of organic free radicals. The range of synthetic reactions includes aerobic radical multifunctionalization of alkenes, metal-free aerobic oxidations and metal-catalyzed oxygenations, cascade radical reactions, photoinduced polymerizations and brominations. The series also includes computational studies on intermolecular reactions.

The renaissance of organic radical chemistry – deja vu all over again

  1. Corey R. J. Stephenson,
  2. Armido Studer and
  3. Dennis P. Curran
  • Editorial
  • Published 04 Dec 2013
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Beilstein J. Org. Chem. 2013, 9, 2778–2780, doi:10.3762/bjoc.9.312

Formal synthesis of (−)-agelastatin A: an iron(II)-mediated cyclization strategy

  1. Daisuke Shigeoka,
  2. Takuma Kamon and
  3. Takehiko Yoshimitsu
  • Full Research Paper
  • Published 03 May 2013

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Beilstein J. Org. Chem. 2013, 9, 860–865, doi:10.3762/bjoc.9.99

New core-pyrene π structure organophotocatalysts usable as highly efficient photoinitiators

  1. Sofia Telitel,
  2. Frédéric Dumur,
  3. Thomas Faury,
  4. Bernadette Graff,
  5. Mohamad-Ali Tehfe,
  6. Didier Gigmes,
  7. Jean-Pierre Fouassier and
  8. Jacques Lalevée
  • Full Research Paper
  • Published 07 May 2013

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Beilstein J. Org. Chem. 2013, 9, 877–890, doi:10.3762/bjoc.9.101

  • Full Research Paper
  • Published 04 Jun 2013

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Beilstein J. Org. Chem. 2013, 9, 1083–1092, doi:10.3762/bjoc.9.120

  • Letter
  • Published 13 Jun 2013

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Beilstein J. Org. Chem. 2013, 9, 1141–1147, doi:10.3762/bjoc.9.127

  • Full Research Paper
  • Published 13 Jun 2013
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Beilstein J. Org. Chem. 2013, 9, 1148–1155, doi:10.3762/bjoc.9.128

  • Letter
  • Published 25 Jun 2013
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Beilstein J. Org. Chem. 2013, 9, 1217–1225, doi:10.3762/bjoc.9.138

The synthesis of well-defined poly(vinylbenzyl chloride)-grafted nanoparticles via RAFT polymerization

  1. John Moraes,
  2. Kohji Ohno,
  3. Guillaume Gody,
  4. Thomas Maschmeyer and
  5. Sébastien Perrier
  • Full Research Paper
  • Published 25 Jun 2013

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Beilstein J. Org. Chem. 2013, 9, 1226–1234, doi:10.3762/bjoc.9.139

  • Review
  • Published 28 Jun 2013

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Beilstein J. Org. Chem. 2013, 9, 1269–1277, doi:10.3762/bjoc.9.143

  • Review
  • Published 02 Jul 2013
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Beilstein J. Org. Chem. 2013, 9, 1296–1310, doi:10.3762/bjoc.9.146

Preparation of optically active bicyclodihydrosiloles by a radical cascade reaction

  1. Koichiro Miyazaki,
  2. Yu Yamane,
  3. Ryuichiro Yo,
  4. Hidemitsu Uno and
  5. Akio Kamimura
  • Full Research Paper
  • Published 04 Jul 2013
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Beilstein J. Org. Chem. 2013, 9, 1326–1332, doi:10.3762/bjoc.9.149

A construction of 4,4-spirocyclic γ-lactams by tandem radical cyclization with carbon monoxide

  1. Mitsuhiro Ueda,
  2. Yoshitaka Uenoyama,
  3. Nozomi Terasoma,
  4. Shoko Doi,
  5. Shoji Kobayashi,
  6. Ilhyong Ryu and
  7. John A. Murphy
  • Letter
  • Published 05 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1340–1345, doi:10.3762/bjoc.9.151

Copper(II)-salt-promoted oxidative ring-opening reactions of bicyclic cyclopropanol derivatives via radical pathways

  1. Eietsu Hasegawa,
  2. Minami Tateyama,
  3. Ryosuke Nagumo,
  4. Eiji Tayama and
  5. Hajime Iwamoto
  • Full Research Paper
  • Published 11 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1397–1406, doi:10.3762/bjoc.9.156

  • Full Research Paper
  • Published 17 Jul 2013
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Beilstein J. Org. Chem. 2013, 9, 1432–1436, doi:10.3762/bjoc.9.161

  • Full Research Paper
  • Published 18 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1443–1447, doi:10.3762/bjoc.9.163

  • Full Research Paper
  • Published 23 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1472–1479, doi:10.3762/bjoc.9.167

Stability of SG1 nitroxide towards unprotected sugar and lithium salts: a preamble to cellulose modification by nitroxide-mediated graft polymerization

  1. Guillaume Moreira,
  2. Laurence Charles,
  3. Mohamed Major,
  4. Florence Vacandio,
  5. Yohann Guillaneuf,
  6. Catherine Lefay and
  7. Didier Gigmes
  • Full Research Paper
  • Published 06 Aug 2013

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Beilstein J. Org. Chem. 2013, 9, 1589–1600, doi:10.3762/bjoc.9.181

  • Full Research Paper
  • Published 07 Aug 2013

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Beilstein J. Org. Chem. 2013, 9, 1607–1612, doi:10.3762/bjoc.9.183

Computational study of the rate constants and free energies of intramolecular radical addition to substituted anilines

  1. Andreas Gansäuer,
  2. Meriam Seddiqzai,
  3. Tobias Dahmen,
  4. Rebecca Sure and
  5. Stefan Grimme
  • Full Research Paper
  • Published 08 Aug 2013

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Beilstein J. Org. Chem. 2013, 9, 1620–1629, doi:10.3762/bjoc.9.185

  • Full Research Paper
  • Published 09 Aug 2013
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Beilstein J. Org. Chem. 2013, 9, 1630–1636, doi:10.3762/bjoc.9.186

  • Letter
  • Published 14 Aug 2013

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Beilstein J. Org. Chem. 2013, 9, 1663–1667, doi:10.3762/bjoc.9.190

  • Letter
  • Published 20 Aug 2013
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Beilstein J. Org. Chem. 2013, 9, 1713–1717, doi:10.3762/bjoc.9.196

  • Full Research Paper
  • Published 21 Aug 2013

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Beilstein J. Org. Chem. 2013, 9, 1718–1723, doi:10.3762/bjoc.9.197

  • Full Research Paper
  • Published 20 Sep 2013

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Beilstein J. Org. Chem. 2013, 9, 1907–1916, doi:10.3762/bjoc.9.225

  • Review
  • Published 01 Oct 2013

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Beilstein J. Org. Chem. 2013, 9, 1977–2001, doi:10.3762/bjoc.9.234

3-Pyridinols and 5-pyrimidinols: Tailor-made for use in synergistic radical-trapping co-antioxidant systems

  1. Luca Valgimigli,
  2. Daniele Bartolomei,
  3. Riccardo Amorati,
  4. Evan Haidasz,
  5. Jason J. Hanthorn,
  6. Susheel J. Nara,
  7. Johan Brinkhorst and
  8. Derek A. Pratt
  • Full Research Paper
  • Published 04 Dec 2013

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Graphical Abstract

Beilstein J. Org. Chem. 2013, 9, 2781–2792, doi:10.3762/bjoc.9.313

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